CHEMICAL EQUILIBRIUM

1. Chemical reactions which proceed in both forward and the backward directions
under the given conditions are called:
A. Reversible reaction B. Irreversible reaction
C. Substitution reaction D. Double decomposition reaction
2. A chemical reaction, equilibrium is said to have been established when the:
A. Decomposition B. Addition Reaction
C. Irreversible reaction D. Reversible reaction
3. In a chemical reaction, equilibrium is said to have been established when the:
A. Temperature of the opposing reactions are equal
B. Velocities of opposing reaction become equal
C. Operating reactions cease
D. Concentration of reactants and products are equal
4. At equilibrium stage of chemical reaction:
A. The concentration of reactants is equal to the concentration of products.
B. The rate constant of the forward reaction is equal to the rate constant of back ward reaction.
C. The rate of forward reaction is equal rate of backward reaction.
D. The energy of activation of forward step is equal to energy of activation of back ward step.
5. The rate of forward step in a reversible reaction:
A. Increase or decrease during the reaction
B. Decrease as the reaction proceeds
C. Increase as the reaction proceeds
D. becomes constant just after the start of reaction.
6. Which of the following factors will disfavors the reverse reaction in a chemical equilibrium :
A. Increase in concentration of one of the reactants.
B. Increase in concentration of one of the product.
C. Addition of one of the products from outside at equilibrium stage.
D. None.
7. The unit of equilibrium constant Kc for the reaction:
H2+ I2 2HI is
-1 3
A. Mole dm B. Mole-1dm3
-1
C. Mole dm D. None
8. Increase of temperature increase the rate of reactions due to:
A. Shortening of the mean free path.
B. Increase in number of collisions of the molecules.
C. Decrease in number of activated molecules.
D. Lowering of activation energy.
9. The law of mass action is given by:
A. Vant Hoff B. Bode stein
C. Goldberg and wage D. Berthelot
10. If the volumes of reactants and products are same in a gaseous phase reaction, then the
equilibrium state is nor affected by:
A. Change of temperature B. Change of pressure
C. Change of concentration D. Catalyst
11. Kp and Kc of the chemical reaction are related with each other as:
Kp = Kc (RT)-2
A. ∆n is the number of moles of reactants.
B. ∆n is the number of moles of products.
C. ∆n is the total number of mole of reactants and products.
D. ∆n is the difference of number of moles of reactants and products.
12. Kp and Kn of the gaseous chemical reaction are related as:
Kp=Kc (P) ∆n
A. Kp is always greater than Kn B. Kn is always greater than Kp
Prepared by: SIR SARWAR AZIZ
 C. It depends upon the nature of reaction
D. It depends upon the nature of reaction, pressure and the system at equilibrium stage
13. Le Chatelier’s braun principle is sometimes known as:
A. Law of mass action B. Law of mobile equilibrium
C. Law of active mass D. All of these above
14. Which of the following factors influences a chemical system in according to Le-Chatelier principle?
A. Temperature B. Concentration
C. Pressure D. Conc. Temperature and pressure
15. When heat is added to a sold, liquid and equilibrium system, then according to
Le-Chatelier’s principle:
A. Amount of solid substance B. Amount of liquid increase
C. Temperature rises D. Temperature falls
16. A salt dissolved in H2O and the heat of solution is negative. What would happen to the
dissolution by increasing temperature?
A. Dissolution increases B. Dissolution decreases
C. No effect on dissolution D. depends upon the structure of compound
17. When the concentration of one of the products at equilibrium stage of a reaction is removed
from vessel, then it:
A. Shifts to the forward direction B. Shifts in backward direction
C. Move in both directions D. In not affected
18. The effect of temperature on equilibrium was studied by:
A. Lewis B. Van der Waal
C. Arrhenius D. Van Hoff
19. For a reversible reaction if the concentrations of the reactants are doubled, then equilibrium
constant is:
A. Halved B. Also the doubled
C. 1/4th of the original value D. Not changed
20. When a catalyst is added to a system at equilibrium:
A. The value of the equilibrium constant changes
B. The equilibrium concentrations change
C. A new lower energy pathway is established
D. The rates of the forward and reverse reaction are no longer equal
21. Water and ice are in equilibrium at O0C and pressure is applied at this stage, that:
A. Equilibrium is not distributed B. Water evaporates
C. More water is formed D. More ice is formed
22. The degree of ionization of an electrolyte in water increase:
A. With the increase of an concentration of the electrolyte.
B. By increasing the dilution
C. On decreasing the temperature of the solution.
23. The extent of ionization of an electrolyte does not depend on:
A. Concentration of solution B. The nature of solute and solvent
C. Size of solvent molecules D. The temperature
24. An acid HA is a weak acid; It is dissociated only 2% it means that out of 1000 molecules of acid,
only:
A. 10 are dissociated B. 20 are dissociated
C. 990 remain undissociated D. 900 remain undissociated
25. In a solution of weak electrolyte at infinite dilution, these are:
A. Only cations in solution B. Only anions in solution
C. Both cations and anions in solution
D. Cations, anions and unionized electrolyte in the solution

Prepared by: SIR SARWAR AZIZ

Prepared by: SIR SARWAR AZIZ