Q1

T T P Liquid Vapor Zliq Zvap fL fV

0.000 460.00 10.000 2.189 486.976 0.004 0.987 75.724 9.868
0
0.000 460.00 50.000 2.183 91.739 0.022 0.929 77.074 46.698
0
0.000 460.00 70.000 2.180 63.296 0.031 0.898 77.758 63.522
0
0.000 460.00 90.000 2.178 47.357 0.040 0.863 78.448 79.274
0
0.000 460.00 89.000 2.178 47.990 0.039 0.865 78.418 78.513
0

10.000 470.00 89.000 2.205 49.453 0.039 0.873 86.621 79.014

0
10.000 470.00 97.000 2.204 44.683 0.042 0.859 86.935 85.131
0
10.000 470.00 100.00 2.203 43.072 0.044 0.854 87.043 87.379
0 0
10.000 470.00 99.700 2.203 43.228 0.044 0.855 87.027 87.155
0

20.000 480.00 99.700 2.232 44.566 0.043 0.863 95.695 87.747

0
20.000 480.00 105.00 2.231 41.887 0.045 0.854 95.904 91.734
0 0
20.000 480.00 112.00 2.230 38.720 0.048 0.842 96.207 96.893
0 0
20.000 480.00 111.00 2.230 39.156 0.048 0.844 96.158 96.166
0 0

30.000 490.00 111.00 2.261 40.380 0.048 0.852 105.25 96.853

0 0 0
30.000 490.00 120.00 2.259 36.771 0.052 0.838 105.62 103.47
0 0 1 2
30.000 490.00 130.00 2.257 33.204 0.056 0.821 106.11 110.55
0 0 3 2
30.000 490.00 122.00 2.259 35.968 0.052 0.835 105.74 104.89
0 0 9 0
30.000 490.00 123.00 2.259 35.605 0.053 0.833 105.79 105.60
0 0 9 7

40.000 500.00 137.00 2.288 32.106 0.058 0.820 116.01 116.37

0 0 8 8
 50.000 510.00 137.00 2.323 33.143 0.058 0.830 125.94 117.30
0 0 9 6
50.000 510.00 150.00 2.320 29.525 0.064 0.809 126.65 126.35
0 0 4 6

Excel Sheet attached for calculations steps

Q2 part C ideal solution

P1 sat =134.95 mmHg

P2 sat=182.79 mmHg given in video lecture and can be calculated at T = 313 K from Antoine
equation.

P = x1*P1sat+x2*P2sat
= 0.49*134.95+0.51*182.79
= 159.35 mmHg

From Roults law

Y1 = x1*Psat/P
Y1 = 0.49*134.95/159.35 =0.415

@ T = 313 K, P = 159.4 mmHg, x1 = 0.49 and y1 = 0.415 mole fraction

Q3
 Phase diagram
80

78

76

74

72

70

68

66

64
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1

Tdew Tbub
s

1 kmole mixture liquid with composition

0.7 is MeOH
Half of the component is vapor then we have temperature of 69 C and liquid composition is 0.6.
Again heating from 0.6
 Phase diagram
80

78

76

74

72

70

68

66

64
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1

Tdew Tbub

Now liquid compositon is 0.5 and vapor composition is 0.67 Temperature is 70 C

Phase diagram
80

78

76

74

72

70

68

66

64
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1

Tdew Tbub

Now liquid composition is 0.39 MeOH in liquid temperature is 71 degC

Q4
At 25 C and 100000 Pa, the following difference has been recorded: G diamond (298K, 105 Pa )
- Ggraphite (298K, 105 Pa) = 2790 J/mol. What pressure do you need to apply to the graphite to
transform it into diamond?

As we have constant temperature 25 oC so

∂∆G/∂P = ∆V
So
d∆G = ∆VdP at constant temperature
applying integration
∫d∆G = ∫ ∆VdP = ∆G2 – ∆G1 = ∆V(P2 – P1)
We got
P2 = (∆G2 – ∆G1)/∆V + P1
Our job is to find the pressure at which the free energy change for this conversion becomes
0, so that diamond and graphite will be in equilibrium and the conversion can take place.
Therefore, our initial state corresponds to ∆G1 = +2790 J mol while the final state corresponds
to ∆G2 = 0
∆G = ∆fGdiamond – ∆fGgraphite = 2790 – 0 = 2790 J/mol
We know carbon molecular weight and densities of graphite and diamond so change in volume
is calculated
∆V = 12.011 g/mol ⨯ (1/3.51 – 1/2.25 ) cm3/g ⨯ 10-6 m3/cm3

∆V= –1.915 × 10–6 m3 mol–1

P2 =( 0 – 2790 J mol) /(–1.92 × 10–6 m3 mol–1 ) + 105 Pa
Answer
P2 = 1.453 × 109 Pa
That would be our required pressure