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Construction and Building Materials 15 Ž2001.

361᎐368

Effect of degree of corrosion on the properties of reinforcing


steel bars

Abdullah A. AlmusallamU
Department of Ci¨ il Engineering, King Fahd Uni¨ ersity of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Received 15 February 2000; received in revised form 10 November 2000; accepted 5 January 2001

Abstract

This paper reports results of a study conducted to assess the effect of degree of corrosion of reinforcing steel bars on their
mechanical properties. Reinforcing steel bars, 6 and 12 mm in diameter, that were corroded in reinforced concrete specimens
were removed and tested in tension. Results indicated that the level of reinforcement corrosion does not influence the tensile
strength of steel bars, calculated on the actual area of cross-section. However, when the nominal diameter is utilized in the
calculation, the tensile strength is less than the ASTM A 615 requirement of 600 MPa when the degree of corrosion was 11 and
24% for 6- and 12-mm diameter steel bars, respectively. Furthermore, reinforcing steel bars with more than 12% corrosion
indicates a brittle failure. 䊚 2001 Published by Elsevier Science Ltd.

Keywords: Concrete; Reinforced bars; Corrosion; Failure

1. Introduction the reinforcing steel. The dense and relatively im-


permeable structure of concrete provides the physical
The reduction in the useful service-life of reinforced protection, while the high alkalinity of the pore solu-
concrete structures, mainly due to reinforcement corro- tion provides the chemical protection. The alkaline
sion, is a cause of concern to the construction industry compounds, mainly calcium and to a certain extent
world wide. Considerable resources are expended to pottasium and sodium, in the cement contribute to the
repair and rehabilitate deteriorating concrete struc- high alkalinity ŽpH) 13.5. of the pore solution. At this
tures. It is estimated that more than $20 billion are high pH, steel is passivated in the presence of oxygen
required for the repair and rehabilitation of highway presumably due to the formation of a sub-microscopi-
structures in the US w1x and more than £600 million for cally thin ␥-Fe 2 O 3 film w3,4x. Hime and Erlin w5x sug-
repairing road bridges in the UK w2x. The cost of repair gested that the passivating layers on the steel surface
and rehabilitation of reinforced concrete structures in could have a composition other than that of ␥-Fe 2 O 3 .
the other parts of the world is not very well docu- According to Page w6x, the lime-rich layer at the steel-
mented, but undoubtedly, considerable resources have concrete interface, provides further protection to the
to be allocated towards restoring the useful service-life steel. This was confirmed by Leek and Poole w7x who
of deteriorating concrete structures. reported that the interfacial layer consists of an aggre-
In normal situations, concrete provides protection to gates-free zone of portlandite wCaŽOH. 2 x of variable
thickness Ž5᎐15 ␮ m. disrupted by inclusions of calcium
silicate hydrate ŽC᎐S᎐H. gel. This layer is thought to
U protect the surface of the steel from direct access of
Tel.: q966-3-860-2900; fax: q966-3-860-2911.
E-mail address: musallam@ksu.edu.sa ŽA.A. Almusallam.. aggressive ions and to act as an alkaline buffer to pH

0950-0618r01r$ - see front matter 䊚 2001 Published by Elsevier Science Ltd.


PII: S 0 9 5 0 - 0 6 1 8 Ž 0 1 . 0 0 0 0 9 - 5
362 A.A. Almusallam r Construction and Building Materials 15 (2001) 361᎐368

reductions resulting from the hydrolysis of corrosion mm, specific gravity of 2.64 and water absorption of
products w8x. According to Sagoe-Crentsil and Glasser 2.3% was used as coarse aggregate, while beach sand
w9x, both CaŽOH. 2 and C᎐S᎐H gel form a buffering with a specific gravity of 2.64 and water absorption of
pair and a high pH is as readily maintained by C᎐S᎐H 0.56% was used as fine aggregate. A coarse to fine
as by CaŽOH. 2 . aggregate ratio of 1.68 and a waterrcement ratio of
Corrosion of the reinforcing steel bars is caused 0.45 were kept invariant in all the concrete mixtures.
either due to diffusion of the chloride ions to the steel Two groups of concrete specimens were prepared. The
surface or due to carbonation of concrete. Corrosion of first group of specimens was prepared with 6-mm di-
reinforcing steel and the subsequent cracking of con- ameter steel bars while the other group was prepared
crete due to the ingress of chloride ions to the steel with 12-mm diameter steel bars. Deformed reinforcing
surface is more predominant than that due to carbona- steel bars meeting the requirements of Grade 60 of
tion of concrete. A number of mechanisms by which ASTM A 615 were utilized in the concrete specimens.
chlorides break down the passive layer have been pro- After casting, the concrete specimens were cured for
posed, e.g. the chemical dissolution of the film w10x, the 28 days. The corrosion of reinforcing steel was acceler-
build up of the metal holes at the filmrsubstrate inter- ated by impressing an anodic current of 2 mArcm2 .
face w11x and also, the high chloride concentrations at This was done through an integrated system incor-
the iron oxiderpore solution interface which leads to porating a DC rectifier with a built-in ammeter to
local acidification and pitting w12x. Leek and Poole w7x, monitor the current and a potentiometer to control the
based on SEMrEDS studies of the passive film break- current intensity. The concrete specimens were par-
down on steel in mortar prisms, have shown that chlo- tially immersed in 5% sodium chloride solution in a
ride ions initiate corrosion by breaking the bond fiberglass tank so that the reinforcing steel bars were
between the film and the metal. Whatever the cause, above the solution. This type of arrangement was se-
corrosion of reinforcing steel leads to cracking of con- lected to assure that the corrosion product formed is
crete and subsequent loss in the load-carrying capacity not washed away and cracks are formed in the concrete
of a reinforced concrete member. specimens. The direction of the current was adjusted so
The reduction in the load-carrying capacity of a that the reinforcing steel became an anode and a
reinforced concrete member due to reinforcement cor- stainless steel plate placed on top of the concrete
rosion is attributed to the combined effect of a de- specimen served as a cathode. A schematic representa-
crease in the bond between concrete andror reduction tion of the test set-up is shown in Fig. 1. In order to
in the tensile strength of the bars. While some data are induce different levels of reinforcement corrosion, a
available on the effect of reinforcement corrosion on calibration curve establishing the relationship between
the bond strength of concrete w13,14x, its influence on the duration of the impressed current and the corre-
the mechanical properties of reinforcing steel is scantly sponding degree of reinforcement corrosion was pre-
investigated. Maslehuddin et al. w13x evaluated the ef- pared prior to conducting the actual experiments. The
fect of atmospheric corrosion on the mechanical current supplied to each concrete specimen was
properties of steel bars. However, it should be noted checked on a regular basis and a drift was corrected by
that atmospheric corrosion does not affect the mechan- adjusting the potentiometer. The desired degree of
ical properties of reinforcing steel as much as its corro- reinforcement corrosion was obtained by applying the
sion in concrete. Also, corrosion of reinforcing steel anodic current for the time period assessed from the
induces cracks in concrete, thereby affecting the in- calibration curve.
tegrity of a structural component. The degree of rein- After the desired level of reinforcement, corrosion
forcement corrosion and the resulting decrease in the was obtained, the concrete specimens were split along
load-carrying capacity of both steel bars and the struc-
tural component needs to be evaluated to assess the
residual strength of concrete and formulate repair
strategies.
This study was conducted to evaluate the relation-
ship between the degree of corrosion of the steel bars
in concrete on their mechanical properties.

2. Experimental program

Reinforcing steel bars were embedded in the con-


crete specimens prepared with ASTM C 150 Type V Fig. 1. Schematic representation of the accelerated corrosion test
cement. Crushed limestone with a maximum size of 19 setup.
A.A. Almusallam r Construction and Building Materials 15 (2001) 361᎐368 363

the line of the steel bars. The degree of reinforcement


corrosion was measured as gravimetric loss in weight of
the reinforcing steel bars after cleaning them with
Clark’s solution according to ASTM G1. After assess-
ing the weight loss, the steel bars were tested in tension
to evaluate their mechanical properties. The mechani-
cal properties of the steel bars were evaluated using an
Instron Universal Testing machine of 250 kN capacity.
A purpose-built extensometer was utilized to measure
the elongation in the bar. The load and elongation data
were recorded using a computerized data acquisition
system at pre-determined load intervals till failure of
the specimen occurred. The data so generated were
utilized to plot stress᎐strain diagrams for each of the
tested specimens. The stress᎐strain diagrams were uti-
lized to determine the yield and tensile strength of the
steel bars. The elongation, due to the applied load, was Fig. 2. Stress᎐strain curve for 6-mm diameter steel bar with 0.88%
measured after the completion of the tensile test and it corrosion.
was expressed as a percentage of the original gauge
length. The tensile tests were conducted on both clean
and corroded reinforcing steel bars so that the influ- 12-mm diameter steel bars, with 11.7 and 32.70% cor-
ence of degree of reinforcement corrosion on the ten- rosion, respectively. In this group of specimens also,
sile properties of reinforcing steel bars could be as- the degree of reinforcement corrosion did not affect
sessed. the ultimate tensile stress. The variation of the tensile
strength of 12-mm diameter steel bars, with the degree
of reinforcement corrosion, is plotted in Fig. 7. These
3. Results and discussion data indicate that the variation in the tensile strength
with degree of corrosion is very insignificant. For exam-
3.1. Effect of corrosion on the tensile properties of steel ple, the actual tensile stress is 760 MPa for the clean
bars bars and 844 MPa for the steel bars with 80% corro-
sion. The data on tensile strength calculated using the
Figs. 2 and 3 are typical stress᎐strain curves for actual and nominal diameter of 12-mm diameter are
6-mm diameter steel bars with varying degrees of cor- summarized in Table 2. The tensile strength calculated
rosion. The tensile strength of both the groups of these using actual area of cross-section is more than 600
steel bars is almost similar. However, the total elonga- MPa specified by ASTM A 615. However, the tensile
tion of the bars with 0.88% corrosion is more than that strength calculated on the nominal area based on a
of bars with 13.9%. Table 1 summarizes the tensile
strength data for 6-mm diameter bars with varying
degree of reinforcement corrosion. These data indicate
that the actual load carried by the bars decreased with
increasing level of reinforcement corrosion. However,
due to a decrease in the cross-section of the bars net
tensile strength is marginally affected. Fig. 4 shows the
variation of the ultimate strength of 6-mm diameter
steel bars with the degree of corrosion. The ultimate
strength of the clean bars and those corroded to 75%
corrosion was 796 and 741 MPa, respectively. It should
also be noted that even after degradation of the bars
due to reinforcement corrosion their tensile strength is
more than 600 MPa specified by ASTM A 615. Table 1
also shows the tensile strength of bars calculated using
the nominal diameter, i.e. 6 mm. Using this criteria the
tensile strength of the steel bars falls below the ASTM
A 615 criteria of 600 MPa when the degree of rein-
forcement corrosion is 11.6% and above. Fig. 3. Stress᎐strain curve for 6-mm diameter steel bar with 13.9%
Figs. 5 and 6 are typical stress᎐strain curves for corrosion.
364 A.A. Almusallam r Construction and Building Materials 15 (2001) 361᎐368

Table 1
Tensile strength of 6-mm diameter steel bars

Specimen Corrosion Average Ultimate Actual tensile Nominal tensile


噛 Ž%. diameter Žmm. load ŽkN. stress ŽMPa. stress ŽMPa.

STI 0 5.9 21.76 796 769.0


ST2 0 5.9 21.76 796 769.0
ST3 0 5.9 21.76 796 769.0
2SAC2 0.88 5.85 21.01 781.7 742.8
2SCB2 1.10 5.80 20.49 775.9 724.8
1SAA1 1.22 5.85 20.86 776.1 737.5
2SAA1 1.45 5.81 20.53 774.5 725.8
2SAA2 1.45 5.89 21.09 774.03 745.6
1SCD1 1.63 5.85 20.762 772.45 734.0
1SCB2 11.64 5.25 16.521 763.2 584.0
2SCA2 12.364 5.10 16.75 819.95 592.2
1SAB2 13.13 4.8 14.62 808.07 517.0
2SAB2 13.89 4.95 14.13 734.00 499.4
1SAG1 17.83 4.95 13.05 678.20 461.4
2SAG2 19.40 4.95 15.03 780.80 531.2
1SAD1 24.95 4.30 10.79 743.00 381.5
2SCC1 27.27 4.15 9.043 668.56 319.7
1SCC1 28.32 4.00 9.281 738.90 328.1
2SAH2 32.02 3.90 9.266 776.00 327.6
1SCA2 40.70 4.10 10.156 769.00 359.0
1SAI2 48.25 4.10 10.134 767.60 358.3
2SAI2 75.00 3.00 4.877 740.80 172.2

diameter of 12 mm is less than the value specified by A huddin et al. w13x exposed reinforcing steel bars of six
615 for reinforcement corrosion of 24% and above. different sizes to the atmosphere for 16 months and
The above results indicate that even at high levels of concluded that the effect of rusting of reinforcement
corrosion, there is no significant change in the tensile due to atmospheric exposure for 16 months on the
strength of bars calculated using the actual cross-sec- yield and ultimate tensile strength of reinforcing steel
tion. However, when the nominal diameter of the bars is insignificant. Their test results indicated either a
is utilized to calculate the tensile strength, these values slight increase or no change in the strength of steel
fall below the ASTM A 615 specifications of 600 MPa with increasing period of exposure. However, in their
for reinforcement corrosion of 11.6% or more for 6-mm tests, nominal diameter of bars was utilized to calculate
diameter steel bars and 24% or more for 12-mm di- the yield and tensile strength. Aldridge et al. w14x
ameter steel bars. Also, the brittleness of steel bars is exposed steel bars of various sizes conforming to ASTM
affected by the degree of reinforcement corrosion as A 350-56T to three different corrosive environmental
will be discussed in the latter part of this paper. Masle-

Fig. 4. Variation of ultimate strength with the degree of corrosion in Fig. 5. Stress᎐strain curve for 12-mm diameter steel bar with 11.7%
6-mm diameter steel bars. corrosion.
A.A. Almusallam r Construction and Building Materials 15 (2001) 361᎐368 365

Fig. 7. Variation of ultimate strength with a degree of corrosion in


12-mm diameter steel bars.

Fig. 6. Stress᎐strain curve for 12-mm diameter steel bar with 32.7%
corrosion.
Uomoto et al. w15x evaluated the tensile strength of
conditions, namely, normal out-doors, moist room with steel bars obtained from structures affected by rein-
100% relative humidity and simulated sea-water spray forcement corrosion. Their study indicated that both
for an exposure time varying up to 12 months. Their the yield and ultimate strengths of corroded steel bars
study indicated that tensile strength of indoor and were within the range of 90᎐95% of the non-corroded
outdoor corroded bars was not affected by the degree bars. Also, Uomoto and Misra w16x conducted strength
of surface corrosion, while the ultimate tensile strength tests on the corroded bars from beams and columns
of the 3 months sea water rusted bars was reduced by exposed to marine environment for varying periods.
approximately 3.7% w14x. They reported that the reduction in both the yield

Table 2
Tensile strength of 12-mm diameter bars

Specimen Corrosion Average Ultimate load, Actual tensile Nominal stress


噛 Ž%. diameter Žmm. ŽkN. stress ŽMPa. ŽMPa.

1PCCT 0 11.75 82.38 759.72 728.1


2PCCT 0 11.75 82.25 758.5 727.0
3PCCT 0 11.70 81.58 758.8 721.0
1PCC 2.11 11.63 80.52 757.97 711.7
2PAG 2.69 11.75 82.12 757.3 725.8
2PCD 3.37 11.70 81.31 756.3 718.7
2PAH 3.93 11.71 81.37 757.5 719.2
1PAG 4.0 11.70 81.68 753.9 722.0
2PAE 4.78 11.71 81.11 753.3 716.9
1PAH 5.09 11.67 80.36 751.29 710.3
1PAE 5.68 11.70 80.96 753.0 715.6
2PFD 6.60 11.58 78.66 746.7 695.2
1PFE 7.80 11.44 76.61 745.32 677.1
1PCA 11.72 11.10 71.94 743.42 635.8
2PFF 12.29 11.00 74.32 782.00 656.9
2PCA 15.65 10.50 69.88 807.0 617.6
1PAC 20.55 10.50 69.45 802.0 613.8
1PAD 24.0 10.20 64.27 786.0 568.0
1PCB 24.0 10.05 59.33 748.0 524.4
2PAD 25.65 10.05 60.5 762.0 534.7
1PAJ 32.65 9.35 54.71 796.8 483.5
1PAB 39.50 8.60 47.34 815.0 418.4
1PAA 48.25 7.30 33.68 816.0 297.7
1PCD 51.00 7.90 40.00 816.0 353.5
1PAF 60.70 7.45 29.36 673.0 259.5
2PAA 80.00 4.50 13.43 844.0 118.7
366 A.A. Almusallam r Construction and Building Materials 15 (2001) 361᎐368

Fig. 8. Load-elongation curves for 6-mm diameter steel bars with Fig. 9. Effect of corrosion on the configuration of reinforcing steel
varying degree of corrosion. bars.

strength and the ultimate strength of steel bars ranged thinned section of the steel bars is stretched by a
from 5 to 10% of the original bars. tensile force, the strain would be concentrated at the
notch and the overall strain of the bar will be less at
3.2. Effect of corrosion on the mode of failure of the bars failure than in an uncorroded bar. Hence, as the notch
becomes deeper, the stress concentration progressively
increases at the locations of notch and the rebar behav-
Fig. 8 shows the load-elongation curves for 6-mm ior effectively becomes more brittle.
diameter steel bars, corroded to different levels. This
comparison indicates that as the degree of corrosion
increases, the corresponding elongation of the bar be-
fore failure decreases. There is a systematic pattern
wherein with increasing corrosion, the bars fail with
decreasing amount of yield strain compared to the
non-corroded bars, which show a large amount of yield-
ing before their ultimate failure. This indicates that
corrosion of reinforcing steel increases its brittleness.
Reinforcing steel bars with 12.6% or more reinforce-
ment corrosion indicate a brittle behavior. Also, the
elongation of bars with 12% or more corrosion is
generally less than that specified by ASTM A 615, i.e.
9%. Fig. 9 shows the effect of increasing corrosion on
the rebar configuration. It is seen that as corrosion
progresses beyond 40%, relatively small lengths of re-
bars show thinning, thereby demonstrating the ten-
dency for notch formation with increasing corrosion.
Figs. 10 and 11 show several severe notches for bars
corroded to 75 and 80%, respectively. This preferential
corrosion is characterized for high levels of chlorides or
for situations where concrete is cracked or honey-com-
bed at specific locations providing ingress to chloride
ions and oxygen to the steel surface at such locations.
Preferential corrosion resulting in the thinning of steel
bars over small lengths would have the effect of reduc-
ing considerably the cross-sectional area of the bars
locally and hence, reducing the load-carrying capacity
of the bars. Preferential corrosion and notch formation
also alters, as seen in Fig. 8, the load-deformation
characteristics of the rebars. When a notch or locally Fig. 10. Effect of 75% corrosion on rebar configuration.
A.A. Almusallam r Construction and Building Materials 15 (2001) 361᎐368 367

600 MPa when the level of corrosion was 12% or more


in 6-mm diameter steel bars and 24% or more in the
12-mm diameter steel bars.
The data on stress᎐strain characteristics of reinforc-
ing steel bars corroded to varying levels of corrosion
indicate a decrease in the ductility of bars with increas-
ing level of corrosion. Furthermore, with increasing
levels of corrosion bars failing at low level of yield
strain compared to uncorroded steel bars that demon-
strate large yielding before failure. Reinforcing steel
bars with 12.6% or more reinforcement corrosion indi-
cated a brittle behavior. Also, the elongation of bars
with more than 12% corrosion was less than 9% speci-
Fig. 11. Effect of 80% corrosion on rebar configuration. fied by ASTM A 615.
The results of this study indicated a close relation-
The above finding is supported by a study conducted ship between the failure characteristics of steel bars
by Almusallam et al. w17x. Their study indicated a and slabs with corroded reinforcement in that a sudden
decrease in the load-carrying capacity of concrete slabs failure of slabs in flexure was noted when the degree of
with corroded reinforcement due to a reduction in the reinforcement corrosion was more than 13%.
area of the cross-section of the bars at the points where
corrosion was concentrated, thereby reducing the
load-carrying capacity of the steel at these locations References
and the bars exhibited sudden failure without yielding.
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