Professional Documents
Culture Documents
ABC 4 (Theory Exercise)
ABC 4 (Theory Exercise)
HCOOH Formic acid Methanoic acid Ants, bees & other stinging insects.
COOH
Oxalic acid Ethanedioic acid Kidney stone [Ca(C2O4)], Cabbage
COOH
COOH
CH2 Malonic acid Propanedioic acid Plants (Leaves of lucerne)
COOH
CH2–COOH
Succinic acid Butanedioic acid Amber, Lignite and many plants
CH2–COOH
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 40
ABC-1, 2, 3 & 4
2 By Oxidation of primary alcohol &
R–CH2–OH R–COOH
(i) KMnO 4 , O H
aldehydes:
O O O
O H2O/H
H2O / H
R–C–Cl
(ii)CH3– CH–C–Cl
CH3– CH–C–OH + HCl
R–C–OH + HCl
CH3 CH3
Acid chloride reacts with water to form O O O
H2O/H
D. (i) CH3–C–O–C–CH3
carboxylic acid. 2CH3–C–OH
O O O O
D. Hydrolysis of acid anhydride: H2O/H
(ii) Ph–C–O–C–CH3
Ph–C–OH +CH3–C–OH
O O O
H O / H
R–C–O–C–R 2R–C–OH
2
E.
O
H O/H
E. Hydrolysis of nitriles: (i) CH3–CH2–CH–CN
2
CH3–CH2–CH–C–OH
R–CH2–CN
H2O / H
CH3 CH3
O O
H2O/H
(ii) Ph–CH2–CN
+
+ Ph–CH2–C–OH + NH4
R–CH2–C–OH + NH4
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 41
ABC-1, 2, 3 & 4
SOCl
R–C–OH
2
R–C–Cl + SO2 + HCl O SOCl O
(ii)
2
+SO2+ HCl
OH Cl
B.
B. Reaction with NH3
O O O
O O + –
–
(i)CH3–C–OH + NH3 CH3–C–ONH4 CH3–C–NH2
+
R–C–OH + NH3 R–C–ONH4
O (ii)
R–C–NH2 + H2O O O
– +
Carboxylic acid reacts with aqueous ammonia CH2–C–OH + NH3 CH2 C ONH4
C.
C. Reaction with RCOOH:
O O
O O O (i)CH3–C–OH + H–O–C–CH3
P2O5,
2R–C–OH R C O C R + H2O
O O
PO ,
P2O5 is a dehydrating agent (removal of H2O).
2 5
CH3 C O C CH3+ H2O
O
CH2–COOH C
CH2
(ii) O + H2O
CH2–COOH CH2 C
O
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 42
ABC-1, 2, 3 & 4
D. Reaction with R–OH D.
O O
O H+
R'OH, H+ (i) CH3–CH–CH2–C–OH + C2H5OH
R–C–OH R C–OR' + H2O
CH3
Carboxylic acid reacts with excess alcohol in
O
the presence of an acid catalyst produce CH3–CH–CH2–C–OC2H5 + H2O
ester. This reaction is called fisher CH3
esterification reaction. O O
H+
(ii) Ph–C–OH + CH3OH Ph–C–OCH3 + H2O
3 Hunsdiecker reaction: O
CH3–CH2–CH2–Br
(i) Ag2O
(i)CH3–CH2–CH2–C–OH
(i) A carboxylic acid can be decarboxylated if (ii) Br2 , + CO2 + AgBr
mercuric ion.
(i) Ag O
R-COOH
2
R-Br+CO2+AgBr(Precipitate)
(ii) Br2 ,
4 Sodalime decarboxylation: O
NaOH CaO
CH
(i) 3 –CH2 –C–OH CH3 – CH3 + CO2
O
NaOH CaO
R–C–OH R–H + CO2 COOH
NaOH CaO
(ii) + CO2
(i) Sodalime: NaOH + CaO
NaOH CaO
(ii) Decarboxylation simply means removal of (iii) Ph – CH2 –COOH Ph – CH3 + CO2
CO2.
Electrolysis
5 Kolbe's electrolysis: (i) 2CH3–COOK + 2H2O
Electrolysis CH3–CH3 + 2CO2 + H2 + 2KOH
2RCOOK + 2HOH
R–R + 2CO2 + H2 + 2KOH
CH2–COOK CH2
Electrolysis
(ii) +2H2O
+2CO2+H2+ 2KOH
CH2–COOK CH2
If n is the number of carbon atoms in the salt
Electrolysis
of carboxylic acid, the alkane formed has 2(n– (iii) 2CH3–CH2–COOK + 2H2O
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 43
ABC-1, 2, 3 & 4
H2O + CO2
Exception :
smelling liquids.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 44
ABC-1, 2, 3 & 4
R–CHO
H2 / Pd (BaSO4 )
Aldehyde
CH3–C–CH3 No reaction
PCC
OH
By Stephen's reduction of cyanide : CH3–CN CH3–CH=O + NH4Cl
(i) SnCl2 / HCl
3. (ii) H2O
Reagents : (i) SnCl2/dry HCl (ii) H2O Ethanenitrile Ethanal
General reactions
Ph–CN Ph–CH=O + NH4Cl
(i) SnCl2 / HCl
R–CN
(i) SnCl2 / dry HCl
(ii) H O
R–CH = O + NH4Cl (ii) H2O
2
Benzene carbonitrile Benzaldehyde
4. Dry distillation of calcium salt of fatty acids : (c) By dry distillation of calcium acetate formate:
O
(a) By dry distillation of calcium formate :
H–C–O
O Ca CH3–C–H
Dry distillation
CH3–C–O – CaCO3
H–C–O O
Ca
Dry distillation
H–C–H O
H–C–O – CaCO3
O (d) By dry distillation of calcium acetate and
O
calcium formate :
(b) By dry distillation of calcium acetate : O O
O
CH3–C–O O–C–H Dry distillation
CH3–C–O Ca + Ca
Ca
CH3–C–CH3
Dry distillation CH3–C–O O–C–H –CaCO3
CH3–C–O – CaCO3
O O O
O CH3–C–CH3 + H–C–H + CH3–C–H
O O O
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 45
ABC-1, 2, 3 & 4
Prediction of reactant
C=O + CH3–C–H
(i) dil.NaOH
C=CH–C–H
(ii)
O H O
O
H
3. Reaction with NH2OH CH3
CH3 OH
OH C=O + NH2–OH H
C=N
C=N H – H2O
C= O + H2 N–OH
– H2O
Aldehyde / Ketone Oxime
Aldehyde Aldoxime
Ketone Ketoxime
General Reactions
CH3
C=N–NH NO2
H
NO2
(yellow–orange precipitate of Hydrazone)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 46
ABC-1, 2, 3 & 4
CH3
C=O + H2N–NH NO2 C=O + H2N–NH NO2
CH3
NO2 NO2
2, 4-DNP 2, 4-DNP
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 47
ABC-1, 2, 3 & 4
K2Cr2O7/H+
4. Find product is –
COOH
COOH
(A) COOH (B) (C) (D)
COOH
OH
+
5. CrO3/H Product is –
CH3
OH
COOH
COOH
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 48
ABC-1, 2, 3 & 4
O
+
H2O/H
6. C2H5–C–OCH3 Product is -
(A) CH3COOH, C2H5OH (B) CH3COOH, C2H5–COOH
(C) C2H5–COOH, CH3OH (D) CH3OH, C2H5–OH
O
H2O/H+
7. CH3–C–NH–Ph A+B
A and B are -
O O
(A) Ph–NH–C–H + CH3 –COOH (B) CH3–C–NH2 + Ph–OH
O O
+
(C) CH3–C–NH2 + Ph–COOH (D) CH3–C–OH + Ph–NH3
O O
H2O/H+
8. C2H5–C–O–C–Ph A+B
Ratio of A and B is –
(A) 1 : 2 (B) 2 : 1 (C) 1 : 1 (D) 2 : 3
9. CN H2O/H Product is –
COOH
(A) (B)
COOH
COOH
Red P Br2
10. CH3CH2CH2COOH CH –CH –CH–COOH
3 2
Br
This reaction is called -
(A) cannizzaro reaction (B) Aldol reaction (C) HVZ reaction (D) Reimer Tiemann reaction
COOH SOCl2
11. Product is –
O
(A) (B) C
Cl
Cl
O
C
(C) (D) COOH
H
Cl
Cl
COOH
12. + NH3 Product is-
O O
(A) (B)
C–O–NH2 C–NH2
COOH
NH2
(C) (D)
COOH
NH2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 49
ABC-1, 2, 3 & 4
(i) Ag2O
13. Ph–CH–CH–COOH (ii) Br2,
Product is-
CH3 CH3
Br
(A) Ph–CH–CH–CH2–Br (B) Ph–CCH–CH3 (C) Ph–CH–CH–Br (D) Ph–CH–CH2
CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH2–Br
COOH
SO3Na
O
(A) CH3–CH2 –CH2–OH (B) CH3 –C H2–C–H
O
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 50
ABC-1, 2, 3 & 4
19. X Y
H2
Pd(BaSO4 )
X is :
(A) (B) (C) (D)
CH3–CH–CH2–OH X
PCC
20.
CH3
O
(A) CH3–CH–COOH (B) CH3–C (C) CH3–CH–CHO (D) CH3–C=O
CH3 CH2–CH3 CH3 CH3
21. Which of the following is product of given reaction
HO OH
PCC
(Pyridinium
Chlorochromate)
CH2OH
O O O O
(A) (B)
CHO COOH
O O
HO OH
(C) (D) None of these
COOH
22.
X is :
(A) (B)
(C) (D)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 51
ABC-1, 2, 3 & 4
Identify ‘X’ :
(A) CH3–CH=O (B) CH3–CH2–CH=O (C) CH3CH2OH (D) CH3CH(OH)CH3
O
C–H
24. R
(i) SnCl2 / HCl
(ii) H2O
Identify ‘R’ :
CN CH2–OH NH2 CH3
(A) (B) (C) (D)
O
Ph–C–O
Ca Product
Dry distillation
25.
Ph–C–O
O
O O O OH
(A) Ph–C–H (B) Ph–C–Ph (C) Ph–C–C–Ph (D) Ph–C–C–Ph
O O H
O
Ph–C–O
Ca Product
Dry distillation
26.
H–C–O
O
O O
(A) Ph–C–H (B) Ph–C–Ph (C) H–C–H (D) Ph–C–C–H
O O O
27. Ca-Salt of Carboxylic acid
X and Y
(A) (H–COO)2Ca + (CH3–COO)2 Ca (B) (HCOO)2Ca + (CH3–CH2–COO)2Ca
(C) (CH3COO)2Ca + (CH3CH2–COO)2Ca (D) None of these
28. Benzaldehyde, when heated with conc. KOH solution, gives
(A) C6H5CH2OH only
(B) C6H5COOH only
(C) C6H5COOK only
(D) a mixture of C6H5COOK and C6H5CH2OH
29. The Cannizzaro’s reaction is not given by :
(A) C6H5CHO (B) HCHO (C) CH3CHO (D) (CH3)3C–CHO
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 52
ABC-1, 2, 3 & 4
31. ( X)
SnCl2
HCl
C6H5COO C6H5CH2 – OH
HO
32. Which of the products is formed when acetone is reacted with dil. NaOH solution after heating?
O CH3 O
||
(A) CH3–C–CH=C–CH3 (B) CH3 – C – CH – CH – CH3
| |
CH3 OH
O OH OH
| |
(C) CH3–C–CH2–C=CH2 (D) CH3 – C — C – CH3
| |
CH3 CH3 CH3
33. Product is :
35.
36. The structure of the compound when acetaldehyde reacts with NH2–OH is
(A) CH3CH=NCONHNH2 (B) CH3CH=NNHCONH2
(C) CH3CH=NOH (D) CH3CH=NNH2
CH3 OH
37. (X) + (Y) H
C=N
– H2O
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 53
ABC-1, 2, 3 & 4
38. BaSO4
H2
Identify (X) and (Y).
(A) (B)
(C) (D)
42. Which of the following compound will not react with I2 /OH–.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 54
ABC-1, 2, 3 & 4
11. (B) 12. (B) 13. (C) 14. (C) 15. (B)
16. (B) 17. (B) 18. (B) 19. (C) 20. (C)
21. (A) 22. (C) 23. (A) 24. (A) 25. (B)
26. (A) 27. (A) 28. (D) 29. (C) 30. (A)
31. (D) 32. (A) 33. (B) 34. (D) 35. (B)
36. (C) 37. (C) 38. (A) 39. (C) 40. (B)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
ABC1TO4 - 55