HW - 7

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2105687 Advanced Chemical Kinetics and Catalysis

Homework 7

The surface area of a boron-doped carbon was determined by measuring N2


physisorption at 80 K. The equilibrium N2 uptakes versus the pressure are listed
in the table below. What is the The P0 value for N2 at the actual temperature
measured was P0 = 732 Torr (760 Torr = 1 atm). The cross-sectional area of N2
molecule is 0.162 nm2.

P (Torr) N2 uptake (µmole N2/g)


26.8 1166
86.2 1286
140.7 1395
190.0 1511
232.1 1636
278.0 1793

Determine the specific surface area of this boron-doped carbon using


a. Linearized model of Langmuir Isotherm
b. Linearized model of BET Isotherm

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