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EGB323 Week 3 Lecture ENG 2019
EGB323 Week 3 Lecture ENG 2019
Lecture 3
Today’s Lecture
Equation of state of a perfect gas
Energy
Specific heats of a gas
Statics of fluid systems
Pressure
Pascal’s law for pressure at a point
Variation of pressure vertically in a fluid under
gravity
Pressure and head
Manometry
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Equation of state of a perfect gas Ideal Gas Law
pV = mRT
where m is the mass and R is the Characteristic Gas
Constant
Ru
R= M
where, M is the molar mass (molecular weight) and
Ru is the Universal Gas Constant.
Ru = 8.314 kJ kmol −1 K −1
Total Energy
Total energy is the sum of all the energies of a
system
Denoted by, E
Denoted by, e, if given on a per mass basis
Internal Energy
The forms of energy related to the molecular
structure of a system and the degree of
molecular activity are referred to as microscopic
energy
The sum of all microscopic forms of energy is
called the Internal Energy of a system
Denoted by, U
Denoted by, u, if given on a per mass basis
Microscopic Energy
The microscopic energy of a system is related to
motion and the influence of some external
effects, such as:
temperature change
gravity
magnetism
electricity
surface tension
Thermal Energy
What we think of a system’s heat content is
actually Thermal Energy
Thermal energy is the sensible and latent forms
of internal energy
Heat
A system cannot contain heat
Heat only exists as energy crossing a system
boundary through a temperature difference
All other forms of energy transfer are work
Enthalpy
In systems that involve fluid flow we frequently
encounter enthalpy, the combination of internal
energy and flow energy:
h = u + pρ
The flow energy, or flow work, is the energy per
unit mass needed to move the fluid and
maintain flow.
Using enthalpy instead of internal energy to
represent the energy of a flowing fluid means
that the energy associated with flow work is
already taken care of.
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Specific Heat Specific Heat
Specific Heat
Specific heat is the energy required to raise the
temperature of a unit of mass of a substance by one
degree in a specified way.
Hence, it has units of kJ kg −1 K −1
Note:
Some texts will display the units as kJ kg −1 ◦ C −1
Specific Heat
Specific heat at constant volume, cv
The energy required to raise the temperature of the
unit mass of a substance by one degree as the
volume is maintained constant. Used for change
R in
internal energy. In an ideal system, ∆u = cv (T )dT
Specific Heat
Formal Definitions
∂u
cv = ( ∂T )v
The change in internal energy with temperature at
constant volume
∂h
cp = ( ∂T )p
The change in enthalpy with temperature at constant
pressure
Specific Heat
Temperature Dependent
The specific heat of an ideal gas changes with
temperature. In fact cv and cp are only dependent on
temperature.
i.e. cv = cv (T ) and cp = cp (T )
Specific Heat
Temperature Dependent
At low pressure, relative to the critical point, all real
gases approach ideal-gas behaviour, and therefore
their specific heats depend on temperature only.
The specific heats of real gases at low pressures are
called ideal-gas specific heats, or zero-pressure
specific heats, and are often denoted cp0 and cv 0 .
Values for u, internal energy, h, enthalpy, and cp
and cv for many gases have been tabulated.
Specific Heat
Internal energy and enthalpy change can be
calculated when specific heat is taken constant at an
average value.
∆u = cv ,avg (T2 − T1 )
∆h = cp,avg (T2 − T1 )
For small temperature intervals the specific heats
may be assumed to vary linearly with temperature.
Specific Heat
Specific Heat
Specific Heat
Specific Heat Relations of Ideal Gases
h = u + Pv
h = u + RT
dh = du + RdT
cp dT = cv dT + RdT
∴ cp = cv + R
cp > cv
cv = 0.718 kJ kg −1 K −1
R = 0.287 kJ kg −1 K −1
∴ cp = 1.005 kJ kg −1 K −1
Compressibility
We know that volume of a fluid changes with a
change in its temperature or pressure
Fluids typically expand when heated or
depressurised and contract when they are
cooled or pressurised
This change in volume is different for different
fluids
κ is the Bulk Modulus of Elasticity
∂p
κ = −ν ∂ν = ρ ∂p
∂ρT T
Pressure
What is Pressure?
The normal force exerted by a fluid per unit area
Only meaningful for a gas or a liquid
In solids we talk about normal stress
Measured in Pascals (Pa)
The dimensions of Pascals are normally
denoted as Newtons per square metre (Nm−2 )
Commonly spoken of in terms of kPa or MPa
(watch your units in calculations!)
Pressure is always positive
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Statics of Fluid Systems Pressure
Pressure
Solids
In solids “pressure” is really normal stress
Defined as “The force acting perpendicular to
the surface per unit area”
As an example, if a person is standing on two
feet and lifts one foot up so that they are
standing on only one foot the pressure on that
foot doubles – half the surface area
Measuring Pressure
Absolute Pressure
The actual pressure at a given position
Measured relative to an absolute vacuum
Gauge Pressure
Most devices do not measure absolute pressure
Typically devices are calibrated to read zero at
atmospheric pressure
They therefore indicate the difference between
absolute pressure and the local atmospheric
pressure
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Statics of Fluid Systems Pressure
Pressure at a Point
Pressure is the compressive force per unit area
This gives the impression of a vector quantity
However, because the pressure at any point in a
fluid is the same in all directions it is actually a
scalar quantity
It has magnitude but no specific direction
Pressure at a Point
Consider a wedge-shaped fluid element of unit
length (into the screen) in equilibrium
The mean pressures at the three surfaces P1 , P2
and P3 , and the force acting on a surface is the
product of mean pressure and the surface area
Pressure at a Point
From Newton’s second law, a force balance in the x-
and z-directions gives:
P
Fx = max : P1 ∆z − P3 L sin θ = 0
P2 ∆x − P3 L cos θ − 12 ρg∆x∆z = 0
P
Fz = maz :
Pressure at a Point
Because we are talking about pressure at a point,
∆z tends to 0 and hence,
P1 = P2 = P3 = P
This result is independent of the angle θ.
Therefore, the pressure at a point in a fluid has
the same magnitude in all directions.
It can be shown, in the absence of shear forces,
that this result is applicable to fluids in motion as
well as fluids at rest.
Pascal’s Law
Pressure in a fluid at rest is independent of the
shape or cross section of the container
It changes in the vertical direction but not in the
horizontal directions
It is dependent on the type of fluid – ie one fluid
at a certain depth is not the same as another
fluid at the same depth
Pascal’s Law
The pressure applied to a confined fluid increases
the pressure throughout by the same amount
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Statics of Fluid Systems Variation of Pressure with Depth
Pascal’s Law/
Variation of Pressure with Depth
Example
An open container in an atmosphere of 100 kPa
contains three immiscible liquids layered on top of
each other. The top liquid is mercury
(ρmer = 13, 600 kg m−3 ) and is 0.2 m thick. The
second layer is oil (ρoil = 850 kg m−3 ) and is 0.1 m
thick. At a point 0.3 m into the third layer, which is
water (ρwater = 1000 kg m−3 ), what is the pressure?
Solution
Assuming that g = 9.8 m s−2 the formula given on
the slide previous to the question can be used:
Manometers
The relationship between pressure and an
elevation change can be exploited to measure
pressure differences
Devices based on this principle are called
Manometers
Manometers typically consist of a plastic or
glass U-tube containing one or more fluids such
as mercury, water, alcohol or oil.
Example
Solution
First calculate the density of the manometric
fluid
ρ = 0.85 × 1000 = 850 kg m−3
Then using the equation for measuring pressure
at depth
Pabs = Patm + ρgh = 96000 + 850 × 9.8 × 0.55 =
100581 Pa = 100.6 kPa
Therefore, the gauge pressure of the gas is
Pgauge = 4.6 kPa
PC = PA + ρga
For the right-hand limb
PD = PB + ρg(b − h) + ρman gh
Equating PD and PC
Limitations
Not feasible for measuring high pressures
because of excessive tube length
Surface tension and capillary action can be a
problem
Slow to respond to pressure changes so they
cannot be used for dynamic measurements
The End!
Don’t forget
Read Chapter 3 of the EGB323 textbook
you should have already read Chapters 1 and 2
Continue to organise your fluid mechanics
materials
Attend the tutorials