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Benzene P1 sat 136.

50
Ethylbenzene P2 sat 24.26
P-x-y diagram for benzene (1)/ethylbenzene(2) at 363.15K
160.00
x1 y1 P 140.00
0 0.0000 24.26

P (kPa)
0.1 0.3847 35.48 120.00
0.2 0.5845 46.71 100.00
0.3 0.7069 57.93
80.00
0.4 0.7895 69.15
0.5 0.8491 80.38 60.00
0.6 0.8941 91.60 40.00
0.7 0.9292 102.83
0.8 0.9575 114.05 20.00
0.9 0.9806 125.27 0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1 1.0000 136.50
x1, y1 x1 y1

Benzene T1 sat 349.35


Ethylbenzene T2 sat 404.99
T-x-y diagram for benzene(1)/ethylben
T (K) P1 sat P2 sat x y
349.35 90.00 14.48 1.0000 1.0000 400
355 107.23 17.99 0.8069 0.9614 390
360 124.53 21.66 0.6643 0.9192 380
365 143.93 25.90 0.5431 0.8685
370
370 165.58 30.81 0.4392 0.8080
T (K)

375 189.65 36.44 0.3496 0.7367 360


380 216.32 42.87 0.2717 0.6531 350
385 245.76 50.19 0.2036 0.5559
340
390 278.13 58.47 0.1435 0.4436
404.99 394.61 90.01 0.000 0.000 330
320
0.0000 0.2000 0.4000 0.6000 0.
x1, y1 x
y
benzene(2) at 363.15K

0.8 0.9 1

x1 y1

for benzene(1)/ethylbenzene(2) at 90kPa

0.4000 0.6000 0.8000 1.0000


x1, y1 x1
y1
benzene(1)/toluene(2)

d) Iteration P1 sat P2 sat a P2 sat (new) T


1 213.92 89.86 2.3806 82.440 376.64
2 198.09 82.44 2.4028 82.027 376.47
3 197.20 82.03 2.4041 82.003 376.46
4 197.15 82.00 2.4042 82.002 376.46

e) Iteration P1 sat P2 sat a P1 sat (new) T


1 213.92 89.86 2.3806 231.00 382.55
2 231.00 97.94 2.3587 229.24 382.25
3 229.24 97.10 2.3608 229.41 382.28
4 229.41 97.18 2.3606 229.39 382.28

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