Sub.Code ; 112 ‘B’ NEB-GRADE Xt 2076 (2019) Chemistry Candidates are required to give their answers in their own words as far as practicable. The figures in the margin indicate full marks. = Full Marks: 75 Time: 3 hrs. s Pass marks: 27 (For part studests ony) Group ‘A’ Attempt any fifteen questions, 15x2=30 J. Nitrogen reacts with oxygen to give N,O, and N,O, respectively. Which “« _ lawof stoichiometry do this data illustrate ? State the la 141 <2! Mass of 2x10?! number of atoms of an element is 04 is the mass of 0.5 mole of the element? é I -3>__ Differentiate between evaporation and b a 4.” Give reasons ith a8 cs Aa i) Gases do not settle at the botti 4 ink ii) Deliquescent substances air. 5. What is the conclusio1 juid when exposed to atmospheric de-Broglie? Write its mathematical relationship. K i . Jpentify. the fo rine of 19" electron of an element having~ ee wu p 4,7 df - = 24 jp. Whatis ‘controlled nuclear fission ? Write an important ee Beco +4 8, wn the Lewis structure of each of the following: Le i) Hor ii)v,0 4 141 9. Give an example of each of such molecule having +1 " j) polar co-valent bond ii) non-polar covalent bond iii) intermolecular hydrogen bond iv) intramolecular hydrogen bond. 10., Which one has greater electron affinity and why ? Cl or F 2 ~. Assign oxidation number to the underlined element in each of the following: i) N,O, ii) Natt, BO, HL 12. State law of mass action. @notesanjal.com 2 5 CEE Contd... S 6 ph l,117B? (2) fs 13, Give reason to show 11 * _ i) AIO, is an amphoteric oxide ii) BaO, is a peroxide. {4. What is meant by para-hydrogen ? How is it converted into, ortho-hydrogen ? il 15. What products would you capac when CO is g +1 i) heated with H, in Presence of ZnO+Cd > ii) passed « oyer hested caustic soda ‘under pressure 16. Write down the molecular formula and one use of each of the following: gape 4x05 i) Boric acid ii) Borax . iii) Silica gel iv) Sodium silicate. S 17. Distinguish between alloys and amalgams giving an ‘ofeach. 1+1 18. Why are alkali metals impart characteristic col jen introduced to the flame ? e@ Z 19% Give the IUPAC name of the followin compounds: 141 * i) (CH,),C-OH ii) CH, CO, 20. Define inductive effect and-wri USE.». 1H 21. An alkene (A) undergoe; is to give ethanal and metas as fi major products id and write its TUPAC name. cHgl: tee 22. Write suitable ‘reaction for the preparation of methane from i) sodium et (CH,COONa) o ii); sium iodide (CH, Mgl). 1H Group B z Attempt any five questions. Ze * 5x5=25 = Define reducing agent giving an example, Balance the following redox reaction by oxidation number or ion-electron method: 1+4> * oN vs MnO, + HCL - > Mnel,+Cl,+H,0 . 24, xplain main postulates c of Bohr’s theory of atomic model. How did this theory justify the origin of spectral lines in hydrogen atom ?7 A+, & Describe laboratory method of preparation of ethene. Suggest a chemical - test to distinguish ‘ethene fromethane.. * » 441. 26. Why can’t HBr and H] be prepared by heating Conc. H,SO, with bromide - and iodide respectively ? Write down correct eather ae prepare them. @notesanjal.com % Contd... :BE (3) 112°B’ How would you test the presence of Br ions in its aqueous solution ? 24241 27, Give the chemistry of plaster of pairs. 5 28. How is sulphurdioxide gas prepared in laboratory ? Write reactions to: show SO, acts as both an oxidising as well as a reducing agent. 342 9. a) A Givalent metal oxide contain Ag 6% of OEE: What is the atomic mass of the metal? > BS ca 2 ~ b) 16.8 gm of NaHCO, when heated Pics 9em of Na,CO, according to the along reaction: gBaLyane 2NaHCO, —4 > Na. ,€O,+H ,0+CO, e i) find the percentage purity of the rc ii) how much volume of CO, will be pt eg atmospheric pressure and 27°C temperature. ue HN wi Be 333 so ‘Conc. HNO, is stored in dark bottle. ii)iron ecoines passive when treated with Conc. HNO; 31, State Boyle’s Law and draw 1 i) Pvs A ii) Vs > Pp nee graphs to sip bog law. US vis the practical Simin ce. ional law ? Atoy balloon blown S at 10° / 242 ois a volume 960 Coy Rok this stage the balloon is distended wi = of its stretching capacity. Will the balloon brust, if it is bron ee ee 2580 21f not, calculate the temperature at he the balloon brust. _ SA ©neteranjal.com : C i a y112‘B’ (4) a 32. Explain the principle and procedure involved in the manufacture of washing soda by ammonia-soda process, Sketch a well-labe How would you convert washing soda into i) soda ash ii) sodium silicate respectively 7 Write down important uses of washing soda, Hed diagram for it, 64242 5x2=10 oo 33. Write short notes on any two, i) Detection of nitrogen in the organic compound, ii) Advantages of modern periodic table. ~ iii) Characteristics of | homologous seri » +7 iv) Relationship between Kp and Key