MATERIAL SAFETY DATA SHEET

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Page 1 oftolal T
Datc ofprcpdation:5 July 2004
Daterelisedr5Jme2003

SECTION 1 : CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

1.1 Product Details

ProductNarne (1) d-Tetramethrin (Neo-P)'namin Fofie)

(2) Clphenothdn (Gokilaht)
Trade Name PESGUARD FG 161
Chemical Name (I) 3,4,5,6-Tetrahydrophthal im idomethyl-( 1R)-cis, trans-chrysanthemate
(2) (RS)-q-Cyano-3-phenoxybenzyl ( I R)-cis,hans-chrysanthemate
Chemical Formula (1) CreHr5ON
(2) C::H:sO:CN
Molar Mass (r ) 33 r.4
(.2) 315.s
Chemical lamily
Manufacturer's Code
Use Public health insecticide
Structural Formula
ocN
1l o cl-l
""; f
cF .r------r-3-o-"r-"
X cHr cHr
),/\2
d-tetrauethrin
o
(cNr,c:cH --a----7'c

cH3 cH3 ry"D

12 Companv Identification
Ilnporter,{Distributor
Name and Address Ag cultural Chemicals (M) Sdn. Bhd.
962, Lorong Perusahaan 8, Tarnan Perindustrian Perai,
13600 Perai, Pulau Pinang, Malalsia.
Telephone Number 604-390 7988
Emerge cy Telephone Number 604-390 7988

1.3 Conta€t Point

Desigration : Ms. Cheong WaiChing, Product Support Manager/

En. Ahmad Labib bin Yusof, Administrative Assistant
Tel. No. : 60,t-390 7988

Pesgudd FG-161
 MATERIAL SAFETY DATA SHEET

Itrtroducton Dctrih
Page 2 oftotal 7
Date ofpr€pa.ation:5 July 2004
Date revhed :5 June 2008

SECTION 2 : COMPOSITION/INT'ORtrtr4.TION ON INGREDIENT

Lhis product is to be considered as a preparatio in conlormance 1() EC directives

Ch€nical Name CAS No. ProDortion Ernosur€ Limit Toricitv Data
CvDhenothrin f racemic) 39s1s-40-7 12%
d-Tetramethrin f racemix) 7696-t2-0 4%
Emulsifier Refer Section 9 Refer Section 11
Trade secrct t0%
Solvent 64742-94-5 Balance

SECTION 3 : PITYSICAL AND CHEMICAL PROPERTIES

Appearance Pale yellow tradsparent liquid

Odour Characteristic odor
Solubiliry Emulsifiable in water
Boiling Point No data available
Meiting Point (rC) No data available
Vapour PressDre (mmHg at 25tC) No data available
Percentage Volatiles No data available
Evapomtion Rate No data available
VapouDensity No data available
Specific Gravity 0.917 (20'C)
Flash Point 72.51C (Tag closed cup)
Autoi gnition Temperature No data available
Flalnmable Linir (%) No data available
Flammability Combustible
Viscosity 7 x 10'3 Pa. s (20rc)

SECTION 4 : IL{ZARD IDENTIFICATION

Initating to eyes and skin

May cause sensitisation by skin contact
Toxic to aquatic organisms.
May cause long-tem adverse effects in the aquatic envircnment
 MATERIAL SAFETY DATA SHEET
Introducton Details
PaSe 3 oftotal 7
Date of prcparatio! 15 July 2004
Date revised :5 June 2008

SECTION 5 : FTRST AID MEASURES

Ingestion knmediately rinse mouth with plenry ofwater and call physician. Do not induce
a
\orniling. Never gi\e an),1hing b) nrourh Io an uncon'ciou. person.
Eye Contact Immediately flush with plenty oflvater, holding eyelids apart, for 15 ninutes. Get
medical attention. Remove contact lenses ifwon.
Skin Contact Remove contaminated clothing. Wash skin witll soap and water immediately. Cet
medical attent;on ifinitation develops or persists.
Inhalation Remove to fresh air and rest. Give artificial respiration ifnot breathing, give
oxygen if breathing is difficult. Never give anlhing by mouth to an unconscious
persoD. Seek irnmediate medical attention.
Notes to Physician Treatment is symptornatic.

SECTION 6 : FIRE FIGHTING MEASURES

Exlinguishilg Media : Use dry powder or carbon dioxide for snall fire, foam for large fire.
Fire Fighting Instruction : Fire fighters should wear full-faced self-contained brenthing apparatus and
protective clothing. Water used to extinguish a fire should not be allorved to
enterthe drainage system or watercourses. Evacuate personnel to safe area,
Keep personnel removed to upwind offire.
Special Haz4rds : Thermal decomposition will produce CO, NOx orHCN.

SECTION 7 : ACCIDtrNTAI RXLEASE MEASURE

Leak and/or Spjll :

Wear protective clothing. Eliminate ignition source. Ventilate area. This chemical is toxic to aquatic
organisms and do not allow to escape into sewage system or water colLrses. Absorb the spillage with inert
matedal such as clay, sand, sawdust etc and collect inlo a drum. Wash the contaminated area with
detergent and small amount of water. Absorb with ineft material and collect the slurry info the drum for
disposal, following local regulations. Ifthe chemical enters body ofwater, notiry the autho ty at once.

Pesgurd FG-l61
 MATERIAL SAFETY DATA SIIEET
lnt.oducton Details
Page 4 oftotalT
Dale ofprepalation:5 July 2004
Daie reriscd:5 Juno 2008

SECTION 8 : ILA.NDLING AND STORAGE

Handling: Read label before use. Tlle usual pr€cautions forhandling chemicals should be obsefled.
Wear protective gloves ofrubber, suitable protective clothing and goggles Wash thoroughly
after handling. Remove contaminated clothing and wash before reuse
Storage : Keep only in original container, tightly closed, in a cool dry and well-ventilafed place, out of
reach ofchildren. Avoid heat at1d direct sunlight Keep away from foodstuffs and animal
feeds. Keep away from all ignition soulces.

Sf,CTION 9 : EXPOSIJRE CONTROL AND PERSONAI- PROTECTION

Exposurc Limit loil mist, minerall ACGIH TLV (2002)

Notice ofintended change for 2002
0.2 mg/n' (TWA)
Engineering Measures Provide adequate ventilation.
Personal Protection The usual precautions for handling chemicals should be observed.
Respiratory Prctection Wear air-pu rying respirator equipped with organic vapour cartridges or
canister
Eye Prctection Safety goggles
Skin Protection Protective rubber glovos and other prctective clothing as appropriate.

SECTION 10 : STABILITY AND REACTIVITY

Conditions to Avoid
Incompatibles
Decomposition Producis
Hazardous Polymedzation
Stability
Direct sunl;ght, source ofheat, open flames, sparks and high temperature.
Alkaline materials
Emits toxic fumes under fire conditions (refor Section 6)
Will not occlr.
Stable under nomal rccommended storage and handling conditions.

SECTION 11 : TOXICOLOGICAI INFORMATION

Toxicity Data :

Acute OralLD5o : (Rat) male 2,350 mg/kg

(Rat) female 2,500 mg/kg
Acute Dennal LD50 : (Rao > 2.000 ng,&g
lnhalation LC5o (4 hr) : (Rat) > 5,050 mg/kg

PcsgldrJ FC-l6l
 MATERIAI SAFETY DATA SHEET
Infioductor Detrils
Page 6 oftotal 7
Dale of preparation :5 JulY 2004
Dalc relised : 5 Junc2008

SECTION 12 | ECOLOGICAL INFORMATION

Mobility & Bioaccumulation No data available
Biodegradabil;ty No data available
Aquatic Toxicity :
d-Tetram€thrin
LC5o (96 hours) (BlDegill) 0.069 mg,4-
LCso (96 hours) (Rainbow trout) 0.010 mgr-

Crphenothrin
LC1 (96 hours) (Rainbow trout) 0.34 P"gl1
ECso (48 hours) (Water flea) 0.43 Pg/l

SECTION 13 : DISPOSAL INFORMATION

Dispose ofwastes and used containers in accordance w;th local regulation
Do not cont'minate surface
rvater of sanitary sewer system.

SECTION 14 : TRANSPORT INFORMATION

Land ftansport (ADRI ND)

ADR Class 9 ADR/RID ltem No llc/llc
RID Class 9 ADR/T.ID Packing Group lll
Hazard Identification No. 90 Substance ldentification No 3082
TREM-Card CEFIC TEC(R)-90G01 LDI Number 3082
p.op", SttippingNuIn", E'nvironmentally hazardous substance' liquid, n'o s (Contains:C)phenothrin)

\ca rr,tn'po tlMDG-cade IMOI

IMO / IMDG code
Class 9 Packing Croup Itr, Page 9028
Lt'{ Numbo 3082 EMS None
MFAG None Marine Pollutant No
frop"t Sftippi,tg NuIn" , EnviroDmentally hazardous substance, liquid, n o s (Coitains: C)?henothrin
and d-Tetmmethrin)

PesguardFG-l6l
 MATERIAL SAFETY DATA SHEET
Ir troductorv Det3 ils
Page 5 oflotal 7
Dale ofPrepdation:5 JulY 2004
Dale reviscd i5 June 2008

There is no ihformatian on Pesguard FG'161fot thefoltowittg. Datafor indi'iduttl techhical

substance were tilized-
Carcinogenicity d-T€tramethrin
(Rat, 1 o4-week feeding) Not carcinogenic
Cvphenothrin
(Rat, 2 year feeding) Not carcinogenic
Renroductive Effect Crphenothrin
(Two-generation study - feeding)
(Rat) No reproductive toxicity
NOEL (adult & offspring) 300 ppm
Mutagenicity d-T€tramethrin
Negative (Ames test, r,7 vtro DNA damage test, chromosomal aberration test)
Cvphenoth n
Negative (Ames test, ll? tito sister chromatid exchange test,
micronucleus test)
Teratogenicity d-Tetramethrin
lRaL.andrabbil\..ubculaneous' \olleralogenic
Cvphenothdn
(Rats and rabbil.. iubculdneous) Not teratogenic
NOEL (Rat, matemal & developmental) 150 mg/kg/dav
(Rabbit, matemal) 50 mg,&g/day
(Rabbit, developmenial) 125 mg^g/day
Effects ofOverexposure
Eye Effect (Rabbit) Slightly iritating
Skin Effect (Rabbit) Strongly initatirlg
(Rabbit) Not irdtating (320 fold dilution)
Sensitiziig Effect (Guineapig) Weak skin sensitizer (Buehler method)

Chrcnic Effects d-Tetrimethrin

NOAEL 1000 ppm
NOEL (Rat) male 48 mg,4<g/day
(Rat) lemale 18 mg/kg/day
Ta.get Organs No data available
Medical Conditions Generally Aggravated by Exposure : No data available

Pesgudd FG-161
 MATN,RIAL SAFETY DATA SHEET
Irtroductory Dettils
Page 7 oftolalT
Date ofpr€paration:5 July 2004
Date rcvised :5 June 2008

Air transport (ICAO-TI / ATA-DGR)

ICAO-TI / IATA-DGR UN number 3082
Class 9 PackinggrouP lI
Proper Shipping Name I Environmentally h^z ardous substance, liquid, n o.s (Contains: Cyphenothrin
and d-Tetram ethrin)

SECTION 15 : RIGIILATORY INFORMATION

Follow all regulalions in your countq/.

Pesticides Act
Class III (Harmful)

CPL Regulations
CIass Irdtant
Risk Phrase R36/38 Iffitating to eyes and skin
R43 May caDse sensitisation by skin contact
R51 Toxic to aquatic organisms.
R53 May cause long-term adv€rse effects in the aquatic environment
Safety Phrase 52 Keep out ofreach ofchildren
536/37139 Wear suitable proiective clothing, gloves and eyes/face proteetion
524125 Avoid contact with skin and eyes
556 Do not discharge into dmins or the environment, dispose ofto an
authorised waste collection point.

SECTION 16 : OTHER INFORMATION

Reference :
MSDS - Pesgnard FG161
MSDS - Pesguard FG-161, date : Nov. 01, 2002
Guidelines for The Classification ofHazardous Chemicals - DOSH 1997
Guidelines for The Fonnulation ofA Chemical Saf€ty Data Sheet - DOSH 1997
cuidelines for Inbelling of Hazardous Chemicals - DOSH 1997

To the best ofour knowledge, the information contained herein is accurate. However, we cannot assume
any liability whatsoever for the accumcy or completeness ofthe hformation contained herein'