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The Silent Boat Killer: All The Answers To The Important Questions
The Silent Boat Killer: All The Answers To The Important Questions
The Silent Boat Killer: All The Answers To The Important Questions
knowhow
What causes galvanic corrosion? rivets would fade away faster than
All metals and alloys boast a native Charlie Sheen’s TV career. Reverse the FIGURE 1: THE GALVANIC TABLE >XcmXe`Zj\i`\j`e]cfn`e^j\XnXk\i
voltage, as shown in the galvanic series situation and fasten aluminium plates
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(see Figure 1). When two dissimilar with small steel rivets, and the corrosion
All the answers to the important questions metals in direct electrical/physical slows to a crawl. This is why sacrificial DX^e\j`ld#Xef[\j]i\j_nXk\i
contact with each other are immersed anodes cannot be left to waste away
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in an electrolyte (a liquid that conducts completely before they are replaced,
In extreme cases B<P
electricity, such as sea water) these because as their size diminishes, so Q`eZ#Xef[\jj\XnXk\i
electrolytic corrosion EfidXcgXjj`m\jkXk\
can completely destroy elements form a galvanic couple, does their effectiveness. 8Zk`m\jkXk\ 8cld`e`ldXccfpj#Xef[\jYiXZb`j_nXk\i
aluminium sterndrives essentially an unwelcome underwater Salinity and pH: liquid conductivity is
battery. Consequently, current flows usually measured in µS/cm (micro :X[d`ld#\c\Zkif$gcXk\[ZfXk`e^]fijk\\c
from one metal electrode (the anode) siemens per centimetre). Fresh water D`c[jk\\cXe[ZXjk`ife#\e^`e\YcfZbjZXjk`ife
through the electrolyte to the other usually lies in the 50 to 500µS/cm
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electrode (the cathode) then continues range, whereas salt water is significantly
around the loop (see Figure 2) using the more conductive at around 50,000µS/ 8cld`e`ldYifeq\#gifg\cc\ij
connection between the two. cm. The alkalinity or acidity (pH) of
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water affects its conductivity too. So the
Why is this such a problem? type of water (fresh, brackish or salt) :fgg\i#_lccj_\Xk_`e^Xe[Xek`]flc`e^
Unlike a domestic mains lead, which where you moor your boat can have a
8[d`iXckpXe[Xcld`e`ldYiXjj#]`kk`e^jefkle[\inXk\i
merely shuffles electrons to and fro, the profound effect on the rate of corrosion.
anodic part of our battery experiences a Marine slime: some of the slimy DXe^Xe\j\Yifeq\XZklXccpXYiXjj #gifg\cc\ijXe[il[[\ij
loss of electrons, and the resulting bacterial films you find covering your
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metallic ions dissolve into the water precious underwater fittings may
– the process is called dissolution. So markedly increase the voltage of certain 0'&('Xe[/'&)'Zfgg\ie`Zb\c#g`g`e^
the anode corrodes because it suffers a metals that lie at the cathodic end to C\X[#b\\cjjX`c`e^YfXkj
physical loss of material. around +0.3v to +0.4V, in particular the
The galvanic series has a cathodic or stainless steel family. This makes them E`Zb\cXcld`e`ldYifeq\#le[\inXk\i]`kk`e^j#m\ip_`^_hlXc`kpgifgj
most noble end (see Figure 1) where the more cathodic, but it also puts more JkX`ec\jjjk\\c$^iX[\j*')#*'+#*)(Xe[*+.#kXebj
metals and alloys are the least active. strain on the anodes because of the
Similarly, the anodic or least noble end is increased voltage differential. Dfe\c#m\ip_`^_jki\e^k_gifgj_X]kj
The silent
other alloys used to make propellers, of choice for most sterndrive legs and
shafts, skin fittings and even hulls. outboard motor casings. However, like
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stainless steel, aluminium alloys quickly Mfckd\k\i XZkjXjXeXef[\
How does cathodic protection aim form a protective oxide coating that is '%*Mkf(%'M
VOLTS $'%.Mkf'%+M
to reduce or prevent corrosion? self healing. That protective film is its Xggifo`dXk\cp
boat killer
It renders all the potentially anodic saving grace, and by and large it ensures
underwater fittings cathodic, by a poorer than expected electrical =cfnf] Trim tabs need
supplying a more anodic electrical contact with neighbouring metal, and \c\Zkifej separate anodes
current from an alternative source. That consequently less galvanic corrosion
source can either be sacrificial anodes, than its place in the table suggests.
or an impressed current system which
generates its own anodic current and Does that mean my sterndrive legs JkX`ec\jjjk\\cj_X]k
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Galvanic and electrolytic corrosion can wreak havoc feeds it into the water through an inert are safe?
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on your underwater metal fittings. But if you know non-corroding anode. Not necessarily. Aluminium sterndrive Xggifo`dXk\cp J\XnXk\i
`jk_\\c\Zkifcpk\
legs invariably have their own dedicated
how and why, it’s easier to prevent the attacks What factors affect the rate of anodes, designed and installed by the K_\jkX`ec\jjjk\\cj_X]k`jk_\ZXk_f[\#k_\dfjkefYc\d\kXc Barnacles can exacerbate
Text: Dave Marsh Photos: MGDUFF & MBY forum galvanic corrosion? manufacturers, who doubtless K_\Xcld`e`ldgifg\cc\i`jk_\Xef[\#k_\c\XjkefYc\d\kXc corrosion by exposing
Voltage differential: in general, the understand their products’ galvanic bare metal under paint
greater the difference in voltage between needs. But if your usual anodes are
the metals, the more potentially severe defunct, then the aluminium sterndrive There is no better way to eliminate galvanic
the corrosion. However, double the could become the anode for the rest of
voltage does not necessarily mean the boat. Sterndrives also need special corrosion than to ensure total separation of all
double the corrosion. The initial current attention because neglect or your dissimilar metals
flow usually falls off due to an effect misunderstanding can have a
called polarisation, and some metals significantly greater effect on their fitting aftermarket prop guards, rope- the alloy reacts with oxygen to form a
(notably stainless steel and aluminium wellbeing than most other areas of the cutters or planing fins; a break in the tough oxide film that renders it resistant
which form an oxide skin) exhibit more boat. Amongst myriad dangers are: crucial connecting wire between the to further corrosion – it changes from
polarisation than others. leaving a partially raised leg with the casing and the transom plate; and active to passive. And this layer
Area ratio effect: as the surface area of lower casing immersed but the anodes unforeseen electrolytic corrosion which obligingly reforms if it’s damaged. Above
the cathodic metal increases relative to clear of the water; water ingress can wreck a sterndrive leg within weeks. the water the stainless can usually find a
the less noble parts, the anodic metals resulting from failure of the rubber plentiful supply of oxygen in the air. But
suffer more. For instance, say you had gaiter; overstretching the inbuilt anodes Why is stainless steel a special case? in slow moving or poorly aerated water
Separate anodes may Even shatftdrive GRP
be needed on the leg boats need annodes to tiny aluminium rivets holding big steel by replacing the alloy propellers with Stainless steels achieve their stainless the chromium can be starved of the Anodes should be replaced
and steering ram protect their sterngear hull plates together, the more anodic high-performance stainless ones, or temperament because the chromium in necessary oxygen. When that happens, if less than half remains
maY2011 97
Boat master knowhow
Both steel and GRP boats are Paint protected the rudder
prone to galvanic corrosion of and trim tab (see left) but the
their sterngear if the correct stainless prop shaft attacked
precautions aren’t taken the more anodic propeller
Crevice corrosion on
stainless steel can trigger
galvanic corrosion There is almost no limit to the harm Bonding metallic fittings together:
good or bad?
electrolytic corrosion can lead to, with a short When it comes to preventing corrosion,
circuit causing fast-acting, untold damage this is the most crucial topic of all, yet
it’s not free of debate. Remember,
However, electrolysis is the result of an electrical/physical connection dissimilar metals submerged in sea
unsolicited stray currents from an between the boats. So your neighbour’s water do not complete the galvanic
external source flowing between metals. faults, such as lack of anodes or faulty circuit on their own, they need that final
There are several culprits such as wiring, become yours. Your anodes could electrical/physical connection. So there
the stainless not only corrodes and poorly installed or damaged wiring, bad end up protecting your neighbour’s huge is no better way to eliminate galvanic
becomes active again, but its electrical earthing on power tools, dodgy float cathodic bronze fittings, or even the corrosion than to ensure total separation
potential can shift to around -0.5V. The switches, and even extremely damp marina’s steel pilings which you may of all your dissimilar metals. There again,
normally passive stainless has become salty conditions causing current leakage. now be connected to. If the boats both any powerboat with an interconnected
conspicuously anodic compared with, Unfortunately, unlike our galvanic cell, have metal hulls, these too can function stainless steel prop shaft and a
say, an adjoining manganese bronze there is almost no limit to the harmful as a giant anode and cathode. manganese bronze propeller will need to
propeller at around -0.3V. current that can be generated, from a connect at least this duo to an anode.
Crevice corrosion can occur in damp day trickle to the torrent of a full How do I stop shorepower problems? An anode must be bonded to the
stainless steel in nooks and crannies, or short circuit. So the damage that Fit a simple galvanic isolator. This parts it’s intended to protect. This
when the metal is poorly set in a bedding electrolytic problems can inflict can be typically comprises two diodes which bonding circuit can take the form of a
compound, or inside a cutlass bearing, far greater and faster acting. restrict current flow in the grounding complete circuit where all underwater
again, where there’s oxygen starvation. The neighbourly aspect of electrolytic (earth) wire when the applied voltage is fittings are bonded together, and/or a
Although the crevice corrosion itself is corrosion arises because many low, but still allow full flow in case of an number of more isolated connections,
not galvanic, the metal’s change in powerboats use shorepower leads, and earth fault. e.g. anode + trim tabs. With everything
voltage can trigger galvanic corrosion. your neighbour’s connection will Far safer is to use a more expensive connected, and with the sacrificial
It’s possible for a corroded stainless doubtless share a common AC isolating transformer. Because windings anodes at the end of the chain, however
fastening to be anodic to an identical grounding (earth) circuit that eventually transfer the power across, a transformer unusual your mix of metal fittings and
neighbour in good order. leads to a big copper grounding rod eliminates the metallic connection fastenings, they should all be protected.
buried in the marina. Even when both between the marina’s shorepower and All-embracing bonding circuits assume
Can neighbouring boats cause boats’ shorepower circuits are perfectly the boat, so the physical metallic link greater importance on boats with
me problems? installed, the common AC earth creates (i.e. the earth wire) is severed. shorepower and 240V systems where
Yep. As always, the electrical circuit
must be complete for problems to arise.
So in strictly galvanic terms, the risk is TABLE 1: what type of anodes can i fit?
low in that it would take, for example,
two poorly painted steel boats rubbing Zinc: Most common and relatively unchanged in fresh water, because of fresh water and salt water
against each other to complete the cheap. It appears anodic to nigh on its relatively poor conductivity, the environments, consider using
circuit and link their separate everything else except a few currents can’t travel as far, so impressed current anodes. There are
underwater parts. The greater risk is aluminium alloys. Zinc anodes should corrosion is more localised. various systems available: most are
from electrolytic corrosion. not be used in fresh or brackish water Magnesium anodes can damage integrated into the boat’s hull, others
because over time they may become timber, so avoid using on wooden hang over the bow and stern. If you’re
How does electrolytic corrosion differ coated with a white oxide crust that boats and aluminium craft. considering one of these systems, it’s
from galvanic? prevents them working. Aluminium alloy: Aluminium anodes best to talk directly with the relevant
If galvanic corrosion is a naughty boy, Magnesium: Normally only used in are used in brackish, and possibly manufacturer. Their notable
electrolytic corrosion is its evil twin. fresh water because their high salt water environments. Like zinc, advantages are that the current can
Electrolytic and galvanic corrosion negative voltage (around -1.6V) a white oxide crust develops in (in theory) be precisely regulated to
trigger the same problem, that of an causes them to waste away too fast in fresh water. provide complete and uninterrupted
unwanted underwater battery eating more conductive salt water. Although Impressed current anodes: If your protection, and once fitted there are
away at the anodic side. So nearly all the the galvanic series remains largely boating involves switching between no anodes to replace.
information here applies to both.
98 maY2011
Boat master knowhow
100 maY2011