——_—. Pen] ey AO TAO KY THI CHON HQC SINH GIO QUOC GIA THPT NU i? NAM 2016 ——PE-FHL-CHINH THUC Mon: HOA HOC s Thoi gian; 180 phut (khGng ké thei gian giao dé) Ngay thi thi nhat: 06/01/2016 Cho: H= 1; C= 12; 0= 16; Na=23; © T(K) = CC) + 273; R = 8,314 Jemol-K Na = 6,022.10" mol'!; 6298 K: Cau I (3,0 diém) 1. G diéu kién chudn, tai 298 K, entanpi ca cdc phan mg va entropi [ S6 TT Phan img PI Br H? 299 (KS) ie os i 4 ~ Chit Nils | 1hO_|__Nz Sigs (I/K.mol) | 666 191 a) Tinh entanpi tao thanh Ar Pex cia NzHg, N20 va NH, b) Viét phuong trinh ca phan tmg oxi héa hoan toan (dét chay) hidrazin tao thanh Nz va H20. Tinh nhiét ding ap (Q,) & 298 K, AG%209 va hing s6 can bing K cia phan tng oxi héa hidrazin. ¢) Néu hon hop ban dau gdm 2 mol NH; va 0,5 mol O2 thi nhiét ding tich (Qy) cla phan img (3) 1a bao nhiéu? 2. Unani tur nhién chita khoding 99,3772 U; 0,7%7}!U (v8 kh6i lugng) cing véi lung nnhé cic dng vi phong xa Ia sin phim phan rf cia cdc ding vj trén, nhur “jRa , 74¢P0,... Mét mu quing urani cé khéi Jugng 10 kg ly md Nong Som (Quing Nam) o hoa! 49 phong xa ota Ra bing 751.10" Ba. ‘a) Hoat 46 phéng x@ cia 24U, 7!9Po va 78U trong mau quang noi trén bang bao nhiéu? Cho Hing 06 cén bing thé ki gitta céc déng vi phéng xa khoi ddu céc ho phéng xa ty nhién va cde con chau ca ching, Cho chu ki ban ri cia “U bing 4,47.10° nim, cia 7a bing 1620 nam, cia *5U bing 7,038.10° nam (1 nam cé 365 ngay). b) Use tinh trung binh cho ring sy phan hach 1 kg. 235y sinh ra 6,55.10"° kJ. Tinh xem trong, bao nhiéu kg quang urani néi trén chita mot lrgng”“U e6 sy phan hach toa ra nang lurong bing 1,82.10° kWh. Cau I (3,0 diém) 1, Nam 1976, J.L. Clark ngudi My phat minh ra dang pin wat 06 sic dign dng Er kha én dinh c& 1,434 V, ngay nay duge sir dung trong céc thiét bj dién ti. Dya trén nguyén tae chung, thiét lap mét pin gdm mot cye hn héng (amalgam) Zn 10% nhiing trong dung dich bao hoa cla Zn$O4,7H20; dién cyc edn lai tgo Ip boi HezSO, va Hg()). Tit cae dit kign 4a cho hay: a) Thiét !4p so 48 pin Clark, chi 18 catot vi anot. Viét cde phuong trinh phin (mg xay ra trén cae dign cue va phan img tong cOng xay ra trong pin. b) Tinh nhigt phan img theo kJ & 25°C. ¢) Dya vio céc sé ligu tinh todn thu durge, nhan xét vé huéng cla phan tg xay ra trong pin. Cho biét, sire dign dong Ey duge tinh theo biéu thie sau: Ex (V) = 1.4328 - 0,00119(T - 288) - 0,000007(T'- 288° 2. a) Sir dung cée ban phan ting va thé dign cye chudn duéi day 46i voi nguyén 16 clo dé tinh tich s6 ion cia nude (K, ClOs + H,O +2e — ClOy + 20H" E=037V ClOy + 2H" +2e > ClO +120 E=120V. trang 1/3») Kali dicromat la mot trong nhimg tic nhin tgo két tia, due six dung rong ri. Ntng edn bing du6i day duge thiét lép trong dung djch nue cia crom(VI): HCrO¢ +120 == CrO,* + HO" pK, = 6,50 2HCrO; === Cr,0;7 +20 pK2=-1,36 Bb qua cée cn bing khéc lién quan dén crom. Gia sir tit cd hg s6 hoat 46 déu bing 1 (nghia 1a c6 thé sir dung ning 46 dé tinh hing s6 cén bing). , : Ding két qua tich s6 ion cia nu6c (Ky) tinh durge 6 ¥ a), tinh hang s6 cn bing ca ede phan img dug day: Cro + HO === HCO; +OH (1) ChO? +20 == 2010 +120 Q) Trong truimg hop khéng tinh duoc Ky cla nude & ¥ a), ly Ky = 1,0.10" dé tinh. ©) Tich s6 tan cia BaCrO, 1AX, =1,2.10. BaCrgO> tan dé dang trong nude. Can bing cia phan img (2) sé chuyén dai theo chiéu nao Khi thém cdc tac nhén sau vao dung djch tuong asi dam dc cla K2Cr,07? i)KOH; ii) HC; ili) Bal; iv) 120. III (3,5 diém) 1. Cho phan ting phan hy ozon 6 phakhi: 20,—*+30, —(*) Phan img nay dugc xem nhu tuan theo co ché sau: M+O;==0,+0+M ot 0+0;—2420, @ day M la phan tir khi tro ndo d6 c6 kha nfing trao déi nang lugng véi ozon khi va cham, trong. khi ban thin né khéng d6i. Bi ring t6c 49 phan tmg (2) l6n hon rit nl iéu so v6i tc 46 phan mg thuan va téc d6 phan img nghich trong cén bling (1) (v2>> v.1 va vz>> v1). 1) Cé thé dp dung nguyén If ndng d6 én dinh doi v6i nguyén tit © duge khOng? Tai sa0? b) Xae dinh biéu thite van t6c phan tmg (*) va piéu dién hing sé téc dO phan img ting quat () theo cdc hing s6 téc dé thanh phan. 2) Dung dich X gém FeSO, 2.10" M, MnSQx4.10°M, H)SQ4 1M. Cho 1 mL dung djch Br; 2.107M ‘yao 1 mL dung dich X, thu dusge dung dich Y. Thém din 2 mL dung dich AgNO; 0,2 M vio dung djch Y thu duye dung dich Z. a) Viét cde phuong trinh phan img xay ra va mé t& céc hign tugmg kém theo. b) Tinh néng d9 cn bing cia céc ion trong dung dich Z. Cho: 8, ape = 1,085 Vs Epyr gee = 0-771 Vis Exra0, 1" hia” K,aqpr= 10°. Coi HoSOq phan Ii hoan toan. Cau IV (4,0 diém) 1, B6i voi nguyén tir H va nhiing ion chi 06 | electron thi nding Iuong cua electron duge xc a dinh theo biéu thie: E, areas v6i Ey = - 2,178.10" J va Z 1a sé higu nguyén ti, n 1a s6 7 Iugng tir chinh, ‘Xie dink nang lugng ion héa theo kJ/mol cia nguyén tir H va nhGng jon mot electron sau a) H; b) He’; ©) Li’; ac ©) Fe* Giai thich sy bién thién ca cdc gid tr nang, Iuong ion hoa khi di tir ng 2. M@t nguyén tit 6 trang thai co ban ¢6 phan Iép electron ngoai cling 18 2 duéi day cia hai electron nay la ding? m=-1 0 +1 m=-1 0 +1 m=-1 0 +1 m=-1 0 +1 m=-1 0 41 »GlI »fLi »fLW »G ,GLn 3. Electron cudi cing trong. nguyen 16 A c6 ete sO luomg tir m = 2; m= -1 m= 41/2. SO electron dc than cia nguyén t8 X 6 trang thai co ban thuge phiin gp 4d hoe Ss eiing bing sb trang 2/3 =1,23.V; n tir H dén ion Fe*** “dich biéu dién nadoelectron déc thin cia A. Cé bao nhigu nguyen t6 X thoa man dir kign trén, dé 1a nhimg nguyén 16 ndo (cé thé sir dung bang tuan hoan céc nguyén t6 héa hoc 4é tra loi)? i Electron cia ion He" & trang thai k{ch thich e6 gid tri 6 luong t chinh bing s6 luong ti phy eda phan I6p chia electron dc thin cia nguyén t X. Nang lugmg cla electron nay 6 He’ biog ‘nang lugng cia electron & trang thai co bin cia nguyén tir H. Xée dinh chinh xée nguyén OX. 4. 1on C3 tdn tai trong mot sé hgp chat, vi dy CaC a) Viét edu hinh electron eta phan tit C, va ion C3 theo li thuyét MO. b) So sinh d6 ban lién két, d6 dai lign két eta C, va ion C}-. Gidi thich. ©) So sinh nang lugng ion héa thir nhat (/,) cba Cp, CF va nguyén tir C. Giai thich. Chiu ¥ (3,0 diém) . 1. a) Thyte nghiém dA xe nhan tinh dfn dign tt cba bge (Ag), déng (Cu) va vang (Au). Dya vaio cdu tgo nguyén tr, gidi thich két qua 46. ) Thye #8, c8 thé ding cdc kim logi nhom LA vao vige din dign chrge khong? Tai sao? 2. Mét hgp kim gdm Cr, Fe, Co viNi, Ngudi to phin tich ham luyng cde kim logi trong mau hop kim theo quy trinh sau. Cén 1,40 gam hop kim, hoa tan hét yao dung dich HNO, die, néng, ri thém NaOH dur vao thu duge dung dich A va két tha B. Loe tach két the, rbi thém dung dich HO; dur vao dung dich nudc Joc, cé can. Lay chat rin thu dvgc hda tan hon toan trong dung dich H,SO, long. Thém mdt lung du KI vao dung dich vira thu duge, Sau khi phiin ing xéy ra hoan toan, chudn 46 lugng fa sinh ra bang dung djch NaS2Os 0.2 M thay t6n hét 30,0 mL. Két tia B duge khudy du trong dung djch NHs dr iG phain ting hoa (oan, thu durge ket tha C va dung dich D. Nung két tia C trong khong khi 400°C dén khéi lugng khong d6i thi thu duoc 0,96 g chat rin E. Thém lugng du KOH va K;S20s vao dung dich D, dun néng 16i phan img hon toan thi thu duge mot oxit mau den F cb khoi Luong 0,81 gam va dung djch G. Hoa tan hét 0,81 gam chat F trong dung dich HNOs, thu duge dung dich H va 100,8 mL khi khong mau I (diéu kign tigu chuan). Viét cdc phuong trinh phan img xay ra va xée dinh % vé kh6i lung cde nguyén 16 trong mau hgp kim trén. Chu VI (3,5 diém) . ‘Nong d6 dug trong mau c6 thé duge xée dinh bing phuong phip Hagedom - Jensen. Phuong phap nay dua vio phan img cia Nas{Fe(CN),] oxi hoa glucozo thanh axit gluconie. Qui trinh phan tich nh Tay 0.20 mL may méu cho vdo binh tam giée, thém 5,00 ml. dung dich Nas{Fe(CN),] (nats! hexcwsiano ferst (Il1)) 4,012 mmol/L r8i dun eéch thiy, thu duoc dung dich A. ‘Thém lin lint cdc dung dich KI dur, ZnCl du va CH;COOH vao dung dich A. Sau khi céc phan ing xy ra hod ton, fuong T sinh ra duge chun dang dung dich NaySz0s 4,00 mmol/L. Gia thi ring ef thinh phiin khéc trong mau khong énh hudng dén két qua thi nghigm. a) Viét cae phurong trink phan img xy ra theo qui trinh trén, | b) Tai sao khdng thé ding céc muoi sit(I1!) kha nhu FeCls, Fe(NO3)s,... 4€ thay cho mudi phire Nas{Fe(CN)s] trong thi nghigm trén, Cho biét pH cia mau la 7,4, ¢) Tinh hing s6 cn bing cia phan ting: 2[ Fe(CN), } +31 @2 2[Fe(CN),]" +15, tir 46 cho biét vai trd cla ZnCl, trong quy trinh trén. d) Tinh néng €6 (mg/mL) cia glucozo c6 trong mau mau, biét ring phép chun d6 cdn 3,28 mL dung, dich NazS,O3 dé dat 6 diém tuong duong, Cho biét: Ef...» = 0.771 V3 By 4, = 0,5355 V Cc phite [Fo(CN)s]”" va [Fe(CN)e]* c6 hang s6 bén tong cng Tan lugt 1a 10 va 10°, - HET ~ + Thi sinh khong diege sit dung tai liéw, * Cain bé coi thi thong gidi thich gi them trang 3/3AO DUC VA DAO TAO KY THI CHON HQC SINH GIOI QUOC GIA THPT DE TH CHINA-THUC NAM 2016 BA N CRINGE Mén: HOA HQC . I DAN UnEYE ‘Thoi gian: 180 phiit (khong ké thai gian giao dé) Neay thi thir hai: 07/01/2016 (Dé thi cd 03 trang, gdm 05 cau) Mot sé ki higu viét tits Me: metyl, Et: etyl, n-Bu: n-butyl, -Bu: rert-butyl, Ph: phenyl, Py: piridin, m-CPBA: axit m-clopebenzoic, Bn: benzyl, PCC: piridini clocromat, 4: de, xt: xi tic. Cau 1 (3,5 diém) 1. Adamantan (dugc d8t theo tit adamas trong tiéng Hi Lap ¢6 nghia 1a kim cong) duge Prelog va Seiweirth ting hgp theo so 8: come Nactiby 4, _ Nile p Du. —¢ — DAKO fs : Tcote — CybeDg MEONA Cullis 2940" Cie 2) Bry CC Cio ‘Adamantan Hay cho biét cdu tric cia cée chat A, B, C va D. . 2. Chit E va G ¢6 cing cong thwe phan tir Cilla. Chit E khong lam quay mat phiing anh sing phan eye, khing bj oxi héa bang KMnO, trong méi trong kit . Chat G lam quay mat phiing anh sang phan cue: khi bj oxi hoa bang KMnO, trong méi trudng kiém, G cho mudi ca axit benzoic. ‘Vidt cOng thite va goi tén eta ede chat G. 3. Cho so dé chuyén h Me ye Ot gy TONS yt xy) meee ‘Me CH, CHC, Cay CHCH coir, PHO Ne Viét cng thc cfu tao cla cfc chat X1, X2, X3 vi X4. Me 4. Methadon la chat duge ding 1am thuéc cai nghién ma ty phd bién a Ph. Ph Me nay. Tit Me:NH, PhCH-CN, EtOH, CH»=CH-CHy va céc chat v6 co Me thiét khdc, viét so 43 téng hop methadon (bé qua yéu 16 lap thé). E102 N Chu TI (4.5 diém) Methadon Me 1. Cho sd6 chuyén hén: mCPBA Dio" AN DHF co [rH Gg DEAM, 4 pNOrCHeCHO I OH CutheNO Vidt céng thite cdu tao cia cfc chét A, B,C, D va E. Biét Bla mét d-lacton. 2. Este cé thé bj thiy phan trong mdi trudng kiém, trung tinh va axit. ‘a) Viét co ché thity phan etyl axetat trong méi trudng kiém, trung tinh va axit. b) Ngudi ta nghién cifu déng hoe cia phan img thay phén 4-nitrophenyl axetat nhur sau: NhO mot giot (0,02 mL) dung dich 4-nitrophenyl axetat ndng 49 0,01 M (lodng, gén nhu khong mau) vao 4 mL dung djch dém X (pH = 10, khéng mau), khudy déu, thu duge dung dich Y c6 mau vang xuat hign. Chiéu mot chim tia sng don sic c6 bude song 400 nm qua dung dich Y dung trong cuvet e6 chiéu “day Lom. Bo 46 hp thu quang 4 ca dung jch Y theo thé gian , thu duge két qua nhur sau: [sy | 60 | 120 | 180 | 240 | 300 | 360 | 420 | 600 | 720 | 810 | 900 | 1200 | 5950 | 6000 [A [O11 [019 [0,26 | 0,31 [0.35 | 0.39 | 0.42 | 0,50 | 0,54 | 0,57 | 0,59 | 0,64 | 0,90 | 0,90 | Gidi thich tai sao dung dich Y o6 mau vang va tinh ndng 46 (mol-L itrophenyl axetat trong dung dich Y tai ¢= 300 s. Xe dinh d6 hap thy quang cia dung dich ¥ tai ¢= 1000 s. ) Néu trong thi nghiém 6 céu (b) sir dung X 4 dung dich d&m e6 pH = 7,65 (khéng mau) thi sau ki hé dat dén trang thai cn bing, dung dich Y 06 d6 hap thy quang 1a bao nhiéu? Cho biét: Dé hp thy quang A cia dung dich long phy thude vao nding 4 C (mol-L'') ciia chat hap thy trong dung dich, chiéu day lép dung dich / (cm), hé s6 hip thy mol ¢ (L-cm"-mol") dc trumg cho ban chat eta chat hép thu va tudn theo dinh luat Lambert - Beer: 4 = elC; 4-nitrophenyl axetat hap thy quang khéng dang ké 6 bude song 400 nm; dung méi sir dung trong céc thi nghiém Ta nuée; trong nude, pK, cia 4-nitrophenol la 7,15. Trang 1/33. Tamoxifen duge str dung dé sin xudt thude Nolvadex diéu tri ung thir vi. Bé tong hgp tamoxifen ngudi ta lim nhu sau: Cho axit phenylaxetic twong téc véi PCls rdi phan tmg voi metoxibenzen trong sy cé mat cia SnCly, thu duge chat G. Chat G phan img v6i Etl cé mat NaH tao thanh chat H. Chat H tae dung véi EtSLi (hoge BBry), thu duge chat I (CysH<0z). Sau khi kiém héa, cho I phan ‘img v6i 1,2-dicloetan, thu duge chat K (CsHis02Cl). Chat K phan (mg v6i phenyl magie bromua, sau 6 sin phim tao thanh duge xt Ii trong méi truéng axit lofing, thu duge chat L, (CoiHasO2C)). Dui tic dung cia HCI trong metanol, L chuyén thanh chat M. Amin héa M bang Me2NH, thu duoc tamoxifen c6 céng thite CzeHoyNO. Xée dinh cng thire edu tao cia céc chat G, H, I, K, L, M va tamoxifen. Cau III (4,5 diém) 1. Ertiprotafib duge sit dung lam thuéc khang té bio ung thu. So dd tng hop ertiprotafib nhur sau: TX, Me CY wm cori goove {pk Me, yaks we FN ] Rdemnane DFC gM cp 2 r 4 = il ee ar cae © taken ae oY al amor Xéc dinh cong thée cau tao cha céc chat A, B, C va D. mé Me — Ertiprotafib 2. Chat E (CiiFyNOi1) duge téch ra tir m6t Loai sao bién, Thity phan Enhé enzym f-glicozidaza, thu duge chat G (CslHi20s, thude day D) va chat H. Cho E phan ting voi Mel/Aga0 du, sau d6 sén pham duge thy phn trong moi trrdng axit, thy duge axit (25,3R)-3-hidroxi-1-metylpirolidin-2~ cacboxylic, chét F (CsHi¢Os) va chat I (CsHiyOs). Khi oxi hoa F va I boi HINOs, thi tir F thu duge trong dé cé axit axetic va axit (25,35)-2,3-dimetoxibutandioic (-T), c6n tit I tgo thinh axit (2R3R)-2,3-dimetoxibutandioic (+T) va axit 2,3,4-trimetoxipentandioie khéng quang K). Dun néng H, thu duge chat L (CisHigN20s). pirolidin 14 di vong no nam canh chita 1 nguyén ti nito. ip thé cia chat K va chi ri u 16 ddi ximg trong edu tric ca K. | cay hinh tuyét déi ciia cdc nguyén tir cacbon bat déi. ©) Xie dinh cfu tric ciia H, L va cho biét L c6 quang hoat khong? 4d) Xie dinh edu tric eda E va v8 cdng thite phdi canh eta E. 3, Bismaleimit tinh thé long (BMI) duge sir dung trong céng nghé dign ti, hang khOng vi try,... Mt logi BMI duge tong hop theo so 46 sau: HAC HNOVE. yy DEMOS 9 FOC! yy, Bat Wad x6 S002 x9 XB Bnet F808 HHO" W806 CuttNOy 2 Biét XB [a aN }-cvofenijooc-¢ yw a) Xéc dinh cOng thite cu to cita cde chat XI, X2, X3, X4, XS, X6, X7 va BMI. b) Viet so dé tng hgp chat X8 tir X3, octametylen dibromua va céc chat can thiét khée. Cfiu EV (3,5 diém) 5 ° mHOLAe 1. a) Monastrol duge ding lam thube te xo ccleeet ché su phan bao cia cdc té bao ung th NH. Trong céng nghiép, monastrol duge téng fio MeO sy hop bing céch sit dyng phan img da téc nhan theo so dé hinh trén. Hay 48 xudt co ché dé giai thich sy tgo thanh sén phim cia phan img. b) Dé xudt co ché dé gidi thich sir tao thanh sén phdm trong mdi phan (rng sau: BANOO G son ry | Ag 2. Phosphoramidon (chat H) la chat de ch enzym thermolysin, mt enzym thuge nhém proteaza. Chit Hila mét mudi dinatri co c6ng thiic CpHs2N;NayPO19, Tién hinh phan clit chAt H, thu duge Aipeptit leuxyltryptophan (chat 1), L-rhamanozo (chdt K) va mudi NaHPOy. Dau N cita dipeptit Trang 2/3duge nbi voi phén doan photphat bing lién két N-P. Nhém photphat lién két voi don vi K qua lién ét este. Metyl héa hoan toan H rdi thiy phn san phdm, thu duge 2,3,4-tri-O-metyl-L-thamanozo va cdc sin phim khéc khéng phai 1 gluxit, Oxi héa K bang axit nitric lofing, thu duge axit monocacboxylic CeHiz05 c6 mach cacbon khéng phan nhénh. Don vi K trong CHO phosphoramidon chita cdc nguyén tir C2, C3, C4, C5 6 hu cée vj tri cacbon tung mg trong L-mannozo va ¢6 1 cing thitc chiéu Fiso celia K va edu tric ota phosphoramidon. Cho biét cOng thite u hinh tuyét d6i giong cia mét sé chat nhu sau: CH,CH(NH,)COOH (CH):CHCH,CHONH}COOH ZN Leuxin IY Cau V (4,0.diém) SS-onit Tryptophan 1. Bé xac dinh tich sd tan cia Heals, mot mu Hy:l> duge diéu ché, trong dé iot tén tai dust dang Ph phéng xa. Dém the d phing xa cia mau Heol thi thay cir 1: mol nguyén tir jot trong mi phat 6 5,0.10" phan ra, Sau dd, ly mot long du Hgok cho vio muée, khudy déu dén bao hda. Lay ra 150 ml. mau dung dich bao héa dé, do thc U6 phin rd duge 33 phan ra/phuit. a) Viét phuong trinh cén bing hda tan cia Hgola(r) trong nude. Tei sao thiy ngén thn tai & dang Hg3*. b) Dua vao cde dit kign da cho, tinh tich s6 tan cla Hg2ta, 2. Trong cde dang ning Iueng bén vie, hidro li ngudn ning luromg phong pha va doi dio. Cach sit dung hidro higu qua nit la tgo dign nang ta pin nhién ligu. Xét mot pin nhién ligu duge tao ra tir hei dign ewe 24" (aq)/Ha(k) vi Ox(k), H'(aqVH20(1) voi ede gid tri thé dign eyre chuan (tai p = 1 atm, T= 298 K) tuong img la 0,00 V va 1,23 V. a) Viét cdc phuong trinh phan img xay ra méi dign cue (anot va catot) va phan img téng quét xay rakhi pin hoat dong (cdc hé sé t6i gin). Tinh E;,, . b) Thé dign cue ota pin phy thudc vao nhiéu yéu 16 nhur ndng d6, Sp suat va nhiét 45. Trong khoang "() nnhigt d6 hep, bién thign thé dign cue chudn cia pin c6 thé biéu din bling hé thie: np Bing cdc kién thite nhigt dng hoc da biét, chimg minh hé thtte (1). ) Cho pin nhién ligu dé cép 6 phan dau véi nong 46 va ap suat ban dau cla cdc chat nhu sau: [H'] @ mdi dign oye) = 1 M; p(Ha) = 0,95 atm; p(O;) = 1,1 atm. Tinh £,, khi pin hoat dong 640°C, Cho biét entropi (J-K"-mol') cia Hy(k), O2(k) va H20() lin hugt la: 130,7; 205,2; 70,0. 4d) Tinh céng c6 ich eye dai (KJ) sinh ra bai pin trén, biét trong qua trinh hogt dng pin trén 48 sinh ra4 mol 20. Cho: R = 8,314 Fmol-K"; T(K) = tCC) + 273; F = 96500 C-mot" 3. Ving thudmg c6 trong cae loai 44, duge tach bing clich cho da nghién tée dang vii dung dich NaCN c6 suc khéng khi. Trong qué trinh nay, vang chuyén thinh [Au(CN)s} tan trong muse (Phan img 1). Khi dgt dén can bing, phan dung dich duc ly ra, vang duge thu hoi bing edch cho phic vang tée dung voi kém va kém duge chuyén thanh [Zin(CN),}" (Phan tmg 2). a) Vit va cn bing phuong trinh ion cia cdc phan img (1) va (2). ) Vang trong ty nhign thrmg & dang hop kim voi bac. Bac ciing bi oxi hba bai dung dich NaCN c6 suc khong khi tgo than [Ag(CN):].. Dung dich c6 thé tich 500 lit chita (Au(CN)2]' 0,01 M va [Ag(CN)T 0,003 M durge cho bay hei dén khi chi con 1/3 thé tich ban dau va duge xir Ii bing 39,65 g Zn. Hay tinh ndng a [Au(CN)] va [Ag(CN)s) sau khi phan img xay ra hoan hoan. ¢) [AU(CN)2]" I mot phurc bén trong mot s6 digu kign nhat dinh. Nang 46 cla NaCN 1a bao nhiéu 48 gitr durge 99% theo s6 mol ciis vang trong dung dich & dang phife xianua. Cho: Zn = 65; [Au(CN)x] 6 Ki = 4.10" [zn(CN),]" +2e + Zn+4CN [Au(CN), | +e + Au+2CN [Ag(CN), +e > Ag + * Thi sinh khong duoc ste dung tai ligu; * Cain bé coi thi khong gidi thich gi thém. ‘Trang 3/3BQ GIAO DUC VADAO TAO KY THI CHQN HOC SINH GIOI QUOC GIA THPT DE THI CHiNH THUC NAM 2016 | a | Mén thi: THYC HANH HOA HQC . Walati ‘Thai gian lam bai: 90 phiit (khOng ké théi gian giao dé) BAN CE } NH Ngay thi: 08/01/2016 (Dé thi cé 02 trang) XAC DINH NONG DQ HCI VA ZnCl, TRONG DUNG DICH HON HOP 1. DUNG CY, HOA CHAT - M6i thi sinh c6 m6t b6 dung cu gim: + 01 mau can xac dinh néng 46 (dung trong Io thay tinh, ma sé m4u duge ghi trén thanh 19); +01 cée thity tinh 250 mL (dé dung dung dich chat chudn), da chira sin khoang 100 mL dung dich NaOH 0,0510 M; +01 do choang (mac khi lim thi nghigm); +01 gid va kep buret; +01 buret 25 mL; + 01 pipet 10 mL; +01 qua bép cao su; +01 binh tam gic 250 mL; + 01 binh xjt tia nude (da 06 siin nude ct); i +01 dia thiy tinh dé lay 1 giot hoac 1/2 giot dung dich tir buret (néu can); +01 binh dink mic 100 mL; +01 céc thiiy tinh 150 mL (dyg dung dich thai tir buret va trang bd dung dich mau); +01 chéi long dé rita éng nghiém; +01 cuén gidy vé sinh. - Ding chung cho 6 - 8 thi sinl + 01 lo kém dng hut nhé giot dug dung dich chi thj metyl dé; +01 hop dung chi thj Eriocrom den T; +01 Io dung dung dich dém amoni va éng dong 10 mL. , Chit §: Thi sinh cdn kiém tra dung cu, hoa chat trude khi bat ddu lam thi nghiém, néu thiéu hodc c6 dung cu bj héng phdi bdo ngay véi cdn b6 coi thi. 2. NGUYEN TAC a) Viée xée dinh ndng d6 HCI trong dung dich dua trén nguyén tic sau: HC] la mot don axit manh, do vay 06 thé xac dinh néng d6 ciia HC! biing dung dich chét chuén NaOH ding chi thj metyl 46. Phan (mg chudn a9: HCI +NaOH — NaCl +H,0 Tir thé tich cia dung dich NaOH 4a ding, tinh dure ndng 49 cia HCI trong dung dich mau. b) Vige xc dinh néng 46 ciia ZnCl}, trong dung dich mau dya trén nguyén tic sau: xée dinh néng d@ ion Zn** bang dung djch chat chudn EDTA (ki higu [a HY”) trong méi trang dém amoni ding chi thj Eriocrom den T. Phan tmg chuan 46: Zn + HY” + 2NH3—> ZnY” + 2NH,* rn thé tich cia dung dich EDTA da diing, tinh duge ndng a6 cita ion Zn trong dung dich mau. 1/23, CACH TIEN HANH Nhan miu: . Gi thi sinh nhgn 01 Io thiy tinh trong dé chita dung dich mu cn phén tich, goi la dung dich A (M& sé m4u duge ghi trén thinh lo). Chudn bj méuz . Ding pipet ldy chinh xéc 10,00 mL dung dich A, chuyén vao binh dinh mite 100 mL. Thém nuéc cat vao binh dén vach dinh mac, lic dé trn déu, thu duoc dung dich B. Phép chudn d6 I: Xéc dinh nong d§ HCl trong dung dich hén hop Buse 1; Chuyén dung dich chat chu’n NaOH 0,0510 M vao buret va diéu chinh vé vach 0. Buc 2: Ding pipet ldy chinh xdc 10,00 mL dung dich B cho vao binh tam gidc 250 mL, thém 2-3 giot dung djch chi thj metyl dé, dung dich lic nay cé mau 46 héng. Chuén 46 bing dung dich chit chudn NaOH 0,0510 M cho dén khi dung dich chuyén sang mau vang (bén trong khoang 15 gidy) thi dimg lai. Doc va ghi thé tich dung dich NaOH da ding (kf hiéu la V;, ldy dén 2 chit sd sau ddu phiy). Lap lai thi nghigm 6 bude 2 it nhat 2 1an dé lay két qua trung binh. Phép chudin dp 2: Xéc dinh ning d§ ZnCl; trong dung dich hin hop Buc 3: Tring rira sach cdc thiy tinh 250 mL bing nude may, sau 46 bang nudc cat roi Tau khé bing gidy. Mang céc lén ban giém thi nhan khodng 10 mL dung dich chuan EDTA 0,0100 M dé trang céc ri dé di. Sau dé thf sinh nh’n khodng 100 mL dung dich chudn EDTA 0,0100 M roi mang vé vj tri cia minh, Bude 4: Théo bé dung dich NaOH trén buret, tring riza sach buret bang nusc cat ri trang bing dung dich EDTA 0,0100 M. Bue 5: Chuyén dung dich chun EDTA 0,010 M vao buret r6i diéu chinh vé vach 0. Bude 6: Ding pipet léy chinh xéc 10,00 mL. dung dich B cho vio binh tam giéc 250 mL. = Ding éng dong ly khong 4 mL dung djch 6m amoni cho vio binh tam gidc, Ide 48 tr6n déu. A Cho mét lirong nhé chi thj Eriocrom den T (mét lurgng bing khodng 1/3 hat gao) vao binh tam gidc rdi lac dé tron déu cho dén khi chi thj tan hét, dung djch c6 mau tim. ‘Chuan 46 biing dung dich chét chudn EDTA 0,0100 M cho dén khi dung dich trong binh tam gic chuyén sang mau xanh (bén trong khoang 15 gidy) thi dimg lai. Doc va ghi thé tich dung dich EDTA da ding (ki higu la V2, ldy dén 2 chit sé sau dau phay). , Lap lai thi nghiém 6 cdc bude 5 va 6 it nhdt 2 Lan dé lay két qua trung binh, 4. YEU CAU ~ Thi sinh ty thiét lap céng thie tinh va tinh néng 46 (mol/lit) cua HCI va ZnCl, trong dung dich A (dung dich mau ban dau). ~ Thi sinh ghi két qua thi nghiém vao “Phiéu d4nh gid va tra di thi thye hanh”, bao gom: + Thé tich (mL) chat chudn NaOH va EDTA da ding dé chudn 49 dung dich B (ghi gid tr] thé tich trung binh). + Néng 46 (mol/lit) cba HCI va ZnCl, trong dung dich A. Se Ghi chi: Can b6 coi thi khéng gidi thich gi thém 2/2BOQ GIAO DUC VADAOTAO KY THI ‘CHON HOC SINH GIOI QUOC GIA THPT DE THI CHINH THUC NAM 2016 Mén thi: THYC HANH HOA HOC L Thi gian lam bai: 90 phuit (khong ké thdi gian giao dé) Neay thi: 08/01/2016 PHIEU BANH GIA VA TRA LOI THI THY'C HANH [Luu y= Thi sin! - KHONG ghi sé béo danh, ho tén, cht ki vio phiéu nay, - Bj trir diém néu; xin Iai miu hode xin thém dung dich “| | Sé phich (Do HD chm thi ghi) hoe lam vo dung ey trong thoi gian lam bai thi | Céin 66 coi thi phi ghi e6” hotc “khéng” vao phn 1. Phan 1: Phan ki ning thye banb (danh cho cén bé coi thi) IT [__ Coking | Ghi chit 1 | Xin tai mau | aa y : | 2 | Xin thém dung djch chuin NaOH | 3 | Xin thém dung djch chuin EDTA | 4 | Lam vo dung cu (buret, pipet, binh dinh mic, céc, binh tam gic) | | Phin 2: Két qua thi nghiém . | Ma sé mau ] Thi sinh ghi ma sé méu (ghi trén thanh lo dung md twong img) vdo 6 bén Phan danh cho thi sinh Phan danh cho edn b§ chim thi | Thé tich (mL) dung | Néng d6 (mol/lity 7 a “Ach aknaitn | n dichchuin NaOH’ | ctaHcIvaZnci, | Seisinéngd Biém a va EDTA trong dung dich A 2 Visson = Che = | | Ta = | Venta = cet | | Phin 3: Diém bai thi thye hamh: 1. Diém phin két qua thi nghigm: .. (anh cho cén b¢ chdm thi) 2. Diém trix phn ki nang thy hanh: Téng diém: bang sé: ...,. Bling ChIES o.ooBQ GIAO DUC VADAO TAO KY THI CHON HOC SINH GIOI QUOC GIA THPT DE THI CHINE THUC NAM 2016 Mén thi: THC HANH HOA HOC . Thai gian lam bai: 90 phiit (Khéng ké thdi gian giao dé) Negay thi: 08/01/2016 HUONG DAN DANH CHO CAN BO CHUAN BI THUC HANH L Kiém tra dung cu Can bd chudn bj thyc hanh kiém tra b6 dung cu cua méi thi sinh theo danh ong sau: +01 céc thity tinh 250 mL (48 dg dung dich chét chun); +01 4o choang (mic khi lam thi nghiém); + 01 gid va kep buret; +01 buret 25 mL; +01 pipet 10 mL; +01 qua bép cao su; +01 binh tam giée 250 mL; +01 binh xjt tia made (48 06 sin nude cit); +01 dia thiy tinh dé lay 1 gigt ho&c 1/2 gigt dung dich tir buret (néu can); +01 binh dinh mire 100 mL; +01 céc thy tinh 150 mL. (dung dung dich thai tir buret va trang bd dung dich mau); +01 chéi léng dé rita éng nghiém; +01 cudn gidy vé sinh 4é lau dau buret va pipet. IL. Chuan bj héa cht Chit §: Héa chat va mdu chudn bj cho ki thi duge dng trong 02 thing riéng biét: DE CHINH THUC va DE DY BI. 1. Trude gid thi 30 phi, cén b6 chudn bi thyc hinh mé thing dymg héa chit va mu trong thing DE CHINH THUC danh cho mdi diém thi (xac nhdn cont nguyén niém phong). 2. Kiém tra héa cht, mau va dung cu trong mdi thing, bao gdm: - Cac lo dung dich m&u ¢6 ki higu “A” trong ma s6 mau cua timg lo; - Dung dich “Bém amoni*; - Dung dich chudn “EDTA 0.2000 M”, - Dung dich chudn “NaOH 1.0200 M”; + Dung dich chi thj “Metyl 43”; - Chi thj “Eriocrom den T”; - Ong dong dung tich 10 mL (dwege boc trong gidy). Chit 56 dng dong trong mai thing dé ce dé ping trang hop bi vo trong qué tinh vin chuyen 3. Chuyén cac dung dich miu vé vj tei thi cia méi thi sinh. $6 mdu cén lai 1a sé mau dy trir €@ phong thi sinh xin lai mau. 4, Cim cong to hut vao cdc lo dung dung dich chi thi Metyl dé va dé vao khu vye ding chung cho céc thi sinh (cir 6 - 8 thi sinh ding chung 1 Io).5. Trdng céc éng dong (ldy tir thing xép) bing dung dich dém amoni. Dé éng dong canh 1p dung dich d¢m amoni vao khu vue ding chung cho céc thi sinh. Néu trong thing c6 2 hod 3 19 dung djch ¢¢m amoni thi can chudn bj tong img 2, 3 dng dong. Chi ¥: Trong truéng hop éng dong trong cdc thing bj vo hét va co sé thi khong cd dng dong khdc thay thé thi cén b6 chuéin bj thc hanh Idy pipet va qua bép cao su du phong dé thi sinh Init dung dich dém amoni. Trong trong hgp nay, cdn béo cho cdc cdn b§ coi thi va ede thi sinh biét, 6. Lay lo dung dich chun NaOH 1.0200 M, chuyén toan b6 dung dich nay vo binh dinh mie 1 lit, Ding binh tia nude cat dé nia c4 nip Ip va thinh lo dung NaOH (it nhét 3 in), gOp toan bo nude ria nay vao binh dinh mite 1 lit néi trén, Thém nude cét dén nira binh, lc déu, sau dé thém tiép nude ct dén vach dinh mitc, day kin binh va lic that déu. Dung dich NaOH chuan nay cé néng 46 0,0510 M, duge ding lam chat chudn cho phép chudn 46 thir nhdt. Chii §: a) Dimg biit da ghi trén thanh binh dinh mic ki higu “NaOH 0,0510 M”. b) Diém thi nao c6 sé thi sinh tie 9-16 thi cén chudn bj 2 binh, 86 thi sinh tie 17 tré len thi can chudin bj 3 binh. 7. Lay lp dung dich chuan EDTA 0.2000 M, chuyén toan b§ dung dich nay vao mt binh inh mic dung tich 1 lit kh4c. Ding binh tia nude cét 48 rita cd np Jo va thanh lo dung EDTA (it nbat 3 lan), g0p toin 66 nude rita nay vao binh dinh mite 1 lit n6i trén, Thém nude clit dén niira binh, lac déu, sau d6 thém tiép nude cét dén vach dinh mic, day kin binh va lic that déu. Dung dich EDTA chuan nay c6 néng 46 0,0100 M, duge ding lam chat chun cho phép chudn 46 thir hai. Chuyén ode binh dinh mite dymg EDTA nay lén ban gidm thi. Chii §: a) Ding bitt da ghi trén thanh binh djnh mite ki higu “EDTA 0,0100 M”. b) Diém thi nao cé sé thi sinh tic 9-16 thi cén chudn bj 2 binh, sé thi sinh tie 17 tre lén thi can chudn bj 3 binh. 8 Tit cd céc thi sinh sé thye hign phép chun d6 thr nhdt véi chét chudn NaOH 0,0510 M ‘ruse. Cén bd chuan bj thye hanh rét khoang 100 mL dung dich NaOH 0,0510 M vao ode 250 ml. sach, khé dat tai vj tri thi cia méi thi sinh. Ding bat da ghi trén thanh céc: “NaOH 0,0510 M. Chii $2 Trong truong hop céc dung dung dich chudn ctia thi sinh cha kh6 thi edn b6 chudin bj thee hanh rét khong 10 mL dung dich NaOH dé trang céc, 46 dung dich viea ding dé trang céc di réi mai rét khodng 100 mL dung dich NaOH. 9. Sau khi thi sinh lim xong phép chuan d6 thir nhat, sé trang riza sach va lam kho cdc 250 mL dé mang lén xin dung dich chun EDTA. 10. Cén b6 chudn bj thye hanh rét khoang 10 mL dung dich chi thj EDTA vao eéc cia timg thi sinh é thf sinh ty trang déu phia thanh bén trong cia céc, dé dung dich trang cdc nay di. 11, Cén b§ chudn bj thyc hanh rét cho méi thi sinh khoang 100 mL dung dich chuan EDTA 0,0100 M vita pha vao céc cia thi sinh, 4é thi sinh mang vé chd va thyc hign phép chudn 46 thir 2, Can b6 chudn bj thuc hanh ding but da ghi trén thanh céc: “EDTA 0,0100 M”. 12, Lun ¥ : Déi voi cdc d6i c6 8 thi sink déu duge chun bj 02 1p dung dich chat chuén EDTA. 0.2000 M. Sau khi cén b6 chudin bj thyc hanh pha xong EDTA trong binh dinh mic (6 buée 7), phit EDTA cho céc thi sinh, néu cén thiéu EDTA thi phai tring rita thét sach binh dinh mite 1 lit (ké ca nip va binh) bing nude cat nhiéu lin va pha thém 1 lit dung dich chat chuan EDTA ntta, sented Hét———---- 22BOQ GIAO DUC VABAO TAO KY THI CHON HQC SINH GIOI QUOC GIA THPT DE THI CHINH THUC NAM 2016 a Mén thi: THYC HANH HOA HQC . Thoi gian lam bai: 90 phiit (khing ké thdi gian giao dé) Nely thi: 08/01/2016 HUONG DAN DANH CHO CAN BO COI THI . Cén bé coi thi huéng din thi sinh ngdi ding vj tri. . Cn bé coi thi phat “Phiéu dénh gid va tra 1di thi the hanh” va gidy nhép cho timg thi sinh. “Phiéu d4nb gia va tra Idi thi thye hanh” gdm 1 ta phéch (trang 1/2) va 1 td phiéu lam bai (trang 2/2) cia thi sinh. Can b@ coi thi yéu cau thi sinh ghi day i théng tin vao to phach va ma s6 mu vao 6 “Ma s6 m4u” trong td phiéu lam bai. i J: Can b6 coi thi kiém tra su théng nhdt gitta ma sé mau ctia thi sinh trén lo mau voi ma sé mdu thi sinh thi ghi trén phiéu lam bai. . Can bé coi thi phat dé thi cho thi sinh, yéu cdu thi sinh kiém tra dung cy va héa chit theo danh myc truéc khi tinh théi gian lam bai. Néu c6 dung cy bj nit, héng,... ma thi sinh yéu cau d6i thi giam thi cé thé lay dung cy dy phong di cho thi sinh. . Can b6 coi thi huéng din vj tri dé hoa chét va dung cy chung cho thi sinh bao gdm Chi thi metyl 44, chi thi Eriocrom den T, dung dich dém amoni va éng dong dé lay dém amoni (Méi 66 dung cu, héa chat ding chung cho 6 - 8 thi sinh). Chi y: Trong truéng hgp dng dong trong thing dung dung cu, héa chdt chung bj ve hét ma ca sé khong cé dng dong thay thé thi gidm thi nhde thi sink ding pipet CHUNG dé Idy dung dich dém amoni. . Trong thdi gian lim bai, thi sinh chi durge phép xin Igi 01 Hn cho méi logi sau: mau, chit chudn NaOH, chit chudn EDTA. Hat gids lam bai, cn b6 coi thi thu lai “Phiéu dan ait va tra 10i thi thyc hanh” va ghi 6 “C6” hodc “Kh6ng” vao cac myc & phan 1 trong phiéu lam bai (trang 2/2) cia thi sinh, Can b6 coi thi va thi sinh d@u KHONG duge kf tén hay ghi ho tén vo phiéu lam bai cia thi sinh, KHONG thu Jai dé thi va gidy nhip. Het