( ｾａ＠ I I PART A )

L fi:/!(WJ ro q ::;n;:rrft Jfi ｾ＠ 'lfl "f''tJ ｦｬＡ＼ｾ＾Ｇ＠ L In still air, fr<1g1anc-e C•fa burning incimsc stick will
lw.f '&?f ｾｴ＠ ｲ［ｾＣ＠ VH ｾ＠ 1J ;Jf'l liE! Jl"liFr be smelt by an ｯ｢ＮｾＺｲｶ｣＠ qu ickcst when the.
Ｌｲｴｦ［ｾ＠ UimT Ｎｾ＠ ｣ｾｰｲｩｮＱ＠ ts .:-arriecl out a1

]_ ＢＧ｛ｩｦＮｊｬ［ｲＡｴｾＣ＠ IL low attitude and high air ｬ＼Ｚｭｰｯｲ｡ｴｵｾＮ＠

2. high altituu..: and lnw air tcmp<:mture.
2- U"<<l " 'Wl ｭｲｦｴｪｾ＠ if f 3. low altin1de and low air temfi'!rulurc..
3. "'['i "i'JW1 <r 'f.ff fii'/W'f ;f I ··1. high altimde and high air temperature.
4. ｾ＠ f1'TITT <1 ｜ｗｉｾ＠ if I
2. How many ｳｱｵ｡ｲ･ｾ＠ arc there in this figure?

)_ 9 2. (;1
I. 9 2. 14
3. 15 4. 17
3. 15 4. 17

3. 'F" ｾ＠ <'mfr ?tt"f JWPr fiPIT1<J .rri.i! •Irrlf if 3. A mounlain m;ld ｨ｡Ｎｾ＠ :; sections. of different slop<.-s
ｾ＠ ｾ＠ ｾＺ､＿ｬ＠ 'l7lf fJ 1 J,ii <1a1i ifiT Jltmr 'Jlfl91J as shown. Whnt is the average ｳｬｯｰｾＺ＠ m nf tile entire
miNffJ? criml'l?

l. 2. (1/3) < m < (l/2)

L 2. (\13) < m < (1/2)
3. 1 < m < ,f3 4. (li•J3}<m<l
-'·' I< m < ｾＳ＠ 4. (lh;3)•:m<l
4. ｾ＠ q,·! Ｇｾ＠ VCTrT J0' ｾＧｉｦ＠ ｾ＠ 1!1W1? if5T 4. Wllich Qf the following graphs slruw> the
rn8 ｾ＠ 'JmJT I Ｂ＠ｾ ｾ＠ 'i ＺｴｾＢｬ＠ ¥'/ "i/ ｣ｯｮ･ｴｾｬ＠ of l!l ｳｵｾＱﾷ＠ solution as a function of the
;:f.t;rnr f,a fl'fi#f" ＠ｾ "iT 'ffH FrArli rrit cumulative amount of sugar addc:d in the process of
'(Fiili'7 q{f ｾ＠ <t ifril <t fl'-td ｾ＼ｊＬｴ＠ mfr <mffrf pxcpariog a :!:aturatcd s.olulion Ｈｬｾ＠ tcrnpcralurc
g? ren1aining oooswntr?

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2 2
1.
_g
1! * ｾ＠
E
ｾ＠ s
ｾ＠
8 "
Ｂｾ＠
ａｮＺｾ＾ｕＢ＠
ａＮｾ｣ｵＢＧＡ＠

3 ｾ＠
3 4.

ｾ＠
ｾ＠

___)
§

) )
2
ｾ＠ ｾ＠ J;

ｾ＠ ｾ＠ "'ｾ＠
r. ｾ＠ ｾ＠
" "
ｯ｜ｪＨｾｉｊｲＡ＠ ,14,ft'UL,"'-l
Ｂｾ＠

ｾ＠ iftiJ: ;i; (t? 5. 'lllcrc arc sand-piles whrch arc ｧ｣ｯｭｬｲｩｾｹ＠ sunihlr
;j; i:i211H'it. IFr but of ｊｩｦｾｲ･ｮｴ＠ ht!ights. Il1e m!ic• of Ｑｾ＠ ｭ＿Ｎｓｳ｣ｾ＠ of
Che Sill}d comprising tvlo randomly chosen ｰｩｬｴ＼ｾ＠ wil!
be equal w the ratio of lite

ｾＺＬﾷＷｲ｡Ｎｴ＠ ＮＺｾＢﾷｦＡｲ［ｬ＠ ｾ＠ ［ＺＬＮｾﾷｲｦ＠ ｾ＠ :4i'JClh f ｲＮｊｾ＠ f{lit'' r

L p1k hctghts.
ｆＺｾｮ＠ .r
2. ｾｱｵ｡ｲ｣Ｍｳ＠ of the pile heights.
J· ｬＮＩＢｦＭＬｾｽ＠ .Ｎｦ［ﾷｲｾｬ＠ .f; U·J;1 ..j;: ＳｦｾＨＧｩＡ［Ｑ＠ ,j) ［Ｌｾｦｩ＠
), (:\li.:JcS of the pile heights.
4. ;:r;;-rr::f! ［ＺＫＮｾﾷｴｲｦＧ＠ Ｂｾｬ＠ u;;r 7.;-::,r:• ·i· ＳＡｾｦｲｊﾷｻＧＬ＠ it ｾＮｲＧｊｔ＠ ,1
4. cuhc-m<lts uf ｴｨｾ＠ pile ｩｬ､ｧｨＱｾＮ＠

Ｖｾ＠ . ;,rp;r.r;; ｾＧ＠ q;· ;::j tTt!J-wr ＮＺｾｦｲｩ＠ ii r:;q:; ｕｊＧＬ［ＺＮｾｴ＠ l! F[!!¢ 6. 'ihcrc arc two idcntk.:il vessels of volume Veach,
1l ｾｬＧ＠ ｾﾷ［ｊＮｽＬｲｴｆｩ＠ ;;;;r;:;g r,_rr.,r; ｈｾｦｴ＠ i!i! ij: I ?'R:l: one empty, and the: Nhcr cont.tining a block of
ｾｲｦｬＬ＠ ;j' '!J,'- 'J!f ¥7'ft >rr:PIJ 'i(fff1 if J ｾＧｩﾷｬＯ＠ wood [}f weight w. The \'Cs:>eh are then fillt'Cl with
r.Q;.J-r;r;rii ｾｴＢｦｮ＠ A 1! B ;ry- rp ＲｊＬｦＮＺｾ＠ 7Flft t l :..itv;ti! Ｇﾷｬｾ＠ water up to the- brim. 'l11c to.vo ｡ｲＺｭｳ｣･ｮｴｾ＠ arc
ｳｨｭｾﾷｮ＠ ｡Ｎｾ＠ A and Bin th.: ｦｩｧｵｲｾＮ＠ fflhc 1-knsity or
water is p M1d g is lhe ace.elerution du·e qo ;b>TJ\'ily,
then

LHU
ｾ＠ A

A,U #w ..ｾＢｦＬＯｴ＠
l. A and D haw ･ｱｵｾｌ＠ ｷｾｩｧｨｌＮ＠
2:. A is heavier than B by an 3mount w.
ｾＮ＠ A . B >ir ( Vpg - 1A:}-;{.frN/ /J·:.r.r,T< if
J. A is hc8vicr than B hy an ｾｴｮＩｕＱ＠ VI¥- w.
4. R A ＧｉＨｖｰｧＭｷＩＺｊｬＡｲＮｩｾ＿＠ 4. H is ｨｾ｡ｶｩ･ｲ＠ than A by an <l:!l)()uJH ｾＭｦｲＬｴ＠ 11·.

7. :;r<li f<iar -m 'NrTil'f o tt " 'lTfff iPi AR <Fr.1i 7. If Ｑｾ＠ father has blo•xl group 0 ｾｮ､＠ Ihe rn<lther l:.a$
tt<•if c;,_; 'i<liTA ifi<T-<Frll 87 ｾ＠ if ;• b!nod group Al;l., wh<lt are the pClssible blood g;uups
cf !heir chil&t."ll?
L O,AB,A
2. A,B 1. 0,.<\B,A
3. A,O 2. A.B
4. B,AB :t A.O
•J, B,,.\B

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s. 'lT17R ｾ＠ w<.:!ITT Ｉｾｰ＠ rr ns ;t; ＧＱｻ＾＼ｾＺ＠ ttzy 8, Nudci of 3!l' and Ｓ ｾＤＬ＠ accdcmk-d through the sam<:
sr;n ｾ＠ Ｌｾ＠ m if w-r ilixa tr (P q) ｰｯＱｾＮｩｬ＠ ､ｩｦｾｲ･ｮ｣＠ ｾｮｴ･ｲ＠
a uniform. Ｈｲ｡ｭｶ･Ｚｳｾ＠
ffifr! Z =15 'I Sit> ｾ＠ Z =16 )I Vfi{ "it ｭ｡ｧｮｾｴｩ｣＠ fidd (Z = 15 for P and l =16 for S ). As
i/;; if! 'Hr,..' .Jmt ｾ［＠ riT ｴｬｾＺｹ＠ ｾ［ｭｲｧ･＠ from tlle magnetic field

1. ?Fif ｾ＠ fil:rt fit;#, fftf#rl ;j'; ｾ＠ if i 1. both nuclei croergx; Ull<lctkctcd.

2. >2p 'Iff RiN ns <t tlftif<r rt $17 # 2. ''Pis ddk.:1cd kess tban ; 1S_
1
J. np is ddle;:!ccl more than <ls_
3. 111' 1lil fikttt 32 S rt fftritrr Ｎｊ､ｦｒｾ＠ ..r t , .:1. bolh are ｴｬｊｾＮＬ｡ｹ＠ Jdl.:ct.xl.
4. <fFif ili'f fll41q ＢＧｾ＠ ?1mT it ,(
9. A pr.-rson cllewing_ a bubble !,<Urn did mH experience
9. ck ｾ＠ if f[i/i
<Rfflit lift'J'Jf ;}; ;;p,fR '!? i3<ml' <fl!Zl 'l>J"' if 0!
r:nk7J; <J.rf ｾ＠ "'""rl· ;t e<1r pai.Jl ill a jet plane while landing whcrca:s ｾｯｬｮ＼Ｉｦ＠
:rt.Y ｾＧｭｬＮ＠ rrr 1[i!ffl vit ｾ＠ :nft ｾ＠ ｾ＠
person not chewing a !,oum had car pain. ＢｬＱｵｾ＠ rcli.Wn
'R"f if 'fi! ｾ＠ C(>lild be
IJ' I i;Tf1liT 7fiPl'V W! # <Tfflf !?
fit;
l. chewing gum is a pain ki ll¢r
1. •r-r&•;;; cr.f-fl'lW' if 1 2. ｣ｨｾｷｩｮｧ＠ ･ｱｵｩｬ｢ｲ＼ｾ｣ｳ＠ pressure on both sides of
2. ｾ＠ lRI' !fl:lJW rw-if ¢ ;fl"lf fWli 1# '{{Ill th<: t:arunun
ili'f ｾｎｒＢｩＧ＠ IRm t I 3. chewm.!!l gum closes tile e1!ir dtum
3. J.fiffJ7J71 <t w:'J ｾ＠ '1iT'1 ili'f rmrr 1T'P1 8'mr t 1 .,. . chewing distracts r.he p<:rsnn
4. ｾ＠ ili'f "fi'tf'ff d rt E':llR ｾ＠ {f •'

I 0. Tllc tcason why ｾ＠ lutt<"ll' eclipse docs not occur at

every full moon ｩｾ＠

I . "f.Q fl)7 'fl2fl'i'f mit ｾＧＯ＠ i'l Ｓｴ＿ｪｩｊｾＮ＠ "Tiff 8lm' 1 ｴｨｾ＠ position of r.hc :sun is not favourab[e .:Hall
2. Fl"i: 71 'f'dt >t ｾ＠ <M $ f!'fl f{ifi if<ri' crt full moons.
11'i1f ｾ＠ ,>i?r;r •/ if I 2. the Qrbital plalles M !he m<1on and that of ｾｨ･＠
3. Fit ftt J!T"{ffr ｾ＠ 1frrrr ｾｦＡ＠ 'I ' 1l<lrth aro incltncd to cad1 other b)' a mmiJ
4. Fl"i: ;J,'lf'fr ｾ＠ ft "''Jr;mJ i.'T ｾ＠ <m:m f. ,• angk.
3. the :<.hapc of ｾ｢･＠ ｣ｾｲｴｨ＠ h n<1t a per!eel sphete.
11. '{'5 ｾ＠ t{i$ 'li'I1R <1ft f.imt ([i£l ftA;f;;t:li itt; <it the moun reflects only t'i'<)nt onc- ｨ･ｭｩｳｰｾｲｴＺＭ
ＧｩｻｦｕＷｊｾ＠ fWr if ｦｴｾ＠ it t c'Pf>f
ｔｾ＼＠ &vr 'tit .mw 'il ｾ＠ W'fr ［ｭｾ＠ Jl.A boy throws il stone vertically upwards with ｾ＠
?rr f.fr.l tt 'i/7 'll>t.t F.a umt wm Iii ｾｲ＠ certain initial velocity. \Vhidl of the f<ll!owing
m ｾ＠ Wfr ｾ＼ｩＧ＠ 'fltt <mfm f. ? gJ:"Jphs depicts the velocity as a function ｯｦｴｩＱｾ｣Ｌ＠ if
the acceleration due to gravity is assumed tc> be
u:nifonn and .:omtant?

12. f(l'li' lft 3ll1ljfrt IR ｎｦＧｾ＠ (p <1 2p) F:l"llfr

<mit ;;t ｾ＠ f!1l!' :rn-r ｾ＠ ｾ＠ ;t ffl. tn?i 12.A rib.jd uniform l)ar of a ｣･ＮＱｾｩｮ＠ ｭＺ［Ｎｾ＠ has two bobs
# ｾ＠ 'Wff"f m:wit ;;mt if 1 ;;Rt t:m if <::nf-lll of ｴｩｬｾＺ＠ s.Jmc size, bm wi;h di ffercnt dcnsitie5 p ｾｮ､＠
"Rll ｾ＠ WI ;:;cyr :;m:{"<l rrr ｾ＠ ?1;;<TT # d rtd' 2p ｳｵｰｾｮ､｣＠ id<:mi-c<llly from tls ends.
<5'1/r.tili'fftmrt

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 a
d d'

1. 2d =d'
J. d =2d'
ｾ＠ p l ......
4.
ｾ＠
d >2d'
2p

iJ < 2tt'
p l
\\lhen !he bar is ](:vel llll a fulcmm as shov.n in !he
figure, tf and d' are rdatw by
• 2p

L 2d =(I' 2. d > 2d'

ＱＳｾ＠ ,'iFJ A <r A' 'f.r<-ll if;w 1$ wW 0" <1 ')0" ｾ＠ .Jhlf:rr 3. d = 2d' 4. d < 2d'
>I' i!i7ffl.· ｾ＠ ff I <ft sfR fft"'j B 1l ｂＧｾ＠ <ftrlfWf
ii. ｩｦ［ＧｾＮ＠ • 'f'< co•,.. ｊＮＭｾｫｲ＠ w ｾｲ＼ｊ＠ f. r ［ｾ＼ｬｩｔＤＯＮ＠
l 3. There air: two points A illld A' on the equator M
;i'; ;y;rn it A 7 A' <IP.i ::#t ｾ＠ B 7 B';i'; 1ftz1 ＼ｾ＠
Ｇｬｦｴ［ｰｲｾ＠ I
longitudes 0" and 90"E, and two ｯｴｬｾｲ＠ points lJ and
B' on the same longitudes, ｲ･ｳｰｾ＼ＺｈｶｬｹＬ＠ but at
latitude 6(YOS. The distru;ces (along the latitudes)
l. AA' = lW' 2. AA'= 2 BR'
betl'iccn the ｰｯｩｮｴｾ＠ A, A' and B, B' am related by
3. AA'; (',13) BB' 4. AA' ('1'2) BB'
I. AA' BB' 2. AA'- 2 BE'

J4. 3. AA'=(13)!JB' 4. AA'=('h)B!J'

14.

./-t;-.. . .',,
_ _ _h_ __ J ＧＭｾ｣Ｎ

<#it -arh<r rmr F. ＼Ｚ［ｾＧ＠ "Tffl il fll1i <rr. ''tor !, 1 A Water is flowing through a tube as shovm. ｔｨｾ＠
'" ｃｾ＾＠ ｾ＠ ｩｾ＠ WW1. 'I B 1$ ﾷｙＺｗｾ＠ cross-se.ctional areas at A and C are eoual. and
ｾ＠ ;ft ,,_,f;p;; #' I ;;:;r;;r :m<1 ｾﾥＱﾧ［＠ if lfil B 11ft gre.atcnhan the cros:s-secliClnal arc.a at B .. If 1he
t>]ifil<lf ;f, lJi1N ｾ＠ i[i{f{f
!low is steady, !hen the pressure on =he walls ｡ｾ＠ B is
L ａＺｳｃｴｦＮｾｩＱｬＧ＠
L less than !hat at A and ｴｨ｡ｾ＠ at C.
2. A ;;· C :¢! if ..,m,v, F ,• :"F'i"l7 2. more than that at A and that at C.
:. A 'l C <I? ｾｻｦﾷｩＧｬｲ＼＠ i:I<Jr q'; m1"f ff I 3. same as th;lt at A and that 8t C.
4. A '1ft fF'f"fT ;if :#/<tf. n C "'t g<'RT ,y· 1FT! I 4. mClrc than that at A but less ｴｨｾｮ＠ ｾｨＺｩｬＱ＠ "t C.

ＱＵＮｍｾｴ｣ｨ＠ the two lists

Raw f.frllerial Pmduc:t

A. Limestone a. Porcelain
I B. GJ:f>SLLTI?. ....ｾ＠ h. Gli!:SS
C. Silica sand c. ｐｬ｡ｾｲ･＠ of Paris
D. Clav d. Cerncrn
ｾﾷＭ

A B c n A B (: D
l. a b c d ]. a b c (l
"'
"-· d c b a 2. ｾ＠ c b a
J. a Ｍｾ＠
d b 3. a c d b
4. d a c h 4. d :il c b

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16. <t>1f<1 -ti(),OOO 'lTR'f it TlT"f ｾ＠ ｾ＠ :¢t 6. "Ibe ••c dating ｭｾｯ＠ is not u5ually us;;d for dating
J.V!j fi'Mfm trJ "c ｾ＠ q;r >l7ir>J 'Pft fi'ffl1! organic substances older than -kiO,OOO ｹｾ｡ｲｳＮ＠ because
;;mrr. ｾ＠
J . such objcciS rarely contain carbon.
l. i(ifr rm-<lf if ＠ｾ fW 1ft Wllr vrrfrl !. I 2. such objects ｾ｣ｵｭｩ｡ｴ･､＠ "C afu:r their ｦｯｭＱ｡ｴｩ･ｾｮＮ＠
3. in those timt'S there ｷ｡ｾ＠ no production of Ｑ ｾｃＮ＠
2. # 'Ri'4
4
iFfPlC r5 m'fff ' c '"' .m 4. m.ost of ｾｨ･＠ 14
C in the sample wollld have decayed.
Ylffi'if Ｑｦｬ＼ｾ＠ if I
3. ;:r.rr 'Wrll ''c <nr ｾ＠ '7tf t.rm m 1
A seismograph receives a S-wavc 60 ｾ＠ after it receives
·t 'Plt 'fir smfit>ff¥f '<c f-Nfi:11 t:t "f'!i' r.t'rr fhe ｐＭｷ｡ｙｾＮ＠ If ｕＱｾ＠ ｶ､ｯ｣ｩｬｾ＠ of P- aml ｓＭｷｩｨﾷｾ＠ are 7
17. rpr; "J:ifffll;,rifl P iWi ｾ＠ ｾｩｦｮｲ＠ <t 60 ｾ＠ m km's and 6 kmls respectively, then tile di$talli:c ･ｾｦｴｨ＠
seisrnic focus from 11le seismograph is
lff'f S <f<Tf ¢cf &l;p/:1 'fio[(ff t. I 'J{I)i[ p '1 .S
<tt rdf:'r.!lf JFI;;-;·:· 7 fiUJ >fto Jltfi ito <1 (, ffr>tJ >fro
1. 2520 !an 2. 42km
r:rfft ?to ｾ＠ rir 7,'7li!l ;t ;tw <tr i[ilftr.flrfr ;t; 'f[.ft if .
3. 7070km 4. 72km

3' 7070 ｴｾｲ［＠ 'ffil 4. n ｦｩｒＺｾ＠ >1:\·J 13. ＧｬＱｾ＠ dl.><:ay nfaradlo<lctive isotope Pproduc<.'"S a
smble daughter isotope D. The ratio oflhe number ･ｾｦ＠
18. ('{i; r;)F,•>/1 ＫｬｾＧｦＢｯＮﾷｩ＠ P q.l !?tv,;.; i,• Ｑ ｾｻ＠ 'j"!h utoms of/) 1o1he number of atoms of P a(lcr 2 half
ｾ＠ D <Fri# i! t ;;:t .Ji<lfg <I; 2.w P :;; D lives wou lrl be
iti' ｓｦｾｻ＠ <1"<<1.'1,(3/f <H ,>f'jrmT ｾ＠ ·
il. 1/4 2. 3/4
114 2. 3i4
3. 3 4. 2
3. 3 4. 2
J9..;;t wr.w <:f<lif:'i'I•r1 :f1 'fti! 7fij Ｌｾ＠
f?tmrq ,'tr;r 19. ｔｨｾ＠ ｳｾ｡ｴｬ｣ｲ＠ plots repre-sent the \'<llU'-'!s measured by
i; ;:wfir mr g 1 ft<ci'i it A mft 'f.'<1 1lit Ｎｾ＠ two ｾｩｭ｟ｬ｡ｲ＠ inslruments. Poirtt A in_ the .figures
ｾ＠ f r ＾ｮｱｾﾷｽ＠ ;·,•fl 'j'Wft IVf r.;t.t Ｌｾ＠ f-1r.r if rcprcscnh the tme V:Jiue. \Vludt of the tolJCI.,'Lilg Ｑｾ＠ a
<'! fibi9 •'lr'l'N if fiWmr' i! ｾ＠ correct de.sc:ription of the quality of these
· ｭ｣｡ｳｵｲ･ｾＧＡ＠

I. fir;{ I · .Jr<Jf; ｊｬｦｾＡｴｲ＠ <:l ＮｾｭｴＬ＠ t;f??_Jf;t; 1. Fig.! : good accuracy, goorl ｰｲ｣ｩｾｯｮ＠
ftD 2 at::lif ?12<i'd::rr 'l .J,'<Vr td't!1ft rig. 2 : good ｾ｣ｵｲ｡ｹＬ＠ good prl'>;;ision
Ｒｾ＠ ｦｾｬ＿＠ 1 :Jt·.,:::r., !:J•J;:.;rr:4Nr i.l ,JJf'fl ［ｾ＠ 2. Fig. I : poor accuracy, poor precision
liur 2 ＺｊｴｾＮｦｽＩ＠ ｢ｾＡｉｊＱＮｨｬＬｲ＠ q Jf?f qfifj•Jf;:; Fig. :Z : good accuracy, poor pre-cision
3. Fig.l :poor ｾ｣ｵｭｹＬ＠ good preci$[On
J. ,ft:R I :;t{"/ t,"!</Rfm f/' ,'}!'!<fit ｾｦ［ｬ＠
t'bt 2 ,Ji(rif ｾＧｗｉＢＤ＠ <.' ｾＧｦｻ＠ ｬｦｾｩＧｊＺ＠
Fig. 2 : poor accur:;tcy, poor prc<::ision
4. Fig. 1 :poor acctlracy, poor precision
4. ｦＨｾＺＮﾷ＠ I .;,o;;;c; ｾｔｲ＠ 'l (l{(;(f qf.('.!jfr:
Fig. 2 : poor ｾ｣ｵｲ｡ｹＬ＠ guod pR-,;:.ision
fi>;:; 2 · ·"'"" 'i<:ml;rr " ｾ＠ qft:jll;
20. <>U1 <f:Jrf 11'<7 i'!ofJ if zmN co, <:# ｾ＠ 0. Even though the conccntra1ion of ｃｏｾ＠ is the S.1JllC ｾＱ＠
ｈＧｦｾ［＠ .＼ＺｊＭｲｾ＠ rjl"frfl. q,ft ＮｊＬｾｴ＠ :nN FR ｾｲｱｬｊ＠ ｾ＼ｬ＠ !.:vd ;,nd al high altitude, the photosynthetic rate
VFFi ;:rr?? ｾ＠ 1f ｾＭｭ＠ rrf& stfol;:n is high<•r in ｾｰｬ｡ｮｴ＠ grown ｾｴ＠ se-a levo::l than in l1l plan!
ｾ［＠ ,9fA i, rmit vrr;:,"/ It t<li (of Ulc- :>ame sp,-cies) grown at high altitude, The
re-ason tor this is
]. ＰＺｾ＠ tR ｾ＠ ilft rfmm: ＮＺｾ＠ t
2. \_{::p;1 'f!•'/i1i ｾ＠ (/{I{IJl'-t' ｾ Ｑ ｩｦ＠ｔ ltfiJT k? / I, light ｩｮｴｾｳｬｹ＠ is more ｾｴ＠ sea le ..·el.
3. ﾷ＼ＬｪｾＡｈ＠ 'R zrr<_p;v<:cfm <NN ＮＢｍｴｩＧ｣ｾﾷ＠ f. 2, ｬ･ｭｰｾｲＮＭｴｵ＠ is lower ＼ｾｴ＠ higher altitude.
4. ?lji:a,·.o 'R ｾ＠ Jl'lffrrr ｾＧｦｩＺ＠ 't I
3. atmospheric pressure ｾ＠ higher at sea ｬ･ｾﾷＮ＠
4. rehlive lmmidity is higher at sea level.

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( ｾｐｔ＠ B ] ( PART n ]
21. In the reJctiom (A) ''nd {B).

nlbO + CJ - (Cl(lbO},,] --(A) nH,O + c1· ｾ＠ [CI(II,O),i --(A)

6H20 + M:l' ---• [t>.·lg(l I;;Okf' (B} 6H/) + ｍｾＺｴ＠ • [\ig{ll 10},,f -·(B)

l_ <ri-tf (A) Cf>H {B) ,.. Jor:ff <M L a11 ｾｩ､＠ in bl)th (A) and (B)
2. (A) # rt•'ll' ·SI'i:i' (!;; i'Mf (B) i! \'<n erR 2_ an acid il1 (A) and ;1 ｢ｾｓＧｊ＠ in ( H}
(I h:1sc in {A) and un ｡ｾ｝Ｈｬ＠ in (13)
4_ a ｨｲｾｳ｣＠ in borh {A) nnd {B)

22. Si. ｐｾ＠ S ｡ｾＢｬｃ｝＠ 4d ifi/JrzFt l.fif ｬｾＡ＿ｵｊＧ＠ f&!:a w;:r

Z2_ Th"' si;,::e: Ｑｨｾ＠ or
d ｵ｢ｩｾＺｬｳ＠ in Si, !', S and Cl
((.) lluws d1e ordt'r
ｾＺＱＴ＠ :,;l(jfHI!f f.frr.'t!l iJ 4',r; if
Cl >S > P>S1
Cl > S .:· P .:· Si 2. CI>P>S>Si
2. Cl > I' > S > Si _i. I'> s > Si > C:!
3. P > S > Si > ('] 4. Si > l' > > Cl s
4. Si P> S CJ

24. The tota I number of lone pairs of electrons in T,

is

l. ｾｦｩＧ＠ 2. ri'h I. zero 2. three

3, .... 4, ·II 3. ｾｩｸ＠ 4. nine-

25. Fe(CD)s q;r -t.rw!R: "'*'•" 'lff: r;:q; tl,..,,;:;"' 25. If .!>.·f L1ssh8ucr spectrum ()f ｆｾＨｃｏＩ＠ ｩｾ＠ recnnled in
en rift ｾﾷｲｦ＠ if :.:4/itrr tftil;.r 7.ry r.t ;:;! th-e presence of ｾ＠ magnetic field. 1lte original
y_'t.;.;;sif i'lff r. ｍＺｾ＠ ｾｬ＠ ｾ＠ vmrr #' vw; spo..--.ctmm with two ｬｩｾ｣Ｍ［＠ change-s into the one
;;it ｾ［Ｇｻ＠ it ｾｭｩｴ＠ wSrh
l. rtPi "R!;pf Ｎｾｭｦｲｴ＠ ｾ＠ I I. tim:<' lin(:s
2. <m mro ifift .if 1 2. f;;)ur lines
3. rfffl k<:Rf ｾｩ＿ｦ＠ if I 3. !ivc lines
4. fT mRl '8tf/'l # I 4. six hn<.:1>

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26. Fe>· <r<o'l oi' ｾ＠ <P ,{i!;.'fF! ;;it EDTA ft 26. lhc spectrophotometric ｲ･ｳｾ［＿ｮ＼Ｚ＠ for lhe litration
ｾ＠ iff?it W ｾＢｦｫＱＯｉｄｲｴ＠ａ ｾＧＭｦｩｊＮﾢＯｬｨ｣ｻｉｐｲﾻﾷ＠ of a mixn1re ofFc 1" and Cu'' kms ag,aimt EDTA
JF}th rnr:rr ;r)rft # l is given bdow.

1. ﾷＭ＾ＡｊｾｯＮＬ＠ ab = ｛ｆ｣ Ｕ
ｾ｝＠ ｾ＼Ｗ＠ S/mfR cd = l. vo1Wl1C ab = ｛ｆ･ｾＧ｝＠ and volume cd=
[Cu"')
2. Ｍｾ＠ = ｛ｃｵ Ｒ
ｾ｝＠ Ｎｾ＠ = ICu''l
and volume cd =
ab rP?.Il c.d.
3 2, vQlume ab "' [ｃｵｾﾷＩ＠
lF1.: ' J [Fe3 •]
3. S!lTliFf ab = 3. volume ab =[Fe''] a.nd volume cd =
JrHi:it¥ EDTA cxccs.sEDTA
•t Sfflr.-pf ab l cu•· l ｾｔｲＧＷ＠ ,wwr:; 4. VQ)umc ab =ＨｃｴＮＺｾｬ＠ and volume cd
cd = J.'Mtrl EDTA excess. EDTA
14
'l7. ｲＬｾＺｩｬ＠＿ "'·'i.i<fi.:r" c if. r<f ＼ｾ［＠ ｾﾷＢＪ＠ 27. In Ｇ｣｡ｲｬＺｸｭｾｴｩｮｧ＠ ｡ｰｬｩ＼Ｚｾｯｮ＠ of radioisowpes,
f't.ot.7or >N:>J!ri, •l rsf<f.f;r r.rm ?- '•c emits
L iff>{ I l. P-particlc
2. o.-1:fiV/f "F! I .:!. ｵＭｰ｡ｲｬｩ､ｾ＠
｟Ｌｾ＠
ｾ＠
ｹＭｉＯｊｩＧｬ＾ｾＢｔ＠ q-,_r 3. y-mdiatlon
4. positrQrt
4. f/If.:;rJ:I·! ?f!T I

28. DNA ;f,t fit ｾ＠

28.. Tite ｩｬｾｵ｡＠ ｢｡ｳｾ＠ pairs ｰｲ･ｾｴ＠ in tile double
ｾ＠ f:;;mri ｾ＠
hdical structure of DNA containing adenine (A),
(A), eff-111't"f (T), 'ffFiJ:Corif.'r.f ｾ＠ (G), thymine {T), ｣［ＮＱｯｳｩｮｾ＠ (C) and ｧｵ｡ｮｩｾ＠ (G}, are
Ｎｾ＠ ﾷｦｾＧｩｭｊｆｉ＠
I. AGandCT
l. AGill!lrCT 2. ACand GT
2. AC ?1'-llf GT J. AGand AC
3. AG rmr AC 4, ATamlGC
4. AT fmf GC
ＲＹＮｔｨｾ＠ oxidation s!a!e of iron in met-hemoglobill is
29. ::f{PfR '1ft
ＤＷＡｗｕｾ＠ 1 I. thr<.-c
2. two
].iff;; 3. four
2. rl 4. zero
3. rm
4. l!f'/1

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30. r\i{C0}-1 q;;• Rfii"S L (L = PMe3 .JH 3(1, Tl1:e reacnons of Ni(<..:0}4 WlUl the ligand L (L
P(OMc:)>)i't ::p:;; ｾ＠ Ni(CO)). ｾ＠ {f PMc 1 or P(Ohk);) yields Ni(CO)JL. The tt:K':lion
{/i; J!fulib·lH ｉｾ＠

L a.c:soc ｩ｡ｾｶ･＠
]. f{(!!;T,"Ii f/'!JI<' ｣Ｎｾ＿＠ l l
dｩｾｓｉＩｃｄｊ＠ \'('
2. ＮＨＫＺＴｾ＠ JP.JiR ｾｩｴ＠ #I J. i111en:Jmnge (I,)
3. l?JF4"'t·:J ｻｉｾＩ＠ JTr"fiTOf zm t 4. in1crch:mge ＨｉｾＩ＠
4. (iJMJP.!{Id);;q;r;' <rft Ｍｾ＠
31.J\S a ligand Cl is

L only a c;·dtmor
l. ｾ＠ r:;-r:mr g: 2. only a :1!-dt)JlOr
2. ｦＬＧｬ＼Ｗｯ｣Ｍｾ＠［ t l 3. bnth a o::r-donor and a n-don<)r
3. ｯＭｲＺｾＷ＠ 7i-r:rrJJ ｾ＠ t 4. " ('Hi<)nor ＼ｾｮ､＠ ＼ｾ＠ ＱｨＺＧｉｃｾ･ｲｯ＠
4. ｾ［ＧＡ＠ a ?:1<rr m;; 11 !lrtr t.
32. <rtr d-:rf!«.f;.r lCJ'-'•''"f i.of/ ｦｬＴﾷｴＭｃＳｾｲＮ｣Ｚ＠ ＧｊＢｾ＠ 32. Til'"' ;;orrt'l:l ､ＭＮＺｬｾ｣ｲｵｮ＠ i.:fJrLliguration ｳｨｯｷｩｮｾ＠
"'t ,;r.fm 1'1. om f. l ｳｰｩｲｈ｢ｾ＠ coupling is

I. b/c/ 1.
,,
lzr." C;;z '
eo l ,, . ,,
2. th,6 ｾ＠
J.c, if I:;:-;

3. ｴｺｾ Ｔ＠ (:I)
ｾ＠
3. b;•
4. !2/ Ct 2 4. h/-te
1

33. ｦｾ＠ ;J.•fWli'f (RLi) .:Cjrfu"'"'"" !4'7t 'ff?i!I=f

ｾ＼ｲＺｦＮｊ＠ <f. f.:w. mft <Pf!."'f if I JJ. The corrcd ｳｴ｡ｾｭ｣ｮ＠ fm Ｑｨｾ＠ :aggrcg;;tting natun: d
alkyl llrhimn (Rl.i) ｲｾＦｧ｣ｮＱ＠ is
1. <{t{i'F'f Tt ｾＮＧｔｊｒ＠ ＼ｦｬｨｲｩＭｾｉｊ＠ ｾｲｭｴ＠
!h..: carb<u!iunnudt"uph!licity increases
# I
with 2%'Tcgalion.
2. Ｂｔｦｾｲ［ｩｬ｛ＧｭＦ＠ the observed ag:,'l'egallon mi:sl's from ｩｴｾ＠
P<frt I clC"etron dcficiciH nature.
3. m:hi."7TWJ #1 ｾＭ＠ ;<fF.f/;7 1 IJ<' 3_ carbanion nudoophi!icity ､ｏ＼ｾ＾＠ r\(J[
'71ft Ｌｾｦ＿＠ 'lR:fit # I ､｣ｰＮｾｬ＠ on <lggr<:g<l1ion.
4. ｾ＠ <rr 'll'i"'r'li' f;}rcf/l< <::m;• .'7R'flu.1f>l' •l' 4. the Mtcnt of af<g><:gation ｾ＠ ｭｾｸ＠ i mum ill
［ｳ＼ｾｦｩｬｴＭ JJ}a,· g ,. polar darlv.;: soh·r:ncs.

34 . .ｊｻｾｦＤＷＱＡ＠ fN.I!lS· (lrCI(CO)(PPhJ)2] ..:. Cl2 34. f.()r the rc<Jctran, tmm-[ [r(:l(CO)(PPh 1),] ＨＧｉｾ＠ -
-+ lra!JS·[hCI;(CO)(PPh,)!J, # ffrl ;rr,:fj tra•tl·[lrCJ 1{CO)fPPi1 1):l, the com:ct observatmn
r:r#.?.,-vr ,it Ｑｾ＠

I. Yeo (iJftmj > vm ＨＮ［ＬＧｦｬｾ＠ 1. "co {pro<luct} > ｖＨ､ｲ･ｾ｣Ｚｴ｡ｬＩ＠

2. vco(produc:t} < Vc(f(reactantj
2. Vco(iJ<r:rr.:) < vco ＨﾷＳＯｐｾ＠
''<'·(, (pruduc!} = v,(, (reactant)
3. vco ( ｩｊｆＧｉｔｾＩ＠ = Vm ( ＧＳＯｾｩｬ＾Ｌ＼ｦｽ＠ 4, V(<J(prnduct} ｾ＠ ｶｾｵ＠ (free CO)
4. Y('o ( ;;;r;rn:) vco ('J'lff CO)

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35. ［ｹＨｾＧｦ＠ w ｾ＠ ｾ［ｦＯｲｯ＠ if. ｾｴｦｬｲＮ［＠ Rift 35. ll1c nucelot\llilk attad:. on oldin.s under mild
3lr;pp;J eonditi{Jn.s

L <riiJ i!fiNf iftm" t f I. ｩｾ＠ always facile

2. ＠ｾ w ＠ｾ Ftt,t ｾ＠ ;ffl"
:!. is more facile than ･ｬｾｴｯｰｨｩ｣＠ ｡ｴｦｩ＾ｾＺｫ＠ on
Ji'fferr ｾ＠ ffl.(U1 imr ｾ＠ f clefi.ns
3. is facile ｦｬｊｲ｣ｾｴｯｮＭｫｨ＠
J_ ｾＭｐＱ＠ ｊｩＧ｡ＮｦｬＢ＾ｾ＠ .. r"' Of!ij1 titoJ t 1
4.
olefim
re>quire.s acti\'a!ion by coordination to
4. <# ｾ＠ mg :it ｾ＠ ｩＳＱｊｦＡｾｖｉＧｴ＠ iJNf metal
wfim;rrr ｾ＠ f I

36. ｾ＠ # \'! ｾ＠ ｾｎＱＵＢ＠ W'hl; if 1 :36. Among the following the strongest ｯＮｾｩ､ｺｮｧ＠
:;1gent is
I. (W04] 1- 2. ｛ｃｲｯｾｦＭ
L ｲｷｯｾＩ Ｒ
Ｂ＠ 2. ＨｃｲＰＴ｝ｾＭ
3. Ｈｍｯｏｾｦﾷ＠ 4. ｛ｒ｣ｯｾｲＧ＠
3. (Moo4t 4. [Rco4rt
37. f.p.;f#rfiJw IT it ｾ＠ t:711'm t 1 37. The least basic among lhc f{>llowiug is

L Al(OH)3 2. La(OHh I. Al(OH)J l. La(OHh

3. Ce{OH), 4. Lu(OH)J 3. Cc(OH)1 4. Lu(OH) 3

38. F[o'ff #E/irtlll A ?ff:li ｾ＠ <iMr.T At ;it f&rl 38. For any operator A aoo its adjtlint At, the
Jfi'RW 11i'2Ff # l t:NCORRECT SliU<-"Jllenl is

I. A At r:fif;!t t I 1. A A' is hermitian

2. AAt+ AtA ｾｴ＠ 2. A A'+ A 1AishennitLa.n
I
3. A + A1 is hcrmi!i:m
3. A +A' z#:tt t 1
4. A - A 1 ｌｾ＠ hermitian
4. A -At ｾｴ＠ I

39. "11fint11.1 Jim Z, lf} ｾＺＮ｜Ｇｫｬ＠ ;;:if;f; ｾ＠ <t 39. ror hydrogen-like atom ｷｩｴｨｾ＠ ｮｵ｣ｬｾＮ｡ｲ＠ charge Z,
#rr. F <wF<:'f <t<l:lJt , o, ,'i(f/kN <tt m the energy of orbilai wilh principal quantum
iJi\i1f fiJm #1f'£l w ｊｯｾ＠ iR<ft t!. ?if t i number 'n' follows the relation

rr r.a::.--
ｺｾ＠ z:z
l. E,<t:: ｮｾｚ Ｑ＠
2. L E, <t: n'Z' 2. ｅＬｾ＠
n n
z zl z
E.<>=--;;- zz
3. En <.(:-- 4. l:l oc-- l, 4. E n
ｾＭ
n:!
n • t\:2

ＴＰＮｾﾢｴｬｳｩｦＡｲＺｎｉｊＧ＠ 40, The avcrag<:: value of me radius <r> in the ls

J/m:rr 'IN <r> f. {<to f. <it? f:w<d} I s.tale of the hydrogen ｾｴｯｭ＠ is (iiQ is Boor rodius)

2. 1.5 a.o 1. a,, 2. 1.5 ｾＧＢ＠

3. 0.75 a.o 4. 0.5 a.:. ), 0.75 ..., 4. 0.5a.;,

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41. AJl'Ji)ll£ tllc follo·.ving, the CORRECT sta!cmcnl

is

smj:r::t1:JJ .fit;pif''..'i),. ｱＮＺＭｾ＠ ｴｦｾＧｙｈ＠ ｒｾﾷｬ［Ｌｩ＠ 'ft;:;;lJ7 l. The number ,-,f itTcdm:iole rc'J)resenw.l ions
Ｑｾ＠ ;'prY cf (JT{R i'[;t;1l ,\' I JS cq;wl ｾ｣＠ ､ｾＭ＠ of s:.mmctry opemlions.
2. "'"({::::iz;4J:!l ｦＮ［ｬｊ､ｴＢｶｾﾷ＠ .Wf ｮｾｦＺＮｷ＠ ｾＧｩ Ｑ ＡｦｊＧｲｔ＠ Ｍｾ＠ The number of im:·duciblc rcprc.,cntation.s
H?/f ｾ［ｽ＠ (/J:•/2 rl ｾＧＱｲｦＷ＠ #' J ｾ＠ is ｾｬ｛ｌＧＡｩ＠ !O lhc ＼Ｉｲ､Ｎ｣ｯｦｬｨｾ＠ symnMry P<)lll(
J. j9f.;:;f) ｾＺ＠ t!N!(IJ{;J t"floTJ "fr1/F if ﾷＳＭｴｲＺＮｦｾＬｊ＠ group
fr1if."i'-! ｾ＠ ;:;rr.: ·3/il;.';...;l 6'f(t .-; 3. The irreducible ＧｐｲｌＭｳｾｮｴＺｩｯ＠ ｗｬｴ＼ｊＮｩｮｾ［Ｚ､＠
4. '-'"·' fl•;·fl1,fit ｾ＠ 7 ｾ＼ﾷＡ＠ ;;orlfiidht in ｾｮＺ＠ point f;T(liJ]l :are J lw;;,ys of ｯｮｾ＠
［｟ｩｽｯＡＺｎｾ＠ ｾ＠ ;;;;:_..,l:f ｾﾷｪＮ［Ｌ＠ t , 1 dirncnsion
4. A ｾｹｲｮｭ･ｴ＠ poim b'J"OUJ) may nc.t contain a
K>t•1lly symmetric incductbk ｲ｣ｰＱｬＧＹｾＮｮｴ｡ｩ＼Ｉ＠
42. ＯｽＡＢＧﾷＺｾ＠ &:'JAB ［ｾ＠ J =0 rf J 1 -7i<R•m
42. ror ｾ＠ ､ｩ｡ｴｯｲｮｾ＠
mole<:ule AB, the ｾｮｲＡＬＧＩ＠ tor ｴｬｾ＠
•1 ｾ＠ iilfl ;r.;;ff ｾ＠ ｾＮＧＩ＠ em 1 .I 1 3 l'l
ro ｬｾｴｩｯ｡＠ ｴｲ［Ｉｮｾｩｬｯ＠
from J 0 10 J - I sl.me is
J.<j cnf'. ·Jhc cn<'<b'Y fnr lhc w101ional ｴｲ｡ｮｾｩｯ＠

1
fr<)m J = 3 to J = 4 state would be
7.S em
4. I. 3.9
3. 1J. 7 cnf'

4J. ｾｴＭＮｦ｛＠ ｬｩｴｾ＠ ,J,ttrj l}} .;;..T.f(<iq; ':(If ..1'

ﾫｦｱＬｾﾷＧｬ＠ a; f?!'\' ｾ･ﾷＱｔ＠ ｾ＠ <t ｾＭＢＧｦｆｩｲ＠ 43. For the ••ibr<ltiCIJlill Raman ｾｰｴＮＧ＼Ｚｲｵｭ＠ of a
ｨｯｭｮｵ｣ｬｾ｡ｲ＠ dtatomic ｭｯｬｾ｣ｵ･Ｎ＠ the sdection
ｾ＠ f<Wif i} l
mle under ium1onic approximatinn is
ＮＺＧ｜ｶ］ｏﾷｾ＠
l. ｾＬＮ＠ 0 Dnly 2. ,\v = ±l onl;•
:i ..•\\' 1m 4. Llv 0.±1 3. /w=±2only 4. Llv- 0, 11

44. fi.W <m! W >h;r ｊｩＧｦｲｾ＠ # ,ft;p:; ,'r,m ']'Nf 44. With incre;ls.o;: in temperature, the G1bbs free
(.f:J ·:.rtf ｦｬｾＧ＠ ,·f; fl.;:{ :fi ?tPA ｾｮ＼Ｂｲｧｹ＠ f<)r the adsNpl ion of a gas on to a solid
stlrl:u:c
l. ｩｾ＠ TfR rt &7i.'7F «""ff<'W'' r.r! w1<fl ill
1. bo:c-<>tll¢S mor<;: ＼＾Ｍｾｩｬ＠ｰ vc from a po:siti ve value
2. FI-TitTfrJi J{Ff ｦｾ＠ ［Ｚ｟ＭｴＮｩＯｅｾｊＧ＠ ｾｴ＠ ｬｾ Ｑ ｴ［Ｇｦｐ＠Ｈ r,;t tifJ·;fl (! J
2. bt'rumes mor<: nt'galive from a posiCive Ｇｾ｝＠
3, ﾷＺｦｴＢＷｬｾＧｩ＠ ｾﾷｬＮｯｴ＠ ·if :_:.,rla21i ｕＧｬｾ＠ 1ft :;;mft tI 3. ｢･｣ｯｭｾ＠ more ｰｯＮｾｩｴ＠ ｜Ｇｾ＠ from a ｮｾｧ｡ｬｩｶ＠ "alue
4. ;;,./,?i"M TfR 'It Ji7Y.R/; ｾ＠ ;jt ;;m# ｾｉ＠ 4. beeorn<:s more negmive from a oogative v,1luc

45. W< -;p; ｲｾｬ＠ <rfT ｾ＠ oR fa; fir.;; <<Fi il IJ/'1 45. The vapour of ;l pure subsl;lno::c. when ｾ＼ＩＨｫ､＠
ｲＺｔｦ［ｮｶｴＢｩＧｪＩＨｾ＠ ·. under a ｰｲｴ｣ＧｓＮｵｾＺ＠ less Lhan its LJ iple-poiJJC
pressure.
l. J:f:trr if >m& f. I
2. ｾ＠ ＠ｾ M Jtt< Pmr :am -r, ｾ＠ 1. ligucfic-s
it vmfl # I 2. ligucfic-s tlrst and then ｾｯｬｩ＼ｊｦ｣ｳ＠
3. ｾ＠ oTH Ｎｾｩ＠ vlfcft .tt 3. solidifies ､ｩｲｾ｣Ｇｃｬ＠ y
4. remaim unchanged
4. ｾＧｭｩｴ＠ I

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 15

46. ,(Jlb'Tr ｾｴｩｭ＠ ｾＬｲＯ＠ <d f-*ltrm ml 46.The ｧｵ｡ｮｴＱ･ｾＬ＠ whk:h are held fixed in a
vrrm ft ｾﾷ＠ € ' c.anonical ensemble arc

L N, T i:IWI p 2. V, T rl'!i!!r N I, N, Tand P 2. V, T andN

3. N, V m/J E 4. ｾＭ v ｃｾ･Ｎｩ＠ p J. N, VandE 4. [.-1., V ancl P

47.firt:.'rf..-'11Gr.r E ｶｾ＠ Ａｵｾ＠ m ＨｾｦｬＩ＠ .Jflf(Jl ,:;· 47. The corrccl value ofE ' oh half cell in the
0

>Jnl;fm ;t f!:rt! E')' w 'frl{:; 'iFf ff 1ollow[rag zraph orE V!; lvg ll1 (molality) is

11. ,. ..,.-
ｾ＠
,_. ..r---
ｬｯｾ＠
{ rn
..-;C

:c·
.: "

ｬｯｾ＠ m
o· c

!. CC'/AC' 2. AB'
L CC'/AC' 2. AB'
3. BB' 4. CC'
3. BB' 4. CC'

48. ｾ＠ ｾ＠ ;ffrl;ft f;tf.r,r:(f 1/i} ｾｩｦ＠ 48. One ofthe assumptions made in the conventional
ifV'l'tl - acti ｾ｡＠ ted ron1pl.:x tllOO[)· is

I. equilibrium is maintained bctwcrn the

l. ｊ､Ｂｾ＠ miT mf1;ftm ｾ＠ i5 lfut wrs:a rc:£.rtants and the ｡｣ｬｩｶｾｴＮ［､＠ ｾｑｉｕｦＩ＠ ｬｾｘ＠
ｾ＠ V!iff If I
1. equilibrium ls maimaincd betw-et'llthc
2. ｊｪｾ＠ .siR ｾ＠ "¢ lj!.."7 ｾ＠ '.fl!trfi:t/1
ｲ･ｾ｣ｴ｡ｮｳ＠ and the produ-cts
ｾｴｬ＠
J. equilibrium is mailll:aincd between tlle
3. ffi'lR'f fff!:ff ｾｦｲＺｭ＠ <f"it«'f ＼ｩｾ＠ >r,?.T = products and the activated romptex
'f'!,i/im T'lf?fl ft I ｾ＠ 'I. equilibrium is maintained between the
4. ｾｦＬ＠ if/fjpfk'J'i:f '<i!JFf vrt ｾ＠ 15 reactants, the act ivated complex and the
'rr<i "fflT<[ e:e."'Tfitrf '{8fi/ t l produc!S
ＴＹＮＱＧ｛ｯｆｾｬ＼＠ l'i:w'1:7°C ｷｺｹｾ＠ t 49. E'or a ｲ･｡｣ｾｩｯｮＬ＠ the rate ronstam k at 27 °C was
k """ 5.4 X 1011 ･ﾷｙＮｾ＠ I found to be:
ｾ｡ｦｴ＠ ｏｊ［ｗｾｉ＠ k = 5.4 xiOu ｣ﾷｾｊＮ＠
The activation ･ｮｾｲｧｹ＠ of ｴｨｾ＠ reaction is
l. 50 1 mot·' 2. 415 J mor 1
I. .S.0Jmor 1 2. 415Jmor 1
3. 15,000 J mor' 4. 125,000 J mor'
3. 15,000 J mor 1 4. 125,000 J mol' 1

50. Duriil);l. the aJditkm [X•Iymcrisation, the reacttQn

proceeds via
I. ｷＮｲｦｴｾｗ＠ t
I. stcp-gm,.,<th pnxcss
2. ']'Rf-'Jfl'5 ｾＣｉ＠
2. frce·radlcat chain ｲ･｡｣ｾｩｯｮ＠
3. 'fitriJ;ft JriiPl <i r 3. cascade process
4. ＣｦＬＭ［Ｎｲｾ＠ i't I 4. :!:ddition reaction

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5L mrr-rr it ｾ＠ ｾＧｦＬＢｩｬＮ＠ ;)' ｻＺＩｲＬＱｾ＠ TH'1!Yj 51. How many atoms are there in lin ､ｲｭｾｮｴ＠ packed
_. in aji::c slr\u::ture
Ｍｾ＠

2. 2 ]. 2. 2
1.
4. 8
), 4 4. 8
3. 4

ＵＲＬＮｪＨｾＺﾷ＠ ＧＡＱｾ＠ q!; ;:rp;-7 ｾｴＮＺ｛＠ ｴ［ｊｾＮＬ＠ $ ［ﾥＵｾ＠ 52. ll1e ［ｳｬｮｴｾＺｲ｣＠ Dbtained Ｇａ＼ｦｴｾｮ＠ all th<: ｴｾｲｳｨ｣､ｮｬ＠
t&;t tfi ;:.i{} fl\l"f/i•·f.' ＮｾＧｦＺｲＡ＠ [i)cl} ｴｾ＠ ｾ＠ ｾ＠ holes an; cx:cupied iH a _/(t· stmcturc is of Lhe
f. i)iJlC

1. NaCt 2, C;;.CI
1. NaCl 2. C£1
}, CaF, 4. ZllS
3. Cab ·t ZnS

53. ｄｩＺ［Ｎｰｾｮｯｊｬ＠ ｯｦｾ＠ sot id (n a liquid, a liquid in a ｧﾷｾｳ＠

a1::d a liquid ｩｮｾ＠ liquid ｾｲＮＺ＠ ｲｾｳｰ｣ｴｩｶ､ｹ＠ knl•wn ;<S

L ｾ｣Ｚｲｯ＠ ....:ll, emulsion, :;.ol

ｾｴＭＺｭ＠ rwm. ?ft::J 1. sol, 3erosol, emolsion
2. rffi(i, ｲｾｴＮＬｦｩＧｬ＼ＭＡ＠ r.[tl.r8 3. Cfll!Llsion, sol, aerosol
}_ ｾｲｎＢｐＮ＠ ?il'fr. ｾ＠ 4_ ｡ｾｲｯｳｬＬ＠ ｾｯｬＬ＠ emulsit)ll
4" ｾ＠ ｾ＠ rmTfl

54. ;;:i{rjj ,,l ;:ot i'k A 1W<I B ;({ J;•Nr ｾｬＮｲｴｦ［Ｚ＠ ;I; 54. Tilt' data obtained from two sets of ＼ＺｘｦＭＧｬＡｲｩｮＱｾ＠
f4J:ztlPrf&cl ｾｦｩｲ＿Ｎ･ｰ［Ａ＠ # 1
1 A olnd B have the fO.tlm.ving ｾｨ｡ｲＭｊＮ｣ｴ･ｩｳ＠

JPfTil A H E'.!pcriment A B
ＺｪｬｩＢｾＨ＠ 5() :;-<Ffj 100 ![<IJJt/
Mc;1;11 Sll ｵｮｩｬｾ＠ 100 units
41"fiF fi1WP7 2 ［ｲｾＷＮＺｬ＠ 2 ｩ［ｾﾷｬＯ＠ Sta:ndard ､ｾＧ＠ iation 2 units 21L1li[S

lt may be ｣ｯｮｬｵ､ｾ＠ that

I_ A .5(ffi·7i ｲＨｾＺｊ［Ｌ＠ t- B '1!/ :>/1Mf 1

l. :\is more pt\-><::ise Eb;1n B
2 A 'ifi7! ｾＣｂ＠ ;ffi'J/TMJ I 2_ Aisles:; precise than B
l ,\ Pff!lf B ｾＱ＠ ﾷｾＭｲ＠ vi'WI if 1 J _ A and B are of the silmc prccisirnt
Ｔｾ＠ A ｾＭｩＷ＠ B ilft ｩＡｦｬＢｴｾ＠ ｴＮＯﾷｨｾｲＦＭ［ｊｩ＠ rm ＬＺｴＩｾｯｊＮ［Ｇ｝＠ 4, ｲ･ｬｯＮｾｴｩ｣＠ pr¢Cision <)fA and R cannot he as:;.c.sscd
';ff;:'J. tli? fF!fl! !::-" l ·-

55. 'l11e !llPAC name of !he cDmpound boiven below is

A
ｾ＠
H'' COOEt
)(1-
H' COOEt

1.A

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 17

L ethyl ＨｒｽﾷＲｭ･ｴｨｹｬＭＴ＼ｊｸｯ｣Ａｮｾ＠ L
enecarboxylatc
2. ethyl (S)-2-mcthyl-4-oxocyclohe;.;-2- 2. ｾｨｹｬ＠ (St-2-mo::!hyl-4-<lX<)cycloh<:x-:!-
enecarboxylule em<t:arbox ;.ol3tC
3, (RH·ethoxycar!mn yl-3-rncthylcyc lo-
hcx- 2-cnone
4. ｻｓＩＭＴ･ｴｨｵｸｹｾ｡ｲｯｮｊＳｭｬ｣Ｈﾭ
hex-2-cnone en one

56.Thc mlljor pr•)duct iomtetl th:.: l(llluwing

ｮｾ｡ﾷＺ［､ｯ＠ is

Nal1, THF

Ｑｾ＠
ｬｾＭ］｜＠ 2.
...:Cj___j/ 1 2.
'-"

3 ｌｦｾｲＩ＠ 4. ＨｾｲＭ＼ＧＬ＠ . ;/'

ｾ｟ＯＭＺ＠ ..;:;...- --:1
4.

57. 'l'ft;if-"'liR '{ti ＼［ｾ＠

57- The uumber ｴｨ［ｾ＠ ［ﾷＬｰＨｾｲ＠ ｾｨﾷＮＺ＠ ｢ｭＮＺｾ､Ｍ
llc NMR ｾ＠ i'J r;rq,·t
txmd ､ｾＭ｣ｯｵｰｬ＠ 1\ ｾＭＱｒ＠ >-pc1.:tnm1 of
TfWT '!. ;;nrm· ［ｨ･ｮｾｭＱｲｵ＼Ｚ＠ and Ｓｮｬｨｭｾ｣Ｌ＠ n::'-P(,Cll•;dy. :trt'

2. 2. rc11 a!l:l

4.

58. c;;rrr ;;(;<,<; lit u,'<l-'i11ff'r'<'lr it ｦｬＺＳｲｾﾷＮ･［＠ ",;'; 5S. The ｃＨｬＭｾｮＺ［Ｌｹｴ＼Ｇ＠ ｴｨｾ＠ ts im·olvc:d !n th•.: Ｌﾷｾｴｬｵｭ＠
::.r'f'JZ:'r lt •;rr #. "lfE'!7 ＾ｲＮＭＺＬ［Ｇｾ＿＠ 'I !I <'Jf ;1 dn1:bk" bond m acid ｢｝ｬＮ｜Ｚｾｹｺｮｨ･［ｩｳ＠ !s

L NADH l, N;\DII
3,

59. (R}- ＧＱＡＺＴＰＭＮｲｩＬｊｦｴﾷｬ［Ｂｾｭ＠ ｯｲｾ＠ rm'(<"'f.'."!i,'i ｾＢ＠ 59. £:poxidati<•n nf I,Rj-cycluhex-2-c:nol with
??' ?f)o:.:t rrv zl!fi'r4if 1\ ＨＯｾｶＬｲ＠ U .;f;! pcr.nccri-t atid yidds s ｾｊＵＺ＠ ｮＱｴｸｾｷ｣＠
95:5
A rmt U
YfQJffl1rlfY:TIJ
* ;} /i'r!;'Oj' ｾ＠ F:ftiTT ;f ! <frfl'py, (,(>ntiJ'-'Lmds A and R ｃＩｊｬＺｇｵｮ､ｾ＠
a.:rr
A :m.J B

｣ｮ｡ｴｩｭＺＭｦｾ＠
!. ｾｩｦＧｴＺＳＡＮｬ＼＠
2. di:;.,srcrc(miets.
2* ;j{J.'rf2JPitJ) f;;{;)1f ｾ＠
3, "C()I1:,1ltution:::.] ｩｳｯｲ｡ｾｦＤ＠
ｾｴ＠ ＿ｩｴＭＺｾｲｮ＠ ｾ＠ 4 ｾ＠ hfltll0t11Cf.:;.
4' ;;r;rm->fi

S/7 RD!12-1AH-2A

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 18

60. ｦｾＺＮＦｊｬ［ｲＯｩＧＬ＠ ｦｾＮｩＧＺｴＡｬｊｯ＠ Ｚ＿ｻＱＹＡｬｊｾＷ＠ U Tht; ｬｾＩｴｲ＠ prnrll\Ct torrno::J in Ｑｨｾ＠ fo llc>'Nit:f!
f! ＡＲｩＮＭＩｊＱｃｲＨｾ､＠ ::'t::-::1Ct10n i::s
ｩＧＨｾｊ＠ ｾ［＠ l

, ___
c. ,_

2,

61. ｾ＠ ｾ＠ * ri'rNm. Yf! ｾＮｦ･＠ ＾･ｲ＼ｓＣｴＬﾷｮｾ＠ 61 , The struclurG of ｭＮＺｬﾷｵＭｩＱｾｲｴ＾ｯｸｹ｣＠ acid thai ｩｾ＠
it ｾ＠ meso- f:tff ｾＩｩ＠ ｾＢＡｔ＼Ｇｩ＠ ;f,t onNr formed on potassium ｾｭｬｮｧ｡ｴ＠ oxid:;;cicm of
f. . "bictk an;,l i$

ｾＬｃｏｈ＠
r-\···-·COOH
\ ...COOH I \ \ ·:-.........-.cooH
__:\COOH /- \ 1' ｜ｾＮ｟ｃｏｈ＠
2.
1. ( ,:-cooH 2. (\ ＺｾＮｃｏｊｦｩ＠
. ___/cooH
'··-;'\,
/ COOH
ｾｦｴｯｈ＠ J COOH
ｾ＠

.,; COOH ,.-:.._.,......,.cooH

'· COOH
Ｍｾ＠ I \

Ｐｾｃｏｈ＠
4.
3. ｾＭ 3. \,
..._,..ｾｃｏｈ＠ ｜ＮｾＭＧ COOH
ＯﾷＺＮＬｾ＠ •. •..i'tr, 1\:oOH "COOH

62. 'The major product ｦｯｲｮｾｬ＠ in the: tol!owing

Tcaction I>

(), ｾＭ
ｂｲｾＮ＠ McOH

'o

C'OXBr Ｏｾｂｲ＠ 1.
('::C8r z.
｣ｾ＠ .....,....Br
L Br 2.
L..,o ··oMe 'o Br
..._O).''OMe
(-,__ＮＬｯｍｾ＠
_..........___...oMe ,. . -. 0M(\ I ·:=rOMe
3 l ｾ＠ 4. ['·o-·'1' '
'-'Bl'
:J.
'o Br
4.
. . . o.J.·.·ar
0 Br

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 19

ＶＳＮｦｲｾ＾ﾥＧｩｆｉＷＢＡｊ＼ｗＣ＠ 1 63. The major pro<luct formed in the following

rc;action is

cb H
1. ｃｆＳｾｈ＠
2. ｴｩＳＰｾ＠
cb H
1. CF:sCOV"J
2.Hso• -
H H

1'
ct> H
2. Q)
H
1.
ct>
H

H
2.
H

Q)
&
H
H

E() (;:')
v
H
3.

H
4.
3.

H
4.
C;J
64. ｦＮＧＯＱｾ＠ if if ::it ｾ＠
64. Among the foltowing, lhc synthetic equivalent
ｗｊＡｦｾｎ＠ 'i>1 ｾ＠
fFl #, <li JJ I
fur acyl anioo is

l. nii:J'oelhanc and base

I. ＢｦＯＦｬｾﾫＧ［＠ <im ｾＱＷ＿＠
2. Ct·cllloroacrylonitri lc
2. ｴＭｾ＠ｃ 3. cthylmagnesium bromide
3. ＧｒｲＡｾｬ＿＠｜ 4. acetyl chloride and ｬｲｩ･ｹｫｵｮｾ＠
4. tWrf'it<>r ＼ｉｦｾ＠ qp.;r ［ｰｾ＠ ｾ＠

tj5, lO% Pd''C '1ft 'J'f{f;.:ifrt if orNf'L'ft rl ｾ＠ 65. Among the ｦＨ［ｬｾｷｩｮｧＬ＠ !h..: compound ｴｨ＼ｾ＠
ｾＬｔ＼ｦ［Ｎ＠ ｴｾｦＮＡＧｩｔ＠ # ｾ＠ JP(J(FRf'T ｾ＠ Wldcrgocs deprolection cnsily on trcatm(;n( wilh
R1'.1H 2 ?•t><if<"fi it 'f"ffl1 t, Ｇｬｾｲ＠ :t/ffirq; t. 1 lt)'drogen in the presence of !0% 1\l/C to generate
RNH1 is

0
2. R .. ｎｊｬＧｯﾷｾＭｰ＠
H

0
J. ｒＮｎｊｬＢＭｾｮ＠ ｾﾭ
H

66. ａｾ＠ (flfh) J.i'<oit >7 ｾ＠ ｾﾷＭｲｴｯ＠ Ili1jFrr 66. Among lite fol!uwing, ｴｨｾ＠ ::unino acid which ｬｾ＠
t!, ｾＡＮｉ＠ bil$ic in nature is

2. ｾｲＮ＠ I}'roSine 2., ｩｴＺ［ｰｾｈｧｭ･＠

J. ｾＨ＠ 4. srtf.:;/f.r.r 3. leucine 4. argimnc

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 20

L Tt -'; ｳｾ＠ hv
.. , I -) 81.1 ,:,
.. 't
ｳｾ＠ ｾ＠
Ｓｾ＠ ｳｾ＠
ｾｉ｟［Ｌ＠ T, ｾＮＬ｜＠
··: -· '

COOH
r·-·cooH
; COOH
'1,
4. /
\--COOH

?jV".3-?l ＶＹｾ＠ Tf:.:: rn::1j•_;·f ｰ｣ｄ､ｵｾＮＺｌ＠ f(umcd )n ｾｨ＼Ｚ＠ ｦＨＩｽｬｯｾｶｩｮ＠

ｔｬＧＮｾＺＬ｣［ｩｭ＠ ［ＭｾＮＺｱｊｯｴｬ･＠ is
1
ti :iq NH3. BL0H
.. ｾＭＪＧﾷ ｾＭ

2. m-GP61\

1 2

40(: VII:.: 'H N1>.!R ｳｰｾ［ＬｵｭＮ＠

LJ;;; z.n •''g.tmc
ｴＺｶｭｾＧｏｵｮ､＠ ｣ｾｨｩ｢ｬｴ､＠ 8 do•,1bkt Tht' 1wo ｬｾＮＬＺｳ＠ of
chc dt>othlet are ;!! 6 2. :b ;tnd 2.38 r:pm. ·fh..:
t-':"!'!tphng ＨＺＰＱｾＡ［ｬｩ＠ (f) 'l'atue is

"! fh:
,) ll><
'IlL-:
j ｦｌｾ＠

'··

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 21

c Wlf/PARTC)

1. si-o > r-o > ｳｾｯ＠ > ct-o 2. P-0 > Si-Q > S--Q > Cl-0
:>. S--0 > ｃｬｾﾷｏ＠ > !'-0 Si-0 ·l. Cl 0 S 0 > P' 0 > Si 0

L Si-0> ｐＭｾ＠ o:.,s 0 -··CI 0 2. l'----0 > Si---0 > S-0 > Ct·-CI
3. S --0 ;· Cl- -0 Ｚｾ＠ P --{) '>i-0 4. Cl-- 0 > S--0 :c· l'-0 > S!-0

Zn(NH1 .) 1 1 ｋｎｉｾ＠ - ｋＺ｛ｚＮｮＨｎｉｾＩ［｝＠

K 1fZn(NH 2}4J- 2 ｾｉＮｎｏｬ＠ ｚｮｾｈ Ｒ ｨＭ 2 KNV;- ,j Ni-h

4.

it. ｬＺｨｾ＠ followin;.t re;Icttnll-5 Ｇｾ［ｬｲｩｺＱｴｽＺ＠ in liquid Nl-lt.

I 2 KNfJ, • KjZn(Nl!1l,J
" 2 NH,'-:OJ --• 7.n{l\[ 11}1 • 2 KNC1'3 .-1 NH 1

13.

Lu,Gd Eu. Yb 3. Dy, \'b

73. th iTd ion iz.atkm energy

1. Eu,Gd Eu. Yil 1. [Jy, YIJ

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 22

4, Lu{lll)
Lo([Jl) 2. Eu(!H) -'·' Nd(Hl)

14. Tit{; bnth.miuoe(lll) ton havmg the ｨｩｧｾｳｴ＠ partition cocfficirmt ｾｴｷ･ｮ＠ tri-n-hutylJlhosphate am!
ｾｯｮ｣ｬｲＮｫ､＠ H"NO, ｩｾ＠

!;)(! [1) 2. Eu(lil) J. Nd{Ili) 4_ Lu([][)

• Kz + KCl + !Cl ' 3Hz0

Ｚ［ＮＭｾ＠ Ｍｾ＠ G<:;•r:t f

l'
2.
i'-:J1.itt ｾ＠
!(I$ .RmF& I
ｾ＠ ｾ＠ * i

ｾＮ＠ CCl, ｾ＠Ｍ 'Wr' ｲｾＢｃｬＬ＠ 'f-f'l'"' ｾ＼Ｇｈ＠ •Jlc? ,·,.r ｾ＠ J.'i]if'J Ｎｾ＿Ｌ＠ i
4. CCL ::.rf? ;·I'll"' ｾＭ h ＺＮｦ［ﾷｾｯＬｲ＠ Ｎｾﾷ＠ ｾ＠ ifrr ＮＺ［Ｌｾ＠ ｾＺ［ｻＭＬＮ＠ r.?,'t if :

\' 1 !!, * KlO, •· 2f!C'I -• >Jz + KCi + l(:[ + 3lh0

lh<: ＼Ｚｾﾷｰｯｩｮｴ＠ !(>r tho:: titrim,tnc ｲ･｡ｾ［＠ ion i.s

I. ｾﾷｮＺ［ｭｰｬｩｯ＠ GfN,H.
2. lCI fQrtn<Htun
3. ｵｩｳＺＱｰＭ･Ｌｲｾｮ＠ ｯｦｴｨｾ＠ yellow co!or due t(o ｃＡｾ＠ in CCL, hl)'er
-t ､ｩｳ［ｊｰﾷｾＮｲｭＺ｣＠ ｯｾＭ the red cc•lor dlte to 11 in CCI, layer

1. A 'ftnB 2- 3. B m"..rrC 4. A, B qr;n(;

76. An}::mg !hi!' ｩﾷｵｨ､ｾＮｳ＠ :--'ClJ (/\}, PCI,; (B) and A>.Cl> (C), !hose which produce lwo ､ｩｴＱｾ･ｮ＠ ｡､Ｎｾ＠
up<>n ｨｹ､ｭｬｽＧ＾ｾ＠ arc

L BandC 4. li.,B andC

I. ｾｔＬ＠ ;.--NI-l,-'' ｬｾＺｏ＠ 2. NHc.>::-.lF, >H10

.'1. H!O > l"T!l > Nf'3 4. H"O ::- NF1 > 1'<1-1 3

77. Tiw deere as ing ordr!'r of dtpoll!' m()ment of molec; ule.s is

L NF1 > NH_, > H.,O 2. Nl!> > ;;..:F, > !1;0
3. ｈｾｏ＠ :-NI-h::· NF, 4. HlO > NI', > NH,

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 23

I. 2. 4.

78. The ｣ｬｵｾｴ･ｲ＠ havmg amdmo ｬＮｹｰｾ＠ Ｎｳｾｮｴ｣ｭ［＠ is

L 2. 3. 4.

79. ｬＨｲＯＭｃｾｉ Ｕ ｽＱＭｴＮｨＨｃｏＩＡｊ＠ (1"'-'Rh, "lfli3::T? {.f:M T= 'li, I qi "C N:VIR ｾＧｉ＠ -if 'IWIIA<i ＺｕｪＭｦｾ＠ -65 "C
"" ｾＭＧｦＡ＠ f!:ri!li zt rn i!. t:Jr:iRfl IT'fftri.1f'r t iFiR"T JRfilf?r ｾ＠ f. I
lift'

ｾ＠
2. .), 4.

10
79, The carbonyl r<:."S.Onance in 1)C NM.R spcctr\ml of ((11' -{\1-I,)Rh{CO)h ( ;Rh, nuclear spin, I = 7>.
l 00%) s.hcrws a triplet ｡ｴｾ＠ 65 <cowing 10 1hc pres cncc of

1. 1erminal CO 2. 3. 4.

1. Ｇ｣ｹｾ［＾ｩｽｍ＿Ｚｭｦｲ＠ f
2. ｬｴＨｪｦ［｛ｩＡｯＢＩＮﾥｾ＠ . . ;ftf. I
3. ;;;rg mrr ;:;q.; ｾｲＮＺｩﾷ＾ｮｴｬ＠ :crt,t tt 1
4. "'f! ｓｉｊＴＧｬｴｩｾ＾Ｂ＿ｖ＠ ﾷｾ＠ jt #fpr ｾ＠ ft .'f?}I?:(.FI ＰＲｬ＾ﾷｾ＠ 'lt!Y <i'lf Jt 'R l:l10 ;ft;.t JT-<:7i17 J/'!j jt fffl'f
.J!JIPfR 'Tfff •VI''fft f I

!10. Low oxidation smle complexes are often ｡ｩｲﾷｳ･ｮｾｴｶＬ＠ bill ar<: ra:rdy water s<:nsiti,·e because

L air is reducing in ｲｵｾｴ･＠ while water is ｩｮｾｲｴ＠

2. both air and watcr are oxidizing in. nature
3. ooth air and water are not ［ＢＧＭ｡ｾＮ｣ｰｴｯｲｳ＠
4. complexes with low oxitlatio-n slates will easily lose ･ｬ｣ｴｲｯｮｾ＠ to 0 1 but vnll not bind to a ':'l·
donor molecule like H20

1. mt'r-[IrCh(PPih)l) 2. /mns-[l£l(CO)(PI'hlh)
3. fiic-[hCh(l'Ph,)}] 4. ＨｉｲｻｐＧｨｾＩＬｊ＠

1
8t The: metal complex ｴｨｾ＠ exhibits 11 criplet as well as a doublet in its J P NMR spectru111 i.s

i. mer-[lrC!ll'l'hJ)l] 2. tnm.s-[IrCl(CO){PPh;)2)
3. foc-(lrCh(PPnJ:hl 4. ( lr(PPn3).r

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 24

82.

2. I\V(COh(SiMc})(CJ)(NCM('hl
4. ｻｏｳＨｎＩｂｲ Ｑ ＨｐｴＭＮﾷｦ･ＺＬＩＧＱｍｾ｝＠

I. 2. ｛ｗＨｃｏｍｓｩｌＧｊＩｬｽｾｔ｝＠

.1. 4. [Os{1'\)Br2(PMcJ)(NMe.)r

R.3.

2. 3. 4.

S3. Th•: nw:::tn:r or· 'PiiHillo•Nc-d ligand f\d:;l ｴｲ｡ｮｾｬｵＺｭｳ＠ for ｯ｣Ｎｴ｡ｬＺｾｩｲ＠ Ni(H) ｣ｯｭｰｬ･ｸｾｳ＠ with
g, O'.l nd s ＡｾＱｴ･＠ is

three one 4. four

,.
--·f',

1..

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 :25

!. [Mn(CO),f:'•1c- 2. [1v1n(COJ)v{c]
3. [Mn(COI6] 4. {(MeCO)tvin(CO},]

[':'vfn(CO},p,f..,
3. [.\tn(CO)o]

l. HCi ＨｾｸﾷＺ＾ｳＩ＠ -AlCh ｾ＠ !..i- 2. H.i: Ai T Lt

3. LiH Ｈ･ＮｾＺｳＩ＠ ｬＮｊｃｾ＠ __.

1 --· I f.l

4.

i:?. ､ｾ＠

i. 21 6; ;:;, .}.

Ri.

sx. ;1fr ;r.;;f;;..t4 m;1it'"ET714.2 t,JJ:.;i:lh. ＺﾣＭ［ｴｩｬｾｉｊＩＮ＠

ｮﾷｴｲ［ＧＡｾＮＢＺ＠ l5J ､ｩＺＭＮＱｾｴｰｊＧｶｮｳ＠ n'nn"
=5730 ,. ,.

·rhc ｴＧ｡ｲ｢｣ｾｮＭｩＮ＠ ole! \\'1.1C<1 :i..ll'np:e- IS iburtd 10 ｢ｾ＠ !4.2 ､ｩｓ＿ＡｬｴＧｐｾＮｊ｜［＠ 1!1111
1
g,
Cakul<th:d ｾｧ＠ of if i0r t?. ｦｴﾷＮ［ｾＺｨ＠ ｾＮＬ｟Ｚｵｬ＠ ｳ［ＮｾｊＩＺ｣＠ ..:Jrb(tn'" i ;:,c u'':ly ts ] 5.]
､ＺｳｩｲｊｌＧ＾Ａ｢Ｌ｡ｾｵｓ＠ ｲｮｪ｡ﾷＧｧＺｾ
Ｑ＠
(:f •., !s 573{1 ｹｴＢ｡ｲｳＩｾ＠ i:::.

I. 4.000 4.

2[Rh,,(C0),.] +JCD 125 "C atmCO!

l ｾ＠ (ij u;r;H;:-} f. ;Fiil>J;

2.. Ｚ［ＮｲｺｵｾＡｦ＠ t, ﾷｩｬＭＷ［ｾｦｊｴ＠ Ji?.'f;
J. ｉＨｐｴＡＷＧＭｲｩｾﾷ＠ Ｎｭｾ＠ rf ｾ＠ .:.'i.G rJ u1 ;:tp(r.

4. ｾＬｴｬ［＠ f. .' (L\G .':I 0)

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 • 4CO ''C, )U() a;m CO j is

Ｚ［ｸｯｌｨ｣ｩﾷｮｊｾ＠ ＺＮｾｮｯｲ＠ ｉｏＺＮｴ［､ﾫＡｨｾｩ＠ Ｇ｢｣ｾｲＬｨ［＠ ｾｲ｣＠ ｫｲｴＩＱｾＮＭﾷ､＠

2. ･ｮ｜ｾｯ［ﾷＺｩＮ＠ ｾＮ＠ Ｚｩ＼ｬＧｦＨｽｲｾＡｃ Ｑ ＮＢ＠ r:'•ＮＺｾ､ﾷｴｲ｢ｯｮｹＱ＠ ｢ｯｮｾｬ］［＠ ar:: ｴＩＺｾ｡ＧＯ｜Ｎ＠ Ｎ｝ｵ｢ｾ＠ ＬＮﾷＺｾ［ｫ･＠ ｲｮ｣Ｚｴ｡ｬｾ｜＠ hQnat'
Ｚｲｾ＠ fom1eJ.
), is Ｎ［ＺｮｴｲｯｰｩｾＬＱｬｹ＠ ｴＺﾷｷｯｾｺｨｫ＠ b1:t ｾＺｴｨ｡ｬｰｋｹ＠ unfa,·or.:.bk sudt ｴｬｾ＠ 1:1G =0
i!. ｾｨＺｲＨＬﾷｊ＠ . 1:::lrn:c.:::.il} ｵｮｦｩｬＧｾＮＺｲ｡｢ｽｶ［＠ ｾＮＺｓｇ＠ ::· 0) .

90. .ｾ＠ ｾ＠ 7ft ffST H • ｾ＠ # if. fr 'Ft ｩＧｾ［＠ ｾｴ＠ I l::'t;.fl ;r,Ji :;r.mfi;:r f:M
1

1.0 M ｾＮＺＭ｡ｃｬ＠ ＵＺＭＢＧｆｲ［ｪｾ＠ ＺＮＭＱｾﾷ＠ .'r/:rrf:(..:, .r:,:.:-::r; ｔＺＧｾＷ＠ i ＮｾＺｴＭｲＨＩｩＱ＠ ｲｾＮＬﾷﾥＭ］＠ it?;r ＧｦｩＺｾ＠ i! Ｓｾ＠ ｾ＠ ｾＭｪ［＠

2. l.50 meq;g

ｩｾ＠ ｲﾷＺｬＧｾＮ＠ 11
j ,·:th 0.') 1:: of .J 8•.·1:Jic 10c: ･ｾ､ｲ＠ ｲＧｾＺ＾ｩ｜＠ ;n rr f••nn. i\ 1.0 M NaCI
Ｎ［Ｑ､ｾＺｩｮ＠ ,..ｾ＠ ｰＺﾷＡＬｻＧｾ＠ ｾｨ］ＺﾷＧｬｩﾧｊ＠ 'lU1 ＩＺＮ｣ＬｾﾷｬＧｭ［＠ ｮｾｵｴＺ｡ｬＮ＠ TIH: collecled
ｾｨＺﾷｸ＠ t5 ［ＺＮＧＩｭｰＡｾﾷｫｬｹ＠ ｾ［Ｚｮｴｲ｡｢＠ .. ｾＭＮｪ＠ tl:/ l }' rnr. ･ｸ＼ＺｨｬｮｧｾＬＭ＠ r1p:u:it)' of the- ｲ｣ｳｾｮ＠

4.

B :·:3l'J;',t::\;; ..J. ＭｾＺＮ＠ ｾｯﾷ＠ ;·1t mo! 1t i C ill! r;w ::f.v ｪｾ＠ Ｎｾ＠
·)_-;· I ｾ｜ｓＮｒ＠ Ｚｾ＠ 1}44 i ｊｴＮＭ［Ｚﾷｾ＿ｦ＠ t,:;rs:;(t/ {. i B .:.;-,_r tJtd:!rrr (v.·.'\\·)
ｻＭｾｲＺ［ＧＬ＠ ;j·

Gl, ﾷＡｾ［ＮＺ＠ ｯｋＱｬｾ＠ Ｇ｜［ＮﾷｵＺｾ Ｑ ｾｬｩﾷｐ＠ ｾｯｮ､ｶＮ＠ ::d· f:i ｜ｾﾷＱｖ＠ is·+;..; t0 ｬｩｾ＠
1
'ern '. Ont;; ｨｴｾｲ＠ ｾｊｩｬ［｜ＺＭｮ＠ f,f( 1
\-dPch ｣ｾＧｬｴＱＡＬ｟ＭｲＮＺ］＠ ｾＺ］ﾷＵｘ＠ g ｰｨＮｈＱＺｊ｣ｾﾷＭｴ［Ａ＠ prcp3rJncn nf ｂｾ＠ shnws :1n ｵｨｳＭＺｾｲ｢ｭ｣Ｎｻ＠ ofOA··H m ｡ｾ＠ em
cc;:. "!he l-:<:rccn;;Jec- ｾﾷＮＺ＠ x·: r·t 1-i in ｰｩﾷ［＿ｾｲＺｄｃｬｴ｣＠ ｾｲ｣ｰＺｈｊｴｯｮ＠ h.

2.

ＮｾＷ＠ Ｍｎｾｬ＠ ［ＮＡＺｾ＠ ｾＺＱＮＡＪＧ＠ "

i"!-"'tf ｊＡｴＨｾＢＧ［Ｚｩ＠ Ｎ｟ｾＬ［ｲｹＺ＠ -,;,t ft'fj::'f,i- ｦｾ＠

-l.

ｾＺ＠ .J ;s ｾｨＮｵ＠ hrdrogcn ｢ｯｮ､ｾﾷＺ＠

ＮｾＡｨｬ＠ i-::. ,;;I::·.) bcrrj(:d

:md 3. A

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 27

93. Ji<Mrl ?mM! f'f4ir<iJ ;;· ｾＺｭＭ＿Ａ＠ ｾＢＧｒｩｴ＼ｬ＠ rirtr# >:# ｾ＠ ｔＧＡＮｾ＠ it 1/::rtt.r >4rf.' t ill! fr ＮＬｾＩ＠ Ｈｾｹｬ＠ b)
(C)'t bj} ll«Y G#«+m''t·f{-1 (PC) I ｾＺＭｦＬＧＨｬＱ＠ Jl4f(. '.Gf :r<l f! 1

1. I'C -- cyl b -. cyt hf 2. cyt ｾ＠ cyt h PC

3. cyt b - c_:-·1 bf-" PC 4. ｐｃｾﾷ＾＠ cyt hf-> cyl b

93. h1 ｰｨｯｴｳｹｮｬｾｲｩ｣＠ systems the ｦ･､ｯｾ＠ mctallopr-otcins ｩｮｶ＼ｬＧ＾ｾ＠ ir1 ･ｬｾ｣ｴｲｯｮ＠ t!'rulsfer are cytoc•hro::m:
(cyt b), c)1ochromc bf complex (cy1 1;-j) and plastocyanin (PC). The pa!hway ('}f de<: Iron flow is

1. PC- cyt b- cyll1- 2. cyt bf C)'t b ·-> PC

3. cyt b-+ cytb/-+ PC 4. PC- cytl:{- cyt b

94. ﾷＮＱＭＺｾｙＩｮｵＢ＿ｉ＠ ［Ｚｲｾｴｭ＠ Mn(,ll}

(l =5/2 Mn)
l. ＺｬＮｾＧｩ＠ 30 5 ?r'li 33 4_

94. The 1otal numbers Ｌｾｦ＠ iin<: ar.<l hypcrflnc Ei'R llnes ･ｸｰｾ､＠ for ｯ｣ｩｾｨＬ［ＺｊｲＮ｝＠ hi£;1·>pill :\·ln(ll)
complexes are respee1ively (I 5.'2 for ;\ofn)

l. 3 and 30 2. 5 nnd 33 j_ 4.

95. <it 'm ;'l¥r <:t TfftT<h ｾ＠ ｾ＠ <rof& .,; t! 1 it ［ＺｭＭｾ＠ l'f W.l'fit ｾ＠ (il ＺｲｮｾﾷＭＮＬ＠ mJI!) (1!)
ｾＭＮｗ＠ J,W'l"J (ll} ll<>7 (iii) ｾＮｔｬＢｒ＠ (lll) # i

' \!I)

ｾｉ＠
tl_-\ \ I
I
ｾｉ＠ \j
'{l,l
__
. . _ .ＭＧｾ＠

(l "!).'l
ＢＹＱﾫｴｾＨｭ］ﾷＧＩ＠ Ｍｾ＠

i. A 'iR (i) :rff!.1T B <m (ii) it 1 2. A "''' (ii) ii47 J!. 4'>1 (rl t, I
3. A "Ff {in} if:l:1l B TR (ii) # I 4. A W (ii) iJI:/JB iP7 (iil) i\1 1

95. The ｍｯｳＮｾ｢ｵ｣ｲ＠ spc.clr.\ of two iwn complexes arc shnwn below. The}' may ｡ｲｩｳｾ＠ from (i)
high-spin iron{lll), (h) high-spin iron(U) an-d (iii) low-spin iron(IJ[)

tn
Ill)

.1)..::: J) ... ,:OJ.

'YII4oot,frriTI ｾﾷＬ＠ --

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 28

...

?
2. J. ｾＮ＠ '
2 l ,""; 1.

.,
")
3. ... .l
2 ;t, 2

8ml.

l4h'
ｴＡｵＺｾ＠ uur.t:llStlH••d ｴＺｬｾＮ［＠ ti!:>X ｜ＺＮＱｾ＠ ｨＺＭｮｾＱ［Ｎ＠ L ｨ｡ｾ＠ .;.::tt·t;i.!,;' (;f
ｾｭｌ＠

I. :;, 6

ｾﾷ＠ ·-1'-:.•Jr Ｌｨ Ｑ ｾﾷ＠ i::..r: ＺＮｳ［ｾｲ＠ ｾｊ＠ ＮＡｾＺﾷ＠ ＿ＺﾷｾＬＮ＠ :,·q ｾﾷＺｲ＠ ｾｩＭ［ｬ＠ ｾ［ＺＢＮ＠ 'f)(tr.;; ;'i:?T t; '
H. ｦｩＭＧ［ｲＺｾ＠ ＳｾｩＬｊＧｦＮＺｻ＠ ·], o:-fl )'f i);·:,·.o .;r.:..r: .;.>...!.•;, 9--}f? ＱﾣＮｾＷ＠ JJ(:r ifJ;.:,r ＭＺＧｨｾｲ［＠ TiT.! ｬｾｴｲＭｰ［＠ :;..<:ar/; J?":?!i Yi
ｾﾷＮＩｲｬ＠
［ｾＢＺｮＭ＠
•(··.Y (:.-.·.' ｾ［＠

I 2.

Sr,;t_:u:;.{1 .;.1:d;;;t ｰｴＮＺｌｵ［ｲＱ｡ｬｇｾ＠ ｣ｾﾷＮＬＺ･ｴｬＩＭＧｚ＠ to ｴｨｾ＠ grotmd st.o.!c t:n:::rg;· ｾＡＩ＠ Ｎａｩｌ｜ Ｑ
Ｏｾｴ｜＠ 'lS ｮＺＮﾷｧｊｴｾＢＧ＠
U. ｾＧＢｭ＠ l:[ t.b.: UlOih <Jfdct anj lirst on:kr com:c:-tion,. t<l the gt(•lLtld state cnc:rg.y is ALW,>,V'-;
ｾｌＢｬＱｩＺＧｔ＠ tJum the eXJ.i..1 t!;H}tll1d ｓＧｴｾＨＬ［Ｚ＠ ｾｃｩｧＩＢＮ＠

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 29

C sum <"if tile zewt.q artier ;md ｴｾｲ＾＠ order corl'Cction,;; tn the ground st;llc energy is kss th:m
the exact ground state ert:crgy.

2. both 1\ and 13 are ｴｭｾ＠

I, only A ls tnle
}. vniy C !5 true 4. btJ ih H and C il.rC true

2.. a+ f), o:

3. 0: + ｾｬＮ＠ 4. IX I 2[1, D'. 2!),

0.(\) 7]; I 2. [o.(l) ＱｾＨＲＩ＠ j3(t) ｣ｾＨＲＩｬ＠ ill 1

4. [a(l} P(:!) + 1}(1) ;,>; i

iO(L For H, ｭｯｬ･ＮＺ［ｾｴ＠ ln the cx<.:i(cd o! , llte St>in part of the triplet ｳｴＺｾ｣＠ 'Nith m, •= 0 i:;;
propor:ionsl to

1. a{l) ｾｻＲＩ＠ 2. [a(l) [1(2)-(l(l) o:(2)]

). a.(l}f1(2) 4. [a( I) Nll + IHU 1.)'.{2)1

c., ｾ＠ t: 1 ＿Ａｾ＠ ｾﾷ＠ 1.l E, 2C 4 , ｃ Ｒ ｾ＠ 2cr., ｾＱＲ｡＠ l n··•(ir'id ff"sl.n

lOL ｾ＠ '4'i l'i:ifln:."J ﾷｾＢＡ｝＠ ｾｬｘＮ＠
｣ＮｾＬ＠ qq Mx, !!7 ｾＮ［ｴ＠ Tl ＮＺ［ＨｱｾＧｬ＠ #i'io/'T It I

l. Sii13 2. l l 1t l

3. 5l 1l 1 4. 4 3

pynJ.Illid.ll, MN, mol.:<:ltle belongs to C,,. point b'l'Oup. ｬ｢ｾ＠ sy11·,mc!ry ｯｰ｣ｾ｡ｴｩｮｳ＠ are: E.
10 I. A ｾｱｵＺｭ＠
The ＼ｲ｡Ｎｾ｣＠ for tht: reducible represe-ntation, when symrnetty ＮｊＧ｝ｃＺｴｬｾ｡ｮｳ＠ of C ..
2C4, c,, 2a, and ＲｯｾＮ＠
applied to MX.,, is

l. 51113 2. ll l l

3. 5 1 1 11 4. 41l l3

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 30

I c_. I "·
I I
1 -1
l
-I -1

L x, z-gf.tcr

lf the ｭｩｬ｡ｾ＠ and tina! ［Ｎｬ＼ｴｾｳ＠ bdung w A, ｾＱｮ､＠ B, ut'<)dliClble ｲ＼ｊｰ･ｳｮｴＮｾＱｩｯ＠ rc:spccth·c:ly, the
::1 ｬｯﾷＮｮｾ､＠ e Jcctrorric ＱｲＳｮＺｾｩｴｊｯ＠ frmn A: to H 1 is

2. y-polarhcd :;._ 4. x, z-polarized

H)J. (1.5 '"' 'l'1 ｾ＠ ,.¢ # r;::.r. ｩ＿ｾ＠ N l 0''"-·f ｾ＠ foiRft <pr. ?firr ifozi 'H 50% 'lJ?'rl"'li'fl ｾＺｶＮＧｭ＠ it
Ｎｾｓｽ＠ rii'•'l ＢｦＮｴｾ＠ lti:' 'til ＭＳＱＧＺ｝ｾﾷ＠ :!i<mfql!f 'J''I!'Ii i! I (log 2 = 0.30 l)

L 1500 ｾｦＧ＠ .;nr' 2. 30 10 }vf" 1 cm· 1

3. 501)0 M·' cnf' 4. 0020 Nf 1 em·'

103. thing cuvcttcs <>ffl.5 em r''"h icn£,th, a lff'M solution oL-. chrom0rth111c shows 50"A! ｴｲ＼ｬＮｾｭｩＡ｡ｮ｣＠
;H o.:<:r1<1in w<We kngtl1. 11K mc>lar cxttnclwn wcfftc tC:!lt of the chron:.ophore at tills wave length LS
ｻｬｯ｟ｾ＠ 2 = (UOJ)
l. lSC:oO t-..1"' {;JlJ I 2. 301(; 1-.f' em·'
J. 5{1GOM" -em' 4. 6020M' 1 em·'

ll).$_ ｾｩｦＣＬｱＮ｣ｴ＠

(A) .2: _,.liT (B) 3

E-+ 'll
1
(C) Ｇｬｾ＠ -> 1.:3 {D} n-+'n (E) :::!: -7 Jl\

A.B. E 2. A,C,E 3. 13,C,D 4. C,D,E

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 (A) '2:_,.:·[[ n:n "'r: ＭｾＩＧ＠
'::::.:-) )D.
(C}
1
/l-+ ',". jD} 'ri-• i.E)

I. /1, B. E 2. A..C, F 3. B. CD 4. C.D.E

ｾ＠ l!l, vfrp; WJ !iiJ'l[f.'IW

:N':J ＱＵｾ＠ ;;;:N (0,}

I. 4fJ96 ｾｭ＠ 2. 6144 em·'

105. Th.: fullowi1ig Ｈｬ＼Ｇｴｾ［＠ wetc olnau1cd from the ｈ｢ｲ＼ｴｩｯｮＬｾ＠ ｦｩｮｾ＠ s.m.Jc.ltnc in the vibronic ｾＮｰ･Ｍ｣ｮｵｭ＠
of a cliatomtl' Jml]..,ruk:

wher<: (•>, ｩｾ＠ ｴｨｾ＠ en.;:rgy ［ｩＮｓＺ＾ｴＢ＼ｾＸｯ＠ wilh 1he tulltiTlll. ｦｲｾｱｵｴｮ｣ｹ＠ c>f vibr.:lt:oo and x, is the
anlumtonicity t•.msl<ult. The <.hssociation energy (D.,) of the ｭｯｬｴｾＺｮ｣＠ ｾ＠

1
l. 4096 em

I 06. T{iF .Jt'r.ift tffl Olil ,;ff111N ｜ｊＧ＿ｩｬｆｉ［｛Ｎｾﾷ＠ !I?!R 4!i llTc1li1' ｔｊｦｩｬＧｾ＠ ?TTfff.n# ｲＣＧＯｾ［＠ <f RNi'f4>' J!4<W1 4!i Ｍｾ＠
;# ｾ＠ R ｬＴｾ＠ ｾ＠ r 1tff: ｾｱ＠ PI·NN 4':-:t ｾ＠ q;r ｾ＠ .:;Wv v.· Ｌｾ＠ ;mr ｾＷｴｦ＠ r;• ..Ft :,.:rtf{! at

!. w<O,q<O 1. w ｾＭ 0, <j < 0

3. w<O, q>O .:.!. w::>O,q:o-0

I 06. An ideal gas was subjoctcd 10 ｾ＠ reversible, ;;:di;;,l:l<ltic exp:-m:>ion and lhen its ｩｮｴｾＡ＠ ｾﾷｯｨＱｭ｣＠ was
reswrcd by ｾ＠ reversible, iso!hcmml ｣ｯｮＱｰｷｳｾｩｬＮ＠ lf 'q' derlCites (he hear ｾ｣ｫｬ､＠ t-o ｌｨｾ＠ systetrt and
'w' the work done by lhe ｾｹｳｫｭＬｬｨｮ＠

L w.:: 0, q -:0 2. ·.v > 1), q <0

3. w•;:(),q>(l 4. w:o.l),q>()

107. <t"fftq :;{lf[.llt( ii ｊｾ＾ＬＧｦｭｬｲ＠ 2NO; (g) ""+ N;P, ＨｧＩｾ＠ ｾＧｎ＠ JrilfT{ (( I N0 2 11llli'N 20, ,f, ｷｾ＠ (J{'4?":lf wa
f/fM"l *N20. <ffl' ftFr.>.f ilifir ｾＮｲ［＠ wr 'iPfi':fi t
I. ＧｬｦＤＱｾ＠ I
2. "" 1l7T ;fr I
3, ｾ＠ -31o7f!f'f W ,f.'/{r;t.rtl >ffl ｾ＠
4. f.k/? 'ffll W ,f?/f!i<;IJ ifw ｾ＠ I

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 32

WI is. il.Jl 0Kothcrmic ｰｭ｣･ｾＺ＾Ｎ＠ In illl eqiJilikium mixture

can he l!ldu(·ed by:

th·2 ｴｾｭｰｲＧｬ［ＱＮ＠
ｴｨｾ＠ ｰｲＺｾｵ［･＠
Ｇ［ｮｾｴ､ＬｋｩＮ＠ an int=r;: g;1:; at ｣ｵｾＮｓｴｩｬｊ＠ vo]utne
ｾｮｲ｣､ｵＮＺｩｧ＠ ｾｮ＠ ｩｲＺｾｈ＠ g::ts :11 cotHtmt ｰｲｴＮｾＵ［ｵ･＠

-I.f!

(as

4,

:1 i ｮｴｾ＠ ｴｾＮＺｲ［＠ pu in t ＺＮｾｮＬ｟ｱｹＩ＠ ＺｾＱｲ＼ﾷ＠

1-0-

L.

i!l] ＺｏＮｬＲｾ［Ｇ＠

I. ','

!I

:•,

1A

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 33

111. 1.lMfflT '11<1

PI l ｈｾＨｰＩ＠ I HCI(a .. ) 1 l AgCl(s) ｉｾ＠ I AgCI(s)l HCl(a,)z IH 1 (p)l Pt
ｾ［ｮｦＣｩｴｭＺＢｒ＠ I

]. E"' 2RT ln (a,), E = RT In (a=)!

2.
F (a 1)1 F (a.} 1

3. E"' 2RT ｬｮＨ｡ＮＩｾ＠ 4. E= RT ln (at)?

F (a.) 1 2F (at),

111. ｔｨｾ＠ comet Nernst equation for the l;Oncentra1km cdl:

Pt H 2 (p)l HCI(a,h I AgCI(s}J Ag IAgCl(s) I HCI(a .t I II,(p) IP! witl)out liquid

junction wootd be

I. E"'2RTln{a,.)t E= RT In (a,h
2.
f (a' )1 F (i!j ),

3. ｅ］ＡＺｾ｛ｮ＠ (a=)l 4. E= RT ｬｮｾＬＩＱ＠

F (a.), 2F (aL)t

J• lf!\1<r q;w.fi ｾ＠ :¥1 ;%wr l

2. ;;p:,t)?:r! ＮｦＴｽｾ＠ ;re;; ｾ＠ rtc::r 0} ｾｩＧＺＱｬ＠ 1
3. 'Hnii ＼ｲｴｦＮｾ＠ ＬＧｲｾｮ＠ dr.:-i:i!?r'l!-1 ｾｩＮＺＧｴ＠ zi!? l±Ze¢J>;-k 1<r <tt #i:mr
4. 'RRif ｾ＠ &rw ｾ＠ ;;k:? :lR' Ｉﾱｚ｣ｾｊ＼ｫｮ＠ 1' #. it<w.

lIZ. Main ｡ｾｓｕｔｬｰｩｯｮＨｳｽ＠ involved itt 1he ､ｾｲｩｙ｡ｴｯｮ＠ frfl::leby<::·Huckel ･ｱｵｾｴｩｻＱｮ＠ is{ arc) ｬｨｾ＠ validity of

I. only ｦＧｯｩｾｮ＠ L-qua(icm

2. Pui:;:;on cqllinion ［ｾｮ､＠ Boltunmnn distribm!on
-'· f>msson equatit>Jl, Bolinn<llUl dislribution1!lld ｉﾱｚ｣ﾢ｝ＺﾷｾｫＮＬｔ＠
4. ｐｭｾｳｯｮ＠ ｾｵｭＱｯｮＬ＠ Eoll:tm:mn dis!rlbulicm <Utd J!.Zc¢;<<k 8T

U3. iiSfi'l"Y ':.'I:J Ti!Ff [MI..,(' ii; m;- (Oif)W<"T ｾ＠ ;;t; ｴｩＺＧｦｾ＠ ｬｯｾｫＺＬ＠ rro,T. ./I $ Ｇｦｾｬ＠ .io'T\'7.!1
-2 .1 ｾ＠ I 7l<{j"f W ｾﾷＮｲＯ［Ｌ＠ f.

I. +] 4. +4

ll3. ln the base (0H-} hydrul}'l"is of a tr.lnsilion ｭ･ｋＱｾ＠ complex [rvll.,r, the Ｌ［ｬｯｾｈＺ＠ ｢･ｲＮＺｾﾷ｣ｃｊｬ＠ log(klt,,}
and .../] is found 1xl be ·· 2.1 . ｔｨｾ＠ ｣ｨ＼ｬｲｧｾ＠ on the complex is

L +I 2. +2 ). +3 4, +4

SJ7 RD/U-tAH-lA

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 34

{k
I., Ｒｫｾ＠ ' !CH,.CHOJ),'"

1. E,(1) Ｍｾ＠ J!,(lt :m.(4) 2. E.{2l + ｾ＠ E,{l)- E,l:4>

Ｑ＠ I
J. E.(2)+ ｾｅＮｻｬＩＭ
"' Ｒ E,{4) 4. '!+ 2 Ef4}
ｾＭＺＬ＠

114 Th-e ril!C law ibr em<: ｯｦｕｬｾ＠ ｭｴｾ｢｡ＡｬｩｳＵ＠ Gfthc n-roi)•Sis ofCHJCHO ｾ＠ 520 "C ｾｮ､＠ ＰＮｾ＠ bar is
2

K<tte--:-lk, ( ".1' [CILCIIOf''

'
.,__ 2k,)
Tnc ovcrnlt acr.1va,ion energy E, in tenns oflh.: r11Lc ｬｾｷ＠ ｩｾ［＠

l. 2.

3, E.(:Z) + Eil) ＭｬｩＮＨｾ＠ 4.

2 2 .

2. L4 ;:.:: 10*. let

3. 1.4 X l(il, to•

115. In the Mhchaelis-Mcntrn meDhanism. fur (!rtzyme ｫｩｮ･ｴｬＮＺｾ＠ lite ･ｸｰｲｳｾｩｯｮ＠ <Jbtainc·d ｩｾＺ＠

v lO''v
--=1.4xl012 - - - -
[EJo(S] [B] o

1. 1.4 :.: ｷﾷｾＬ＠ w• l, ].4 X 10\ 10'

3. 1.4 x :o· w"" 1
,

I. ｾＬｲ＠ ｬｦｩＧＺｾ･＠ 1Mr :pr.· W-!J7f"f 2. ｜ｾ＼ｍ＠

3. ｾ＠ f.Bta'fl7: r:rrn ｾｦｩＧ＠ Ｇｨｾｉ＼ｆｦ＠ 4. ｾ＠ r;rr:fQ>'e rrm lf.:iFr

sn Rllt12--tAH-lB

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 116. The nwsl us<:o:laci<l caro1y:<.t in oil industry and ｾｨ＼ｴ＠ ｾ｝･Ｂｩ＼ｬｮ＠ pro-ces,; arc ｲｾｓｰ･｣ｴｬｶｽＧ＠

1. a!uminophosph:;ne rulll fl::!fonnlng 2. aluminosilicatc and ｣ｲ＼ｾＮｃｫｩｮｧ＠

3. ｡ｬｭｵｩｮｾ｣ｴ･＠ and refonning 4. aluminophosphale and cnt.cking

117. ｾｬｦＭＧｴｉｒｆ＠ ;J; k >t<;r (E. L98 x 10·'''J) # ｾ＠ ｾ＠ ｾ＠ w:rkrf&.r ｾ＠ # fi!?r! <rhM mR ;mq;r
ｾ＠ h If [h = (l.626 x 10·l•;,, ｾ＠ = 3 x JO'ms'J

l. 1000 nm. IN 2. IOOCI nm, IR

3. 500 nm, visible 4. 500 nm, FAR JR

117. Tile w:;wdcngth :and the spe-ctral resion for a sin.gle electron lm:nsft"T across the band S'IP in a
.5¢1lliCOJldUdN(f:,- 1.%: X J0' 1'J) are
[h- 6.626 X IO·)·J$, c 3" JO'm!i' 1)

I. I000 II.Jl'J, uv 2. 1000 nm, JR.

3. 500 nm, visible 4. WO run, FAR JR

1. :z.u, A 2. 1.43 A 3. 4.29 A 4. 5.72 A

118. The ｨｭｩｾＺ｣＠ pammcto::r of an element :;.t:abilized in afiv: structun: is 4.04A. The atomic radius of the
clement is

1. 2.86 A 2. L43A 3. 4.29A 4. 5.12 A

1. 'Niffl"l'llr:fl rttn ｊｲｬｭＭｾ＠ ｾ＠ wJ

2.
3. ｊｐｾｬｭＭ＠
ｾ＠ rP!Il
ｾ＠
'lllRlfT
ｾ＠
'llr-f * I
'll'r-l it I
4. l''IPfiTT rr>.7 JF!Wf ｾ＠ "'N'! it I

119. The number-avemsc molar ｮｾ＼ｴｓ＠ (M 0

) <1nd v.ocight-average ll.lOhu' m<IS:s (Mv..) of a polymer are
obtained rcspcctivc[y by

I. os100mctry :and light s.cam:ring rm:asurenwnts

2. osmometry and vi:>cos[ty meas-urements
3. light Sl)3.ttcring and sedimentlltion mca.q(TCmcn ＱＮｾ＠
4. vi:>cosity and Hght scattering measurements

X 4.1 4.2 4J 4A Ｔｾ＠ Ｔｾ＠

Y(Se-t A} 10.2 10.6 10.9 1u 11.8 12.2
Y(Set B) l0.2 10.6 1Ll 11.3 1 L8 12.2

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 36

\ 4J ,p 4.3 4.4 4.5 4.6

YtS,;t .\) 11}.2 10.6 10.9 11.5 [1.8 12.2
YIS.ct ll/ [1}.2 10.6 lU !U 11.8 12.2

!I 1he ｳｬｯｾ＠ <>nd ｩｬＧｴｾＺﾷｔ＼ｃ｝ｓ＠ ofthc rcgrcsoinn ｬｩｮ･Ｍｾ＠ fttr [},<)two sets ru·e denoted ｢ｾﾷ＠
l·1). ｦＧｾＮｰｴｔｩｈｉＩ｜＠ 1hc-n

J.

121. ,\ i!\'' no <r ｑｾ＠ Ｎｾ＠ H NMR ｲ＼ｵｾＢ＠

1
if "11 f!iR! ｾ＠ ｾ＠ 1 <Pi'iffm ｲｮｾｦｩｴ［＠ ｾＺｦＨＮｊｲＧ＠ :i ,ft:IT:
ｾ［＠ ｾ｟ＬＭ［Ｚ＠ .i! }

A B

1. 1).9 ·;;'l'or2.l A ;cf; ｦｾﾷＨＺＧ［＠ 7.7 rrur.l9 R ;i; ff;r; 7.7 <t'l',r3.9 A <i; ｦＮＺｾｲ＠ 6.9 rr<l72.1 B ［ｩＮｾ＠ ,f<rrt
3 ｲＬｾｊ＠ ｩＱＢｔＳＮｾ＠ A ;t ｴＺＮｾ＠ 7.7 iTi'.cr2.1 B it: 1(?,; 4. 7.7 <WT2.1 A ,.; ｦｾ＠ 6.9 1l''<r3.9 B <l f<?('

Ill. Compuu.mls A ;md B <Lx.hib11 two singlet-;:, caC'h in their 'B t'\ 1\'lR s.poctn. The ｾｸｰ｣ｴ､＠ chcmic:al
shHt> afC at S

I. 6.9 <lnd 2.1 for A: 7.7 and 3.9 for R 2. 7.i and 3.9 for A; 6.9 :mu 2.1 tor B
J 6.9 and J.\1 ｉｾｊｲ＠ A; 7.7 and 2.1 forB 4. 7,7 aod 2.1 for A: 6.9 and 3.9 for 8

,, .·- www.examrace.com
 37
01\c Ok
1. ａｾ＠ ｴｵＺｏｾ＠ Ac{) , \ .-9r
El ,
ｾ｜Ｚ［ｬＬｏｉａ＾＠
- J, Q

.l>dJ /!4)

ON: 0/v.;

ｾ＠
I
2. A, !l • ｍｏｾ＠ MO OMn
IWQ B• A:::O

?N: OA<:
t .
3. A=
ＢＧｾ＠ ""' N:O
_,ll:c
B o
ａ｣ｩｦｾ＠ f.cO ' \
AcO QM(t
0/o: ()Ac
4. ａｾ＠ ａ｣ｯﾷｾ＠ A!;{) \
!l = ｾ＠ lv;O· I
MO !J.r A<.O ()Me

OAc

A cO ｾＺ［ＬＮ｟Ｍｏ｜＠
l _H_B_r___ A
ａ｣ｏｾ＠ AcOH
Aco ""o.o.c
O,!,e QM
l
1. ａﾷｾ＠
ＢＧＭ＼＾ｾ＠ AI..O· '• 84
Bit ｾＬ＠ />£0 ' \ ,CMo
At;<)

OAc Ok
2. Ail ﾷＢＭＰｾ＠ M:J- \
81>
ｭｯｾ＠
ｭｯｾａＢＧ＠
ＭｬＮ｟ｾｯ＠
111:0 lit At;<)

0.0£
ｾ＠
"I• ｾｅｩ＠ Sii
ｾ＠ k OMo
0.0.::
'?""
·- ..... ｾ＠ NJ::J a•'
Bll ｫｏＧｾ＠ "":()- ' \
AJ::O Q'Ja

1. NBS (2 eq,), Ell10, A

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 38

Nx::oI
Cl
()[tne. 2.
ｎｾ＠ｴ "
1. " I "1 , I ,
·.:;...N ｾ＠

p Cl

3. ｾＭＩ＿＠
l:,N I""..--___..cH
4. (:Cr) N

123. The structure ofth<!. ｴｲｩｾｹ｣ｬ＠ compound fom1ed in ehc following two !>tep sequence is

Cl

Ｍｾ＠

1. 2.

3. 4.

1. 'titci $,fliJ>i! ＺｩＧｦｬ［ＮｲｴＡ＼Ｌｾｷ＠ｉ l'irrr?rtctJ .ft>rr :>.1rrf:lTI rfClf t.YTffl V'fci•A.iitl,.•r, {1,7)-H fWrlc
2. Wit ｾ＠ ＬＮｊｾ＠ ..tti&.':;olZ"M¢ qfffl ｙｾ､ＮｺＨｪ＠ ｾ＠ ｾ＠ ｾＷ＠ ｦｾ＠ ｾﾷＢＮ］ｎｆｦｩ＿ｊｲＺ＠ [ 1,7]-!I f?F.P.;
3. ｲｾＱ＿＠ ;i-Prfr.,;odfh:;;;nli't7 ｔＮｾｬｩＡＧｊ＠ ｊＮｩＧｲＺｬｴ］ｾ＠ ｾｲ＠ q,id ［ｩＡｾＧｬｈ＠ gwli'l'7m«(l,7]-11 fir'R
4. ｾ｡ＭＧ＿ＨＮｻ＠ ＺｲＮｾ［ＧｵｬｊｨＭﾢ＠ ｬＤﾷｴｲＮｦＡｾ［ｊ＠ l!l''! ｳｩｊｲ［ｬｾ＠ rtJU ｾ＾Ｚｲｦ＠ ｾ｜＠ fl ,7]-H Fl!wJ

I 24. ｔｨｾ＠ 1wc1 s1cp CC>lwcr<>lon nf 7-dchydroclmlc<;tcrol1o vttamln D, proceeds through

L photochemical dcctrocycltc ､ｾｓｲｯｴ｡ｹ＠ ring ｯｾｭｮｧ＠ and thenna.l ant.a:rafac!alll, 7)-ll shtll.
2. phvlochemi..:<:i ｾｬ･ｴｲｯ｣ｹ､ｩ＠ ｾｏｬｦｴｩＨＩＧ＠ rillg ＭｯｾｬＩｩｮｧＺ＠ ;>nd lheml;ll ［＾ｮｴＺ｡ｲｾｩ｣ｬ＠ (I, 7 J·H &hill.
3. ＡｨｾｮＺｴｬ｡＠ dL"\!!mcyclic ｾｯｮｭＱＳｴｲｹ＠ ring ()pen ｩｮｾ［＠ and r•hll\(:>eh::mi.:;al supmfacial{l.1]-H ｾｨｩｦｴＮ＠
4. ;hcnn:;l cle-:::<wcycHc <lisr01owry ring ()pcning: and ｴｨ･ｭＱｾｩ＠ supmfacial fl ,7]-H shift.

A s
Ｈｩｮｾ･ｲｭ､｡ｬＩ＠

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 :39

125. The intem1odiatc A a11d the ｭｾｯｲ＠ product B in 1h.e follnwing reaction are

A----... s
ＨｩＱｴ｣ｾ･Ｉ＠

0
i. A !s soy! calion: B IS ｾ＠
u.....ｾｲＺｭ＠

ｮ
Ｍｾ＠
2. A is ac-t I e(llion; B is }=o
ｾｎＮ＠
H
0
3. A Is acyl nilrene; B is ｾｲｬ＠
ｾｎｈ＠
H
ｲ［ＧＢｾｸＭ N
4. A iS ocyl nitrene: B is U : )'=o
',;>- ｾｎ＠

I -""(Br
' K0 8u Ｈ･ｸ｣ｾｽ＠
1
...
(B)
>r '"-./ . "COOH

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 40

12(,_ for Lh<' following !wc ｲｾ｡｣ｴｭ＠ A and B, £hG <:OITect s1a1emem is

K0 1Su (excess)

(6) r --'j:Br l<O'Bu {excess)

y-...__ '''COOH

Bgives ｾ＠
_:::_ COOK
1
/'-..._
ｂｧｩｶ･ｳｾ＠

3 t10l11 A and B give

4. C.o1h A am! B give

127. ｦＮＧｲＺＡｴＭ［ｬｾ＠ ｾｲｴ＠ ..ｾ＠ sr m t{fW 'JI.fl:i' ｬ［ｾＨｐｦ＠ B, lR ｾｬｪｰ＠ *177[} cm- 1
qt{ ｩＡｔｊｾｆｬ＠ ｾｬｊｉＡｲＮｴｕ＠ ;j-..:0
［ＮＢｾﾷｦＺＧ＠ .r ...\ ｆｦｐＧｾＷ＠ B orf.t ｲｴ［Ｚｾｙ＠ l. ,

9-BBN MsCI, NEt

3
A------ .. B

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 41

!:1
1. A=
ｾｃｏｍ･＠ OH
B= Wo
.o
A
tl
ｾｃｏｍ･＠
2.
A=
B= !Vo
...._ Ｌｾｯ＠
OH Ft
3. A=
fr·cooMe B= Qj:o ｾﾷｏ＠

4, A=
Hd
.ChCOOMe B= rL.p<O
..._ 0

127. ｔｨｾ＠ ma:jor compound B fo.rmed in the re-action ｳ･ｱｵｮｾ＠ given be!Ciw exhibited a cal"OOnyl
absorption baJld :;Jt l 770 ern- 1 in theIR spectrum. The structures A and Bare

ｾ＠ =---
9-BBN MsGI,NEtL.p.
HzO;:.NaOH A B
COOMe

tt
1. A is
ｾ｣ｯ＠ OH
Bi$
q:ro fj

z. tt
A is
｣Ｚ＾ＭｴｯｾｫＩ＠ e+t
ｬｩｾ＠ Ｈｩｾｯ＠
" 0

3. Al!o
HYCO OM&
!! ﾷｾ＠ uro
H

4. A.l!o
r;" f)'---o
f-16. -1 COOMc
I! is,
-LrJ

128. ＮｲＺｾ＠ ｾ＠ ｡ｾＬｱＮ＠ Tl" W'i>r Fl ＺｯＮｾ＠ ｾ＠ <n fit;;;;; ｾ＠ ...ｾ＠ mft 'Jil!/"'1 'liT ｊＮｩｦｾｫｵｲ＠
＼ｾ＾ｗＢｩＮｦｲﾷ＠

｡ｬｫＮｋｍｮｏｾ＠ NaOH/
A B ｾＭﾷＢｯ C
o:-plnene pincnic ｩｬｾ､＠ pinic acid

1, A it ｾＷｦｩｭ＠ @'li?'Rr t.. B .J.!l'<C ＼Ｚｾ［＠ ｷｲｐｭｬｴｩｾ＠ 3f"(f {: 1

2. A"' I?'!R.fd·ll'·<'lf?fff fl:Miif'ff /J. B ,j,fiq"ff ;;frdcr fff:lf C Ｚ･ｾｲｊｦＮｩｬ＠ .W"iff f: I
3. A it ｴｩｲｒＮｾＧｦＯ＠ fif.JfllJ'Il t. D ｾ＠ Jttc'Fr i ffi!/T c t'i' :;Jf1 i!ii<ITiimi'Rit (J{1f'l t f
4. A ;y ｾ＠ ft.:J,"T.r-fl ｾ＠ B ｾ｣＠ c >iRr <:wifi'itii!ffiJ«, ,s,-.;;; !f 1

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 42

12S. Consider the followu1g reacti.on ｾｱｵｮ｣＼Ｎ＾＠ ｳＱｾｲｴｩｮｧ＠ ..,tith mnno!<:rpene ct-pini!ne. ldm1tll'/ 1he cnrrec!
ｾＱ［ＳｴｃｉｮＮ＠

alk K.Mn04
A B c
a-pinene pinonic ac:icl pinic acid

1. A has a ＼Ｚｬｩｓ｜ｌ｢Ａｴｵｾ［､＠ double lxmd; Band Can: dicarbox)·lic <Kids.

2. A i:u:Ls a Lri:>ubstiluted double ｢ｯｮ､ｾ＠ B is a me1byl ｫｾｴＨｭＬ［＠ and C is a dicaxbox.ylic acid.
3. A has, a disubs!inned double bond; H is arncihyl kct<)nc; :md Cis a dicruboxylic add.
4. A has an ex.xyclic d,;uble hnnd; Band C = ｉｭｯ｣Ｚｾｲ｢ｃｬｸＩｩ＠ ｾ｣Ｚ｛､ｳＮ＠

1. (2Z,6.l)-Jil1?r-2,6-Qd'l 2. {2£/.>E)-JifilCl-2,6-:glft-r
3. ＨＲｅＬＶｚＩＭｾＮＢＧＺ＠ 4. (3L,5.1:;l ..ｾＳＬＵＭｬ｢＠

129. ﾷｮＱｾ＠ rn:.jor produ.ct f<mm:d whrn ＨＳｒＬＴｓＩＭｊｵｮｾｴｨｹｬＮｸ｡ＱＵﾷ､ｩ｣＠ i:;. he-ated at 240 •c is

1. (2Z,6Z)-acta-2,6-dicne 2. ＨＲﾣＮＶｅｽｯ｣ｴｾﾷＬＭ､ｩｮ＠

3. (2E,6Z)-ocla-2 ,6-dit!tl<: 4, (3Z,5.1:.)-<Icta-3,5-di<.-n::

A-
hv
ｾＭＧｾＯ＠
0

ct>
0
1. 2.
ｏｽｍｾ＠
H 0

3. ｶﾷｾｲｏ＠
'-v-''
4_
C))
130. Stn.Lcl\lre of the slllirting material A in the following phoh:x:hemie<J11'-"•.lrrish rMctlon, is

0
hv
A-
00
1.
ct5 2_
｣ｯＭｾｳ＠
p

a:ro
H 0

3. 4_
ex)

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 43

(a) ｾ＠ !fi 1t enantiotopic ｦ｡ｾ＼Ｚ＾＠ t f

(b) ｾ＠ ;;;;r Jmli1i"7l re-facial t J
(c) 'l'1fJ ·1/W dia>t<;'feosdoctive ＬＭｷｱｾ＠ ;j l

1. ＪｭＢＨｾＩ＠ il"!!i7 (b) 2. ｾＨ｡Ｉ＠ f]'2,7 (c}

3. ｾＨ｢Ｉ＠ l'f'JJ (c) 4. (a). (b) i11l1 (c)

131. Core;idering the following reaction, 3m0ng ｾＭ｣Ｌ＠ tl:lc com:ct ｳｴ｡ｾＱｮ･＠ are

c6
ｾ＠

,&
0 Et
liAIH4
---- o5"' 65%da

(a) ｬｨｾ＠ cru:bonyt gro1.lp has cnamir:Hopic ｦ｡ｾｳ［＠

(b) 1hc hydride aLiacb:. is rt·facial;
(t;} it is ｾ＠ ､ｩ｡Ｎｳｴ･ｲｯｾｬ｣ｨﾷ＠ ｮＺ､ｵｾｬｩｯＮ＠

l. (a) ｾｮ､＠ (b) ＰＱｬｾ＠ 2. (a) and (c) only

3. (b) and {c) rnily 4. (a), {b) and (c)

co ,&

1. ｾ＠
.A 0-"
OH
""":
/
2. ccrOH
I d -4

3.
cO ...9
0

_/
4. roo ...9

132. The tlllljcr product lormcd in the following rca<:t,jc.n SlXjllcnce is

co 1.111'-CPBA

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 44

3. 4.

1. DIBAL {1 eq.)
_z=··-:_:C='ｈＺＮＬｾ｣｟ＢＧｃＡＱｧ＠
J.PCC

2.

3. 4.

IJl 'T1lc maJOr pnXlUc( ｦｯｭｾ､＠ ｬｨｾ＠ following ｲｾＲＺｃｬｩｯｮ＠ s..:qu?nte lS

1 Dli3Ai:.l1 eq.)
ＮＬＲＵｈ Ｒ ｾｃｈＢＧＱｧｂｲ＠ __ ,..
3. PCC

1'

3. 4.

( :t ., Ｚ＿､ＧＡｻｾ＠ ..l( ..lf'ri (II 95

1: b) t;:fit.!f:tr;,':.r!:'7[7:7 (li) ll5
to.:·) ｾｲｮＩＺＧｔ＾ｩ＠ (iii) ]75
(d) tl/f(f·! ｾｲ［ｮＺｬｴＬｊＢ＠ (:n:)

1. (O)·(iii) (b)-{ii) ((1-(l\·) (d)-{ i>

ＨｾｽｩＩ＠ (ll)·(iv) (c)-(i} (rl)-(if)

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 45
3. ＼ｾｈｩｬ＠ (b)-(ii} {c)-(iv) (d)-{ii}
4. (a)-(lii) ｾ｢ＩＭＨＱ＠ ｻｾＩＭＨｌｩ＠ (d)-{iv)

134. Match ｉｬｾ＠ following:

compound nc mm chemical shift (5 ppm)

(a) ｯ｡｣ｴｩｾ＠ acLd (i) 95

(b) ｡｣･ｴｵｮｩｲｬｾ＠ (ii) llS
(c) acerone (iii) l7S
(d) carb.-m ｴＨＺｲ｡｣ｨｬｄｩ＼ｾ＠ (,iv) 205

I. (a)-{ iii) (b}-(ii) (c)-(iv) ld}-(i)

2. (a)-{iii) {b)-(il') (c).(i) ( d)-(ii)
J. \'b}-(ii) (c)-(iv) (d)-(ii)
4 (b)-(i) (cHii) (d}-(iv)

1. A=

A=

OH
). _. n-ilu.;SnH
Jp
'·r ｾ｟Ａｊ＠ ＲＭｦＮＺｸＡＨＩｬＧｩｾｏｉ＠
DEAD
A .
AIBN ,\
•

(DEJ.D ｾ＠ ＼ｬｩ･ｾＱ＠ a.>:OOiOiti:X>:<)1.:l!<o)

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 46

t
ｾ｜Ｎ＠

L Ais

jY
g-""'V

v
I if

Sis

'Y" c?
. . p-
H?V
I

2. A is

I
I
\--.-::<·\ ;=.
,, o-f
0""""\..:__j} H,,'
A
.)J')
3. A is ,.--1.,.....- SIS
I ＩＧＢｾ＠
'· I· ｾＭ
Ｍｾｲ .J
ｾＩＧＺ＠ ..... ,<"'::::...'-\

ｯｾＢ＠
' •' H.••｟ｯＭｩｾ＠ }
ｾﾷ＠
4. A is

yY "'' yif
.
I
'--)I

136. ｾ＠ J!P?.9RJr *m i1JMl 3&: ｾ＠ tt 1

ｾＢＧ＠ "'a"'
0
COOMe
1. Ｈｊｾ＠ 2.
O..v
0 0

r)l.L::,. 4. K
3. . .I
l...._....-" £()
136. The maJor ｲｯ､ｵｾｬ＠ foonLxl in the tl) i]()Wing rcacti0n is

0
｣ｾＭｂｲＮ＠ NaOMe
ｾＭ

0
'I fOOMe
1. ＨＧＺｾ＠ 2. ｾ＠ 1...__ __/
...._./ 0
0

3. Ｈｾ｜＠ ｾＮ｟ＬＭﾷ＠
4.
,z-f.;___)
'.---

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 47

l. A Cll 11,, Zn--Cu; B = ｾﾷＱ･ｓｔＬ＠ NaH

2. A = CH:I", Zn-Cu; B = i:\•lc;S'{O} r, NaH
3. ａｾ＠ ｍ｣ｾｲＬ＠ ｎｾｈ＠ 13- Me;S:'(O} r, NaB
4. A = Me;S-{0) I, ｎｾｬ＠ B= ｃＺｈｊｾＬ＠ Zn·Cll

137. The ｲ･［ｾｧｮｬｳ＠ A and Bin ｾｨ･＠ fotlDwing rea.ctions m-i:

L A = Cfhh. Zn.Cu; B = MclS'I', Nl!H

2. A = Cfhh. Zn-Cu; B = MelS'(O) 1", Na.H
3. A= M.e3 S'r, NaH; B MeJS+(O) r, NaH
4. A= ｍ･ｾｓＧＨｏＩ＠ I', Nail B =CI-hh.Zn-Cu

ｓｨ［ｵｰｬＢＧｾ＠ <p<t<m1ion
A B
ｬＭＨｾＩ､･ｴｨｹ＠ t;amate

1. A• Ｏｾｏｈ＠ e= ｾＭｏｈ＠
2. A•
Ｉｾｏｈ＠ 8"
ｩｾｏｈ＠
3. A=
Ｍｾｏｈ＠ B= ｾｏｈ＠ 0

4.
"'"' ｾｏｈ＠ B,.
ｾｏｈ＠ 0

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 48

138 The A Md B fonmd in lh:: following rea<:tion s.-quence urc

Shilrplos:s ｾｸｩ､｡ｬｮ＠
A B
L·(+)-dielhyl1artr<3tG

｟ＮＩｹＭｾ＼ＡＬｏｈ＠
f:f' 0

J.-..,_/'-,/'-; --::-'/''tlH
o' ·e:r

ｾ｡ＺｊＩ＠
｣ｹｾｶＬ｡＠
1_ A= 8=

2. A= ｾＧ＾Ｍ＠ ·--/ e(
ｯ｝ｩｾ＠ I j B=
ｯＬＭＧＰｾＢＮ＠
(IBu
o·- ＭＬｾＺ［Ｎ＠

( \
.. ｾ｟Ｏ＠
C))
ｾＭ｡ＺｊｃＩ＠
J, A:-: 8=
' ｬｾｵｲＧ＠

r\
\--J
4. A=
ｾｳＺｏＭｯ＠
a- ,-"
B= O'il "Bu

1A

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 49

139. The maja.r products A 11:nd B fOTl'l"ltd in the following reaction sequence are

F\
I "Bu
A B

1. Ais
ｾｓＺｊＮＩ＠ 0 "-..;'
Bi!l ｾ｡ｵ＠

2. Ais ｾｬＺｑ＠ 0 ｾＢＧ＠

Bi-s ｯｾ＠ "Bu

S. Als
ｾＧｬＩ＠ a, I
0
Bis
OJ
4. Ais

ｾＭＺｯ＠ ｂｾ＠
ｕＧｬＮｾ＠

l. (a) Me;SiCHiOMe, "BuLi; (b) ｈｾｯﾷ［＠ (c) NaBI;., McOH

2. (a) ｐｨ Ｕ ｐｔｉｌＬｏｍｾ＠ ct·. "BuLi; (b) H 30'; (c) NaBH4 , McOH
3. (a) NH:NliT$; (b) NaOEt; (c) CICOOEt
4, (a) NH.,NHTs; (b) 2 eq. "BuU; (c) HCHO

140. Tile CO·rrect reagent combillation I reaction ｳ･ｱｵ｣ｮＮｾｴ＠ for eff«ting ｴｨｾ＠ following CDnvertion is

Ｍｾ＠ ｾｏｈ＠
l. {a) Me3SiCH 20Mc, "Bul..i; (b) H,o·; (c) NaBH,, MeOH
2. {a) Pb3 P'CH2 0Me cr, •BnLi; (b} H,o·; (-c) NaBII •. MeOH
3. {a) NHlNHTs; (b) NaOE!; (e) CICOOEt
4. {a) NH2NHTs; (b) 2 eq. "Buli; (c) HCHQ

sn RD/12-lAH-4

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 50

Me 2CuLi
ｾＢ＼＠

Et20

1.

3<

I.

1.

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 51

142_ The <::orrect s-equence of reagents for effeming the f<:.llnwing cnnveN:inn ｩｾ＠

0
ｐｨｾｏｅｴ＠
0

2.

ｃｦＮＱｔｉＰａｍＡｾ＠
3_ (a} Cl (Tebbe's ｲ･ｾｧｮＱＩ［＠ (b) ｈｾｯﾷＬ＠ (G) KOII

4. (a) ｐｨｾｃｈ Ｑ ［＠ (b) HJO';(c} KOH

ｾ･＠ NaH PhCHO

A B
ｾｲｬ＠ H
PTSA,8

1. A"' ｾｯｈ＠ ･ｾ＠

0-)__ "N \
H
Ph
)-d
2. A"' ･ｸＩＧＭｾ＠
N
H
I
B;; o:Qo ｾ＠ Ph

3. A" u;Q
OH ,---<1- N
H
1!1=
ｾ＠ 0 ｾ＠ ｾ＠

4. A= cQ N
-._,_)
OH
B=
ｾＧ＠ \_J
0

143. The major products A and B formed in the following rcaetion sequmce are

co
Me
NaH PhCHO
A B
N [;:o PTSA,A
H

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 1. A= ｾｏｈ＠
N
H
B=
o:h Ph)-- a

2. A= ｾｏｈ＠
h N
H
B"
crX · ｾ＠ Ph

3. A= ,!()_) H
B"
ｾ＠
0

Ph I
1

4. A= ｾＭＩ＠
l)_ OH
B;:
ｃｏＭｾｴ＠
Ny' ｾｎ＠ ...___,,0

144, ｾＪ［｜＠ ＱＧｦｬＯｩＢＨｻＮ＿ＡｊｾｎｴＺｂ＠ Kl

0 A ()xBr
'ar
ａｧｎｏｾｬｩＺＲＰ＠
B

OH
1
A = CH2Br2 tror K0 Bu Bz (rBr
I
.......
OH

ｾＭ A Ctl26r2 1'fW K0 8u
1
B;
Qer
OH

3. A =CI-IBr 3 ;:rrJJT KO'BtJ B= (rBr

OH
4. A = CI-!Br3 ir'.'r KOtau B= Ｉｾ＠
(_h ＭｾＢＧﾷｂｲ＠

144, The reagent A required, and the majm product B ｴｾｲｮ｣､＠ ln the [olkiwing reacticl!l sequenee arc

Br
0 A
O>< Br
B

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 53

B=

6=

4. A= CHBr 3 ll'l\v ｋｏｴ･ｩｾＮｲ＠ B=

H......r-f'OH

＾ＨｾＩ＠
A.

l. ａＧｻＱｦｬｾｴ＠ I
2. A ｾ＠ ｾ＠ fit$f17f t I
3. ａ＼ｨｾＧｬｩｲｴｷＢＣ＠ I
4. A 1:7 ｾ＠ <m fi!MVr t I

145. Among fue choices, the corr«t slatemenc for A fOITIIOO in the fullolli'ing reaction
ｈｾｏ＠
+
0ｾ＠ /i''''\-t.N0
A
I. A is a single emmtlomer
2. A is a ｲ｡ｾｭｩ｣＠ mixture
3, A is a mixrure of two d.iaslercoolcrs
4. A is a mixture of two epi.mers

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