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CSIR Chemical Sciences June 2013
CSIR Chemical Sciences June 2013
CSIR Chemical Sciences June 2013
2013 (I)
'<tl/2/rJ セDQOイj@ <
JlFf 'Q?f
"ffllll : 1:oo ere y:urfqi : 200 afq;
1. arrq;t セ@ q;t セ@ セ@ t 1 "ffl. rRtiHT セ@ Tf VCP "fit 4"cm4'Nt (20 'JfJTT 'A' Tf + 50
WIT 'B' + 75 WIT 'C' Tf) 6/'Wf セ@ rrFr HmcqIセ@ 7fT! セ@ I 3{Tq7fi}- 'JfJTT Gセ@ w Tf
セ@ 15 J/1? WIT 'B' Tf 35 セ@ fr.!H 'JfJTT 'C' Tf w25 セ@ ¢ imR ・mセ@ iセ@
f.1Wf?n # セ@ セ@ ct imR セ@ 7fT! ff6T ctcrc? セ@ 'JfJTT 'A' w15, 'JfJTT 'B' w35 ff1!H
WIT 'C' # 25\Jfff# qft iJffq qft liflVl{T. I
2. imR Q"5f J7WT # セ@ TflJT t I JrrFfT ?T<f "f1W 3tf? セ@ CfiT "fTlf セ@ # セ@ W •wfq
セ@ {$" rft'rcliT Tf T[fi5 fJJ 3tf? wtfr セ@ OW cmff W cpt_r:pt rytf セ@ I セ@ セ@ t nT 3lJfT
:{fcJiifJ<ilc'< # rft7cFiT セ@ "ifiT セ@ "fiR セ@ セ@ 1 "¢t rmJ # imR Q"5f C!iT セN@ iJffq
# I "ffl rft'rcliT Tf ?TP CfiT1f "fiRrt cff セ@ セ@ TFf '<fc;rr.r セ@ I
3. imR Q"5f cff. T[fi5 · 1 Tf セ@ 7fT! セ@ fR JffRT #c;r "f1W, rrf1T, 3fTFfT WT ff1!JT "ffl rRTIHT
rft'rcliT CfiT セ@ セ@ I 3flTTEi; セ@ セ@ liR'ift セ@ I
4. Jf1Tl arq;ff 。CNセイヲ@ ffffff セ@ Tf ffi:;r *«. fctrm . . セ@ セ@ セ@ cffrrr • #
セ@ セ@ 7[ffT q;t arrffll q;rc;rr ·CfR セ@ I W VC1i TfT?l セ@ ctft /Gtd/c:J:fJ .t tiP "fftJ
セ@
セ@ セ@ Tf セ@
CfiT mfr rRtcff # セ@
セ@ f.ii!m' CfiT 'lfr セ@ -w qrc:;pf rR, セ@ ., m w セ@
rrdT CfR 1lfVTTT, fGtw# atrrrr. セ@ grf.t; fGtw#. 3lJfTqft
ffffff セ@ ctft 31t4'1i1JRI セ@ mfrrc;r, l# WiiR'fT t 1
. 5. 'JfT7T 'A' ff1!JT 'JfJTT 'B I Tf 'JTf'llcp rrFf ct 2 aiCfi ' WIT 'C' Tf 'JTf'llcp rrFf 4 aiCfi CfiT t I セ@
Tfc?ff imR CfiT ':ti UJ/f#fC/7 セ@ 25 % ctft CR # t$"ln·lifljPTT I
6. Jlfllq; rrFr cff セ@ =erR fctcPc;rr セ@ m
7fT! セ@ I # cffcrc;r VCP Fc/ctJc;cr dT "'mftn J12NT
•mTmlf ffln t I 3{Tq7fi}- セ@ Jnrf CfiT wtfr Jl2NT wifrr'f7:r ffl c{p=rr t I
7. r:rq;c;r rpffl セ@ llT 3FJ{?!fr rrfJc!;T CfiT 'fT'llPr Cfl"<'& §"\'" 'CfTV Vfl'f 'CIT<? セ@ CfiT ffl 3tl?
3RT 'JfTffr rrfriHT3iT cff セ@ 3TllTRJ セ@ iJfT セ@ t I
8. セN@ cvT imR llT ?TP qr;:fl' cff セ@ cmff 3tf? セ@ セ@ rytf セ@ セ@ I
9. rR'tiHT w:rrra 'EfT Vfl'f w ffl rR'tiHT セ@ 3tl? imR Q"5f q;f $'fcJiifJ<>Ic '< C!iT 3fCml ?#rr
セi@
10. ¢C'1Cfl,<ilc'< CfiT 'iJT:T<If1T m ctft JTTdfr rytf t I _
11. fctRft rrFr Tf fctftirffr cff セ@ Tf セ@ titil"< OJ Jl6TC'f "irTfT I
S/46 BJ/13-1AH -1
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lfPI' 'iii' I PART 'A' 3. 'QCfi OR" Cf;T セ@ セ@ ' 'R q;tt * セ@ 'QCfi
3. 2
2. 7
fm;r(t ;;g'i"l" セ@ セ@ at セ@ h. セ@ 4. 1
ᄋセ@ セ@ セ@ セ@ セ@ ;;g'i"'' セ@
セᆬ@ 3. A square pyramid is to be made using a wire
such that only one strand of wire is used for
each edge. What is the minimum number of
1. セア[イュQ@
times that the wire has to be cut in order to
2. セア[イュQ@ make the pyramid?
3. セア[イュQ@
1. 3 2. 7
4. セア[イュQ@
3. 2 4. 1
1. During an evening party, when Ms. Black, Ms.
Brown and Ms. White met, Ms. Brown 4.
remarked, "It is interesting that our dresses
are white, black or brown, but for each of us
the name does not match the colour of the
dress!". Ms. White replied, "But your white
dress does not suit you!". Pick the correct
answer.
1. 2.
1. Ms White's dress was brown.
i Ms. Black's dress was white.
3. Ms. White's dress was black.
3.
4. Ms. Black's dress was black.
2. v\AヲゥセNrLC@ ,:)
4. Identify the next figure in the sequence
'ClJ!lf セ@ Vc!fi 3f'IT 00 セ@ セ@ セ@ セ@
セ@ 3"ictrn<h)U11 # セ@ セ@ Cf;T セ@ セ@ :
1. R2 2. R2 {2
1. R2 2. R2 {2
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160
160
A. What is the ratio of the men to women Pt;IT セ@ セ@ a セ@ セ@ en)" 'QCfl セ@ ft:rm. 1
customers who wanted child care facilities.?
cm;r セ@ -mtt セ@ セN@ セ@ tfr :
セ@
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8.
A
D B
t:: fAST
11. m 15 'Qa:tkft'ICfl セ@ セ@ セ@ セ@ セ@
9. 1JCfl セ@ tlGTif セr@ セ@ セ@ tR セ@ R t" ll iセ@ fi:OOCfl セ@ セ@ 'Q'TlR1 セ@
"
セ@ ¥ "
-;;m:)' セi@
1JCfl セ@ $ セ@ 1JCfl q;'f-Jrr セ@ セ@ セi@ セ@ セ@ セ@ セ@
"
t" セ@ CflT 20 セ@ em- セicヲャHG@
.
セ@ セ@ Cfi{J セ@ セ@ セ@ 1JCfl セ@ 1if'l.1T fcf; q;'f-Q" セ@ q:lj'f セ_@
"' "'
セ@ セ@ 1JCfl 3m{ cmor e (< 45°} trr, セ@ 3
1. 4 2·
1
21
セ@ セ@ セcヲャ」HGエ@ trrl m t セ@ セ@ em 1 1
3 · 105 4· 20
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11. Two integers are picked at random from the 13. How many rectangles {which are not squares)
first 15 positive · Integers withou t are there In the followi ng figure?
replacement. What Is the probab llltytha t the
sum of the two numbers is 207
3
2. 1
1.
4 21
1 1
3. 105 4.
20
1. 56 2. 70
3. 86 4. 100
12. セ@ 2013 em 'C!7fl セM@ セ@ lt 10
セN@ 1ft. X 10 セN@ 1ft. セ@ 'lffiifcfl· セ@ I ᄋセ@ セ@
14. セ@ q;t :· a®b = ·'QC'f セ@ WI'
mft' セ@ Cfi)" 5 1ft. X 7.3 'Jft. 3lTJJTtt em;)' 'Q'ifi
{a,b) + '\tr セ@ g)' (a,b) (1ttT
,·· t":
1. 38.5 2. 49
3. 63.65 4. 154
1. 56 2. 70 2. 49
1. 38.5
3. S6 4. 100 3. 63.65 4_. 154
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1 1 1
16. What is the value of -1X2 + -2X3 + -3X4 + ··· to
oo?
1. R/3 2. R/4
3. R/8 4. R/12
1. 2/3 2. 1
3. 2 4, OCI
11. セ@ R/2 Cfil' 'Q'q; セ@ Cfil' mm, -;;h' 'Q'q; s)tt 2. 3400
4.
セ@ 'Q'q; Rtt i(trr fliT t. 'Q'q; セ@ l\tfr tmr
5200
HセrエGI@ CュMセ@
18. Choose the largest number:
セ@ 1T<m' p1'liT -;;rrcrr t fct; セ@ Cfil' '&q; 3fTUT
SuャGセエ@ エュイCセcヲゥャG@
セ@ iil'taTT:
# セ@ セ@ Cfi)IS6Cfll セ@ セ@ セ@ ?
1. R/3
3. R/8
2. R/4
4. R/12
セi@ /a10nm
Unit Cell (not to scale)
NLセ@
H
S/46 BJ/13-1AH-2.
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19. A crystal grows by stacking of unit cells of 20. A solid cylinder of basal area A was held
10x20x5 nm size as shown In the diagram dipped hi water In a cylindrical vessel of basal
given below. How many unit cells will make a area 2A vertically such that a length h of the
crystal of 1cm3 volume ? cylinder is immersed. The lower tip of the
cylinder is at a height h from the base of the
セ@
..
1. 2 h
3. ih
--------
-------
--------
------- セ@ 3
1. 2h 2. -h
2 \
'•
"-
5
3. セィ@ 3 4. ·-4 h
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2. +1
3. 0
22. The ligand in uranocene is -
4. -1
24. The oxidation state of molybdenum in [(q 7-
tropylium)Mo(C0) 3r is -
1. +2
2. +I
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25. {pエcャLNセ@ ·cffir SQaャヲッGAセ@ c); &)' <j(l-:tlitfl1 cfi'r 27. [W2(0Ph)6] ;A' tmj·Uf<j. 3fliitit cfi'r mT セ@
セZm@
1. 1
2. 2
l. [セNMLHjャエhSIRcィ}@ 3. 3
4. 4
2. trans-[Pt(NH3)2Ch]
ᄋIイセN_@ ZMセ」ヲ@ .NZᄋセ@
27. The number of metal-metal bonds in
3:li;·botli*cis-[J.>t(NH3)2Ch] atrr trans-
[W2(0Ph)6] is -
[Pt(NH3)2Ch] aWrr
. .• :··\ ' . 2 1. 1
4. cis-[Pt(NH3)2CI4] - 2. 2
25. The. reaction of [PtCI4] 2- with two equivalents 3. 3
4. A
ofNH3 produces -
2. .trans-[Pt(NH3)2Ch]
4. Atg + T28 + Tt 8
26. DセJGゥエ@ セウョエaoゥ@ t"aftii<H セ@ cmur
セsヲゥjuェ@ tmj-'tl t" .ltrlJir tancrf· セ@ セ@ • 28. The Mulliken symbols for the spectroscopic
states arising from the free-ion tertn Fare -
1. T28 + E8
2. Tt 11 + T2g + Ttu
3. T tg + T28 + A211 .
2. NO
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3. B, C and D only
2. NO
4. A, B and C only
1.<lilt 'AJ1 (1 Jl
1. H2NC(O)NH2·Na2S04 2. il CjISCfi (01 tf:l OQ
3. 31\SG\fi (0141'J OQ
2. H2NC(S)NH2·Na2S04
4. セ@ ゥcェsャヲHoiセq@
3. H2NC(O)NH2·H3P04
32. The coordination geometry of copper(II) in
4. H2NC(S)NH2· H3P044.
the type I copper protein plastocyanin is -
30. Flame proof fabrics contain - 1. square planar
2. tetrahe-dral
1. H2NC(O)NH2 ·NazS04
3. octahedral
2. H2NC(S)NH2·Na2S04 4. distorted tetrahedral
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1; oxidative. addition
2. . ・ャセエイッーィゥ」@ substitutibt1
3. nucleophilic substitution 3. como
4. migratory insertion
4. A mo
35. SGQ|sgャヲセ」Zゥ@ Ni(II) セ@ .:)
c\l EPR セ@ Miffi:r
36. For neutron activation analysis of an element,
セ」ヲゥGイM
the favourable characteristics of. . both the
'(!ql .
target and the product are from the following-
1.
2. G)" (A) high neutron cross-section area of
3. cfrir target
4. ᄋセ@ (B) long half-life of the product
35. The number of ·EPR signals observed for (C) 16w neutron cross-section · · area of
octahedral Ni(II) complexes is - target
3. three 1. A and B
4. zero 2. Band C
3. Cand D
4. A and D
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l.cJ
\}' ]jヲセャ@ KjヲセR@
2. QC.fi
3. セ[。@
セ@ I セ@ セi@ セ@ GQRセ@ セ@ tfi(ilGi セ@
4. cfra:r
f\;lcrtCfll セ@ lTTif HセI@ セイZ@ E1
37. The concentrations of a species A undergoing セ@ E2, セi@ セ@ cfi'r セ@ :Nf'r E1
the reaction A セ@ P is I.O, 0.5, 0.33, 0.25 mol
dm- 3 at t = 0, I, 2 and 3 seconds, respectively.
セ@ cf;'r CRU セ@ t?
The order of the reaction is -
I. two
QNセ@
2. one 3
2.
4
3. zero
4. three 1
3.
4
38. セ@ セ@ セ@ It セ@ CfiUT セ@ ftil1:r n =
CfiT
Rセョ]i@
Jt:R セi@
セfcrtGaBg@
セ@ セ@ セ@ 'A" 3q1Cf(1
4. Jf
39. The wave function 'I' of a certain system is the
セョ]SR@ セfcrt@
linear combination
セ@ m.<:r :Nfr CfiT Jt:R WIT -
1. 4
2. 5
3. 9
where セ Q@ and '1' 2 are energy eigen functions
4. 10
with eigenvalues (non-degenerate) E 1 and E2,
38. The difference in energy levels of n = 2 and n respectively. What is the probability that the
= 1 of a particle-in-a one dimensional box is 6 system energy will be observed to be E 1?
units of energy. In the same units, what is the
difference in energy levels of n = 3 and n = 2 1. {3
for the above ウケエ・セ_@ Vl6
I. 4
2. 5
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2. B-A- B
2. 1Po
3. 1So
42. A triatomic molecule of the type Aih shows
4. •s. two IR absorption lines and one irGMセ。ュョ@
line. The structure of the molecule i.s - ·
41. Vcli 3iUj cfi'r E, 2C6, 2C3, C2, 3crd, Otrr 3crv
l..B- B-A
ヲAjゥセ、@ セF\liq@ セi@ セ@ セ@ セ@
セ@ cfflt Otrr 'tl) R::41 セ@ セ@ 2. B-A- B
ヲエ\hセゥ@
Gセ@
ョセ@
1. 3, 12
2. 5, 12 3.
3. 6, 12
4.1\
4. 6, 6
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Pcl <'t liCI1 Cfi)" NaO H c); セ@ Pcl <'t liCI1 't セ@
m- 3C\I'fl)CI1 Cf;t h 7fliT セi@ $lf セ@
セ@ セ@ ヲエセ@ # Cfi(OI" セ@ cfi'l" セ@
セ@
セ@ 3i1lJ Kセ@ 3i1lJ セ@
セM
'Hfslilld セ@
1. 1
2. 2
3. 3 N q'{IFfiOIJTl" セ@ セ@
'Hfslillct セ@ セ@
'R c:j;qfilCfi
1. 1
4. 3N- 8
S/46 BJ/13-1AH-3.
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セュイエ@ 2. bJ;,
1. 6 3. 2bJ;,
2. 12
4. 4bFc
3. 60
49. q{CFJIOj 'Ff: fi'li)\Jlcrt セSヲGLゥfェjZ@
4. 720
tM
47. Calculate the total number of microstates for 6
identical particles with their occupation 1. Ea = 0, D.S# = +ve, D.H# = +ve
numbers {1, 2, 3} in three states is "
2. Ea = 0, AS# = - ve, AH" =- ve
1. 6
3. Ea = +ve, !J.S" = -ve, AH# = -ve
2. 12
4. Ea = +ve, AS# = +ve, /J.H# = +ve
3. 60
4. 720 49. In atom recombination reactions
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4. 2 USNTaセ@ セ@ セ@ セ@ '8'lil011 セ@
セM 1.
2. 2
1. セZarGャ@
RNセ@
..::1
3. 4
SNセ@
4. 8
4. Cfl) (>11$5
53. The inter planar distance (A ) for a (100)
51. The aggregation of surfactant molecules is plane in a cubic structure with the lattice
known as- parameter of 4 A is -
1. micelles 1. 1
2. clusters 2. 2
3. gel 3. 4
4. colloid 4. 8
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64. G)' セ@ c); afi'ir セエ|Zヲャ。ゥイ@ iJOTfifi -0.99 *'I 3. (2R,3.E)- 7..ーィ・ョケャエセSN@ ..2..ol
2. almost uncorrelated
4. CC OCOCH 3
CHa
. 3. connected by a 」。オウ・セヲエ@ relationship
56. Among the following esters, the one that
4. not connected by a cause-effect
relationship undergoes acid hydrolysis fastest is•
1. cr 6-
OCOCHa
セpィ@
QH
2. CC OCOCHa
OH
Wセーィ・ョケャエMSRッ@
3. . VOCOCH3.·
l. ·HRrLSzIセ@
2. (2S,3Z)-7-phenylhept-J..,en-2-ol OH
3. (2R,3E)-7-phenylhept-3-en-2-ol 4. CC OCOCHa
CH3
4. HRsLSeIMWーィ・ョケャエセッ@
57. 10% Pd/C セ@ セ@ セ@ GhiDアZH^エIセヲ」m@
55. The IUPAC name for the compound given
セ@ セ@ セ@ HQDセI|ゥtエ@ c); セ@ セ@
below is -
セM
QH
セNpィ@ 1. GhiDアZHエIセcnイャ^ゥ@ a-m ・Q\ゥセイエ@
2. GhiDアZH^エIセ」ヲャイゥ@ ·om セ@ qセIgGゥヲ@
1. (2R,3Z)-7-phenylhept-3-en-2-ol . 3. GhiDゥヲH^エIセcnQ@ <1m セ@ qセIH\G^ャ@
2. (2S,3Z)-7-phenylhept-3-en·2-ol 4. GhiDTB\IセアZ[ゥm@ ᄋセ@ •
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Br
1. a-i b-ii
1. 0'Br 2. a-iv b-iii
3. a-iii b-iv
4. a-iii b-i
2.
6o. ュmセヲゥcQ@ セ@ セ@ セ@ セ@ cm;rr
セM ,:)
3.
セP@ 2. LiAIH4
4.
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1.
mセLqh@
1.
セッ。@
2. l) OH
G^QセP@
NLセ@
2.
Me
3. O''OH ·.,,,.,.....oH 3.
G^HZセP@
4.
MX''oH
セoh@ 4.
セP@
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1. homotopic
2. isotopic
3. enantiotopic
1.
4. diastereotopic
3.
^HᄋZセッ@ 2. 1760 cm" 1 q't
3. 1710cm"1 q"t
4.
:yClo 4. 1660 cm" 1 q't
RNセ@
1. セャGエ[icヲゥサo@
3. 3<"SflRFE\cfl
セ@
Br N·Me
H
. NaNH2
co N
I
Me
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67, セ@ 311'(11 セァIゥャ@ セ@ セQsヲGZャウ[ゥA@ 'Cf'(>RT
65. The reactive intermediate involved in the
セ@ _
following reaction is セ@
co N
I
Me
2. セ@
SNセ@
1. セエャァI\ゥヲ@
セiDIq@
4. DセSャI@ (il
67. The heterocyclic ring present in the amino
1. a carbocation ゥウセ@
acid histidine
2. a carbanion
1. pyridine
3.. a free radical 2. tetrahydropyrrole
3. indole
4. an aryne 4. imidazole
1. エゥヲrセ@ (1<>1' セ@ セ@ •. セ@ セ@ セ@
セ@
2. エャヲrセゥ@ c2"Jm セ@ セN@ ('I1IT セ@ セ@
エュヲゥセ@
3. エャヲrセゥ@ セ@ セ@ セN@ ('I1IT セ@ セ@
ᄋセ@ セ@
4. エャヲrセゥ@ (1<>1' セ@ セN@ ('I1IT セ@ セ@
1. G)'
セ@
2. 'ill"{
3. '{J: 68. The gauche conformation (<p = 60°) of n-
4. 3ITO butane posseses "
66. Number of isoprene units present in lupeol is
1. plane of symmetry; and is achiral
2. Craxi s ofsymmetry; and is chital
3. centre· of symmetry; and is achiral
4. plane of symmetry; and is chiral
1. two
2. four hv
3. six
4. eight
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3. <:
1.
2.
3.
Barton reaction
Patemo-Buchi reaction
Norrish type I reaction
4. c:C
4. Norrish type II reaction
1. D--
H.._;;;:;
2. 0
3. <:
4. c:C
H
5/46 bjOQセahMT@
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!Jpl' '!r/PART .'(;'
73. The number of lone-pairs are identical in the
pairs:
71. 'QCii セ@ セ@ 41 Ar mfflict; セ@ t I. XeF4;CIF3
2. Xe04, ICI4.
34,500 fcrErCurffiio:rc cfir セ@ t ヲ。エセrッ@ tm:rr 6 3. Xe02F2, ICI4.
セ@ 75 filiJc c); GfiG' fm:re:a:r セ@ セ@ 4. Xe04, CIF3
2. 110 fm:rc
I. (A), (B), (C) (1"tJT (D)
3. QXPセ@
2. (B), (C) (1"tJT HdIセN@
4. 220 f.m:Jc
3. (A), (B) (1"tJT HdIセ@
71. A radioisotope 41 Ar initially decays at the rate of 4. (A), (C) (=ltff (D) $cr(;r,
34,500 disintegrations/ minute, but decay rate
falls to 21,500 disintegrations/minute after 75 74. Among the following, those can act as Mossbauer
minutes. The t 112 for 41 Ar is: nuclei are
(A) 1291 (B) 57Co (C) 57Fe (D) 121 gb
I. 90 minutes
2. 110 minutes l. (A), (B), (C) and (D)
3. 180 minutes 2. (B), (C) and (D) only.
4. 220 minutes · 3. (A), (B) and (D) only.
4. (A), (C) and (D) only.
72. MeTiCI3 (11.JT(C0)5Mo(tht) セ@ セ@ tntr
セ、ャオゥ_@ NMe3, PMe3 (1"tJT CO cfir セ@ 75. cr (1"tJT 011 セ。Qッウ@ ᄋセ@ tntr C1ilo1 .m . セ@ ,:)
mtTR'OJO: il<j¢q;(>ictlJ4 't"tJio=q:Q'I セ@ iiG1f(1T
セ@
61
I. CO ::> PMe3 > NMe3 and CO > NMe3 > PMe3 (A) Be(II), Ba(ll) (B) Ba(ll), Co(II) (C)
2. PMe3 >CO> NMe 3 and NMe3> CO> PMe3 Co(II), Zn(II) (D) Be(II), Zn(II)
3. NMe3 > PMe3 > CO and CO >PMe3 > NMe3
4. NMe3 > CO> PMe3 and PMe3>NMe3>CO I. (A) nt1T (B)
72. The orders of reactivity of ligands, NMe3, PMe3 2. (B) nt1T (C)
and CO with complexes MeTiCh and 3. (C) nt1T (D)
(C0)5Mo(tht) are
4. (A) (1"tJT (D)
l. CO> PMe3 > NMe3 and CO> NMe3 > PMe3
2.. PMe3 > CO> NMe3 and NMe3 > CO> PMe3 75. Which: of the pairs will generally result in
3. NMe3 > PMe3 > CO and CO >PMe3 > NMe3 tetrahedral coordination complexes, when ligands
4. NMe3 > CO> PMe3 and PMe3>NMe3>CO are cl- or 011:
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76. セ@ セ@ olt tR" セヲゥZAア[ャ@ セ@ セ@ [CoCI4t セi@ 1. there are two iron centers per active
site.
;H1};;qo1 セ@ tR" セ@ tar iftm セ@ セ@ セ@ 2. both iron centres are hexacoordinated in the
active state.
セ@ illfr Jm!Wrcr セ@ tR" セ@ tar 3. one iron is hexacoordinated while the other is
pentacoordinated in the active state.
セ@ セ」ュオイ@
4. it is found in marine invertebrates.
I. Co(II) changes its coordination from 79. [Bu4N]2Re2CI 8 TGャセᄋ。ゥWQB@ 'n'lf til4{Ji '# 15000
tetrahedral to octahedral.
em·• tR" v.:i cfm fs f.;m" flSfiiFIOI セ@ CfiT'lUT
2. Co(II) changes its oxidation state to
Co( III).
3. Tetrahedral crystal field splitting is NOT equal
to octahedral crystal field splitting. I. 1t -+1[.
4. Co(II) forms kinetically labile while
forms kinetically inert 2. B-+ B•
Co(III)
complexes. 3. B-+1t•
4. 1t-+ 0.
77. 79. Intense band at 15000 em·• in the UV-visible
spectrum of [Bu4NhRe 2CI 8 is due to the
transition:
l. セ@ セ@ セ@ セ@ .3IT<RCi"i' セ@ I. 1t -+1[ •
セi@ 2. B-+ B*
3. B-+1t •
2. セ@ 3{CI"ftTT セ@ セ@ .3IT<RCi"i' セ@
4. 1[-+0.
tcfm Ghifゥイ・ャセHQ@ セ@ セi@
3. セ@ 3{CI"ftTT セ@ 1Jijj' .3IT<RCi"i' tcmr 80. セ@ rot."lfJi' セ@ セiD|jGQ@ セ@ Ce(S04)2,
GhifゥエイcセHBャ@ セ@ セ@ セ@ セ@ 'W KMn04, HN02 '(11.TT h セ@ セ@ '# $<'14{1111
GXjゥエイciセHQ@ セ@ セ@ I アセ。aQ@ セ@ セ@ セイZ@ -
4. セ@ セ@ .:1
セ@ '# q'fliT セ@ セi@
I. 1e, 1e, 2e c=rtn' 4e
77. For the metalloprotein hemerythrin, the statement
that is NOT TRUE is 2. 1e, 3e, 2e c:rtrr 4e
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83. n-BuLi セ@ PhBr cfi'r セ@ 1. CO < C2F4 < CzH4 < NEt3
セ@ セᄋ@ セ@
2. CzF4 < C2H4 < NEt3 < CO
3. CzH4 < NEt3 <CO< CzF4
I. 2 n-BuPh + Brz + Liz 4. NEt3 < CzH4 < CzF4 < CO
· 2. PhPh + octane + 2 LiBr
3. n-BuPh + LiBr
4. PhLi + n-BuBr
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85. Identify the order representing increasing 7t- 88. Three bands in the electronic spectrum of
acidity ofthe following ligands [Cr(NHJ)6]3+ are due to the following transitions:
C2F4, NEt3, CO and c R セ@
(A) 4A28--+ 4T1 8
1. CO < C2F 4 < C2H4 < NEt3 (C) 4A2g--+2Es
2. C2F4 < cRセ@ < NEt3 <CO
3. C2H4 < NEt3 <CO< C2F4 Identify the correct statement about them
4. NEt3 < cRセ@ < C2F4. < CO
1. Intensity of(A) is lowest
86. firH:r セ@ セ@ セ@ セ@ セ@ iiacfil;q
.;)
2. Intensity of (C) is lowest
3. Intensities of(A), (B) and (C) are similar
セHエ」ヲnIVBL@ 4. Intensities of(B) and (C) are similar
1. VCl64-
2. (11 5-CsHshCr
89. m セ@ tt$<ti<ll)\ilcn ftJmm セ@ rn:cr
3. [Co(N02)6t セ@ .;) <h)' q$illfa'lQ
4. [Ni(EDTA)] 2-
86. The species with highest magnetic moment (spin (A) Nb, Ta (B) Mo, W (C) La, Lu (D) Sc, Y
only value) is 1. A C1m B tcfN
2. A C1m C tcfN
1. VCl64-
2. (11 5-CsHs)2 Cr 3. B CfmC tcfN
3. [Co(N02)6t 4. aLb・ヲュcセ@
4. [Ni(EDTA)t
87. Ir4(C0) 12 セ@ tm=r-tm=r .3fTiiitrr 'cfil" セ@ セ@ 89. Identify the pairs in which the covalent radii of
.;) .;)
elements are almost similar
(A) Nb, Ta (B) Mo, W (C) La, Lu (D) Sc, Y
1. 4
2. 6
1. A and B only
3. 10
2. A _and C only
4. 12
3. Band Conly
87. The number of metal-metal bonds in Ir4(C0) 12 is 4. A, B and C only
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91. セihエャヲゥAtィ」Z@
T->
(C) [Co(NCS)4f"
.:ld_
2. (A) and (B) only
l. 2
92. In complexometric titration 2. 3
S(substrate) + T{titrant) - t P(product) 3. 4
The end point is estimated 4. 5
spectrophotometrically. If S and P have & = 0, the
shape of the titration curve would look like. 94. Distribution· ratio of "A" between CHCh and
water is 9.0. It is extracted with several, 5 mL
aliquots of CHCh. The number of aliquots
needed to extract 99.9 % of "A" from its 5 mL
aqueous solution are
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I. QLセ@
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32
Ill. Unlmolecular gas phase reactions are second 99. x rrm y m<tM cfi %nr セ@ kl 11>1 m1 (i セ@ faQ"
order at low pressure but become first order
· at high pressqre. · 、nセ@
2. A= -2/3, B=1
3. A= -2/3, B=-1
4. A=O, B=O
X y
- h2 -1 1
4. O<E<-·-2
8mL 0 2
- h2 2. Tヲセ@
4. O<E<--2
8mL 3. Sd 'Cfl'lffCfi'
4. sヲセ@
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1. 3d orbital
2. 4f orbital
3. Sd orbital
4. Sf orbital
103. Identity the Mulliken notation for the following
irreducible representation
1. L3/6
X
2. L3/3
3. L3/4
4. L4/4 1. C2v
2. 54
3. D2d
4. D4d
-1
S/46 BJ/13-1 AH-5A
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1. 91ines
2. 81ines
3. 71ines
4. 61ines
a-E p 0 0
1. Czv
2. s4 p a-E p 0
1.
3. D2d
0 p a-E p
4. D4d
0 0 fJ a-E
105. Nb (tRmUT セTQI」ヲゥGイ@ . ヲセ\ィゥBャエr@ 3fCfftrr c)l
.;)
a-E f3 0 0
f3 a-E p 0
1.
1. Yセ@ ;# 0 fJ a-E f3
2. Xセャ@ 0 0 fJ a-E
SNWセC@
4. Vセャ@
S/46 BJ/13-1AH-5 B
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I 109. A system consists of gaseous H2 , 0 2, H20 and C0 2
a-E fJ 0 fJ
where the amount of C0 2 is specified and the
fJ a-E p 0
equilibrium constant for the reaction 2H 2 (g) + 0 2
2.
0 fJ a-E fJ (g) +::! 2H 2 0 (g) is known. The number of degrees
a-E p 0 p' 1. 2
2. 3
p a-E p 0 3. 4
3.
0 p a-E p 4. 5
セ@ セ@ tit1 ..;)
alfrlCfiCI: セ@ セ@ e,:1 セ@ aTS Cfi)"
a-E p 0 p
p a-E p 0
4.
0 p a-E p
0 p a-E (a) 3QOIIJiklCfiC1: セ@ H」Ijヲ\Zイッセ@ l:fO ('fii-1l"Cf
0
(b)diklCfiCI: セ@ H、IDエ^iセcヲゥャ@ セ@ セ@
l. 2
2. 3
3. 4
4. 5
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111. 100 MHZ セ@ q;r;4 lfi:{o; am nmr セGエQヲゥ」@
'illT セ@ q;{O')' tf;f lfill AX foicbW TMS
nm 1.0 ppm セ@ G.ft tR" 'm"{
*
4.72, 4.6, 1.12 3. セ@ -croT セ@ u セ@ d'l セ。イ@
H^ヲセ@ セ@ 6-J JAX ( Z jt ) セ@ 6AX (ppm セIL@ "
セエイ@
c)l m;r A[ャゥjセヲZ@ セGイ@ 4. m セᄋ@ セ@ -« 3'i't'Jfr it tfft:<mtn-
1. QRセit@ 3.6 fcnm \iTT セイ@ セ@
2. VセSN@
11.3 Which of the followin g statements is true for a
3. 12 a-m 2.s6 cyclic process?
4. 6(lm'2 .86
1..
fdq :-_" 0
Ul. An AX system gave 41ines at 4.72, 4.6, 1.12 and
1.0 ppm away from TMS using an nmr fdw=O
spectromet·er operati ng at 100 MHz. What are 2.
the values of JAx (in Hz)and 6Ax (in ppm), 3. Heat can be comple tely converted Into work.
respecthtely? 4. Work can be comple tely convert ed Into heat.
1. 12and 3.6 H4.(a)'Q'Cfi 0.01 セ」ャG@ NaCI セ@ CflllT (b) 'Q'&1 0.01
2. 6 and 3.'6
[jZセ@ Na 2 S0 4 セ@ cf1T セ@ セア[@ 。ャGjrtセ@
3. 12 and 2.86
4. 6 and 2.86 WlFiiifcl'lf.mcf ** trtrtrrf;Rtr
QRNセ@ k8T 1, = J.'ff;f 1WJr -;,;mr dt セ@ SMQセ@ 1. (a) 0.0:1.0 mol kg- 1 (b) 0.010 mol kg- 1
2. (a) 0.010 mol kg- 1 (b) 0.030 mol kg- 1
S^セ@ セ@ {Ej) セ@ セ@ foW;r セ@ セ@ 3. (a) 0.010 mol kg- 1 (b) 0.025 mol kg- 1
セcrG@ (E1) セᄋ@ 2 ᄋセ@ 3Tfi'lq; 6, c)) ftRr tl"r.RT 4. (a} 0.010 mol kg- 1 (b) 0.015 rnol kg- 1
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1. 10- 2 ks
2. 10 2 k8
3. 460.6 k 6
4. 4.606 k 8
:111 . .A. plane of spacing d shows first order Bragg
116. f.!:sTcn:r セ@ 0 + ne <==! R ih セ@ Cfi'to:r ffi diffractio n at angle 8. A plane of spacing 2d
3-ITRur rAs-+ oo
11 7. "QCfi d CfiT rn;r セ@ CfiT セ@ fclcrl;-., 3. This is a covalent term and is importa nt as
fj Ch'rcrr tR:' セ@ 13"! 2d セ@ .3fc:RuT '(-'f(>f f'Aa-l> 0
4. This is an ionic term and is importa nt as
I. セMjヲ@ セ@ 28 '!:f.( f?,'@Q'dl!! イNセウMK@ 0
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1. 108 g/mol
セ@ B t" 0.1 M fci<;rlm em' セ@ 'ETiiFCf
2. 104 g/mol
0.1761 l\"1 3. 105 g/mol
4. 106 g/mol
B
·at i\.1 nm. Another O.lM solution of compound
0.1761 using I. 103 g/mol
gives the optical density value of
2. 104 g/mol
1c:m cell at i\.1 nm.
3. 105 g/mol
4. 106 g/mol
What will be the transmittance of a solution that
Is simultaneously 0.1M in A and O.lM in B using
the same cell and at the same wave length? 121. fo)Hr セ@ セ@ ffi1Ff11ffiffilet セ@ c)j ft:rQ' セ@
セ@
13 C NMR ヲセcサfi@ セ@ trftr
'ti Cl'ficJHU I nm- i1JftO セ@ eft セ@ 3ft "11111 Cfll t) !f1Cfl4t>"5
セi@
4. B"(!"Cfl" セ@ :mrc; セ@ セ@ セ@ mcT;r
!f1Cfl4t>"S 13 C NMR ヲセcjoi@ セ@ trftr セ@
セi@
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121. Among the following, the correct statement for
123. Foi <hii 1"<>1 ffikt f' q i<1 ::co 1 cfi ft:rv cfitCi1' m 'QCf,'
the following reaction is
セ@ fi1thl1 ffi \7SI (1 * セ@ セ@ セ@
1. MeMgBr, Et2 0
2. H3P04
A B
A B
1. A is the major product and it will have 1. A "Qqi' セ@ セ@ セ@ om セ@ '(!q1 セ@
five signals in the proton decoupled
13 C NMR spectrum.
セi@
2. A lrcfl セ@ セ@ セ@ om セ@ lJCfl
2. A is the minor product and it will have Q.,-t'l;h<R セ@ tl
eight signals in the proton decoupled
13C NMR spectrum. 3. 8 "Qqi' セ@ セ@ セ@ c:rm セ@ Vt11 sm=r
3. B is the major product and it will have
セG@
five signals in the proton decoupled
4. 8 'C!Cfi セ@ セ@ セ@ nm セ@ 1JCfi
13C NMR spectrum. lJ.,-t'ISh<R セ@ セi@
123. Which one of the following statements is true for
4. B is the minor product and it will have the following transformatio n?
five signals in the proton decoupled
13C NMR spectrum OH
セcho@ セmァbイN@ QH
Et2 0 /'... ).._ -
Ph I Ph- I NLセ@ + pィセ@
セ@ セ@ セ@
122. A Cfi)" セ@ W ;R- B t" 4fiClACi1 t" fmr A B
セjゥエ@ Cfif 34 liCfC1 Sli11 セ@ 1. A is the major product and it is a Cram
.:>
product.
OH 1\ 2. A is the major product and it is anti-Cram
I
0 0
セoh@
product.
セcho@
A
_ _._
v B
3. B is the major product and it is a Cram
product.
4. B is the major product and it is anti-Cram
1. Mn0 2; (CH 20Hh I p-TSA; PCC. product.
2. PCC; Mn0 2 ; (CH 20H)z I p-TSA;
3. PCC; (CH 2 0Hh I p-TSA; セ@ セ@ 124. f.i <hl1 f<>1 \7SI C1 f' 4 i(i '{ o I <f; ft:rv cfitCi1' tiT Qq:;
4. セ@ セ[@ (CH 20Hh I p-TSA; MnOz. セ@ Foi <hl1 R:t \7SI (i ;P,- セ@ セ@ 6
122. For the following three step conversion of A to B,
the appropriate sequence of reactions is
OH {\
&0 tya (ro +
l. m-CPBA 34 セcヲHゥ@
.:J
セ@ 6 ('l'm B
1. Mn02 ; (CH 2 0H}z I p-TSA; PCC.
2. PCC; Mn0 2; (CH 20H)z I p-TSA;
セG@ .:J
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H03Sro
2.
HO セ@
&"
A
セ@ A + (7
A
3.
co
1. Suitable reagent is m-CPBA and B is the
A B
4.
om
major product.
エRVNセィイャヲゥr@ セ@ if· セ@ RJrmnT wrt セ@
2. Suitable reagent is m-CPBA and A is the
major product. アヲ」イセ@ セ@ セ@ セ@ セ@
3. Suitable reagent is aq. H20 2/NaOH and B is
エセ・@ major product.
4. Suitable reagent Is aq. H20 2/NaOH and A is
1.
0=0
125.
the major product.
2. 0=0
SNセ@
4. 0=<
127. UV-Vis ヲセcsHjBゥ@ J:f QCfi 51$C.fClan$5 CfiT
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+ _____
1. .1. _,....
I I 2. TiC1 3 , HCI
2.
1. Do
GBPセ@ 2.
Do
hoセLM H h> 3. DNH,
4.
Hooc-· A 4.
DNH2
127. In the UV-Vis spectrum, a diterpenoid exhibited a
129. G"tr fs Mセzjヲ「ZャHBG@ HセGィT\BUI@ 13 C NMR 'f<)<f?JO'I
Amax at 275 nm. The compound, among the t. _, .!)
セ@ rna01(>1i セ@ セ@ セヲZ@ セ@
1. I
ohュZセ@
2.
I I
HO
F I
I
..&
..&
..&
..&
OH
A B
HOOC,... H
ohュZセ@
+
1. f1
2. TiCI3, HCI HO
F I
I
.&
.b
.&
.
.b
OH
A B
S/46 BJ/13-1AH-6,
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a· 7.80 (2 H, d, J =8HZ), 6.80 (2 H, d, J =8 Hz), 4.10
(2 H, q, J = 7.2 Hz), 2.4 (3 H, s), 1.25 (3 H, t, J"" 7.2
Hz)
1
,
2.
eioセ@
. iセ@
MeO .d 0
131. a-Pinene on reaction with dilute alkaline KMn04
SNセ@ HO o
produces a dlol, which on ·further. oxidation with
chromium trioxide gives product A, which
セom・@ undergoes a positive halo.form test, , The.
4. A..)
サZセ@ Zセァ。ョゥ」@
compound A Is
ᄋセ@
0
1. ᄋセ@
. eioセN@
2
QSRNセ@ 3114l51$5 <);' 'QCii セ@ <);' mtr.
MeO)l_) 0
ac=HOi'l{ftiii セ@ セ@ t .¢ crrm セ@
SNセ@
セ@
o セVQ@
4. ffoMe.
HO
Et
セ@ セ@ セ@ t セ@ 3lfcl)" sヲャセ[アゥ@
Sf$"31JCftll$5 セ@ 31Jcwflfcl セ@ セN@ A
. '
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132. The major product formed in the reaction of 133. The major product formed in the following
guanosine with one equivalent of methyl iodide is reaction is
1.
c¢ 0
2. 1.
2.
3.
3.
4.
4.
c¢ 0
1.
1. Gly-Leu + toluene + carbon dioxide
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1. XIs
ro COOEt.
N02 ·
o
Y Is セMcoeエ@
セnO@
H
•
2. X Is
セP@
セNL@ CQ.OEt Yis
OC( OH
N02 . N 0
H
N02
:Et Vis 9.:(.
NO 0
H
2. Phe-Leu + toluene + carbon dioxide '
2. m・ocセ@
UoH
OH
4.
0-y
0
OH 3. Vis
y(o
HO セcoeエᄋ@
OH
Me
"· . 0I-"" OH
SniHCI 0I "" 0H
A¢-;_0
.
0I 0H
hセ@ 0
1• ·,UoH
3. pィセoh@
0
OH
.v OH
HN03
0 2N-
セoh@
(70%)
0
セ@
{9o%) H2N.
·(YOH
..f: セHsoEI@
A¢-;_O
AcHN
r(Y?H
セnq R@ セnh R@ (90%)
2. m・ocセ@
OH
OH
4.
Oy HO
(25%)
(90%) VJ-..NHAc
CC N0 2
+ (COOEth NaOEt X Zn I AcOH y
1. 57 3fit 20%
2. 57 3fit 68%
3. 83 "3fit 68%
4. 83 3fit 20%
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A crOH Sn/HCI
I -1
o:OH
-1
Ae;_O o:OH
F OH
N02
A
(25%)
(90%) A NH 2 (90%) A NHAc
Hy}yH MeyfyOH
2. and
hセ@ hセm・@
F H
The overall yield for the formation of p-
hydroxyacetanilide and o-hydroxyacetanilides F OH
Hy}yH Hy}yOH
from phenol, respectively, are approximately 3. and
hセ@ m・セh@
l. 57 and 20%
F Me
F Me
2. 57 and 68% Hy/yF HyfyOH
4. and
3. 83 and 68% hセ@ hセo@
H Me
4. 83 and 20%
139. p-TSA セ@ ScBセI[H」Zャゥ@ m:IT セ@ セ@ セ@ (5)-
F OH
Hy}yH MeyjyOH
2.
hセ@
and
hセm・@ 2. hoセ@
F H 0........_,0
F OH Ph
Hy}yH HyfyOH
3. and P セPh@
hセ@ m・セh@ 3.
F Me Ph)-d
F Me P Ph@セ
Hy}yF HyfyOH lセ@
4. and ,· 0
hセ@ hセo@ 4. Ph''
H Me
139. Reaction of (5)-1,2,4-butanetriol with
138. The most stable conformations of 1,2-
benzaldehyde in the presence of a catalytic
difluoroethane and d/-2,3-butanediol are
amount of p-TSA furnished the major product A.
The structure of A is
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46
.1. QNセ@
2. cb OH
2. 3.
ᄋセ@ 8 "'-/
4. C? 0
3.
QTNセhヲbャイッHBL@ '' ; '
セ@ . '
lT セ@ ctT(q1' セ@ ..:>
セ@
4.
1. NaH, CS2, Mel
QTVNゥIAィセrァサ@ ᄋセ@ "8 セ@ 」エャHアGᄋセ@ 2 200°C
セNエ@
1.
KH/THF
2.
3.
IH
4.
'2.
CD OH
141. The. major product formed In the following
:3.
セ@
0
reaction Is
C) 0
. 1. NaH, CS 2 , Met
....
d5 OH
セMNZ⦅ᄋL@
KHlTHF
S/46 BJ/13-1AH..,-7B
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0
1. 1.
2.
-P:
)(yo
·
2.
0
3.
3.
セ@
4.
4.
>cz:H
QTSNヲゥャィjサ[Iセ@ 3ffilfslilll '# セ@ セ@ セ@ ..;)
セ@
hv, EtzO
2 &
1. c:: )
1.
p\
0
cf
2.
3.
(!P
2. )(yo C8 OH
0 4.
ct)
3.
-0-OH A
1. WOH
2.
GP
3.
00 OH
4.
CD H
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144.fi1Ma"lffllo ᄋセ@ Sfi1f '# セ@ ifi'r gBセtヲ@ , 1. GAnゥtセヲ@ セhiヲゥQ_ャ@ セit@ '# cヲゥャッZイMセ@ HヲセャB@
B
«HillfiiCfl '# ヲゥュMセQ@
2. Ph 3P=OHC00Et 3. @セ セイ@ '# cャゥ[Zイセ@ @セ (ftTf キュセイ@
(excess)
hャヲゥセ@ セ@ Cfila:r- セ@ I
4. セt@ 'HllllfiiWi セit@ # fS«- セ@ (ftTf
ᄋセGCM@
1. A Is hv
0 ($.
H
4. A is 6. B is '-{"cooEt
セcoeエ@
144. Predict the condition A and the structure of the 1. con-rotatory in photochemical;. and
major product B in the following sequence. dis-rotatory in thermal conditions.
photochemical conditions
;
2. A is hv B is :c:COOEt
COOEt
x::::COOEt
3. A is 6. B is
. . COOEt
4. A is 6. B is
:C::,
QTUjセcィイヲエ^ャサAIH@ 't\%-i{O( df ilsfi'ICfi{OI CfiT セ@
3q':).CfH セ@ セ@
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