Oman Refinery Company LLC.

,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

LIQUEFIED PETROLEUM GAS

MATERIAL SAFETY DATA SHEET

1. Product & Company Identification

Commercial Name: Liquefied Petroleum Gas or LPG
Application: Used as a cooking gas.

Manufacturer: Supplier: Emergency Contact:

Oman Refinery Company LLC. Oman Refinery Company LLC. Phone (+968) 24570999
P.O. Box 3568, Ruwi, P.O. Box 3568, Ruwi, (24 hours) and During
Postal Code 112, Muscat, Postal Code 112, Muscat, office Hours (+968)
Sultanate of Oman Sultanate of Oman 24570718
. Fax (+968) 24560254

2. Composition/ Information on Ingredients

Chemical Family: Aliphatic Hydrocarbons

Hazardous ingredients:

Hazardous Approximate CAS Number UN Number

components Percentage
By weight
Propane 74-98-6 1978
Butane 106-97-8 1075

Note: May contain a very small dosage of odouriser for leak warning of the gas.

Hazardous warning: 2A- Flammable Gas

LPG Page 1 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

3. Hazards Identification
HIGHLY FLAMMABLE. KEEP AWAY FROM SOURCES OF IGNITION.

Potential Health Effects

Main Hazards: Vapourised liquefied petroleum gas is highly flammable and can form
explosive mixtures with air. The vapourised liquid does not support life. It can act as simple
asphyxiant by diluting the concentration of oxygen in the air below the levels necessary to
support life. It can act as a simple asphyxiant.

Adverse health Effects: The liquefied petroleum gases are non-toxic. Prolonged inhalation of
high concentrations has an anesthetic effect.

Biological hazards: Contact with the liquid phase of the liquefied petroleum gases with the
skin can result in frostbite.

Vapour inhalation: As the vapourised liquid as act the simple asphyxiant death may result
from errors in judgment, confusion or loss of consciousness which prevents self rescue. At
low oxygen concentrations, unconsciousness and death may occur in seconds without
warning.

Eye Contact: Contact with the liquefied or pressurized gas may cause momentary freezing
followed by swelling and eye damage

Skin Contact: Contact with the liquefied or pressurized gas may cause frostbite (cold
burn).This material is a gas under normal atmospheric conditions. No harmful
effects from skin absorption are expected.

Inhalation (breathing): Low degree of toxicity by inhalation. Asphyxiant. High

concentrations in confined spaces may limit oxygen available for breathing. .

Ingestion (Swallowing): This material is a gas under normal atmospheric conditions and
ingestion is unlikely.

Signs and symptoms: Effects of overexposure may include irritation of the respiratory tract,
irritation of the digestive tact, diarrhea, transient excitation followed by signs of nervous
system depression (e.g. headache, drowsiness, dizziness, loss of coordination, disorientation
and fatigue.)

Light hydrocarbons are simple asphyxiants and can cause anesthetic effects at high
concentrations. Symptoms of overexposure, which are reversible if exposure is stopped, can
include shortness of breath, drowsiness, headaches, confusion, decreased coordination,
visual disturbances and vomiting. Continued exposure can lead to hypoxia (inadequate

LPG Page 2 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

oxygen), cyanosis (bluish discolouration of the skin), numbness of the extremities,

unconsciousness and death.

4. First Aid Measures

Eye Contact: For contact with the liquefied gas, hold eyelids apart and gently flush the
affected eyes with luke warm water. Seek medical attention immediately.

Skin Contact:
Treat burned or frostbitten skin by flushing or immersing the affected areas in luke warm
water. After sensation has turned to the frostbitten skin, keep skin warm, dry and clean. If
blistering occurs, apply a sterile dressing.. Seek medical attention immediately

Inhalation breathing): If respiratory symptoms develop, move victim away from source of
exposure and into fresh air. If symptoms persist, seek medical attention. If victim is not
breathing, clear air way and immediately begin artificial respiration. If breathing difficulties
develop, qualified personnel should administer oxygen. Seek medical attention
immediately

Ingestion (Swallowing): This material is a gas under normal atmospheric conditions and
ingestion is unlikely.

Pressure injection: Always obtain immediate medical attention even though the injury may
appear minor.

5. Fire Fighting Measures

Extinguishing media:

Do not extinguish fire unless the leakage can be stopped. Do not use water jet. Use Dry
Chemical Powder, Carbon dioxide or foam.

Special Hazards:
The rupturing of cylinders or bulk containers due to excessive exposure to a fire could result
in a BLEVE (Boiling Liquid Expanding Vapour Explosion) , with disastrous effects. As the
flammability limits in air for the main constituents of liquefied petroleum gas vary between
approximately 2 and 11% by volume, extreme care must be taken when handling leaks.

LPG Page 3 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

Emergency Actions:
If possible, shut off the source of the spillage. Evacuate area downwind of fire. Post notices
“NO NAKED LIGHTS –NO SMOKING “ . Use water to keep fire-exposed containers cool
and to protect personnel effecting shutoff. If a leak or spill has not ignited, use water spray
to disperse the vapours and to protect personnel attempting to stop leak, prevent runoff
from fire control or dilution from entering streams, sewers or drinking water supply.
.
Special protective equipment:
For fires in enclosed areas, fire fighters must use self-containing breathing apparatus.

Unusual fire and explosion hazards:

Extremely flammable. vapour accumulation could flash and/ or explode if in contact with
open flame. Pressurized containers may explode if exposed to open flames or high
temperatures.

Hazardous decomposition products::

Carbon monoxide

Environmental precaution:
Vapourised liquefied petroleum gas is heavier than air and could form pockets of oxygen –
deficient atmosphere in low lying areas.

6. Accidental Release Measures

Personal Precautions: Do not enter any area where liquefied petroleum gas has been
spilled unless tests have shown that it is safe to do so.

Environmental Precautions:

The danger of widespread formation of explosive LPG/ Air mixtures should be taken into
account. Accidental ignition could result in a massive explosion.

Small spills:

Do not extinguish the fire unless the leakage can be stopped immediately. Once the fire has
been extinguished and all spills could result in a massive explosion.

Large spills:

Stop the source if if it can be done without risk. Contain the leaking liquid, with sand or
earth or disperse with special water/ fog spray nozzle. Allow to evaporate. Restrict access
to the area until completion of the clean-up procedure. Ventilate the area using forced-
draught if necessary. All electrical equipment must be flameproof.

LPG Page 4 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

Notification procedures:

Report spills as required to appropriate authorities

7. Handling and Storage

Handling: Contents under pressure. The use of explosion proof electrical equipment is
recommended and may be required.

Do not enter confined spaces such as tanks or pits without following proper entry
procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory
protection is advised when concentrations exceed any established exposure limits,

Use good personal hygiene practices.

Before working on or in tanks, which contain or have contained this material, refer to OHSA
regulations, ANSI Z49.1 and other references pertaining to cleaning, welding, or other
contemplated operations.

Empty containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze,
solder, drill, grind or expose such containers to heat, flame, sparks, or other sources of
ignition. They may explode and cause injury or death. Containers should be disposed of in
an environmentally safe manner and in accordance with governmental regulations.

Before working on or in tanks, which contain or have contained this material, refer to OHSA
regulations, ANZI Z49.1 and other references pertaining to cleaning, repairing, welding, or
other contemplated regulations.

Storage: Keep containers tightly closed. Use and store this material in cool, dry, well-
ventilated areas away from heat, direct sunlight, hot metal surfaces and all sources of
ignition. Post area “No smoking or open flame”. Store only in approved containers. Keep
away from any incomplete material. Protect containers against physical damage. Outdoor or
detached storage is preferred.

Cylinders containing liquefied petroleum gas should only be handles and stored in the
vertical position. Cylinders should never be rolled. Do not allow cylinders to slide or come
into contact with sharp edges and they should be handled carefully. Ensure that cylinders
are stored away from other oxidants. Comply with all local legislation.

LPG Page 5 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

8. Exposure Controls/ Personal Protection

Ventilation System:
Use in well-ventilated area with local exhaust ventilation. Ventilation required and
equipment must be explosion proof. Use away from all ignition sources.

Engineering control measures:

Engineering control measures are preferred to reduce exposure to oxygen-depleting
atmospheres. General methods include forced-draught ventilation, separate from other
exhaust ventilation systems. Ensure that all electrical equipment is flameproof.

Personal protection:
Self-contained breathing apparatus should always be worn when entering area where
oxygen depletion may have occurred .Safety goggles , gloves and shoes, or boots, should be
worn when handling containers.

Skin Protection:
No special requirements under ordinary conditions of use. Thermally protective gloves must
be worn when handling liquid to prevent skin contact and frostbite.

Other Protective Equipment:

A source of clean water should be available in the work area for flushing eyes and skin.
Impervious clothing should be worn as needed.

Occupational Exposure Hazards:

As vapourised LPG is a simple asphyxiant, avoid any areas where spillage has taken place.

Occupational Exposure Limits;

Chemical Name CAS No. Exposure Limits Toxicity data

(OSHA PEL) (ACGIH TLV)
Propane 74-98-6 1000 ppm The ACGIH recommends a limit of
1000 ppm in air be applied for all
simple asphyxiates and a minimum
of 19.5 % oxygen (volume) be
maintained.
Butane 106-97-8 800 ppm The ACGIH recommends a limit of
1000 ppm in air be applied for all
simple asphyxiates and a minimum
of 19.5 % oxygen (volume) be
maintained.

LPG Page 6 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

9. Physical and Chemical Properties

Typical physical characteristics are given below. Consult product data sheet for specific
details.

Appearance Liquefied Gas

Colour Colourless
Odour Foul
Vapour pressure-mmHG 20 .C 750-1050
Vapour density (Air=1) 1.72
Evaporation rate NA
Density 20.C,Kg/l 0.55- 0.57
Percent volatile 100%
Solubility in water Negligible
LEL% 1.6
UEL% 9.3
Auto ignition temperature .C 426.C
Note:

NA=Not applicable, NE=Not established, D=Decomposes

10. Stability and Reactivity

Stability:
Stable under normal ambient and anticipated storage and handling conditions of
temperature and pressure. Flammable gas.

Conditions to Avoid:
Heats, sparks, flame, and build up of static electricity

Materials to avoid (Incompatible Materials): Contact with strong oxidizing agents such as
nitrates, perchlorates, chlorine, fluorine.

Hazardous decomposition products: Combustion may generate toxic carbon monoxide.

Hazardous polymerization:
Will not occur

LPG Page 7 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

11. Toxicological Information

• Acute toxicology

o Oral toxicity (rats)

Not applicable

Dermal toxicity ( rabbits)

Not applicable

o Inhalation toxicity (rabbits)

Practically non-toxic (LC50: greater than 5 mg/l) Based on testing of similar products
and /or the components.

o Eye irritation (rabbits)

Practically non-irritating. (Drain score: 0 or greater but 6 or less). Based on testing of
similar products and /or the components.

o Skin irritation (rabbits)

Practically non-irritating. (Primary irritation index; 0.5 or less). Based on testing of
similar products and /or the components.

ƒ Other acute toxicity data

This product is an asphyxiate. Simple asphyxiates act by displacing oxygen in the lungs
thereby diminishing the supply of oxygen available to the blood and the lungs. Continued
lack of oxygen may result in convulsions, loss of consciousness and death. Since exercise
increases the tissue need for oxygen, symptoms will occur more quickly during exertion in
an oxygen-deficient environment. Oxygen in enclosed spaces should be maintained at 21%
by volume. In addition, exposure to this product may cause as general central nervous
system (CNS) depression typical of anesthetic gases or intoxicants.

12. Ecological Information

There is no information available on the eco-toxicological effects of petroleum gases. Because
of their high volatility, they are unlikely to cause ground or water pollution. Petroleum
gases released into the environment will rapidly disperse into the atmosphere and undergo
photochemical degradation.

LPG Page 8 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

13. Disposal Considerations

o Waste disposal:
Product is suitable for burning in an enclosed, controlled burner for fuel value or
disposal by supervised incineration.

o RCRA information
Disposal of unused product may be subject to (Resource Conservation and recovery
Act) RCRA regulations (40CFR 261) due to the characteristics / chemicals listed
below. Disposal of the used product may also be regulated due to ignitability,
corrosively, reactivity or toxicity as determined by the toxicity Characteristic leaching
procedure (TCLP)
.

14. Transport Information

USA DOT
Shipping name Petroleum Gases, Liquefied
Hazard class & Division 2.1
ID Number UN 1075
ERG number 22
Packing group NA
STCC NE
Dangerous when wet No
Poison No
Labels Flammable Gas
Placards Flammable Gas
Product RQ NA
Marpol III status NA

RID/ADR
Hazard class 2
Hazard substance 4(b)
Label 3
Danger number 23
UN Number 1075
Shipping name Mixtures of hydrocarbons (Liquefied Gas)
Remarks NA

IMO
Hazard class & Division 2.1

LPG Page 9 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

UN Number 1075
Packing group NA
Shipping name Petroleum gases, Liquefied
Labels Flammable gas
Marpol III status NA

ICAO/ IATA
Hazard class & Division 2.1
ID/ UN number 1075
Packing group NA
Shipping name Petroleum gases, Liquefied
Subsidiary risk NA
Labels Flammable gas, cargo Aircraft only

15. Regulatory Information

Risk /Safety Phrases

Risk Phrases
R3 Risk of explosion by shock, friction, fire or other sources of ignition
R 13 Extremely flammable liquefied gas
R 18 In use, may form flammable / explosive vapour –air mixture
R 20 Harmful, if inhaled
R 44 Risk of explosion if heated under confinement
Safety Phrases
S9 Keep container in well ventilated place
S 23 Do not breathe gas / fumes /vapours / spray
S 27 Take off immediately all contaminated cloth
S 50 Do not mix with any oxidizing agent
S 51 Use only in well ventilated areas

LPG Page 10 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)

 Oman Refinery Company LLC.,
P.O.Box 3568 Ruwi, Postal Code: 112, Muscat, Sultanate of Oman

16. Other Information

™ OSHA Precautionary Label test: Contains Liquefied Petroleum Gas
™ Warning:

o Extremely flammable liquid and gas under pressure. May cause flash fire.
Exposure to high concentrations may cause general central nervous system
depression and suffocation. Keep away from heat, sparks and flame. Avoid all
personnel contact with liquid and breathing gas. Keep container closed and
secured. Use only with adequate ventilation. Do not depend on odour to detect
presence of gas.
o First aid: if inhaled and symptoms develop remove to fresh air. If not
breathing give artificial respiration, preferable mouth to mouth. If breathing is
difficult, give oxygen. Get medical attention. For freeze burns, immerse exposed
area in warm water and get medical attention.

™ Attention::

o Empty containers may contain product residue, including flammable or

explosive gas. Do not cut, puncture or weld on or near the container. All label
warnings and precautions must be observed until the container has been
thoroughly cleaned and destroyed.

Revision Information: First issue of the Material Safety Data Sheet

Compiled by: QHSE Department of Oman Refinery Company LLC

Disclaimer of Expressed and implied Warranties:

This information on the Material Safety Data Sheet is based on data believed to be
accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO
WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE,
OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING
THE ACCURACY OR COMPLETENESS OF THIS INFORMATION PROVIDED
ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION
OF THE PRODUCT, THE SAFETY OF THE PRODUCT, OR THE HAZARDS RELATED
TO ITS USE. No responsibility is assumed for any damage or injury resulting from
abnormal use or from any failure to adhere to recommended practices. The information
provided above, and the product, are furnished on the condition that the person receiving
them shall make their own determination as to the suitability of the product for their
particular purpose and on the condition that they assume the risk of their use. In
addition, no authorization is given nor implied to practice any patented invention
without a license.

LPG Page 11 of 11 Date of Issue: June, 2007 Revision: 0 (First issue)