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ORGANIC CHEMISTRY FUNCTIONAL GROUPS:

FUNCTIONAL GROUPS WITH SINGLE BONDS TO OXYGEN

ALCOHOL
(R= CnHn+2 or H) HEMIACETAL
The functional group when an -OH group (R= CnHn+2, R = CnHn+2 or H)
is attached to the central carbon atom. When one OH group in a 1,1-diol is
Alcohols can be primary (RCH2OH), replaced by one OR group this gives
secondary (R2CHOH) or tertiary a hemiacetal
(R3COH).

1,1-DIOL
(R= CnHn+2 or H)
DI = two, OL = alcohol functional group
Two -OH groups are attached to the
same carbon atom

ETHER ACETAL
(R= CnHn+2, R = CnHn+2 or H)
(R= CnHn+2 or H)
When the OH groups in a 1,1-diol
A central oxygen atom is bonded
are replaced by two OR groups this
to two hydrocarbon groups
gives an acetal

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