Nombre Dan Jefte Rivera Almaraz

Materia Termodinamica
Tema Calor latente de vaporización

Profesor MIP. Eladio Daniel Aquino Chan

Datos Acetona:
Tb= 329.7 °K
Tc= 508.7 °K
Pc= 46.6 atm
P= 1.0 atm
ꙍ= 0.309
Datos Agua:
Tb= 373.0 °K
Tc= 647.3 °K
ΔHv,b= 9,708.3 cal/g*mol
R= 1.987 cal/g-mol K

Calculos:

Tb,r= 0.6481 Pr
Pr= 0.0215 0.02
ΔZv(Interp)= 0.9660 0.0215
ΔZv(Graf.)= 0.9674 0.03

ΔHv,b= 6,908.69 cal/g-mol

ΔHv,breal= 7,230.00 cal/g-mol
% error= 4.44 %

ΔHv,b= 7,164.7 cal/g-mol

% error= 0.90 %
 ΔHv,b= 7,218.4 cal/g-mol
% error= 0.16 %

ΔHv,b= 7,068.6 cal/g-mol

% error= 2.23 %

Datos Acetona:
T1= 100.0 °C
T2= 300.0 °C
Tc= 647.3 °K
ΔHv,b= 9,708.3 cal/g*mol

Calculos:

ΔHv(at 300°C)= 5,910.1 cal/g-mol

ΔHv(tabla)= 5,949.0 cal/g-mol
% error= 0.65 %

Table 1.6 Values of ΔZv as a Function of Reduced Pressure

Pr Zv-ZL
0 1
0.01 0.983
0.02 0.968
0.03 0.954
0.04 0.942
0.05 0.93
0.06 0.919
0.08 0.899
0.1 0.88
0.15 0.838
0.2 0.802
0.25 0.769
0.3 0.738
0.35 0.708
0.4 0.677
0.45 0.646
0.5 0.612
0.55 0.578
0.6 0.542
0.65 0.506
0.7 0.467
0.75 0.426
0.8 0.382
0.85 0.335
0.9 0.28
0.92 0.256
0.94 0.226
0.95 0.21
0.96 0.192
0.97 0.17
0.98 0.142
0.99 0.106
1 0
 Formulas: Formulas:
1. Clapeyron equation and compressibility factor [20]: 3. Riedel method [22]:

2. Chen method [21]: 4. Pitzer correlation:

Zv-ZL
0.968
0.9660
0.954
 Calculos:
T1= 373.0 K
T2= 573.0 K
Tr,1= 0.5762
Tr,2= 0.8852

ced Pressure
Zv-ZL Logarithmic (Zv-ZL) Polynomial (Zv-ZL)
1.2
f(x) = − 0.201451196416801 ln(x) + 0.32330455435827
R² = 0.77899823822677

1
f(x) = − 22.1107823475 x⁶ + 56.5488846839 x⁵ − 51.6161858597 x⁴ + 18.8032429287 x³ − 1.45105284103 x² −
R² = 0.998429005981897
0.8

0.6
Pr

0.4

0.2

0
0 0.2 0.4 0.6 0.8
Zv-ZL
0.2

0
0 0.2 0.4 0.6 0.8
Zv-ZL
 Formulas:
od [22]:

ation:
L) Polynomial (Zv-ZL)

32429287 x³ − 1.45105284103 x² − 1.11700591458 x + 0.99190482756

6 0.8 1 1.2
L
6 0.8 1 1.2
L