Liquid Solutions

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Anupam Gupta
Anupam Gupta
B.Tech & M.Tech - IIT Delhi

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Liquid Solutions
JPP
JPP 1

Anupam Gupta
On the basis of intermolecular forces predict the correct order of
decreasing boiling points of the compounds:

A. CH3OH > H2 > CH4

B. CH3OH > CH4 > H2
C. CH4> CH3OH > H2
D. H2 > CH4 > CH3OH
Which characterises the weak intermolecular forces of attraction in a liquid ?

A. High boiling point

B. High vapour pressure
C. High critical temperature
D. High heat of vaporization
The vapour pressure of water at 20°C is 17.54 mmHg. What will be the
vapour pressure of the water in the apparatus shown after the piston is
lowered, decreasing the volume of the gas above the liquid to one half of
its initial volume (assume temperature constant)
A. 8.77 mmHg
B. 17.54 mmHg
C. 35.08 mmHg
D. between 8.77 and 17.54 mmHg
How many grams of NaOH will be needed to prepare 250mL of 0.1 M solution

A. 1g
B. 10g
C. 4g
D. 6g
How many grams of glucose should be dissolved to make one litre solution of
10%(w/v) glucose.
A. 10g
B. 180g
C. 100 g
D. 1.8 g
All of the water in a 0.20 M solution of NaCl was evaporated and a 0.150
mol of NaCl was obtained. What was the original volume of the sample ?

A. 30 mL
B. 333 mL
C. 750 mL
D. 1000 mL
 Multi Option Correct

Which of the following form ideal solution?

A. C6H5l + C6H5Br
B. C4H9Cl + C4H9Br
C. n - hexane + 1 heptanol
D. C6H5OH + CHCl3
 Multi Option Correct

The total vapour pressure of binary solution is given by p = ( 110 xA + 125 xB )

mm where xA and xB are the mole fractions of components A and B
respectively it suggests that
A. The vapour pressure of solution (nA = nB) is less than the pure B component
B. The vapour pressure of solution (nA = nB) is more than the pure A component
C. Vapour pressure of pure A is 110 mm Hg and that of pure B is 125 mm Hg
D. The vapour pressure of pure A and B are 125 mm Hg and 110 mm Hg respectively
Benzene and toluene form nearly ideal solutions. At 20 oC, the vapour
pressure of benzene is 75 torr and that of toluene is 22 torr, The partial
vapour pressure of benzene at 20 oC for a solution containing 78 g benzene
(MW - 78) and 46 g toluene (MW-92) in torr is:
A. 50
B. 25
C. 375
D. 53.5
Two liquids A and B form an ideal solution. When total pressure of this
solution is 600 torr, the amount fraction of A in the vapour phase is 0.35
and in liquid phase is 0.70. The vapour pressure of pure A is:
A. 300 torr
B. 1300 torr
C. 200 torr
D. 400 torr
At higher altitudes, water boils at temperature < 100°C because

A. temperature of higher altitudes is low

B. atmospheric pressure is low
C. the proportion of heavy water increases
D. atmospheric pressure becomes more
The molality of 15% (wt./vol.) solution of H2SO4 of density 1.1 g/cm3 is
approximately-
A. 1.2
B. 1.4
C. 1.8
D. 1.6
Equal volumes of 0.1 M AgNO3 and 0.2 M NaCl are mixed. The concentration of NO3-
ions in the mixture will be
A. 0.1 M
B. 0.05 M
C. 0.2 M
D. 0.15 M
25 mL of 3.0 M HNO3 are mixed with 75 mL of 4.0M HNO3. If the volumes are
additive, the molarity of the final mixture would be
A. 3.25 M
B. 4.0 M
C. 3.75 M
D. 3.50 M
10 gram of glucose are dissolved in 150 gram of water. The mass % of glucose os
A. 5%
B. 6.25%
C. 93.75%
D. 15%
If 100 ml of M NaOH solution is diluted to 1.0 L, the resulting solution contains-

A. 1 mole of NaOH
B. 0.1 mole of NaOH
C. 10.0 mole of NaOH
D. 0.05 mole of NaOH
Vapour pressure (in torr) of an ideal solution of two liquids
A and B is given by : P = 52XA+ 114
where XA is the mole fraction of A in the mixture. The vapour pressure (in
torr) of equimolar mixture of the two liquids will be

A. 166
B. 83
C. 140
D. 280
Mole fraction of a liquid A in an ideal mixture with another liquid B is XA. If
X′A is the mole fraction of component A in the vapour in equilibrium, the
total vapour pressure of the liquid mixture is
( p°A = vapour pressure of pure A : p°B = vapour pressure of pure B)

A. B.

C. D.
The variation of total vapour pressure of an ideal solution of two liquids A
and B is depicted below. The total vapour pressure denoted by the point ‘X’
will be
A. 34 mm
B. 46 mm
C. 40 mm
D. 24 mm
 Multi Option Correct

For chloroform & acetone or for a solution of chloroform & acetone if ps

(observed (actual)) is compared with ps (Theoretical (Raoult)) then which
of the following is / are true?
A. ps(actual) < ps(Raoult)

B.

C.

D.
Consider a binary mixture of volatile liquids. If at XA = 0.4 the vapor pressure of
solution is 580 then the mixture could (p0A = 300torr, pB0 = 800 torr)

A. CHCl3 - CH3COCH3
B. C6H5Cl - C6H5Br
C. C6H6 - C6H5CH3
D. nC6H14 - nC7H16
Identify the false statement

A. The volume of a solution cannot be less than the sum of volumes of the
pure solvent and solute used to prepare the solution (binary solution of
two liquids)
B. At constant T and P, ΔGmix be necessarily negative for an ideal solution
C. An ideal binary solution (p0A ≠ p0B) cannot form an azeotropic mixture.
D. In binary solutions ideality is more of an exception rather than a rule.
Which of the following represents correctly the changes in thermodynamic
properties during the formation of 1 mol of an ideal binary solution.

A. B.

C. D.
 Multi Option Correct

Which of the following is/are correct for an ideal binary solution of two
volatile liquids (eg. benzene & toluene) ?

A. its vapor is always richer in the more volatile component (compared to the
liquid).
B. the liquid will gradually become richer in the less volatile component if such
a mixture is boiled (distilled).
C. the pT (ie. the total pressure) above the solution will be the sum of the vapor
pressures of the two pure components.
D. the boiling point of the solution will be less than the boiling points of the
two components.
The vapour pressure of the solution of two liquids A(po = 80 mm) & B(po =
120 mm) is found to be 100mm when xA = 0.4. The result shows that

A. Solution exhibits ideal behaviour

B. Solution shows positive deviations
C. Solution shows negative deviations
D. Solution will show positive deviations for lower concentration and negative
deviations for higher concentrations.
Which of the following is not correct for an ideal solution ?

A. Raoult's law is obeyed for entire concentration range & temperatures

B. ΔHmix = 0
C. ΔVmix = 0
D. ΔSmix = 0
Which of the following is less than zero for ideal solutions?

A. ΔHmix
B. ΔVmix
C. ΔGm
D. ΔSmix
At 323 k, the vapour pressure in millimeters of mercury of methanol-ethanol
solution is represented by the equation p = 120XA + 140, where XA is the mole
fraction methanol. Then the value of
A. 250 mm
B. 140 mm
C. 260 mm
D. 20 mm
Consider two liquids A & B having pure vapour pressure P0A & P0B forming an
ideal solution. The plot of 1/XA vs 1/YA (where XA and YA are the mole fraction of
liquid A in liquid and vapour phase respective;y) is linear with slope and Y
intercepts respectively:

A. B.

C. D.
Total vapour pressure of mixture of 1 mol of volatile component A (PA° = 100
mmHg) and 3 mol of volatile component B (PB° = 60 mmHg) is 75 mm.
For such case:
A. there is positive deviation from Raoult's law
B. boiling point has been lowered
C. force of attraction between A and B is smaller than that
between A and A or between B and B
D. all the above statements are correct
The vapour pressure of a pure liquid A is 40 mmHg at 310 K. The vapour
pressure of this liquid in a solution with liquid B is 32 mmHg. Mole fraction
of A in the solution, if it obeys Raoult’s law is
A. 0.8
B. 0.5
C. 0.2
D. 0.4
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