 detThe molar concentration of a solution is determined by the amount of solute and the volume of solution.

 Solution of problems involving molar concentration, amount of solute and volume of solution.
 Use of the experimental method of titration to calculate the concentration of a solution by reference to a standard solution

1. (ii)Calcium carbonate is added to a solution of hydrochloric acid. Write an equation for the
reaction between hydrochloric acid and calcium carbonate.

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(2)

–3
(ii)Determine the volume of 1.50 mol dm hydrochloric acid that would react with exactly 1.25
g of calcium carbonate. (SOLUTIONS Q- not GASES-1.3 pg. 33)

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(3)

(iv) Calculate the volume of carbon dioxide, measured at 273 K and

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1.01×10 Pa, which would be produced when 1.25 g of calcium carbonate reacts
completely with the hydrochloric acid.

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(2)
(Total 7 marks)
 Calculation of reacting volumes of gases using Avogadro’s law.
 Solution of problems and analysis of graphs involving the relationship between temperature, pressure and volume for a
fixed mass of an ideal gas.
 Solution of problems relating to the ideal gas equation.
 Explanation of the deviation of real gases from ideal behaviour at low
2. Which change in conditions would increase the volume of a fixed mass of gas?

Pressure /kPa Temperature /K

A. Doubled Doubled
B. Halved Halved
C. Doubled Halved
D. Halved Doubled

3. Propane and oxygen react according to the following equation.

C3H8(g) + 5O2(g)  3CO2(g) + 4H2O(g)

Calculate the volume of carbon dioxide and water vapour produced and the volume of oxygen
3 3
remaining, when 20.0 dm of propane reacts with 120.0 dm of oxygen. All gas volumes are
measured at the same temperature and pressure.

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(Total 3 marks)

3 3
4. 3.0 dm of sulfur dioxide is reacted with 2.0 dm of oxygen according to the equation below.

2SO2(g) + O2(g) → 2SO3(g)

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What volume of sulfur trioxide (in dm ) is formed? (Assume the reaction goes to completion
and all gases are measured at the same temperature and pressure.)

A. 5.0

B. 4.0

C. 3.0

D. 2.0
(Total 1 mark)
rel moles= LR 3.0dm3/2> coefficient ; n(O2) = 2 dm3
SO2 = 1.5 dm3< is less

SO2 is LR
5. Under what conditions would one mole of methane gas, CH 4, occupy the smallest volume?

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A. 273 K and 1.01×10 Pa

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B. 273 K and 2.02×10 Pa

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C. 546 K and 1.01×10 Pa

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D. 546 K and 2.02×10 Pa
(Total 1 mark)

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6. The temperature in Kelvin of 2.0 dm of an ideal gas is doubled and its pressure is increased by
a factor of four. What is the final volume of the gas?

3
A. 1.0 dm

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B. 2.0 dm

3
C. 3.0 dm

3
D. 4.0 dm
(Total 1 mark)

7. State and explain what would happen to the pressure of a given mass of gas when its absolute
temperature and volume are both doubled.

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(Total 3 marks)

Gas Stoichiometry (some above also)

8.

(ANS 0.652dm3
Given->n= 12.45g HgO [1 mol O2] ANS Q-> RT (22.7) =
(Mr) < [2mol HgO] P
any gas at STP 22.7 dm3mol-1

9.