Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr.Super60 CTA-34 Date:03-08-20
Time: 08.00Am to 11.00Am 2017_P2 Max.Marks:183
KEY SHEET

PHYSICS
1 C 2 D 3 A 4 C 5 A
6 D 7 D 8 BCD 9 AB 10 BCD
11 ACD 12 AC 13 ACD 14 BC 15 B
16 C 17 D 18 A

CHEMISTRY

19 B 20 A 21 B 22 C 23 D
24 C 25 C 26 AD 27 ABCD 28 ABCD
29 ABD 30 ABC 31 ABD 32 AC 33 D
34 C 35 D 36 B

MATHS
37 C 38 B 39 C 40 A 41 C
42 D 43 D 44 AC 45 BCD 46 ABC
47 AD 48 BD 49 ABC 50 ABC 51 D
52 B 53 C 54 A
Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
SOLUTIONS
PHYSICS
1.Sol: Concept of triangle law of vector addition.

0 A
2.Sol: Q  V , A is different, so Q is different.
d

1 2S
3.Sol: S  at 2 or t 2 
2 a
t12 
2  d cos 1  
2 d 2 2  d cos 2  2d 2 2d
, t2   , t3 
g cos 1 g g cos 2 g g
Thus t1  t2  t 3 .
120
4.Sol: Resistance required   8
15
2

Resistance of each bulb 

 120 
500
2

Ratio 
120   3.6  ' 3 ' bulbs
8  500
5.Sol: Parallel component of v to B doesn’t produce the force.
6.Sol: Let they meet after time t sec.
V1 cos 45t  V2 cos 60t  a
a a
So V1  , V2 
cos 45 t cos 60
For vertical  V2 sin 60  V1 sin 45  t  h
7.Sol: In an elastic collision,
Conservation of KE :
1 1 1 1
m1u12  m2 u22  m1 v12  m2 v22 .
2 2 2 2
Conservation of linear momentum (horizontal) :
m 1 u1  m 2 u 2  m 1 v1  m 2 v2 .
 v1  v2    u1  u 2  or v1  u2  u1  v2 .
Substitute for v1 in the momentum equation :
 2m 1   m2  m1 
v2    u1    u2
 m1  m2   m1  m 2 
 2u 1  u 2  m 1  m 2 
 v2  2  U     u cos    2U  u cos  .
Final velocity of the spacecraft :
2 2
v  u sin    2U  u cos  
 u2  4U 2  4uU cos 

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s

8.Sol: After closing switch let charge q remains on A

VA  VC
Kq K2Q K  4Q  q  K6Q Q
   q
R 2R 3R 3R 2

9.Sol:

(A)  F  Bi  
2a  2
(B) From symmetry VB  VD  VO

10.Sol:

30
a common   2m /sec2
15
Freq to move  5  2  10 N
N  10
 50  10
1

5
  0.2

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
11.Sol:Use Kirchoff’s rules.
1
12.Sol:    T1  T2  T3
T
Area under the curve E  &  gives intensity so
 Ae3 T34  Ae2 T24
Now as T3  T2  e3  e2
13.Sol:Time durations are different but v is same. v is different.
1  1
14.Sol: E1  E2 …….(1)
 1 1  1 t   1 1  1t 
……(2)
 1 1   1 t    2 1   2 t     1   2    1   2
15.Sol:During each cycle, the system sucks gas out of the chamber and pushes it into the
atmosphere. Since V0  0 , the inlet valve opens the moment the piston starts moving to
the left. When the piston is all the way to the left, a fraction  V /  V   V  of the gas is
in the cylinder. As the piston moves to the right, all of this gas is pushed out, so after a
single cycle,
 V 
Pf  Pi  
 VV
And in general,
t/ t
 V 
P  t   Pa   .
 VV
While this is technically correct, it can be simplified significantly. Write
 t/ t
 V  Rt/V
P  t   Pa  1 


V 
 Pa 1  x 
1/x
 
Where x   V /V  1 . Then using the definition of e,
1/x
e  lim 1  x 
x 0

We have
P  t   Pa e Rt/V .
When the piston is all the way to the left, the pressure is P  t  and the temperature is
Ta . As the piston moves to the right, the gas is adiabatically compressed until its
pressure reaches Pa and the outlet valve opens. Since PV  is constant during adiabatic
compression and PV /T is constant by the ideal gas law,
11/ 2/5
 P   P 
Tout  t   Ta  a   Ta  a   Ta e2Rt/5V
 P t   P t  
   
Where we used   5 /3 for a monatomic ideal gas.
16.Sol:Since V0  0 , the inlet valve will not open immediately when the piston begins moving
to the left; instead it will open once the pressure in the cylinder equals the pressure in
the chamber. Since the expansion of the cylinder is adiabatic, PV  is constant, so
 
 V0   V 
Pmin  Pa    Pa  1   .
 V0  V   V0 
17.Sol:

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
7 2
 about ICR  mr 
5
7 5 i  n b cos 
i  r 2 n B cos   mr 2    
5 7m
5 i r n B cos 
f5  macm  mr  
7
d 5 n i B
18.Sol:    cos 
d 7 m
2 5  n i B
  sin 
2 7 m

CHEMISTRY:
N B 0.05 1
19.  
N C 0.15 3
Assume the number of atoms of B formed = x
Then number of atoms of C formed = 3x
Total energy emitted = 40 x + 80 (3x)
40x  240x
Energy emitted per atom =
4x
= 10 + 60
= 70 MeV
1 1 
20. Au  2CN   O 2  g   H 2 O  Au  CN 2  OH  --------------(1)
4 2
  
Au  2CN   Au  CN 2 -----------------(2)
O2  2H2O  4e 
 4OH -----------------(3)
Au 3  3e 
 Au ------------------(4)
Au 3  2e  
 Au  -----------------------(5)
Thermodynamic operation
1
(1) = - (4) + ( 2 ) + (3) + (5)
4
1
G1o  G o4  G 2o  G 3o  G 5o
4
1
   3 F 1.5   RTn X   4  F .41   2  F 1.4 
4
G1o   RT n X  F  4.5  0.41  2.8
G1o  RT n X  1.29F
21. Nitrous oxide is produced by thermal decomposition of ammonium nitrate.
NH 2 OH  HNO 2 
 N 2O  H 2O
22. In PCl5 ,the anionic part is PCl6 ,which contains 12 XAX angles.
23. With negative charge on metal, synergic bonding is more from metal to ligand, thus M-
C bond order is more.

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
Br

AgNO3
  . NO3 + AgBr 
24.

. NO3
is Aromatic, high resonance energy and high dipole moment

25.
Cl Cl Cl Cl

Cl
2 Cl excess / h
 

(1) Cl
R,S R,S
S, R S, R
R, R R, R
same same
S,S S,S

(3) (3)
Total : 7
26. Basic nature CaO  MgO  ZnO  BeO
Solubility LiOH  NaOH  KOH  RbOH  CsOH
LiCl has less melting point due to more covalent nature
27. In polymeric BeCl2, each Be associate with 4 Cl atoms.
Cationic part of I2Cl6 is ICl2 which contains two sigma bonds and two lone pairs.
BeH2 solid has each Be associate with 4 hydrogen atoms.
28. Cl2 acts as oxidizing agent with FeSO4, Na2SO3, SO2 and I2.
29. All chiral molecule are resolvable
A: Planar B: Planar
C: Chiral as it is a symmetric
D: achiral
30.
Cl
14
Na

dryether , +
14
14 14 14

14 14

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
31. 2D Square Pacing

r 2 
P.F  2

 2r  4
Coordination number = 4
Number of voids per sphere = 1 in square packing.

1
Number of atoms per square = 4 1
4
Number of voids per square = 1
2D Hexagonal packing

1
Number of atoms per hexgonal unit = 1 1   6  3
3
Number of voids per hexagonal unit = 6
Number of voids per atom = 2
1 2
 r   3
6
P.F   
3 2
 2r 
4

r 2  
P.F  2
 
2 3r 2 3 3.464
 P.FHCP   P.FS.P
32. K 
eq T
1
  K eq   H   0
T2

G   RTn K eq  0
G   H  T S
RT1 n K eq1  H  T1S
H S
n K eq  
1
RT1 R

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
H S
n K eq  
2
RT2 R
H S

RT1 R T
 2
H S T1

RT2 R
H S H  S
 T1   T2
R R R R
S
 T1  T2   0
R
S  0
33. Pyrolysis of esters and Test amine oxide
O R2
+
R1 N
R O CH3 -
R3
Eg: O
34 F , OH , NH 2  are poor leaving groups
35. x Ethanol  0.9
x water  0.1
Solute is water and solvent is ethanol according to given comprehension solute is non-
volatile
x water  1000 1000
m 
x Ethanol M Ethanol 9  46
C2 H5OH  24  6  16  46
2  1000 1000
TF  K F m    4.83
9  46 9  23
 TF solution  155.7  4.83  150.87
36. PS  Px Ethanol
PS  40  0.9  36mm

MATHS:
37. Ans: C

2007

Sol: I=
3
 sin 3
  cos 3   cos 2   sin   cos   cos 2  
d

  sin  
2009
 cos  
2009

4

3
2007
  tan  sec  cot  cos ec  cos ec    sec  cos ec  cot  
2
= d

4

sec   cos ec  cot   t

 sec  tan  cot  cos ec  sec 2   d  dt
2 3 2 3
2007  t 2008 
I  t dt   
8 1  2008  8 1

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
2008 2008


2  3    8 1 
2008
A=2, b=3, c=8, d=2008
a + b + c + d = 2 + 3 + 8 + 2008 = 2021
38. Ans: B
Sol: adding these equation, we get
2k k2
2  5
3 2
2
i.e. 3k  4k  18  0
18
k1k 2   6
3
39. Ans C
 1  1 
Sol:
 a  b 
2

E   a 4  4  4   b 2  3  2   c  1  2 
E min  6  5  2  60
40. Ans: A
f  h   f  0
d  f '  0   lim
h 0 h
an 1  h   2bh  h 2  ch 3
d  lim
h 0 h4
 h 2 h3 h4 
a  h     ....   2bh  h 2  ch 3
2 3 4
d  lim  4

h 0 h
a a
 a  2b, a  2,  c and d   .
3 4
41. Ans: C
Sol: C
Equation of ellipse is  y  2  y  2     x  3 x  3  0
y

 0, 4 
 3, 2 y2
x 3
x  3 x

 3,  2 y  2  3,  2

4
It passes through (0, 4)   
3
x 2 y2
Equation of ellipse is  1
12 16
1
e
2

42. Ans: D

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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
dy
Sol:  y tan x  2x sec x
dx
dy
cos x    sin x  y  2x
dx
d
 y cos x   2x
dx
y  x  cos x  x 2  c , where c = 0 since y(0) = 0
   2      2
when x  ,y   , when x  , y   
4 4 8 2 3 3 9
2
    
when x  , y '    
4 4 8 2 2
2
    2 4
when x  , y '    
3 3 3 3 3
43. Ans: D
 /4
Sol: A  4   sin x  cos x  cos x  sin x dx
0

 /4  1 
A  8   cos 0  8    1
 2 
 4 2  2  1
44. Ans: AC
n 1 n2
n n 1
Sol: I n    x  n  dx    x  n  1 dx  ...
n n 1
2n
2n 1
.....    x   2n 1 
2n 1
dx
n 1
  x  n  n 1 
   .....
 n  1  n
1 1 1
I n    .....  ,
n 1 n  2 2n
1 1 1 1
I n    ...  (n times)  I  n  
2n 2n 2n 2
1 1 1
I  n     ...  (n times)  I  n   1
n n n
Also lim I  n   n2
n 

(Using limit of sum as definite integration)

45. Ans: BCD
Sol: equation of plane ‘P’ is 7x – 7y + 8z + 3 = 0
46. Ans: ABC



Sol: 24x 4  1x 3  2 x 2  3 x  1  0 


1
  ;   2  3  4  4
24
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Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
  2  3  4 1
AM  GM    .2 .3 .4  4
4
   2  3  4  1
1 1 1
  1,   ,   ,  
2 3 4
 1  50; 3  10
   1 is root  24  1  2  3  1  0
 1  2  3  25  2  35
47. Ans: AD
1
Sol: Eccentricity of ellipse =
2
x2 y2
Let equation of ellipse be 2   1  1
a 2 1
a 1  
 2
2 2
x  y  2  (2)
dy  dy 
As, (1) and (2) intersect orghogonally, so     1 at point of intersection.
dx  (1) dx  (2)
48. Ans: BD
 7 t 
t 
Sol: Let x  2t then 2  4 
 21 t
 t 2  7t  4  4t
 t 2  3t  4  0  t  4,1
1 1
 x  , 2   &   2
16 16
(B) is correct &
x 1  4  5  x  1  4  5, 5
 x  1  1, 9
 x  1  1  x  0, 2
 D is correct
49. Ans: ABC
2
Sol: A 2  4I  A  64  A  8
 ABT  adjA
 A 2 B T  AadjA  A 2 B T  8I
 B  2I
ABT  adjA  2A  adjA
 A  adjA  A  8
50. Sol: ABC
   
a is in direction of x   y  z 
   
i.e.  x.z  y   x.y  z
  1   
 a  1  2   y  z  
 2 
  
a  1  y  z  .....(1)
     
Now a  y  1  y  y  y  z 
Sec: Sr. Super60 Page 11
Sri Chaitanya IIT Academy 03-08-20_Sr.Super60_Jee-Adv_(2017-P2)_CTA-34_Key & Sol’s
 
= 1  2  1  1  a  y ....(2)
    
From (1) and (2), a  a  y  y  z 
    
Similarly, b  b  z  z  x  
         
 
Now, a  b   a  y  b  z  y  z    z  x  
   
 
  a  y  b  z 1  1  2  1
   
  a  y b  z  
51. Ans: D
52. Ans: B
Sol 51-52: x  y  x 3  y 2
x  y  x 3  y  2
Case – 1
0  x  3; 0  y  2
x + y = -x + 3 – y + 2
5
x+y=
2
Case : 2
0  x  3 ;y  2
x + y = -x + 3 + y – 2
1
x
2
Other two cases will be rejected
1
x
2
y4

x
O
53. Ans: C
 1  3  3 1
Since, f     f     0  S lie in   ,  
 2  4  4 2
54. Ans: A
3 1
Sol:  s
4 2
1 3
t
2 4
1/2 3/4

  4x  3x  2x  1 dx  area    4x  3x 2  2x  1 dx
3 2 3

0 0
1/2 3/4
 x  x  x  x   area   x  x  x 2  x 
4 3 2 4 3
0 0

1 1 1 1 81 27 9 3
    area    
16 8 4 2 256 64 16 4
15 525
 area 
16 256

Sec: Sr. Super60 Page 12