Sri Chaitanya IIT Academy., India.

A.P, TELANGNA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
SEC: Sr.Super60 PTA-01 Date: 18-10-2020
TIME: 09.00Am to 12.00Pm 2016-P1 Max. Marks: 186

KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
D B A D A ACD AB AC BC ABD
11 12 13 14 15 16 17 18
AC D ABC 7 5 3 6 5

CHEMISTRY
19 20 21 22 23 24 25 26 27 28
B C A A A ABCD ABCD ACD ABCD AC
29 30 31 32 33 34 35 36
AB B D 3.00 4.00 5.00 8.00 7.00

MATHEMATICS

37 38 39 40 41 42 43 44 45 46
B D A D A AC ABCD BCD A ABCD
47 48 49 50 51 52 53 54
ABCD AB BD 4.00 5 7 7 7
Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
SOLUTIONS
PHYSICS
3
 4S   4 3  P0 4 S  4  4  5 R 
1.  P0    R        
 R  3   2 5R  3  4 
4 S 125 P0 25 S 96 S 16 nS
 P0     P0  
R 128 4R R R
 n=6
2. For system of two gases n1CV dT  n2CV dT  PdV  0
1 2

1 7R 4 RT
 2 R  dT  4   dT  dV  0
2  4  V
dV
dT  7 dT  4T 0
V
2dT dV
 0
T V
T 1
2 ln  ln  0; T  600 K
300 4
1 7R
U   2 R  600  300   4   300  2  10 4 J
2 4
1 W
3. Specific heat, C  CV 
n T
13 R 3 R
 
2  
3  n
6 2  5n  3 
n  6 .
2 2
 Q   ML T 
4. S    
2 2 1
LT K
 m  T   M  K 
2
1 
1 m 
L12 2  1 m2
1 12 1  
T  K  4 sec  2  2k 1 128 sec2  K
1 5

128 Kg  K
1
1 new unit = J / kg  K
128
5.
I II

T1 T2
P  2AT14  AT24 (steady-state condition of sheet I)
….. (i)
And 0  2AT  AT (steady state condition of sheet II)
4
2 1
4
….. (ii)
 P  3 AT24  3 kW

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
6. Area under graph is more for circle  WQ  WP
As  U is same  QQ  Q P
KAd  d
7. H  K  2 r L 
dr dr
r2 
dr 2KL 2
  d
r1
r H 1
dQ 2KL  2  1 
H  80 
dt  r2 
n  
 r1 
dm
 L  80 
dt
dm 80  80  
    kg/second.
dt L 80  4200 4200
8. Use Principle of Calorymetry.

9. Thermal resistance of k1 
k1  R 12

Thermal resistance of k 2 
k 2   R 22  R12 
For same heat current k1R12  k 2  R 22  R12 
10. Problem model is similar to Gauss law situation.
11. ‘ca’ is not polytropic process. So ‘C’ is variable.
T
Also max  4
Tmin
12. Mean free path depends on number concentration.
Q
13. C
n T
14.
2 kg 3 kg 2 kg 3 kg
V1 V2
A B A B V = 4m/s

2  V1   3  V2    2  3 V
 2V1  3V2  20 …. (i)
loss in KE = heat energy
1 2 1 2 1
2  V1   3  V2    2  3 V 2   2  3  S  T
2 2 2
3 3V 2
V12  V22  40  15 or V12  2  55 …. (ii)
2 2
Solving equation (i) and (ii), we get,

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
V1  1 m / s or 7 m / s and V2  6 m / s or 2 m/s
For collision V1  V2 . So V1  7 m / s
T2  T1 T3  T2
15. 
 1    2 
   
 K1A   K 2 A 
K1  tan 60   K 2  tan 45   k 2  3 k1  200 3 SI units
dm dQ KAT
16. L   T and latent heat is same in both cases given in
dt dt 
dm KA  2 1
question So  2  1 
dt  2 1 2
 dm  K1A1
 
 dt 1  1 A 2  4A1
A1 1

 dm  K 2A 2 A2 4
  2
 dt  2
0.1 KA K K1
 1 1 2 K2  1 4
 dm  K 2 A 21 4 K2
 
 dt  2
0.1 1 1
 4 
 dm  4 2
 
 dt 2
 dm 
   0.2 gm / s
 dt  2
x  0.2
15x  3
17.

dx

dx 4kRx
4x 2 L 
dt Rx
2
L R
t
k 6
18.      T  2 mm
  
  actual  2  1  1 mm   Y  actual 
  
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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
CHEMISTRY
19. Organic dibasic acid  H 2 A  silver salt  Ag 2 A 

Ag 2 A  s    Ag  s 
Applying PoAC on ‘Ag’
n Ag  2n salt
WAg 2Wsalt

108 Msalt
2 108  Wsalt
M salt 
WAg
2 108 

0.5934
 364.00
M acid  364  214  150
C4 H 6O 6
48
weight % C  100  32%
150
2
weight % H  6   4%
3
2
weight % O  96   32  2  64%
3
20. Volume of CO  x ml
Volume of CO2  y ml
Volume of N 2   200   x  y  ml  z
1
CO  g   O2  g  
 CO 2  g 
2
x
x x
2
x
 40 ml  x  80ml
2
x  y  100  y  20 ml
z  100 ml
21. Initial condition
n = 1, T = 300 K, V = 1 lt
Final condition
N = 1, T = 1200, V = 4 lt
 Z1 F TF VI 1
 
 Z1 I TI VF 2
2
 Z11 F TF  VI  1
   
 Z11 I TI  VF  8
  F  VF 4
  
  I  VI 1

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
 u rms F TF 2
 
 u rms I TI 1
22. AsO 34  2H   2I  
 AsO 33  H 2 O  I 2
I 2  2Na 2S2 O3 
 2NaI  Na 2S4 O 6
Since x F of I2 in both reactions are same
e AsO3  e Na 2S2 O3
4

MM  Na 3 AsO4   3  23  75  64  69  139  208

1 0.2 V  ml 
2 
208 1000
10000
V  ml    48.076  48.1
208
23. e FeO  e KMnO 4
n FeO1  0.1 0.25  5
n FeO  0.125
n Fe2  eK 2Cr2O7
n FeO  1  2n Fe2O3  1  1 0.1 6
0.125  2n Fe2O3  0.6
0.475
n Fe2O3 
2
WFeO  0.125   72   9 gm
WFe2O3  38gm
38  100
Mass % of Fe2O3   80.85%
47
24. Conceptual
25. Conceptual
26. (A) Assume 100 gm oleum mass of H 2 O added = 9 gm
1
Moles of free SO3 
2
Mass of free SO3 = 40 gm
(Correct)
(B) 1 gm = Oleum
WSO3  0.4gm
WH2SO4  0.6 gm

n NaOH  2 n SO3  n H2SO4 
22.25 1  0.4 0.6 
  2  
1000 2  0.8 98 
1600 2400
22.25  
80 98
22.25  20  24.49( incorrect)
(C) eSO3  eH2SO4  eBa  OH  2

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
5  0.4 5  0.6  2 1112
2 
80 98 1000
30000
500   1112
49
1112.24  1112  correct 
109 1000
(D) m 
98  500
109
m  2.224  correct 
49
mass 950
27. (A) d   gm / ml  950 kg / m 3
volume 1000
230
nE 46 5
(B) x E   
n E  n H2O 230  720 5  40
46 18
1
x E   0.11 (correct)
9
5mole
(C) M   5 mol / lt (correct)
1  t 
5  1000 500
(D) m    6.94
720 72
B C
28. Z  1   2  ......
V V
BP CP 2
Z 1    .....
ZRT  ZRT 2
 Z 1  B
Lt  
P 0
 P  RT
Z  1  B ' P  C ' P 2  ....
Z 1
Lt  B ' C 'P  ....
P 0 P

 Z 1 
Lt    B'
P 0
 P 
Similarly we can prove (C) option
29. (A) It is incorrect because in low pressure range at Boyles temperature a real
gas behaves like ideal gas
(B) It is incorrect because at critical conditions a real gas can be liquified while
ideal gas cannot be liquified
30. Since x F of I2 in both reactions are same.
eCu2  eS O2
2 3

n Cu2  nS O2
2 3

 24.3 
WCu 2     0.1  63.5
 1000 

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
24.3  63.5 107
Mass % of copper in copper salt =  100
0.305
0.243  63.5
=
0.305
= 50.59
= 51
31. 150 ml of H 2O2 part I x ml
e KOH  e H 2SO4
1
n KOH  2  0.2 
2
n KOH  0.2
0.1
n H 2O 2   0.25
0.4
Part II (150-x) ml
6.74
n O2 
22.4
6.74  2
n H 2 O2 
22.4  3
6.74
n H 2 O2   0.2
11.2  3
0.45
Molarity of H 2O2 
0.15
Volume strength = 3  11.2 = 33.6
32. 2M  s   x H 2SO 4  aq    M 2 SO 4  x  aq   xH 2  g 
e M  e M2 SO4 
4

2 4.51

E E  48
2E  96  4.51E
2.51E  96
96
E
2.51
Dulong &Petit law
Atomic Mass  0.057  6.4
6400
Atomic Mass 
57
Atomic Mass 6400  2.51
Valency  
E 57  96
Valency  2.93
Valency  3
33. e NaOH  e Na 2CO3  eHCl
n NaOH  n Na 2CO3  0.1 0.025
n NaOH  2n Na 2CO3  0.1 0.30
n Na 2CO3  0.1 0.005
n NaOH  0.1 0.020

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
n NaOH 4

n Na 2 CO3 1
34. A  g  
 2B  g   3C  g 
1  2 3
rmix M gas 105 3
  
rgas M mix M mix 2
105  4 35  4 140
M mix   
9 3 3
140 140

3 1  4
1  4  3
1

2
3
x C  2  0.5
3
a 4.105 410500
35. TB     500K
bR 0.1 0.0821 821
Since the gas is at low pressure range and at Boyles temperature it behaves as
Ideal gas.

RT 0.0821 500 82.1

V   t
P 2 4
164.2  4 8
d  gm / ml    g / ml
82.11000 1000
36. Assume 1 lt of solution
Wsolution  1300gm

A  4 M n A  4 WA  500gm

n B  6 WB  600 gm
 B  6 M
Wx  200gm

Wx  200 gm

n x  4 mol

n A : nB : nX
4:6:4
2:3:2
232  7

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
MATHEMATICS
37. 2 2
x  y  6x  4y  9  0
2  3m
y  mx, 2
1  m2

4  9m2  12m  4  4m2

m= 0 or 5m = 12  m = 12/5
12
y  x and y  4 are tangents
5
5
Equation of circle is  x  0   x     y  0  y  4   0
 3
38. Diagonals of rhombus are angle bisector of adjacent sides.
Equation of bisector of the sides are
ax  y  16  x  ay  6 
  
2 2
1 a  1 a 
 ax  y  16    x  ay  6
 3a  5 16    3  5a  6
7
 a  4,
4
9
Sum of values = 
4
40. The set S is symmetric about the line y = x and contains (2,3), so it must also
contains (3, 2). Also S is symmetric about the x-axis, so it must contain (2, -3)
and (3, -2). Finally, since S is symmetric about both coordinate axes, it is also
symmetric about the origin.
41. Circumcentre will lie on the perpendicular bisector of AB
f  x, y   x 2  y2  2gx  2fy  c  0
Now, s f  0,     2  2f  c  0 and its roots are (1, 1).
 f   1 and c = 1
1 
f  ,0  2  2g  c  0 and its roots are  ,5 
5 
1
  5  2g
5
13 1
g  and  5  c
5 5
13
Thus, g   , f  1, c  1
5

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169 13
r  g2  f 2  c  11 
25 5
2 1 1
42. m 
1  1 2
1 1
 
2 5  52
m1    
 1 1   2 5  1 
1    
 2 5
1 1
 
2 5
m2 
 1 1 
1    
 2 5
43.

44. Let P  , 
       5
75
this form a polygon and a area of this polygon is
4
A 75
 
3 12
sin  cos  2 
45. 
2 4

2 2 sin   1  2sin 2   2sin 2   2 2 sin   1  0

2 2  8  8 2 2  4 1
sin     1
4 4 2
 1  2 
sin    
 2 

So line L is inclined with tangent at P at    
2 
46. Let x  y  16  0 and C 2 : x  y  12x  32  0 (centre (6, 0); r=2)
2 2 2 2

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
C1 :  0,0  ; r1  4; C2   6,0  ; r2  2
y

A
C1
r4 C

r2
(12, 0)
 x
 0, 0  O  6, 0  C2 P  h,0 

D
B

Let P  h,0 be the point of intersection of direct common tangents

h h 6
Then   h  12
4 2
If A, B, C and D be the points of contact of direct common tangents then AB and
CD will be the chord of contact of P w.r.t circles C1 and C 2 .
4 20
 Equation of AB is x  and equation of CD is x 
3 3
Now, equation of any circle through intersection of C1 and AB is
 4  4 
x 2  y 2  16  1  x    0 or x 2  y 2  1 x   16  1   0
 3   3 
Also equation of circle through the points of intersection of C 2 and CD is
 20   20 2 
x 2  y 2  12x  32   2  x    0 or x 2  y 2  x   2  12    32    0.....(ii)
 3   3 
As (i) and (ii) represent same circle, so
20 2
32 
 2  12 3 1
   1  6,  2  6 s
1  4  1
 16  1 
 3 
Hence the circle is x 2  y 2  6x  8  0  x 2  y 2  2gx  2fy  c
Clearly g 2  f 2  c   32   0 2   8   9  8  17
47.

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
A,B,C are point of intersection of internal tangents
I3 A I2
 1, 1 1: 2 1, 2 
 1 
A ,0
 3 
I3 B I2
 1, 1 1:1  2, 2 
 3 1
B  , 
 2 2
I1 1: 2 I2
1:1
 2, 2  1, 2 
C  1, 2 
48.
C

A  3, 4

D  1,1

B  5, 2 

D  1,1 is midpoint of AB.

C C
CD  BD cot  5.cot
2 2
Now, tan C  2
C
2 tan
2 2 C C
  tan 2  tan  1  0
C 2 2
1  tan 2
2
C 1  5 C 5 1
 tan   cot 
2 2 2 2
 5 1 5
 CD  5    5 1  
 2  2
3
Slope of BD is
4
4
 Slope of CD is  tan 
3
Using parametric form of straight line, coordinates of C are given by
 5  5 1  cos ,1  5  5 1  sin   53 5   3 5 1 
 1 
 2 2 
or 
2
, 2 5  3  and 
  2   
,  2 5 1
     

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
49. Note that  is right angled at  0, 6  . Centre of the circle is  2, 3  . Slope of the line
joining origin to the centre is 3/2. Take parametric equation of a line through
 2,3
2 x  2 y 3
with tan    as   r
3 cos  sin 
where r 13 . Get the co-ordinates on the circle
50.

51.

The equation of the line joining the origin and the centre of circle C 2 , (2,1) is
x
y or x  2y  0
2
52.

2h  2x1  x 2 ; 2k  x1  x 2
2k  x1  x 2 2k  2h  2k  x 2
2h  2k  x1; x 2  4k  2h

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Sri Chaitanya IIT Academy, India 18-10-2020_Sr.Super60_Jee-Adv(2016-P1)_PTA-01_Key & Sol’s
x2  k
 1  x 2  k   x 2  h
x2  h
hk
x2 
2
hk
From (1) & (2)  4k  2h
2
h  k  8k  4h  5x  7y  0  7y  5x
7 K  3 7
mL2  eq.   5k  15  7h  28
5 hy 5
7x  5y  43
2 2
53.  x  c   y  c  c2 , c  0
7c  12
p  r,  c  c  1, 6
5
Sum = 7

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