Pak-Turk Maarif International School & Colleges, H-8 Campus, Islamabad

CHEMISTRY HSSC-II
Crash Quiz # 3
Unit # 20 & 24
Total Marks: 45 Time Allowed: 1 hr 20min

SECTION-A (Marks 11)

Q. 1 Circle the correct option i.e. A/B/C/D. Each part carries one mark.
i. The instrument which allows the radiations in interact with a sample of chemical and analysis the
changes.
a) Spectrometer b) spectroscope
c) Photometer d) hydrometer
ii. Which of the following cannot be a unit for wavelength?
a) Angstrom b) Nanometer
c) meter d) cubic meter
iii. The wavelength of IR lies between.
a) 2100nm-2400nm b) 2500nm-25000nm
c) 2000nm-20000nm d) 2200nm-24000nm
iv. UV-Visible spectrometry occurs due to _____.
a) Molecular Vibration b) Atomic Vibration
c) Stretching of atoms d) Electronic transition
v. The amount of energy available in radio frequency radiation is sufficient for which of the
following?
a) Excite an atom b) Vibrate an atom
c) Vibrate a molecule d) Affect the nuclear spin of an atom
vi. Which of the following is the strongest acid?
a) HCOOH b) CH3COOH
c) CH3CH2COOH d) ClCH2COOH
vii. Which reagent is used to reduce a carboxylic group to an alcohol?
a) H2/Ni b) HI/P
c) NaBH4 d) LiAlH4
viii. The IUPAC name of
CH2COOH
|
CH2 COOH

a) Succinic acid b) Butanoic acid

c) Dibutanoic acid d) But-1, 4-dioc acid
ix. Reverse of esterification is known as:
a) Trans esterification b) Dehydration
c) Hydrolysis d) Decarboxylatio
x. The first step in mass spectrometer is:
a) Vaporization b) Ionization
c) Acceleration d) Excitation
xi. TMS stands for
a) Tetra methyl silicon b) Tri methyl silane
c) Tetra methyl silane d) Tetra butyl silane
 SECTION-B (Marks 21)

Q.2 Attempt ALL parts. All parts carry equal marks. (7 x 3 = 21)
i. What are the components of spectrophotometer?

ii. Which bond give rise to strong peak at about 1720cm-1 and weak peak at 3000cm-1?

iii. What is NMR spectroscopy? State its basic principle.

iv. How amide is prepared from carboxylic acid?

v. Why acid halides are very reactive toward nucleophilic attack?
vi. Lower carboxylic acids are water soluble, why?
vii. Write down the structural formulae of the following:
(a) Valeric acid (b) Propionic acid (c) Oxalic acid

SECTION-C (Marks 13)

Q.3 a) How will you convert acetic acid into methane and anhydride? (6)
b) What is the basic principle of Atomic absorption spectroscopy (7)