CHE 111 Review, Test 3

1) Given the following sets of quantum numbers for n, l, ml, and ms, which of these sets is
not a possible set for an electron in an atom?

n l ml ms

A) 3 0 -1 +½
B) 3 2 2 -½
C) 4 3 2 +½
D) 6 2 -1 -½
E) 5 3 2 +½

2) Gamma radiation emitted from radioactive 57Fe has a wavelength of

86 pm. What is the energy of one photon of this gamma radiation?

3) Determine the shortest frequency of light required to remove an electron from a sample
3
of Ti metal, if the binding energy of titanium is 3.14 × 10 kJ/mol.
15
A) 7.87 x 10 Hz
15
B) 4.74 x 10 Hz
15
C) 2.11 x 10 Hz
15
D) 1.27 x 10 Hz
15
E) 6.19 x 10 Hz

-33
4) Determine the velocity of a marble (m = 866 cg) with a wavelength of 3.46 × 10 m.

A) 45.2 m/s
B) 11.3 m/s
C) 22.1 m/s
D) 38.8 m/s
E) 52.9 m/s
5) Which of the following transitions (in a hydrogen atom) represent absorption of the smallest
frequency photon?

A) n = 5 to n = 6
B) n = 5 to n = 4
C) n = 4 to n = 1
D) n = 1 to n = 3
E) n = 1 to n = 2

6) How many different values of ml are possible in the 3d sublevel?

A) 2
B) 1
C) 3
D) 5
E) 7

7) If two electrons in the same atom have the same value of "l ", they are

A) in the same sublevel, but not necessarily in the same level.

B) in the same level, but different sublevel.
C) in the same orbital.
D) in different levels and in different shaped orbitals.
E) none of the above.

8) Determine the end (final) value of n in a hydrogen atom transition, if the electron starts in
n = 1 and the atom absorbs a photon of light with an energy of 2.044 × 10-18 J.

A) 3
B) 4
C) 2
D) 5
E) 6

9) A balloon is inflated from 0.0100 L to 0.500 L against an external pressure of 10.00 atm.
How much work is done in joules? 101.3 J = 1 L x atm

A) -49.6 J
B) 49.6 J
C) 0.49 J
D) -0.49 J
E) -496 J
10) Determine H for the following reaction,

N2(g) + 3 H2(g)  2 NH3(g). Given the thermochemical equations below:

N2(g) + O2(g)  2 NO(g) H = +180.8 kJ

4 NH3(g) + 5 O2(g)  4 NO(g) + 6 H2O(g) H = -906.2 kJ
2 H2(g) + O2(g)  2 H2O(g) H = -483.6 kJ

A) -1209.0 kJ
B) -1189.0 kJ
C) -756.5 kJ
D) -241.8 kJ
E) -91.5 kJ

11) A 4.98 g sample of aniline (C6H5NH2, molar mass = 93.13 g/mol) was combusted in a
bomb calorimeter with a heat capacity of 4.25 kJ/°C. If the temperature rose from 29.5°C to
69.8°C, determine the value of ΔH°comb for aniline.
3
A) +7.81 × 10 kJ/mol
3
B) -3.20 × 10 kJ/mol
3
C) +1.71 × 10 kJ/mol
3
D) -1.71 × 10 kJ/mol
3
E) -7.81 × 10 kJ/mol

12) A 35.6 g sample of ethanol (C2H5OH) is burned in a bomb calorimeter, according to the
following reaction. If the temperature rose from 35.0 to 76.0°C and the heat capacity of the
calorimeter is 23.3 kJ/°C, what is the value of H°rxn? The molar mass of ethanol is 46.07
g/mol.

C2H5OH(l) + 3 O2(g) → 2 CO2(g) + 3 H2O(g) ΔH°rxn = ?

A) -1.24 × 103 kJ/mol

3
B) +1.24 × 10 kJ/mol
3
C) -8.09 × 10 kJ/mol
3
D) -9.55 × 10 kJ/mol
3
E) +9.55 × 10 kJ/mol
13) Give the set of four quantum numbers that could represent the last electron added
(using the Aufbau principle) to the Mn atom.
1
A) n = 3, l = 0, ml = 0, ms = -
2
1
B) n = 4, l = 1, ml = -1, ms = -
2
1
C) n = 3, l = 2, ml = 2, ms = +
2
1
D) n = 4, l = 2, ml = -1, ms = +
2
1
E) n = 4, l = 2, ml =1 , ms = -
2

14) Give the ground state electron configuration for Sb.

2 2
A) [Kr]5s 4d
2 10 2
B) [Kr]5s 4d 5p
2
C) [Kr]5s
2 10 3
D) [Kr]5s 5d 5p
2 10
E) [Kr]5s 4d

15) Give the ground state electron configuration for Pb.

2 2
A) [Xe]6s 6p
2 10 2
B) [Xe]6s 5d 6p
2 14 10 2
C) [Xe]6s 5f 6d 6p
2 14 10 2
D) [Xe]6s 4f 5d 6p
2 14 10 2 2
E) [Xe]6s 4f 5d 6s 6p

16) How many of the following elements have 2 unpaired electrons in the ground state?

Zr Te Ba Pb
A) 1
B) 2
C) 3
D) 4

17) How many of the following elements have 3 unpaired electron in the ground state?

B Bi Sb Nb
A) 1
B) 2
C) 3
D) 4
18. Short answers:

1) The valence shell configuration of Thallium, Tl, is ____________.

2) The group of elements that have a valence shell configuration ns2np6 ____________.

3) The element with the smallest atomic radius in group 5A is

______________________.

4) The element with the highest ionization energy in period 4 is __________.

5) The abbreviated electron configuration of Cu? __________________.

6) Which type of orbital is designated by n=6, l = 1 ____________________.

7) Maximum number of orbitals identified by these quantum numbers n=5, l=2 _______.

8) Maximum number of electrons identified by these quantum numbers n=4, l=1, ms = -1/2

_____

9) Identify the set of all four quantum numbers for the last electron added to complete the
electron configuration of Co. ___________________________________

10) The abbreviated electron configuration for Mn3+ is _____________.

19. For the atoms or ions below write the abbreviated electron configuration, the orbital
diagram, and identify the number of unpaired electrons:

A) Ru

B) Sn

C) V3+

D) Ag+
CHE 111 Test 3 review

1) Each of the following sets of quantum numbers is supposed to specify an orbital. Which of
the following sets of quantum numbers contains an error?

A) n = 2, l = 1 , ml = -1
B) n = 4, l = 2, ml =0
C) n = 3, l =3 , ml = -2
D) n = 1, l = 0, ml =0
E) n = 3, l = 0, ml =0

2) Each of the following sets of quantum numbers is supposed to specify an orbital. Choose the
one set of quantum numbers that does not contain an error.

A) n = 2, l = 2, ml =-1
B) n = 2, l = 2, ml =0
C) n = 3, l = 2, ml =-3
D) n = 4, l = 3, ml =-2
E) n = 4, l = 2, ml =+4

3) Identify the correct values for a 3p sublevel.

A) n = 3, l = 1, ml = 0
B) n = 2, l = 1, ml = -2
C) n = 1, l = 0, ml = 0
D) n = 2, l = 0, ml = 0
E) n = 4, l = -1, ml = -2

4) Identify the correct values for a 4f sublevel.

A) n = 3, l = 1, ml = 0
B) n = 2, l = 1, ml = -2
C) n = 1, l = 0, ml = 0
D) n = 2, l = 0, ml = 0
E) n = 4, l = 3, ml = -2

5) Determine the end (final) value of n in a hydrogen atom transition, if the electron starts in
n = 4 and the atom emits a photon of light with a wavelength of 486 nm.

A) 1
B) 5
C) 3
D) 4
E) 2
6) Electromagnetic radiation with a wavelength of 531 nm appears as green light to the human
eye. A laser that emits 1.3 × 10-2 J of energy in a pulse of light at this wavelength produces
__________ photons in each pulse.

A) 2.9 × 10-17
B) 9.2 × 10-24
C) 1.8 × 1019
D) 3.5 × 1016
E) 6.5 × 1013

7) The energy required to break one mole of carbon-hydrogen bonds is 414 kJ/mol. What is the
longest wavelength of light capable of breaking a single carbon-hydrogen bond?

8) Which of the following transitions in a hydrogen atom would emit the longest wavelength
photon?

A) n = 1 to n = 2
B) n = 3 to n = 2
C) n = 5 to n = 1
D) n = 2 to n = 8
E) n = 6 to n = 5

9) What type of orbital is designated by:

A) n=3, l=0, ml=0 ____________

B) n=4, l=3, ml=-1 _____________

C) n=6, l= 2, ml = 3 ___________________
10) How many orbitals have these sets of quantum numbers IDENTICAL:

A) n=4

B) n = 3 and l = 3

C) n= 6, l = 2, ml = -2

D) n= 7 and l = 0

11) How many electrons can be described by the quantum numbers n = 5, l = 3, ms = -1/2?

A) 1
B) 3
C) 5
D) 7
E) 9

12) Which of the following transitions represent the emission of a photon with the largest
energy?

A) n = 2 to n = 1
B) n = 3 to n = 1
C) n = 6 to n = 3
D) n = 1 to n = 4
E) n = 2 to n = 5

13. For a hydrogen atom, calculate the wavelength of the line in the Lyman series that results
from the transition n = 4 to n = 1. The Rydberg constant equals -2.18 x 10-18 J.

A) 30.4 nm
B) 97.2 nm
C) 114 nm
D) 121 nm
E) 182 nm

14. How many electrons can be described by the quantum numbers n = 7, l = 1?

A) 0
B) 2
C) 6
D) 7
E) 14
15. For each of the following atoms or ions:
A) Write out the abbreviated electron configuration.
B) How many unpaired electrons are there?
C) Is the species diamagnetic or paramagnetic?
D) Give a complete set of four quantum numbers for each valence electron.

A) V B) In

16. According to the following reaction, how much energy is evolved during the reaction of
32.5 g B2H6 and 72.5 g Cl2? The molar mass of B2H6 is 27.67 g/mol.

B2 H6 (g)  6 Cl2 (g)  2 BCl3 (g)  6 HCl(g) ΔHo = 1396 kJ

rxn

17. For the elements below identify the number of unpaired electrons:

A) Ni

B) Pd

C) Te

D) Pb

E) Sb
18. A 7.18 g sample of aniline (C6H5NH2, molar mass = 93.13 g/mol) was combusted in a
bomb calorimeter with a heat capacity of 17.11 kJ/°C. If the initial temperature was 24.50°C,
use the information below to determine the value of the final temperature of the calorimeter.

4 C6H5NH2(l) + 35 O2(g) → 24 CO2(g) + 14 H2O(g) + 4 NO2(g)

ΔH°rxn= -1.28 x 104 kJ

19. Determine H for the following reaction,

N2(g) + 3 H2(g)  2 NH3(g). Given the thermochemical equations below:

N2(g) + O2(g)  2 NO(g) H = +180.8 kJ

4 NH3(g) + 5 O2(g)  4 NO(g) + 6 H2O(g) H = -906.2 kJ
2 H2(g) + O2(g)  2 H2O(g) H = -483.6 kJ

A) -1209.0 kJ
B) -1189.0 kJ
C) -756.5 kJ
D) -241.8 kJ
E) -91.5 kJ