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Ductile Iron 101
Ductile Iron 101
Bob Roberts
27-Mar-2015
"The information contained herein is FORD PROPRIETARY information and may include FORD CONFIDENTIAL information as defined in Ford's
Global Information Standard II. Reproduction of this document, disclosure of the information, and use for any purpose other than the conduct of
business with Ford is expressly prohibited" Copyright © 2016 Ford Motor Company. All rights reserved.
Training Outline
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Ductile Iron Introduction
• What is Cast Iron?
• What is Ductile Iron?
• Why Use Ductile Iron?
• Ductile Iron Properties
• How Does Ford Specify Materials?
• What is High Quality Ductile Iron?
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What is Cast Iron?
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What is Cast Iron?
Pearlite Ferrite
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What is Ductile Iron?
Ductile iron is a cast iron that has
been treated while molten with
magnesium or rare earth elements
(i.e., cerium) to induce the formation
of free graphite as nodules or
spheroids, which imparts a
measurable degree of ductility.
It was “discovered” in 1943 in an Spheroidal Graphite
Flake Graphite
(Unetched Sample)
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One Iron with Many Names . . .
• Ductile Iron is also known as Nodular or
Spheroidal Graphite (SG) iron.
• Other types of cast iron include malleable
iron, gray iron, white iron and compacted
graphite (CG) iron.
• The characteristic that distinguishes them
from each other is the form of the carbon
present. Most cast irons contain graphite.
• The term morphology is used to describe
the type and shape of the graphite.
Spheroidal Graphite
(Unetched Sample)
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One Iron with Many Names . . .
• Ductile Iron is also known as Nodular or
Spheroidal Graphite (SG) iron.
• Other types of cast iron include malleable
iron, gray iron, white iron and compacted
graphite (CG) iron.
• The characteristic that distinguishes them
from each other is the form of the carbon
present. Most cast irons contain graphite.
• The term morphology is used to describe
the type and shape of the graphite.
• Structure can be further classified in terms Ferrite Pearlite
of percent pearlite and percent ferrite (Etched Sample)
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Cast Iron – Graphite Morphology
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Nodularity
• NODULARITY – percentage of
spheroidal (round) nodules
• Nodularity requirement depends
upon the application
• Higher nodularity requires more
process discipline & inspection =
higher cost
• SAE grades require 80% min.
nodularity
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Why Use Ductile Iron?
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Typical Ductile Iron Components
• Control arms
• Steering knuckles
• Brake calipers
• Bearing caps
• Camshafts
• Crankshafts
• Exhaust manifolds
• Brackets
• Plus……..
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How Does Ford Specify Materials?
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SAE Ductile Iron Specifications
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Ford Ductile Iron Crankshaft Specification
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What is High Quality Ductile Iron?
• Consistent chemistry
• 200 nodules/mm2 minimum
• 90%+ Nodularity
• 0.5% carbides & inclusions
(max.)
• 1% porosity and/or micro
shrinkage (max.)
• Consistent matrix
microstructure
• Pearlite/ferrite within
specification (application
dependent)
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Ductile Iron Manufacturing
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Ductile Iron Melt Process Steps
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Cupola Melting of Cast Iron
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Cupola Melting of Cast Iron
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Induction Melting of Cast Iron
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Iron Chemistry and Carbon Equivalent
CE = Carbon + 1/3 Silicon + 1/7 Mn
Carbon Equivalent Range for Ductile Iron Factors That Limit Carbon & Silicon Range
CE = C + 1/3Si = 4.55
Tendency
Carbon Content (%)
CE = C + 1/7Si = 3.9
Solubility of C in Austenite
1 3.5
CE = %C + 1/6% Si = 2.0
Excessive
Shrinkage
0 3.4
0 1 2 3 4 1.5 2.0 2.5 3.0 3.5
Silicon Content (%) Silicon Content (%)
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Metal Chemistry: Gray vs. Ductile Iron
ELEMENT Ductile Gray
Carbon Equivalent 4.35 - 4.70% 3.85 - 4.25%
Carbon 3.50 – 3.90 3.20 – 3.50
Silicon 2.20 – 2.80 1.80 – 2.50
Manganese 0.10 – 1.00 0.50 – 1.00
Sulfur 0.015 Max. 0.15 Max
Copper 0.05 – 1.50 0.15 – 0.80
Magnesium 0.03 – 0.06 NONE
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Magnesium Treatment
Sandwich Treatment Ladle
Magnesium Treatment
• Key process control is Fade Time
• The time Mg-treated iron can be held will
depend upon the subsequent processing.
• Mg fade occurs in about 12 – 15 minutes in an
environment rich in oxygen (ladle).
• It may not fade for several hours when held
under pressure or in a minimal oxygen
environment (pressure pour furnace.
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Ductile Iron Processing
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Inoculation
Inoculants are added to create nucleation sites that
promote spheroidal (nodular) graphite formation
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In-stream Inoculation
Unpoured molds
Instream Inoculation Poured molds
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In-stream Inoculation
In-stream
inoculation
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Non-Destructive Testing Methods
• Ring test – hit casting with hammer and listen for “ring”
• Acoustic resonance
– scientific version of ring test
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Ductile Iron
Casting Controls Checklist
W-CMS
Worldwide Casting Manufacturing Standard
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Ductile Iron Casting Controls Checklist
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Ductile Iron Casting W-CMS
Char.
Class.
(min Test / Inspection Recommended Suggested Best Evidence or Gap
Area Item Characteristic level) Frequencies (Minimum) Control Method Measuring System Practice G/Y/R identified
Raw material
Fixed Limits:
than 0.0012% can result
in softer materials and
Chemistry control
Al, Mg, Ti, V, Mo, Ni lower UTS
1
Inoculation location / target (in-stream)
7.4 (per SS#1301) HIC each pour or batch Work instruction checksheet
Center
SiC maystream
pouring for
source basin
Boron
above
be a possible Verify, Verify,
7.5 Alloys/Inoculants
1.2 Inoculation application timing
certification each material
each mold lot Work instruction
Approval process Visual
Certification contamination
Inoculation system
7.6 Non-metallic
1.3 verification
certification
1.4 Sand raw material (Core and Molding)
each material
each shift lot
each material lot
Pre-control
Approval process
Approval process
Weigh check
Certification
Certification
Verify
1.5 Mold and Core Sand additives certification each material lot Approval process Certification
1.6 Inventory control (handling and storage) each material lot Store appropriately Visual FIFO
1.7 Non-metallics (fluxes) each material lot Approval process Certification
Manufacturing aides
1.8 (screens/filters/ceramics) each material lot Approval process Certification
Melting / Holding Operation: Induction (Batch) / Cupola (Continuous)
1) Final Carbon
Equivalent ranges (4.3-
Pre-Control:
4.6%) depending on
CE, C, Si, S, Mn, P,
spectrometer section thickness
Cu, Cr, Sn,
Metal Chemistry (Major Elements) each heat lot / (C & S Leco 2) Round robin verification
2.1 (per SS #2297/2323) HIC Every hour Determinators) study
Boron amounts higher
than 0.0012% can result
Fixed Limits: in softer materials and
Al, Mg, Ti, V, Mo, Ni lower UTS
Pb, Ce, B, La*, Te* Te, W, La are dependent
each heat lot / spectrometer upon product/process
2.2 Metal Chemistry (Other Elements) Every hour needs
each heat lot / Daily verification
2.3 Metal Temperature Every hour Pre-control Immersion pyrometer w/calibrated unit
2.4 Metallics charge makeup (weight) each charge Recipe Weigh scale Auto compensation
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10.7 Leak testing (if specified) per Print/ES or PV plan Acceptance Criteria
per Material Spec, ES, or
each heat lot /
mass airflow Standard GTS-1.4.1
Detailed thermal analysis
Key point:
10.8.1 Microstructure: %Nodularity HIC Print Pre-control Visual comparator 80% Nodularity minimum
2.5 Thermal analysis (CE, C, Si) Every hour Pre-control Thermal arrest unit (trace) cooling curve
Measure inputs
10.8.2
Desulfurization (method dependent), if
Microstructure: Nodule count (nod/mm2)
2.6 required HIC
per Material Spec, ES, or
Print heat lot/ batch
each minimum level
Pre-control
(Weigh Scale or flow
Visual comparator
rate) 200 nod/mm2 minimum
Validate and set
per Material Spec, ES, or
10.8.3 Microstructure: Pearlite Print
per Material Spec, ES, or
micro analysis Visual comparator 1) Alarm / Digital display
2) All treatment ladles,
appropriate
10.8.4 Microstructure: Ferrite Print micro analysis Visual comparator intermediate ladles, and
pouring ladle liquid or
Surface
solid chillheels
metal - Maximum
are
sample size and
Transfer method Work instruction 4%
removed after use or fade
2.7 (per SS #2742)
10.8.5 Microstructure:
2.8 Alloy additions Carbides
per Material
each
each
ladle Spec, ES, or includes heel removal Weigh scale
Print heat lot/ batch maximum level
Recipe Visual comparator
Weigh scale
Matrix
time
Maximum
Auto
carbides -
expires
1%
feeding
frequency
Pre-inoculation additions (product
2.9 dependent) each ladle
each heat lot for (batch)/
Recipe Weigh scale Auto compensation
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2.10 Slagging continuous (cupola) Work instruction Visual inspection
2.11
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Typical Ductile Iron Failure Modes
• Wrong microstructure
– Flake Graphite
– Low Nodularity
– Carbides
– Exploded Graphite
• Shrinkage
• Non-metallic inclusions (sand/slag)
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Potential Failure Modes and Avoidance Practice
Flake Graphite
Flake Graphite:
• Results in lower ductility from
inadequate formation of nodules
due to Mg fade (loss), too high
sulfur content, extended exposure
to oxygen, or untreated base iron.
The negative effect is 50%
reduction in material strength.
Avoidance Practices:
• Effective ladle tracking system
• Control the time between Mg
treatment and last pour
(Magnesium Fade Time).
– Usually, this time period is controlled to
less than 12 minutes time between Microstructure of flake graphite
treatment to pouring with automated (not spheroids)
alarms & interlocks to prevent pouring
out-of-spec fade time
• Hold treated iron in a low oxygen
pressure pour furnace 42
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Potential Failure Modes and Avoidance Practice
Low Nodularity
Compacted Graphite:
• Primarily due to sulfur
contamination or inadequate
inoculant, compacted graphite
can results in lower ductility
from inadequate formation of
nodules.
Avoidance Practices:
• Hold treated iron in a low
oxygen pressure pour furnace
• Control the time between Mg
treatment and last pour
(Magnesium Fade Time).
• Monitor Sulfur content of metal
and Sand. Microstructure of Compacted
• Control weight of inoculant Graphite (not spheroids)
additions.
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Potential Failure Modes and Avoidance Practice
Carbides
Carbide Formation:
• Carbides are brittle constituents that forms when
iron solidifies below the iron carbide eutectic point
(2050F) due to excessively fast cooling rates.
• Chill carbides can occur at part features such as
sharp corners, thin walls or fins.
• Other contributors include carbide promoter
chemistry elements (Cr, V, Mo and other trace
elements), low Silicon content or lack of
inoculation.
Avoidance Practices:
• Establish startup controls to confirm the following Microstructure of Carbides in ductile
KPIVs prior to release of first parts poured: iron
– Sand temperature is high enough to prevent
chill carbides.
– Ladles are hot enough to prevent
unexpectedly rapid Mg fade rates
– Verification of inoculant addition
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Potential Failure Modes and Avoidance Practice
Exploded Graphite
Exploded Graphite:
• Results from excessive Mg and/or
rare earth elements (Ce, La, Nd).
• Normally found in the thicker
sections where the cooling rate is
slowest, but could be at the surface
if sand is contaminated.
Avoidance Practices:
• Control Mg treatment weight
additions, paying special attention to
the morphology of the 1st part
poured (using high magnification).
Exploded graphite
Image from
www.solidmetals.net 45
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Potential Failure Modes and Avoidance Practice
Low Nodule Count
Avoidance Practices:
• Control of nodulizing agent Nodule Count Density
In-Stream Inoculant:
• Inoculation target – center of
metal stream above mold to
assure Ferro silicate power is
mixing with metal stream.
Avoidance Practices:
• Manual check point for
operation, time period no
longer than casting line
length. Metal Stream Inoculant Feed Tube
• Backpressure sensor for
material presence.
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Questions?
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