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Basic Ductile Iron Training

Bob Roberts
27-Mar-2015

"The information contained herein is FORD PROPRIETARY information and may include FORD CONFIDENTIAL information as defined in Ford's
Global Information Standard II. Reproduction of this document, disclosure of the information, and use for any purpose other than the conduct of
business with Ford is expressly prohibited" Copyright © 2016 Ford Motor Company. All rights reserved.
Training Outline

• Ductile Iron Introduction


• Material Characteristics
• Ductile Iron Manufacturing
• Ductile Iron Casting Controls Checklist
• Typical Ductile Iron Failure Modes

2
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Introduction
• What is Cast Iron?
• What is Ductile Iron?
• Why Use Ductile Iron?
• Ductile Iron Properties
• How Does Ford Specify Materials?
• What is High Quality Ductile Iron?

3
Copyright © 2016 Ford Motor Company. All rights reserved.
What is Cast Iron?

• In simple terms, cast iron can be thought of as


steel with free graphite (carbon).
• The shape of the free graphite controls the
physical and mechanical properties.

Flake Graphite Compacted Graphite Spheroidal Graphite

4
Copyright © 2016 Ford Motor Company. All rights reserved.
What is Cast Iron?

• In simple terms, cast iron can be thought of as


steel with free graphite (carbon).
• The shape of the free graphite controls the
physical and mechanical properties.
• The matrix microstructure also influences the
properties.

Flake Graphite Compacted Graphite Spheroidal Graphite

Pearlite Ferrite

5
Copyright © 2016 Ford Motor Company. All rights reserved.
What is Ductile Iron?
Ductile iron is a cast iron that has
been treated while molten with
magnesium or rare earth elements
(i.e., cerium) to induce the formation
of free graphite as nodules or
spheroids, which imparts a
measurable degree of ductility.
It was “discovered” in 1943 in an Spheroidal Graphite
Flake Graphite
(Unetched Sample)

attempt to make carbidic gray iron as


a replacement for chromium to help
the war effort.

6
Copyright © 2016 Ford Motor Company. All rights reserved.
One Iron with Many Names . . .
• Ductile Iron is also known as Nodular or
Spheroidal Graphite (SG) iron.
• Other types of cast iron include malleable
iron, gray iron, white iron and compacted
graphite (CG) iron.
• The characteristic that distinguishes them
from each other is the form of the carbon
present. Most cast irons contain graphite.
• The term morphology is used to describe
the type and shape of the graphite.
Spheroidal Graphite
(Unetched Sample)

7
Copyright © 2016 Ford Motor Company. All rights reserved.
One Iron with Many Names . . .
• Ductile Iron is also known as Nodular or
Spheroidal Graphite (SG) iron.
• Other types of cast iron include malleable
iron, gray iron, white iron and compacted
graphite (CG) iron.
• The characteristic that distinguishes them
from each other is the form of the carbon
present. Most cast irons contain graphite.
• The term morphology is used to describe
the type and shape of the graphite.
• Structure can be further classified in terms Ferrite Pearlite
of percent pearlite and percent ferrite (Etched Sample)

– Amount depends on application and specification

8
Copyright © 2016 Ford Motor Company. All rights reserved.
Cast Iron – Graphite Morphology

Flake Graphite Compacted Graphite Spheroidal Graphite

9
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Nodularity

• NODULARITY – percentage of
spheroidal (round) nodules
• Nodularity requirement depends
upon the application
• Higher nodularity requires more
process discipline & inspection =
higher cost
• SAE grades require 80% min.
nodularity

10
Copyright © 2016 Ford Motor Company. All rights reserved.
Why Use Ductile Iron?

• Cost depends upon many factors, but is


generally lower vs. steel for semi-complex to
complex geometry parts.
• The following characteristics of Ductile Iron lie
between Gray Iron & Steel:
– Density, Strength, Fatigue Life, Toughness, Modulus,
Ductility, Machinability, Thermal Conductivity,
Coefficient of Thermal Expansion & Dampening
Capacity . . .

11
Copyright © 2016 Ford Motor Company. All rights reserved.
Typical Ductile Iron Components

• Control arms
• Steering knuckles
• Brake calipers
• Bearing caps
• Camshafts
• Crankshafts
• Exhaust manifolds
• Brackets
• Plus……..
12
Copyright © 2016 Ford Motor Company. All rights reserved.
How Does Ford Specify Materials?

• Whenever possible, Ford uses


International Standards, i.e., SAE, ASTM
to specify materials.
• For components with
unique/different/additional requirements a
Ford Engineering Material Specification
may be used.

13
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SAE Ductile Iron Specifications

14
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Ford Ductile Iron Crankshaft Specification

15
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What is High Quality Ductile Iron?

• Consistent chemistry
• 200 nodules/mm2 minimum
• 90%+ Nodularity
• 0.5% carbides & inclusions
(max.)
• 1% porosity and/or micro
shrinkage (max.)
• Consistent matrix
microstructure
• Pearlite/ferrite within
specification (application
dependent)
16
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Ductile Iron Manufacturing

• Melting process for manufacture of ductile iron is


basically same as gray iron, but with a couple additional
steps.
– Additional potential failure modes need to be considered
• The most common methods for primary melting are the
same for ductile and gray iron:
– Cupola Melting
– Induction Melting
• The most common method for holding is in an induction
furnace. Treated iron may be held in specially designed
“low oxygen” or pressure pour furnaces.

17
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Ductile Iron Melt Process Steps

• Melt Base Iron


• Desulfurize/Alloy Base Iron
• Magnesium treatment
• Inoculate Iron
• Pour Iron

18
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Cupola Melting of Cast Iron

19
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Cupola Melting of Cast Iron

• Adds sulfur to the iron


• Additional processing required
to remove the sulfur
20
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Induction Melting of Cast Iron

21
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Induction Melting of Cast Iron

• High energy usage due to


electric induction
• Batch melting
• May constrain capacity

• Facilitates tighter melt


chemistry control
• Does not add sulfur
• Additional processing not
required

22
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Iron Chemistry and Carbon Equivalent
CE = Carbon + 1/3 Silicon + 1/7 Mn
Carbon Equivalent Range for Ductile Iron Factors That Limit Carbon & Silicon Range

1.5 2.0 2.5 3.0 3.5


5 3.9
Eutectic Composition
Hypereutectic
CE = %C + 1/3 %Si = 4.3
Graphite
Ductile
Preferred Range Flotation
4 3.8

CE = C + 1/3Si = 4.55
Tendency
Carbon Content (%)

Carbon Content (%)


For Carbides
3 3.7
Hypoeutectic
Gray
Preferred Range
2 3.6
Low Temp
Impact

CE = C + 1/7Si = 3.9
Solubility of C in Austenite
1 3.5
CE = %C + 1/6% Si = 2.0

Excessive
Shrinkage

0 3.4
0 1 2 3 4 1.5 2.0 2.5 3.0 3.5
Silicon Content (%) Silicon Content (%)
23
Copyright © 2016 Ford Motor Company. All rights reserved.
Metal Chemistry: Gray vs. Ductile Iron
ELEMENT Ductile Gray
Carbon Equivalent 4.35 - 4.70% 3.85 - 4.25%
Carbon 3.50 – 3.90 3.20 – 3.50
Silicon 2.20 – 2.80 1.80 – 2.50
Manganese 0.10 – 1.00 0.50 – 1.00
Sulfur 0.015 Max. 0.15 Max
Copper 0.05 – 1.50 0.15 – 0.80
Magnesium 0.03 – 0.06 NONE
24
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Magnesium Treatment
Sandwich Treatment Ladle

• 2 ton sandwich treatment


ladle filled from holding
furnace, which introduces
magnesium ferrosilicon alloy
into molten iron.
• Magnesium ferrosilicon alloy
is “sandwiched” between the
bottom of the ladle and steel
punchings used to cover the
alloy.
• Ladle height is larger than
diameter (3:1 ratio) to provide
sufficient metal head above
bottom pocket to increase Mg
recovery
25
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Manufacturing Process Steps

Magnesium Treatment
• Key process control is Fade Time
• The time Mg-treated iron can be held will
depend upon the subsequent processing.
• Mg fade occurs in about 12 – 15 minutes in an
environment rich in oxygen (ladle).
• It may not fade for several hours when held
under pressure or in a minimal oxygen
environment (pressure pour furnace.

26
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Ductile Iron Processing

Courtesy: Gartland Foundry


27
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Ductile Iron Processing

Courtesy: Gartland Foundry


28
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Inoculation
Inoculants are added to create nucleation sites that
promote spheroidal (nodular) graphite formation

29
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Inoculation
Inoculants are added to create nucleation sites that
promote spheroidal (nodular) graphite formation

Inoculants may be added:


• In-stream as pouring ladles or molds fill
• In-the-mold (inmold)
• Both in-stream and inmold

Potential failure modes of poor inoculation


• “Poorly inoculated” iron may have carbides and other
“undesirables” present in microstructure, which
adversely affect machinability.
• “Over-Inoculated” iron may contribute to shrinkage.
30
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In-stream Inoculation
• DISA mold line stopper
rod box showing
stopper rod in closed
position
• Inoculant gravity
feeder system shown
by arrows

31
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In-stream Inoculation

Unpoured molds
Instream Inoculation Poured molds

DISA Green Sand Mold Line direction of travel

32
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In-stream Inoculation

In-stream
inoculation

33
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Non-Destructive Testing Methods
• Ring test – hit casting with hammer and listen for “ring”
• Acoustic resonance
– scientific version of ring test

• Ultrasound – measure sound wave velocity in part

34
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron
Casting Controls Checklist

W-CMS
Worldwide Casting Manufacturing Standard

35
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Casting Controls Checklist

• The Casting Manufacturing Controls Checklist is


contained in Ford’s Worldwide Casting
Manufacturing Standard, W-CMS
• W-CMS is a global standard for minimum
manufacturing requirements of metal cast
components and provides generic control plan
expectations for casting processes by material
type.
• Lessons learned globally have been captured in
the W-CMS standard.

36
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Casting W-CMS
Char.
Class.
(min Test / Inspection Recommended Suggested Best Evidence or Gap
Area Item Characteristic level) Frequencies (Minimum) Control Method Measuring System Practice G/Y/R identified
Raw material

Lot/Document control Verify supplied sample


Restricted substance Radioactivity testing
compliance (WSS- Certification and/or Monitor steel for possible
1.1 Metallics certification each material lot M99P9999-A1) Spectrometer Boron contamination
Key point:
SiC may be a possible
1
1.2 Alloys/Inoculants certification each material lot Approval process Certification
source for Boron
contamination
develop approved
1.3 Non-metallic certification each material lot Approval process Certification
1.4
1.5
Sand raw material (Core and Molding)
Mold and Core Sand additives certification
each material lot
each material lot
Approval process
Approval process
Certification
Certification
supplier process
1.6 Inventory control (handling and storage) each material lot Store appropriately Visual FIFO
1.7 Non-metallics (fluxes) each material lot Approval process Certification
Manufacturing aides
1.8 (screens/filters/ceramics) each material lot Approval process Certification
Melting / Holding Operation: Induction (Batch) / Cupola (Continuous)
1) Final Carbon
Equivalent ranges (4.3-
Pre-Control:
4.6%) depending on
CE, C, Si, S, Mn, P,
spectrometer section thickness
Metal Chemistry (Major Elements)
2.1 (per SS #2297/2323) HIC
each heat lot /
Every hour
Cu, Cr, Sn,
(C & S Leco
Determinators)
2) Round robin verification
study
Key point:
Boron amounts higher

Fixed Limits:
than 0.0012% can result
in softer materials and
Chemistry control
Al, Mg, Ti, V, Mo, Ni lower UTS

each heat lot /


Pb, Ce, B, La*, Te*
spectrometer
Te, W, La are dependent
upon product/process
each heat
2.2 Metal Chemistry (Other Elements) Every hour needs
each heat lot / Daily verification
2.3 Metal Temperature Every hour Pre-control Immersion pyrometer w/calibrated unit
2.4 Metallics charge makeup (weight) each charge Recipe Weigh scale Auto compensation

2 each heat lot / Detailed thermal analysis


2.5 Thermal analysis (CE, C, Si) Every hour Pre-control Thermal arrest unit (trace) cooling curve
Measure inputs
Desulfurization (method dependent), if (Weigh Scale or flow
2.6 required each heat lot/ batch Pre-control rate)

1) Alarm / Digital display


2) All treatment ladles,
intermediate ladles, and
pouring ladle liquid or
solid metal heels are
Transfer method Work instruction removed after use or fade
2.7 (per SS #2742) each ladle includes heel removal Weigh scale time expires
2.8 Alloy additions each heat lot/ batch Recipe Weigh scale Auto feeding
Pre-inoculation additions (product
2.9 dependent) each ladle
each heat lot for (batch)/
Recipe Weigh scale Auto compensation
37
2.10 Slagging continuous (cupola) Work instruction Visual inspection
2.11
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Casting W-CMS
Char.
Class.
(min Test / Inspection Recommended Suggested Best Evidence or Gap
Area Item Characteristic level) Frequencies (Minimum) Control Method Measuring System Practice G/Y/R identified
Magnesium Treatment (Tundish,
Raw Sandwich, Converter)
material

Lot/Document control Verify supplied sample


1) Sandwich Treatment
Restricted substance Radioactivity testing
ladles have a height to
compliance (WSS- Certification and/or Monitor steel for possible
diameter ratio of
1.1 Metallics certification each material lot M99P9999-A1) Spectrometer Boron contamination
1H:(2 - 3)*D
2) Pre-heated ladles (gas
SiC may be a possible
Dimensional burner)
1 source for Boron
Magnesium Treatment Ladle PM Each repair / build of verification: Fixture 3) Operator inspection of
1.2 Alloys/Inoculants certification each material lot Approval process Certification contamination
3.1 (per SS #2220) ladle Forms or mold (gig) or gage ladle each shift
1.3 Non-metallic certification each material lot Approval process Certification
1) Photo eye or vibration
1.4 Sand raw material (Core and Molding) each material lot Approval process Certification
sensors for conversion
1.5 Mold and Core Sand additives certification each material lot Approval process Certification
detection
1.6 Inventory control (handling and storage) each material lot Store appropriately Visual FIFO
2) Magnesium Treatment
1.7 Non-metallics (fluxes) each material lot Approval process Certification
materials are added to
Manufacturing aides
the treatment ladle as
1.8 (screens/filters/ceramics) each material lot Approval process Certification
Magnesium (Alloy) Addition (wt %) late as possible prior to
3.2 (per SS# 2742) Melting HIC
/ Holding Operation:
each treatment Induction Pre-control
(Batch) / Cupola (Continuous)
Weigh iron and alloy tapout
1) Final Carbon
Equivalent
1) Filing theranges (4.3-
treatment
Pre-Control:
4.6%) depending
ladle avoids directon
CE, C, Si, S, Mn, P,
spectrometer section
pouring thickness
over the material
Cu, Cr, Sn,
Metal Chemistry (Major Elements) each heat lot / (C & S Leco 2) Round robin verification
chamber.
2.1 (per SS #2297/2323) HIC Every hour Determinators) study
2) Fill rate optimized for
Boron
magnesiumamounts higher
recovery
Target and Fill Rate: than 0.0012%
3) Preferred can result
methods are
3 Magnesium Treatment Filling Ladle design
Fixed Limits:& pouring in softer and
Tundish materials
Pure Mgand
3.3 (per SS #2220) each treatment Al, Mg, Ti,
position V, Mo, Ni Visual inspection
interaction lower UTS
Converters
Pb, Ce, B, La*, Te* Te, W, La are dependent
each heat lot / spectrometer upon
1) Alarmproduct/process
system
2.2 Metal Chemistry (Other Elements) Every hour needs
2) Fade time counters

2.3 Metal Temperature


2.4 Metallics charge makeup (weight)
each heat lot /
Every hour
each charge
Pre-control
Recipe
Immersion pyrometer
Weigh scale
Daily verification
and alarms
w/calibrated
Auto
account for
unit time
the total reaction Key point:
(initialcompensation
metal in the
treatment ladle to last
each heat lot / Detailed thermal analysis
ladle poured)
2
2.5 Thermal analysis (CE, C, Si) Every hour Pre-control Thermal arrest unit
Measure inputs
(trace)
3) Typicalcooling
totalcurve
time is 12 minutes
reaction Mg Fade time
Desulfurization
Mag Fade time (method dependent),
(time of treatment if
to last (Weigh Scale or flow (studies should support
required
2.6 mold poured) each heat lot/ batch Pre-control rate) going beyond 12
3.4 (per SS #2269) HIC each treatment Pre-control Timer minutes)
1) Alarm
Assembly / Digital
aidesdisplay
2) All treatment
directs material ladles,
into
intermediate
treatment chamber ladles, (i.e.
and
pouring
funnel). ladle liquid or
solid metal
2) Vision heels are
system to
Transfer method Work instruction removed after use or fade
control additions
2.7 (per SS #2742) each ladle includes heel removal
Work instruction - Weigh scale time expires alloy
3) Automated
2.8 Alloy additions each heat lot/ batch Recipe
Add Weighed alloys Weigh scale Auto feeding
addition systems
Pre-inoculation additions (product and steel in proper 4) Use clean steel plates
dependent)
2.9 Alloys / Rare Earths / cover steel additions
3.5 (per SS #2220)
each ladle
each heat lot for (batch)/
treatment
Recipe
order and location in
the ladle
Weigh
Weighed
steel
scale
alloys and Auto compensation
or punchings
steel
as cover 38
2.10
3.6 Slagging HIC continuous
eatch ladle (cupola) Work instruction Visual inspection
2.11
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Casting W-CMS
Char.
Class.
(min Test / Inspection Recommended Suggested Best Evidence or Gap
Area Item Characteristic level) Frequencies (Minimum) Control Method Measuring System Practice G/Y/R identified
Inoculation (StreamRaw / Pour Box / Ladle / In-mold)
material
7.1 Correct Inoculant Material each production run Work instruction checksheet Color code
Lot/Document control Alarm supplied
Verify system sample
7.2 Inoculation presence (in-stream)
Detection of in-mold inoculation presence
HIC each pour or batch Restricted/ substance
Pressure weight
compliance (WSS-
Pressure sensor / scale
In-stream: camera
Radioactivity
Vision system
Certification and/or Monitor
testing
steel for possible
Key point:
7 7.3 Metallics
1.1 (in-mold) certification HIC mold
each material lot Alloy detection
M99P9999-A1) presence
Spectrometer In-mold:
Boron laser
contamination
Jig fixture

1
Inoculation location / target (in-stream)
7.4 (per SS#1301) HIC each pour or batch Work instruction checksheet
Center
SiC maystream
pouring for
source basin
Boron
above
be a possible Verify, Verify,
7.5 Alloys/Inoculants
1.2 Inoculation application timing
certification each material
each mold lot Work instruction
Approval process Visual
Certification contamination
Inoculation system
7.6 Non-metallic
1.3 verification
certification
1.4 Sand raw material (Core and Molding)
each material
each shift lot
each material lot
Pre-control
Approval process
Approval process
Weigh check
Certification
Certification
Verify
1.5 Mold and Core Sand additives certification each material lot Approval process Certification
1.6 Inventory control (handling and storage) each material lot Store appropriately Visual FIFO
1.7 Non-metallics (fluxes) each material lot Approval process Certification
Manufacturing aides
1.8 (screens/filters/ceramics) each material lot Approval process Certification
Melting / Holding Operation: Induction (Batch) / Cupola (Continuous)
1) Final Carbon
Equivalent ranges (4.3-
Pre-Control:
4.6%) depending on
CE, C, Si, S, Mn, P,
spectrometer section thickness
Cu, Cr, Sn,
Metal Chemistry (Major Elements) each heat lot / (C & S Leco 2) Round robin verification
2.1 (per SS #2297/2323) HIC Every hour Determinators) study
Boron amounts higher
than 0.0012% can result
Fixed Limits: in softer materials and
Al, Mg, Ti, V, Mo, Ni lower UTS
Pb, Ce, B, La*, Te* Te, W, La are dependent
each heat lot / spectrometer upon product/process
2.2 Metal Chemistry (Other Elements) Every hour needs
each heat lot / Daily verification
2.3 Metal Temperature Every hour Pre-control Immersion pyrometer w/calibrated unit
2.4 Metallics charge makeup (weight) each charge Recipe Weigh scale Auto compensation

2 each heat lot / Detailed thermal analysis


2.5 Thermal analysis (CE, C, Si) Every hour Pre-control Thermal arrest unit (trace) cooling curve
Measure inputs
Desulfurization (method dependent), if (Weigh Scale or flow
2.6 required each heat lot/ batch Pre-control rate)

1) Alarm / Digital display


2) All treatment ladles,
intermediate ladles, and
pouring ladle liquid or
solid metal heels are
Transfer method Work instruction removed after use or fade
2.7 (per SS #2742) each ladle includes heel removal Weigh scale time expires
2.8 Alloy additions each heat lot/ batch Recipe Weigh scale Auto feeding
Pre-inoculation additions (product
2.9 dependent) each ladle
each heat lot for (batch)/
Recipe Weigh scale Auto compensation
39
2.10 Slagging continuous (cupola) Work instruction Visual inspection
2.11
Copyright © 2016 Ford Motor Company. All rights reserved.
Ductile Iron Casting W-CMS
Char.
Class.
(min Test / Inspection Recommended Suggested Best Evidence or Gap
Area Item Characteristic level) Frequencies (Minimum) Control Method Measuring System Practice G/Y/R identified
Product Testing and Inspections
Raw material
Automatic impression
10.1 Surface Hardness subgroup sample/lot Pre-control
Lot/Document control Brinell measurement
Verify supplied sample
per Material Spec, ES, or Restricted substance Radioactivity testing
10.2 Mechanical Property (from part if possible) Print Tensile tesing
compliance (WSS- UTS-YS-Elongation
Certification and/or Monitor steel for possible
1.1 Metallics certification each material lot M99P9999-A1) Spectrometer Resonance
Boron Inspection or
contamination
10.3 Surface Integrity per Print/ES or PV plan Acceptance Criteria NDT (Magnetic Particle)
UT
10.4 Internal Integrity per Print/ES or PV plan Acceptance Criteria NDT (Xray) or DT NDTmay
SiC whenbepossible
a possible
1 source for Boron
1.2 Alloys/Inoculants certification each material lot Approval process Certification 1) Ultrasonic Velocity
contamination
1.3 Non-metallic certification each material lot Approval process Certification Testing or Resonance
1.4 Sand raw material (Core and Molding) each material lot Approval process Certification Testing
1.5 Mold and Core Sand additives certification each material lot Approval process Certification 2) Test equipment
1.6 Inventory control (handling and storage) each material lot Store appropriately Visual includes appropriate
FIFO
1.7 Non-metallics (fluxes) each material lot Approval process Certification tester calibration
Manufacturing aides (minimum weekly) and
1.8 (screens/filters/ceramics) each material lot Approval process Certification verification (each shift).
3) Each part's nodularity
Melting / Holding Operation: Induction (Batch) / Cupola (Continuous)
test has a positive
1) Final Carbon
indication (marking) of
Equivalent ranges (4.3-
Pre-Control: acceptance and an error
4.6%) depending on
Nodularity testing Safety parts (Inverted CE, C, Si, S, Mn, P, Correlation to proof when a reject is
spectrometer section thickness
10.5 (per SS #2220 / 2297 / 2323) Delta): 100% Cu, Cr, Sn,
Non-destructive testing %nodularity identified
Metal Chemistry (Major Elements) each heat lot / (C & S Leco 2) Round robin verification
Per Part Print:
2.1 (per SS #2297/2323) HIC Every hour Determinators) study
10 Special
Boron amounts higher
Characteristics/Pass
than 0.0012% can result
Through
Fixed Limits: in softer materials and
Characteristics.
Al, Mg, Ti, V, Mo, Ni lower UTS
Consider key
Pb, Ce, B, La*, Te* Te, W, La are dependent
1st Piece and Last Piece pattern/core features At PPAP: Full layout
each heat lot / spectrometer upon product/process
SC/PTC/ Each cavity / each prone to damage or Dimensional gage or with point cloud scanning
2.2 Metal Chemistry (Other Elements) Every hour needs
10.6 Dimensional HIC production run wear. CMM (Laser or light)
each heat lot / Daily verification
Air decay or
2.3 Metal Temperature Every hour Pre-control Immersion pyrometer w/calibrated unit
air-under-water or Leak Test Robustness
2.4 Metallics charge makeup (weight) each charge Recipe Weigh scale Auto compensation

2
10.7 Leak testing (if specified) per Print/ES or PV plan Acceptance Criteria
per Material Spec, ES, or
each heat lot /
mass airflow Standard GTS-1.4.1
Detailed thermal analysis
Key point:
10.8.1 Microstructure: %Nodularity HIC Print Pre-control Visual comparator 80% Nodularity minimum
2.5 Thermal analysis (CE, C, Si) Every hour Pre-control Thermal arrest unit (trace) cooling curve
Measure inputs

10.8.2
Desulfurization (method dependent), if
Microstructure: Nodule count (nod/mm2)
2.6 required HIC
per Material Spec, ES, or
Print heat lot/ batch
each minimum level
Pre-control
(Weigh Scale or flow
Visual comparator
rate) 200 nod/mm2 minimum
Validate and set
per Material Spec, ES, or
10.8.3 Microstructure: Pearlite Print
per Material Spec, ES, or
micro analysis Visual comparator 1) Alarm / Digital display
2) All treatment ladles,
appropriate
10.8.4 Microstructure: Ferrite Print micro analysis Visual comparator intermediate ladles, and
pouring ladle liquid or
Surface
solid chillheels
metal - Maximum
are
sample size and
Transfer method Work instruction 4%
removed after use or fade
2.7 (per SS #2742)
10.8.5 Microstructure:
2.8 Alloy additions Carbides
per Material
each
each
ladle Spec, ES, or includes heel removal Weigh scale
Print heat lot/ batch maximum level
Recipe Visual comparator
Weigh scale
Matrix
time
Maximum
Auto
carbides -
expires
1%
feeding
frequency
Pre-inoculation additions (product
2.9 dependent) each ladle
each heat lot for (batch)/
Recipe Weigh scale Auto compensation
40
2.10 Slagging continuous (cupola) Work instruction Visual inspection
2.11
Copyright © 2016 Ford Motor Company. All rights reserved.
Typical Ductile Iron Failure Modes

• Wrong microstructure
– Flake Graphite
– Low Nodularity
– Carbides
– Exploded Graphite
• Shrinkage
• Non-metallic inclusions (sand/slag)

41
Copyright © 2016 Ford Motor Company. All rights reserved.
Potential Failure Modes and Avoidance Practice
Flake Graphite

Flake Graphite:
• Results in lower ductility from
inadequate formation of nodules
due to Mg fade (loss), too high
sulfur content, extended exposure
to oxygen, or untreated base iron.
The negative effect is 50%
reduction in material strength.
Avoidance Practices:
• Effective ladle tracking system
• Control the time between Mg
treatment and last pour
(Magnesium Fade Time).
– Usually, this time period is controlled to
less than 12 minutes time between Microstructure of flake graphite
treatment to pouring with automated (not spheroids)
alarms & interlocks to prevent pouring
out-of-spec fade time
• Hold treated iron in a low oxygen
pressure pour furnace 42
Copyright © 2016 Ford Motor Company. All rights reserved.
Potential Failure Modes and Avoidance Practice
Low Nodularity

Compacted Graphite:
• Primarily due to sulfur
contamination or inadequate
inoculant, compacted graphite
can results in lower ductility
from inadequate formation of
nodules.
Avoidance Practices:
• Hold treated iron in a low
oxygen pressure pour furnace
• Control the time between Mg
treatment and last pour
(Magnesium Fade Time).
• Monitor Sulfur content of metal
and Sand. Microstructure of Compacted
• Control weight of inoculant Graphite (not spheroids)

additions.
43
Copyright © 2016 Ford Motor Company. All rights reserved.
Potential Failure Modes and Avoidance Practice
Carbides

Carbide Formation:
• Carbides are brittle constituents that forms when
iron solidifies below the iron carbide eutectic point
(2050F) due to excessively fast cooling rates.
• Chill carbides can occur at part features such as
sharp corners, thin walls or fins.
• Other contributors include carbide promoter
chemistry elements (Cr, V, Mo and other trace
elements), low Silicon content or lack of
inoculation.
Avoidance Practices:
• Establish startup controls to confirm the following Microstructure of Carbides in ductile
KPIVs prior to release of first parts poured: iron
– Sand temperature is high enough to prevent
chill carbides.
– Ladles are hot enough to prevent
unexpectedly rapid Mg fade rates
– Verification of inoculant addition

44
Copyright © 2016 Ford Motor Company. All rights reserved.
Potential Failure Modes and Avoidance Practice
Exploded Graphite

Exploded Graphite:
• Results from excessive Mg and/or
rare earth elements (Ce, La, Nd).
• Normally found in the thicker
sections where the cooling rate is
slowest, but could be at the surface
if sand is contaminated.

Avoidance Practices:
• Control Mg treatment weight
additions, paying special attention to
the morphology of the 1st part
poured (using high magnification).

Exploded graphite
Image from
www.solidmetals.net 45
Copyright © 2016 Ford Motor Company. All rights reserved.
Potential Failure Modes and Avoidance Practice
Low Nodule Count

Nodule Count Density:


• Normally found in the thicker
sections where the cooling rate is
slowest, but could be at the
surface if sand is contaminated.

Avoidance Practices:
• Control of nodulizing agent Nodule Count Density

(inoculant) additions. While most Image from


inoculants act almost instantly, www.solidmetals.net

they do lose their nodulizing


affect over time. Therefore, it is
important to add the inoculant as
late as possible in the process.
• In-stream inoculation must be
carefully monitored for weight
addition and aim of injector
nozzle.
46
Copyright © 2016 Ford Motor Company. All rights reserved.
Potential Failure Modes and Avoidance Practice
Insufficient Inoculation

In-Stream Inoculant:
• Inoculation target – center of
metal stream above mold to
assure Ferro silicate power is
mixing with metal stream.

Avoidance Practices:
• Manual check point for
operation, time period no
longer than casting line
length. Metal Stream Inoculant Feed Tube
• Backpressure sensor for
material presence.

47
Copyright © 2016 Ford Motor Company. All rights reserved.
Questions?

48
Copyright © 2016 Ford Motor Company. All rights reserved.

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