Cachon Nanotubes
The descoving of buckyballs Led te the descovery
of other Forma of carbon that eve Structurally
roleteck, 2:5. Corben hanotubss ,
Theos. are cylindeical in shyctere oncl alo resemble
a rlledk—up sheet of Graphite, with the
Carhen moleckes arangecl ih rapeeting
Arxagons .
They have a dvamoter of a few nanometers
anc can be open at beth endo, Sealedt at
one end or Seolecl at both ends .
a carbon hanotebe open at bath’ onda
Carbon nanetibes have. proved to have very
sefil pro parties
¢
WMcni but Mighty’, thoy are many tines shongen
than steel.The mechanccal (Shffria, strength ; tug hice),
Fherinal and olachica proprtics of pire buclyhube
matinvels mnabhe a muthituele of appleatous,
from bottonica anc fuel cells to fibres anol
cables to pharmacedcticals ancl biomedical
matinols.
They awe foun in the hetteries of most
laptop computers ,
The world’s smellet trot fhe
The worlol’'s smableet tattoos as heon
Mack. from a Carbon nanotube.
a carbon nanetibe closed atone unel ~ & nano™test—tube!One enc of the tbe is closect by a fullerene
Cap thet contacns both pentagons anc hexagons
The tee hos & volume of x10 din?
Thetibe ag erablect OxPorol Sccenhsts to
se. the tube’s one-dimensional camty to
previa a template for the syuthess of
unbranchect pelymen chatns of CeeO ,
fillerens oxide .
This proues havinallag wegudr2s expensive cotnlysts
that ave sensitive to acr and water
Without the one- dimensional cantty , the
polymer wad branch in all devectonsReachiong ih_hanescale teaf=febeo
The potential of nanoscale trot-tubes For
Canryciy out reactona i berry syploredt ,
The nancrcale tiottrbe Aas various
devi votives otinched is Shown as follow?
a Chemical reaction ih a hanotche — polymensetion
ef CeO to form (CecO)n
These could be immobilisect en3ymes enabling
fast voachions in the syntherin of haw Ange
There ore distihet advantages of carycha out
There veachions on % Nahescale
Tr a nerinat testtube , the parteles have do
collide Po react ancl these collisione rely on
random movement
In inary reactions net all the particles react,
or unwanted Siete products ore procacect.These. problema reoult in reccodl Yyielel .
By contrat, @ nanoscale vaaction , whore
jndewiderel molecules are brought together,
Cam have an excesdingla Aish yell .
Trapped ockma in a corbon nahefivbe .
Another kincl of structure bechg devebopecl
involves buckyball cage containing trappecl
ccfome .
Those buckyball cages ore then encrappecl Insidle,
GO nanctabe, rather Like paas ih a poo.
@
“pena in a pod” — buckyballe conteniing trappect otra,
thamoekven inside, a carben nanctabe .
The pucpose of tis work by sccentists ih Oxforel
is to ihutotiqate the strrcture 0 On information
storage display.
”Supramolecular chemistry ~ making superto[ecles
Supramolecadar literally moana * beyoncl the molecule’,
Dus do molecules Can recognise eoch other, biological
molecules Such a2 MZ ymeo recogmas an!
other molecdes,
ob bind
Crown etter were Created a2 synthetic prolecutes
which Can recognise oncl binck fo metal ‘ona
to Form & complex:
F : oO
ic
a metal ion bound by a crown other molecule
The Field Aas developed in mang dereetions with
chemists synthesising ever Mors complex ancl
Finely -funscl super molecules from molecules
thot recoght se each other and binel to each
otter by non-covalent effects, inelaclong
Hrydrogen boncling ancl van cler Waale! forcesThire Super —molecules are being des ighact
do ba cattalysts, fo transport drugs, fo tranche
eleehiecty ond to harvest Inghh, among many
other things .Meleceler poston
The molecular moter 16 powered by Light.
The molecule vstetes obowt a corben- carbon
dowbLe bond .
The groupe ecther side of the dele honcl
are identical ancl UV light Comate these to
bnder go cs-trans iSomen Sotion .
Becawa of the large siza cf the gps, which
ave chiral, the motor con only rotate, in OMe
derection.
the First light-driven moleclon motor