Long Test I

26.7
26.70992
1. The [H+] in molarity for acetic acid 26.710
with pH = 3.4
3.34 x 10-6 M 7. The pOH of 3.4 x 10-6 M NaOH is
2.95 x 10-9 M
3.98 x 10-4 M 5.47
2.75 x 10-4 M 8.53
7.00
2. A solution contains 2.43 g of 3.56
Na2CO3 . 10H2O (MM=286.00) in
each 12.6 mL. What is the molarity?
8. The amount (mL) of concentrated
0.674 M HCL (12.0) needed to prepare 100
3.52 M mL of 2.0 M HCL
5.25 M
8.09 M 8.5 mL
83 mL
41.5 mL
3. This describes how an analyte 17 mL
respond in the presence of
interfering species.
9. What is the molarity of sol’n that
Selectivity contains 33.33% (w/w) H2SO4
Sensitivity (MM=98.08) by weight and has a
Reproducibility density of 1.250 g/mL?
repeatability
2.200 M
38.00 M
4. How many grams of K2SO4 (MM=
4.284 M
174.27) are contained in 50 mL of
21.24 M
0.200 M sol’n?
1.74 g
0.871 g 10. Calculate the approx molarity of a
0.436 g 13.0% (w/w) solution of H2SO4
2.58 g (MM=98.08) with specific gravity of
1.090.
5. This describes the correlation of two 2.90 M
variables in calibration 2.43 M
1.22 M
Standard deviation 1.44 M
Pearson correlation coefficient
Calibration slope
y-intercept 11. A solution is prepared by dissolving
27.03 g FeCl3 . 6H2O (MM=270.30)
6. The sum of three terms: 0.0121, and diluting to give a final volume of
25.64, and 1.05782 is 400 mL. Assuming 100 percent
ionization of the ferric chloride
26.71
 FeCl3.6H2O. Find the formality (F)
8 g/mL
of the Fe 3- and the Cl- ions. 8 kg/mL
0.750 F Fe3+ ; 0.250 F Cl- 8 mg/mL
0.250 F Fe3+; 0.750 F Cl- 8 mg/L
0.675 F Fe3+; 0.325 F Cl-
0.325 F Fe3+; 0.675 F Cl- 17. A solution of hydrogen peroxide sold
as a bleach and disinfectant
12. These are measures of random contains 3.0% by weight of H2O2
errors (MM=34) and has a density of 1.01
g/mL. The weight (g) of H2O2 in on
Standard dev
Variance mL of this solution is
RSD 0.06 g
All of the choices 33.3 g
16.65 g
13. How many mL of 0.1 M KN03 and 0.03 g
how many mL of H2O must be
mixed to give 250 mL of 0.02 M 18. What is the equivalent weight of
KNO3? H2SO4 (MM = 98.08)
100 mL KNO3 ; 150 mL H2O 98.08 g/eq
150 mL KNO3; 100 mL H2O 49.04 g/eq
50 mL KNO3; 200 mL H2O 32.69 g/eq
200 mL KNO3; 50 mL H2O 24.52 g/eq

14. How many grams of pure acetic acid 19. How many grams of KBr (MM=119)
(MM=60) CH3CO2H (l) having a are required to prepare 150 mL of
density of 1.049 g/mL is needed to 2.00 M solution?
prepare 1.00 L of 6.00 M CH3CO2H
17.8 g
(aq). 1.59 g
100 g 28.9 g
86.3 g 35.7 g
360 g
422 g 20. The mass (g) of 2.60 moles of
baking soda NaHCO3 (MM=84)
15. To what volume (mL) must 25 mL of
250 g
HCl (sp. Gr. 1.100) be diluted in 109 g
order to make a solution of HCl with 437 g
a sp. Gr. 1.040? 218 g
28.6 mL
3.60 mL 21. These affects the accuracy
26.4 mL
1.40 mL Instrument error
Method error
Personal error
16. A 8 ppm Cr (III) is equal to
 27. This is a chemical analysis where
All of the choices
we perform qualitative analysis

22. Consider the 19 9F atom. This atom Analyzing the amount of carbon
impurity in steel
contains x protons, y electrons and x
Knowing the components of
neutrons, the values of x,y,z are. beer
9,9,10 Seeking the extent of phosphate
10,9,9 pollution in Laguna de Bay
19,9,9 Checking the pesticide residue
9,9,19 level in lettuce

23. This describes the sensitivity of the 28. How many atoms are there in 1.43 g
method of Na (AM=23)

Linearity 6.02 x10^22 atoms

Pearson correlation coefficient 2.37 x10^22 atoms
Calibration slope 3.74 x10^22 atoms
y-intercept 8.61 x10^22 atoms

24. What is the pH of a solution that is 29. The weight (g) of solid BaCl2
3.2 x 10-4 M HCl (aq) (MM=208) needed to prepare 25 L of
0.10 BaCl2 solution
4.20
3.49 260 g
10.5 520 g
8.34 1040 g
0.0120 g
25. How many grams of SrCl2. 6H2O
(MM=266.62) are required to 30. How many significant figures are in
prepare 500 mL of 0.550 M solution? the following mass: 0.00047800 kg

2.75 g
73.3 g
1.03 g
36.7 g
26. A 20-mg sample of ore was found to
contain 100 ppm gold. The analysis
done can be classified as
Microanalysis; major constituents
Microanalysis; ultratrace const.
Ultramicro analysis; ultratrace
con
Semi-micro analysis; minor consti
5
31. All of the following relationships are
true EXCEPT
0.328 g= 328 mg
23 km < 4.5 x 10^7 mm
0.84 kg > 8.4 x 10^4 mg
41.3 mL >8.72 x 10^2 L
32. How many grams of H2SO4
(MM=98.08) are present 40.0 mL of
0.20 M sulfuric acid solution?
261 g
2.0 g
 substance, what is the molarity of
0.78 g
7.84 g final solution?
0.107 M
33. Detection of systematic errors could 0.135 M
0.056 M
be done by
0.081 M
Analyzing unknown materials None of the choices
Certified reference material
(CRM) determinations
38. A solution is prepared by mixing 8 g
Selecting a method of analysis
Measurement of property of ethanol C2H5OH (MM=46) and
5.0 g of water (MM=18). Calculate
the mole fraction of each component
34. Concentrated phosphoric acid
(MM=98) is 75% by mass H3PO4. If 0.862 C2H5OH ; 138 H2O
the molarity of centrated H3PO4 is 0.138 C2H5OH ; 0.862 H2O
0.941 C2H5OH ; 0.0589 H2O
12.5 M, what is the density (g/mL)
0.0589 C2H5OH ; 0.941 H2O
0.919 g/mL
1.63 g/mL
39. A 30% w/w solution of H3PO4
2.01 g/mL
0.785 g/mL (MM=98) has a specific gravity of
None of the choices 1.180, what is its molar (M)
concentration, assuming complete
neutralization?
35. How many mL of water must be
added to 10 mL of 12.0 M HCl 7.22 M
solution to make a 3.0 M HCl 1.08 M
solution 3.61 M
10.8 M
10 mL
25 mL
30 mL 40. A 4.10 normal solution of H2SO4
40 mL (MM=98.08) has a density of 1.21
g/mL. What is the molar
concentration of the sol’n?
36. The indeterminate error is
1.69 M
Caused temperature changes
2.48 M
Introduced by non-ideal chemical
4.10 M
or physical behavior of the
1.37 M
reagents
Caused by uncontrollable
variables 41. A 2 ppb Mgco3 is equal to
From personal judgements,
prejudice or number blas 2 mg/mL
2 g/L
2 ug/L
37. If a 27.0 mL of water is added to 2 mg/kg
35.0 mL of 0.10 M solution of any
42. How many moles of NaOH are 47. What is the normality of solution that
contained in 200 mL of 0.500 M contains 3.30 g of HNO3
solution (MM=63.01) in each 15 mL?
0.100 mol 3.49 N
2.50 mol 6.98 N
10.0 mol 0.770 N
20.5 mol 0.143 N

43. A solution is prepared by mixing 48. A solution is prepared by dissolving

10.00 g of ethanol C2H5OH 27.03 g FeCl3. 6H2O (MM=270.30)
(MM=46) and 55 g of water and diluting to give a final volume of
(MM=18). Calculate the 400 mL. Find the molarity
weight-percent (%) of ethanol
0.250 M
(EtOH) 0.675 M
16.34% (w/w) 0.750 M
86.00 % (w/w) 0.323 M
62.01% (w/w)
15.38% (w/w) 49. It is desired to make a 0.1000 M
solution by adding water to 5.000 g
44. This is used to express confidence of CuSO4.5H2O (MM=249.70) What
intervals is the final volume (mL)?
Q-test 250.3 mL
T-test 200.2 mL
F-test 100.5 mL
ANOVA 50.00 mL

45. A solution is prepared by mixing 8 g 50. This is a measure of accuracy

of methanol CH3OH (MM=32) and
Standard dev
40 g of water (MM=18). Calculate Absolute error
the methanol solution %RSD
CV
4.53 m
1.01 m
6.25 m 51. A solution contains 3.55 g of
7.00 m Na2CO3. 10H2O (MM=286.00) in
each of 22.9 mL. What is normality
46. The description for a trace
0.542 N
component of the sample is 1.08 N
> 1% of the sample 5.42 N
0.001 % - 0.01% of sample 1.63 N
0.01% - 1% of the sample
< 0.001% of the sample 52. How many moles of sodium ions
(AM=23) are present in 2.50 L of
0.300 M Na3PO4 (MM=164)
 C. Decreasing the
0.919 mol
1.63 mol temperature
2.25 mol D. Allowing some gases to
0.785 mol escape at constant P and T
E. Adding a catalyst
53. The molality (m) of a solution
prepared by dissolving 2.00 g of 3. For the following reaction at
urea CO(NH2)2 (MM=60) in 58 g of equilibrium, where will the shift of
water equilibrium be if container volume is
increased?
0.575 m
0.473 m
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
1.44 m
0.696 m 𝚫H°rxn= 30 kJ/mol

A. Left
_________________________________
B. Right
C. No change
Exercise 2
4. For the following reaction at
1. The reaction 2SO3 (g) ⇌ 2SO2 (g) + O2
equilibrium, where will the shift of
(g) is endothermic. If the temperature equilibrium be, if the total pressure is
is increased, increased?

A. More SO2 (g) will be produced 2NOBr (g) ⇌ 2NO (g) + Br2 (g)
B. K will decrease 𝚫H°rxn= 30 kJ/mol
C. No change will occur in K
D. More SO3 (g) will be A. Left
produced B. Right
E. The pressure will decrease C. No change
D. None of the choices
2. When the substances in the
equation below are at equilibrium, at 5. For the following reaction at
pressure P and temperature T, the equilibrium, where will the shift of
equilibrium can be shifted to favor equilibrium be, if the concentration of
the products by NO (g) is increased?

CuO(s)+H2(g) ⇌ H2O(g)+Cu(s) 2NOBr (g) ⇌ 2NO (g) + Br2 (g)

𝚫H°rxn= -2.0 kJ/mol 𝚫H°rxn= 30 kJ/mol

A. Increasing the pressure by A. Left

means of a moving piston at B. Right
constant T C. No change
B. Increasing the pressure by D. None of the choices
adding an inert gas such as
nitrogen
6. For the reaction, equilibrium to favor formation of
H2O2(g)→ H2O (g)+ ½ O2(g), 𝚫H°=-106 more products?
kJ/mol and 𝚫S°=58 J/K.mol at 25°C. 2NOBr (g) ⇌ 2NO (g) + Br2 (g)
Calculate 𝚫G° for this reaction at this 𝚫H°rxn= 30 kJ/mol
temperature. A. Decreasing the volume by
increasing the total
A. -1.73 x 104 J/mol pressure
B. - 1.54 x 108 J/mol B. Add more NO (g)
C. - 1.23 x 105 J/mol C. Remove Br2 (g)
D. - 1.96 x 105 J/mol D. Lower the temperature
E. None of the choices E. Remove NOBr (g) selectively

7. For the following reaction at 10. Which of these statements is false?

equilibrium in a reaction vessel,
which one of these changes would
cause the Br2 concentration to
increase?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Lower the temperature
B. Remove some NO (g)
C. Remove some NOBr (g)
D. Compress the gas mixture
into a smaller volume
E. None of the choices
8. Carbon tetrachloride reacts at high
temperatures with oxygen to
produce two toxic gases, phosgene
and chlorine.
CCl4(g)+O2(g) ⇌2 COCl2(g)+2Cl2(g)
K= 4.4 x 109 at 1,000 K
Calculate the K for the reaction:
2CCl4(g)+O2(g) ⇌2 COCl2(g)+2Cl2(g)
A. 2.2 x 109
B. 4.4 x 109
C. 1.9 x 1019
D. 8.5 x 1028
9. For the following reaction at
equilibrium which choice gives a
change that will shift the position of
PCl5(g) ⇌PCl3(g) + Cl2(g)
𝚫H°rxn=+87.8 kJ/mol
A. Increasing the system
volume shifts the equilibrium
to the right
B. Increasing the temperature
shifts the equilibrium to the
right
C. A catalyst speeds up the
approach to equilibrium
and shifts the position of
equilibrium to the right.
D. Decreasing the total pressure
of the system shifts the
equilibrium to the right.
E. Increasing the temperature
causes the equilibrium
constant to increase
11. The entropy change on vaporization
(change in Svap) of a compound or
element is
A. Always negative
B. Always positive
C. Sometimes it’s positive and
sometimes it’s negative
D. Always equal to one
E. None of the choices
12. For the following reaction at
equilibrium, where will the shift of
 equilibrium be, if temperature is
decreased?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
D. None of the choices
13. Consider the reaction:
N2(g)+3H2(g) ⇌2NH3(g)
If nitrogen is removed from the
system at equilibrium, what will
happen to the hydrogen (H2) gas
concentration?
A. It will increase
B. It will decrease
C. There will be no change
D. Concentration will be halved
14. For the following reaction at
equilibrium, where will the shift of
equilibrium be, if the temperature is
lowered?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
D. None of the choices
15. For the equilibrium reaction:
2SO2(g) + O2(g) ⇌2SO3(g)
𝚫H°rxn= -198 kJ/mol
Which one of these factors would
cause the equilibrium constant to
increase?
A. Decrease the temperature
B. Add SO2(g)
C. Remove O2 (g)
D. Add a catalyst
E. None of the choices
16. The following reactions occur at 500
k. Arrange them in order of
increasing tendency to proceed to
completion (least to greatest
tendency Example 1<2<3)
A. 1<2<3
B. 3<2<1
C. 2<1<3
D. 2<3<1
E. 3<1<2
17. Ozone (O3) in the atmosphere can
react with nitric oxide (NO):
O3(g)+NO(g) → NO2(g)+O2(g)
Calculate the 𝚫G° for this reaction
at 25°C. ( 𝚫H°=-199 kJ/mol,
𝚫S°=-4.1 J/K/mol)
A. -1.63 x 103 J/mol
B. +2.31 x 103 J/mol
C. -1.98 x 105 J/mol
D. None of the choices
18. For the following reaction at
equilibrium, which one of the
changes below would cause the
equilibrium to shift to the LEFT?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Increase the container
volume
B. Remove some NO (g)
C. Remove some Br2 (g)
D. Add more NOBr (g)
E. Decrease the temperature
19. On analysis, an equilibrium mixture
for the reaction:
2H2S(g) ⇌2H2(g)+S2(g)
Was found to contain 1.0 mol H2S,
4.0 mol H2, and 0.80 mol S2 in a 4.0
vessel. Calculate the equilibrium
constant, K, for this reaction.
A. 13
B. 10
C. 3.2
 D. 0.07
E. None of the choices
20. In which of these gas-phase
equilibria is the yield of products
increased the total pressure on the
reaction mixture?
A. CO(g)+H2O(g) = CO2(g)+H2(g)
B. 2NO(g)+Cl2(g) = 2NOCl(g)
C. 2SO3(g) = 2SO2(g) +O2(g)
D. PCl5(g) = PCl3(g) + Cl2(g)
E. None of the choices
21. For the following reaction
equilibrium, where will the shift
equilibrium be, if more NOBr (g)
added?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
D. None of the choices
22. For the following reaction
equilibrium, where will the shift
equilibrium be if some NO(g)
removed?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
D. None of the choices
23. Hydrogen peroxide (H2O2)
decomposes according to the
equation:
H2O2(l) →H2O(l) +½ O2(g)
Calculate the Kp for this reaction at
25°C.
𝚫H°=-98.2 kJ/mol, 𝚫S°=70.1 J/K.mol
A. 1.19 x 105
B. 7.09 x 1020
C. 6.47 x 1026
D. 2.75 x 107
E. None of the choices
24. The equilibrium constant at 427°C
for the reaction:
N2(g)+3H2(g) 2NH3(g) is K=9.4x105.
Calculate the value of 𝚫G° for the
reaction under these conditions.
A. +5.40 x 104 J/mol
B. - 5.40 x 104 J/mol
C. + 3.29 x 104 J/mol
D. - 3.29 x 104 J/mol
E. None of the choices
at
of 25. For the following reaction at
is equilibrium, where will the shift of
equilibrium be, if NOBr (g)
concentration is decreased?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
at D. None of the choices
of
is 26. For the following reaction at
equilibrium in the reaction vessel,
which one of these changes would
cause the Br2 concentration to
decrease?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Increase the temperature
B. Add some NO (g)
C. Add more NOBr (g)
D. Compress the gas mixture
into a smaller volume
E. None of the choices
27. Consider this reaction at equilibrium:
2SO2 (g)⇌O2 (g) +2SO3 (g)
𝚫H°rxn= -198 kJ/mol
If the volume of the system is
compressed at constant
 temperature, what change will occur
in the position of the equilibrium?
A. Shift to produce more
SO2(g)
B. Shift to produce more O2(g)
C. Shift to produce more SO3(g)
D. No change
E. None of the choices
28. At 1500°C the equilibrium constant
for the reaction:
CO(g)+2H2(g)→CH3OH(g) has the value
Kp=1.4x10-7. Calculate 𝚫G° for this
reaction at 1500°C.
A. -1.97 x 105 J/mol
B. +1.97 x 105 J/mol
C. -2.33 x 105 J/mol
D. +2.33 x 105 J/mol
29. The equilibrium constant for the
reaction:
Ni(s) + 4CO(g)→ Ni(CO)4 (g)
Is 5.0 x 104 at 25°C..
What is the equilibrium constant for
the reaction:
Ni(CO)4(g) ⇌ Ni(s)→ 4CO (g)
A. 5.0 x 104
B. 2.5 x 109
C. 1.3 x 10-6
D. 2.0 x 10-5
E. None of the choices
30. For the following reaction at
equilibrium, where will the shift of
equilibrium be if some Br2 (g) is
removed?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
31. Consider the following equilibria:
2SO3(g) ⇌2SO2(g) +O2(g)
K1= 2.3 x 10-7
2NO3(g) ⇌2NO2(g) +O2(g)
K2= 1.4 x 10-3
Calculate the equilibrium constant
for the reaction
2SO2(g)+2NO3(g)→ 2SO3(g) +2NO2(g)
A. 3.2 x 10-10
B. 6.1 x 103
C. 2.4 x 103
D. 4.5 x 10-7
E. None of the choices
32. For the following reaction at
equilibrium, where will the shift of
equilibrium be if Br2 (g) concentration
is decreased?
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol
A. Left
B. Right
C. No change
D. None of the choices
33. For the reaction equilibrium
2SO2(g) ⇌O2(g) +2SO3(g)
𝚫H°rxn=-198 kJ/mol
If we increase the reaction
temperature, the equilibrium will
A. Shift to the right
B. Shift to the left
C. No change will occur
D. The question cannot be
answered because the
equilibrium constant is not
given.
__________________________________
Long Test 2
1. The effect of a catalyst on a
chemical reaction is to
 Enable an alternate path for the
reaction that has a higher
activation barrier
Increase the energy of the
reactants
Increase the energy of the
products
Increase the frequency of
collisions between reactants
and products
Enable an alternate path for the
reaction that has a lower activation
barrier
2. All of the following statements for a
chemical system in a dynamic
equilibrium are false, EXCEPT
The concentration of reactants
and products remain constant
over time
The chemical reaction proceeds in
the forward direction until all
reactants are consumed
The reaction is endothermic
The reaction is exothermic
The concentration of reactants
and products must be equal
3. A large equilibrium constant
Indicates that a reaction has a
large rate constant
Indicates that a reaction has a
small rate constant
Indicates that the reaction
favors the formation of
reactants
Results from the addition of a
catalysts to a reaction mixture
4. What is the correct equilibrium
expression for the formation of
ammonia ga from nitrogen gas and
hydrogen gas?
K= (PNH3)2/ PN2 x(PH2)3
5. The value of the equilibrium constant
for the following reaction is 345.
“A+2B = 3C+D”. What is the value of
the equilibrium constant for the
reaction below? “2A+4B = 6C+2D
K = (2x345)2 = 4.76x10^5
K= (345)2= 1.19x10^5
K= 2x(345)2 = 2.38x10^5
K=345
k= (345)½ = 18.6
6. Use the equilibrium constants for the
following reactions
2NO(g) = N2(g)+O2(g) K1=2.4x10^13
2NO(g) +O2(g) = 2NO2(g) K2=2.4x10^12
To determine the equilibrium constant for
the reaction below:
N2(g) + 2O2(g) = 2NO2(g)
15.8x10^18
2.4x10^30
1.7x10^-43
1.0x10^-18
5.38x10^42
7. The reaction below was studied at a
high temperature. At equilibrium, the
partial pressures of the gases are as
follows: PCl5 = 1.4x10-4 atm, PCl3 =
2.4x10-2 atm, Cl2 = 3.0x10-1 atm.
What is the value of Kp for the
reaction?
PCl5 (g) = PCl3 (g) +Cl2(g)
4.3 x10-4
32
 51
0.019
2.3x10^3
8. All of the following may change the
ratio of products to reactants in an
equilibrium mixture for a chemical
reaction involving gaseous species
EXCEPT
Removing a gaseous product
Adding a gaseous reactant
Adding a solid reactant
Decreasing the volume
Increasing the pressure
9. Which of the following may change
the ratio of the products to reactants
in an equilibrium mixture for a
chemical reaction involving gaseous
species
Increasing the temperature
Adding a catalyst
Adding a gaseous reactants
10. The formation of ammonia from
elemental nitrogen and hydrogen is
an exothermic process
N2(g)+ 3H2(g) = 2NH3(g)
deltaH= -92.2 kJ/mol
Assuming the reaction is at
equilibrium, which one of the
following changes will drive the
reaction to the right?
Increasing the temperature
Adding a catalyst
Adding ammonia
Removing hydrogen
Increasing the pressure
11. Adding nitrogen gas to the
equilibrium system below will (refer
to previous number)
Have no effect
Cause the reaction to shift to the
left
Lower the standard enthalpy of
formation
Double the rate of reaction
Cause the reaction to shift to
the right
12. In which of the following equilibrium
systems would a decrease in volume
(at constant temperature) have no
effect on the reactants
H2(g) + Cl2(g) = 2HCl (g)
13. Which of the following changes will
increase the amount of oxygen
produced in the following equilibrium
system?
2HgO(s) = 2Hg(l)+O2(g)
deltaH = +181.6 kJ
Decreasing the volume of the
reaction vessel
Increasing the amount of
HgO(s)
Removing Hg(l)
Increasing the temperature of the
system
Increasing the pressure on the
system
14. If a chemical system at equilibrium is
disturbed by adding a gaseous
species (Reactants or products), the
reaction will proceed in such a
direction as to consume part of the
added species- is a statement
 Le Chatelier’s principle H <0 and S>0

15. The equilibrium constant for this 20. What is G at 75 degrees C for a
reaction is 5.3x10^8 at 298 K. What reaction with H= 241 kJ and S=48.2
is the equilibrium constant at 1500 J/K?
K? (R=8.31 J/mol.k)
-3370 kJ
1.1 x 10^84 +305 kJ
6.8 x 10^16 +237 kJ
9.1 x 10^31 -1650 kJ
9.4 x 10^18 +224 kJ
4.3 x 10^42
21. Ammonia is synthesized from
16. Predict the signs of S and H for the nitrogen and hydrogen gases at a
freezing of water into ice at 273 K temperature at 575 degrees C.
N2(g)+3H2(g) = 2NH3(g)
H< 0 and S< 0
H< 0 and S >0 H=-92.2 kJ and S=-0.1987 kJ/K
H >0 and S = 0
H = 0 and S >0 What is G for the reaction at 575 C?
H >0 and S< 0
-260.7 kJ
-92.0 kJ
17. All of the following events result in -186.6 kJ
an increase in entropy, EXCEPT +2.20 kJ
+76.3 kJ
The melting of candle wax

The formation of N2O4(g) from 22. The value of the equilibrium constant
NO2(g) for a particular reaction is 6.32x10^6
at 298 K. Calculate G for this
The dissolution of sodium chloride reaction (R.8.31x10-3 kj/K)
in water
2.48 10^3 kJ
The evaporation of ethanol 2550 kJ
-7.84 kJ
The combustion of carbon -38.8 kJ
128 kJ
18. Which of the following reactions is
likely to have the most positive 23. If G > 0, then
charge in entropy? K >1
C(s) + O2(g)= 2CO(g) K<1
K> 0
K <0
19. If G is negative at all temperatures, K=0
then which of the following 24. What is the correct equilibrium
statements must be true? constant expression for the following
 reaction
CO2(g)+ 2H2O(g) = CH4(g)+2O2(g
K= PCH4x(PO2)2/
PCO2x(PH2O)2
25. Write the balance chemical reaction
which corresponds to the following
equilibrium constant expression?
K= (PN2O5)2 / PO2 x (PNO2)4
The reaction will proceed in the
direction of forming more NOBr
until equilibrium is reached
The reaction will proceed in the
direction of forming more NO
and Br2 until equilibrium is
reached
The reaction is at equilibrium

29. For the reaction

26. For the equilibrium reaction
2SO2(g) + O2(g) = 2SO3(g). Which
one of these factors would cause the
equilibrium constant to increase
Add a catalyst
Add SO2 (g)
PCl3(g) + Cl2(g) = PCl5 (g). At a
particular temperature Kc= 3.42.
Suppose a system at that
temperature is prepared with [PCl3]=
0.400 atm, [Cl2] = 0.350 atm, [PCl5]
= 0.500 atm. Which of these
statements is TRUE?

Decrease the temperature The reaction will proceed in the

direction of forming more PCl5
Remove O2 (g) until equilibrium is reached.

The reaction is at equilibrium

27. For the following reaction at
equilibrium, which one of the The reaction will proceed in the
changes below would cause the direction of forming more PCl3
equilibrium to shift to the RIGHT? and Cl2 until equilibrium is
reached.
2NOBr (g) ⇌ 2NO (g) + Br2 (g)
𝚫H°rxn= 30 kJ/mol

Increase the temperature

Add some NO (g)
Add more Br2 (g)
Remove some NOBr (g)
Decrease the container volume

28. For the reaction

2NOBr(g) = 2NO(g) +Br2(g)
H= 30 kJ/mol. At particular temp
Kc=25.6. Suppose a system at that
temperature is prepared with [NOBr]
=1.40 atm [NO]=1.35 atm and [BR2]
= 1.50 atm. Which of these
statements is TRUE?