Download as pdf or txt
Download as pdf or txt
You are on page 1of 17

INTERNATIONAL JOURNAL OF ENERGY RESEARCH

Int. J. Energy Res. (2017)


Published online in Wiley Online Library (wileyonlinelibrary.com). DOI: 10.1002/er.3770

Investigation of heat transfer during melting of a PCM


by a U-shaped heat source
Mohammad Bashar and Kamran Siddiqui*,†
Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario, Canada

SUMMARY
An experimental study was conducted to investigate the melting process of a phase change material (PCM) and the
associated convection heat transfer due to a U-shaped heat source embedded in the PCM. The experiments were conducted
at four input heat fluxes that varied from 3450 to 5840 W/m2. The results showed that the heat transfer behavior, interface
movement, and the heat transfer coefficients differed both axially and vertically inside the chamber. The local convective
heat transfer coefficient in the inner region, enclosed by the U-tube, was found to be about 35% higher than that in the outer
region over the input heat flux range, resulting in faster melting in the inner region than in the outer region. As melted
domain grew vertically from 15% to 100%, it was observed that the overall h in the inner region increased by 40–55% from
the lowest to highest heat flux. The melting rate was also found comparatively high up until 65–70% of the total PCM
volume melted because of the higher contribution from the inner region. It was also observed that the Rayleigh number
increased by approximately 23% in the inner region and 18% in the whole domain as the heat flux increased from 3450
to 5840 W/m2. A new Nusselt–Rayleigh number correlation is proposed for the heat transfer during the melting process
due to a U-shaped heat source. Copyright © 2017 John Wiley & Sons, Ltd.
KEY WORDS
PCM; U-shaped tube; latent heat; thermal energy storage; heat transfer coefficient; interface; melt fraction

Correspondence
*Kamran Siddiqui, Department of Mechanical and Materials Engineering, University of Western Ontario, 1151 Richmond Street,
London, ON, N6A 5B9, Canada.

E-mail: ksiddiqui@eng.uwo.ca

Received 9 December 2016; Revised 13 April 2017; Accepted 14 April 2017

1. INTRODUCTION the thermal energy is stored by simply increasing the


temperature of the storage media, although the mass and
Thermal energy storage (TES) is a means to store thermal material property of the media play important roles. On
energy for a certain period of time for its intended later the other hand, latent heat storage is based on the
use [1]. In general, TES systems improve the energy capture/release of energy when a material undergoes a
efficiency by reusing waste heat as well as by reducing phase change, typically between solid and liquid phases.
the mismatch between supply and demand [2]. It is a Latent heat thermal energy storage (LHTES) is particularly
crucial component in energy systems utilizing intermittent attractive because of its two important features: Firstly, it
renewable energy resources such as solar energy that can can provide a high-energy storage density (amount of heat
also fluctuate unpredictably [3]. TES also improves the per unit mass), and secondly, it has the capacity to store
performance and reliability of an energy system by energy at nearly a constant temperature or over a small
plummeting peak operating loads and helps the system to range of temperature variations around the phase transition
work within an optimal range [4]. Hence, TES has enormous temperature [9,10].
potential to perform numerous roles in conserving energy, The LHTES is a potential and proven solution to
which in turn helps to attain energy sustainability [5–7]. realistically and effectively offset the unreliability issues
For thermal energy in a TES to be stored, a physical associated with renewable energy resources [2,11–15]
media is needed that would hold the heat. Heat can be and has also been used in a diverse range of industrial
stored in two ways, either by using a physical method or applications, such as metal processing, food preservation,
by applying thermo-chemical energy method. Through solidification of castings, building systems, and electronics
the use of physical techniques, heat can be stored in cooling [8,16–22]. TES has also been used as an integrated
sensible or latent heat form [8]. In sensible heat storage, component in solar thermal systems [23,24]. However, for

Copyright © 2017 John Wiley & Sons, Ltd.


Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

its effective use as a potential heat storage media, desirable melting inside a rectangular enclosure through a heated
thermodynamic, kinetic, and chemical properties of these sidewall, Hale and Viskanta [32] reported the significant
phase change materials (PCMs) must first be carefully effects of convection on the melting pattern, nature of
assessed [25]. Some of the key parameters that need to the solid–liquid interface, and heat transfer coefficients.
be considered when selecting a PCM are latent heat, In a similar study, Ho and Viskanta [33] experimentally
melting point, and heat source/sink temperatures. As the and numerically investigated the melting of wax inside a
latent heat is the primary mode for heat storage, higher similar chamber. They reported that except for the initial
latent heat of a PCM is highly desirable. This further stages of heat conduction period, natural convection
implies that for the effective utilization of the LHTES, it significantly affected the melting and was the dominant
should operate within a narrow temperature band about mechanism and controlled the melting rate and the
its melting point. Larger difference between the PCM solid–liquid interface profile. Gadgil and Gobin [34]
melting point and source/sink temperatures results in a argued that, in such case, once the PCM started melting,
higher fraction of heat storage in the form of sensible heat, the effects of conduction may be ignored in further heat
which undermines the underlying benefit of LHTES. In transfer analysis. Yuksel et al. [35] developed a
addition, longevity, economic, and the environment effects theoretical model to predict the time and temperature
of PCMs must also be taken into considerations [3,26]. during the charging and discharging of a PCM TES. They
The design of the heat source that carries the heat argued that the entry and average properties related to the
transfer fluid (HTF) is one of the key factors that dictates system can be implemented in the analysis. They also
the overall heat transfer rate and performance of the observed the influence of internal conduction resistance
storage system. During heat addition/extraction to/from during the melting of solid and that of natural convection
the PCM, the heat transfer occurs in both solid and liquid in the liquid state.
domains of the PCM. Because the fraction of each phase Recently, Bondareva and Sheremet [36] numerically
continuously changes (one increasing, while other simulated the melting process inside a square cavity heated
decreasing) the local heat transfer within the PCM domain from the bottom wall. They found that an increase in
is transient in nature. However, the correlation between the Rayleigh number has a profound effect on the flow
average heat transfer and the melting rate has not been well behavior as well as heat transfer. They observed the
established [27]. Conduction is the heat transfer mode in formation of two thermal plumes, which behaves
the solid phase, while natural convection governs the heat asymmetrically as the buoyancy forces dominate over
transfer in the liquid phase. The rate of heat transfer is inertial forces. The authors extended this work by
typically higher in the liquid domain than in the solid simulating the melting process in a cube subjected to
domain because of the presence of convective motion bottom wall heating [37]. They found that the velocity
induced by buoyancy, which accelerates the transportation and temperature fields in the middle of the cavity were
of heat. As the buoyancy acts vertically (aligned with similar to the two-dimensional case. At moderate Rayleigh
gravity), the orientation of the heat source/sink plays a numbers, they observed single thermal plume, while two
crucial role in the generation of buoyancy-induced flow thermal plumes were observed at high Rayleigh numbers.
and its magnitude and extent. This, in turn, directly In a separate study, the authors also observed that an
influences the heat transfer within the PCM domain. Hence, inclined magnetic field in the cavity influences both flow
an improved understanding of the natural convection and temperature patterns [38].
process within the liquid domain with respect to the heat In an experimental investigation during melting and
source/sink orientation is vital to design efficient TES. solidification processes of pure gallium inside a rectangular
Gau and Viskanta [28] reported the presence of chamber heated from a sidewall, Gau and Viskanta [28]
convective flow patterns through the visualization of the correlated the changing volume of the melt with the heat
melting process of paraffin wax in a rectangular enclosure transfer rate through some relevant dimensionless
heated from below. Diaz and Viskanta [29] observed that parameters, like the Nussult number (Nu) and the Rayleigh
multiple Benard-like cells are formed during initial stages number (Ra). In another numerical study for melting of tin
of the melting of n-octadecane through a bottom heat in a 2-D rectangular enclosure heated through a sidewall,
source, which grew and merged into a single cell with Christiano and Luiz [17] observed that the total melting
time. The growth of buoyancy-driven instabilities that time reduced with an increase in the Rayleigh number
control the convection heat transfer, along with the upward (Ra) and argued that this increase (of Rayleigh number)
movement of the solid–liquid interface, increases the is the consequence of the enhancement in the natural
complexity of the problem [30]. However, Hsu et al. [31] convection.
argued that the timescale of interface movement is much There is a wide variation in PCM-based TES systems
lower than that of the convective motion and, hence, its from the design point of view. These include but not
influence on the convective flow can be ignored. limited to various shapes like flat plate, annular cylindrical
There are limited studies investigating the heat transfer or square tubes, micro/macroencapsulations with different
during phase change, and most of them considered a shapes of the containers, and slurries containing PCM as
sidewall as the heat source. In one of the pioneering well. Furthermore, these storage systems may have
experimental investigations on the PCM (n-octadecane) different arrangements of the heat sources based on

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

practical applications. In addition, the heat source section of 150 mm × 125 mm were used, respectively.
configuration could be a combination of different Both the front side and backside of the U-shaped acrylic
geometric arrangements that further complicates the plate were separated from the front glass pane wall and
problem. the back acrylic wall, respectively, by two pieces of 2-
A major challenge in designing a PCM-based thermal mm-thick rubber gaskets, cut into the same size and
storage is the effective heat transfer to and from the PCM contour of the U-shaped acrylic plate as shown in
medium during the phase change, which greatly influences Figure 2. The rubber gaskets, which were placed all along
system efficiency [3]. This heat transfer mechanism is the contact area between the main chamber and both the
directly affected by the geometric configuration of the heat front and back walls, were helpful in preventing the fluid
source/sink because of buoyancy. The complexity further leakage and minimizing the heat loss from the chamber
arises because of the simultaneous changes in liquid and to the surroundings.
solid fractions. The geometric configuration of the heat A U-shaped tube made of thin-wall smooth copper tube
source/sink in thermal storage system is likely to be more (Copper Alloy 122, wall thickness 0.355 mm, outer
complicated than that of the simple heat source diameter 4.76 mm) was used as the heat source for the
configurations of sidewall or bottom wall reported in the storage chamber. This copper tube, hereinafter, is referred
literature. Hence, there is a need to extend this research to as the HTF tube, because the heat source was a high-
to consider more complicated configurations of the heat temperature fluid passing through this tube. The tube was
source/sink that are of practical interest and to conduct a inserted in the chamber from the open top end and was
thorough investigation of the phase transformation patterns positioned vertically (Figure 2). A clearance of
and the associated heat transfer. approximately 3.5 mm between the tube and the front
In real-world thermal storage systems, one practical and back walls were kept throughout the experiments.
way to charge and discharge the heat is via an HTF that The distance between the two legs (left and right side)
runs through piping embedded into the storage medium of the U-shaped HTF tube was approximately 50 mm
(i.e., PCM). To the best of our knowledge, there is scarcity over its vertical length. The outer edge of each leg was
of studies investigating the phase change behavior and approximately 22 mm away from the corresponding
associated heat transfer in such configurations. The present sidewall of the chamber (Figure 2b). The maximum
study used a piping configuration embedded into the PCM immersion depth of the tube inside PCM was
that is very practical for real applications, that is, a U- approximately 95 mm. The total linear length of the tube
shaped heat source. No study has been reported in the in contact with the PCM inside the chamber was
literature that investigated the heat transfer and phase approximately 250 mm. All sides of the chamber except
change process in this or similar geometry. Another the front glass wall and the open top end were insulated
importance of this heat source configuration is that it (FC-2300-LD, Fibre Cast Inc., Burlington, Ontario,
combines different heat source orientations and their Canada) to avoid heat losses to surroundings. The storage
influence on the melting process. The present study chamber was vertically attached to a metal frame using bolt
comprises experimental investigation to improve and nuts. The upper part of the chamber was left open to
understanding of the underlying processes during solid– room atmosphere to accommodate thermal expansion of
liquid phase transition due to a U-shaped heat source. the PCM during melting. The open space at the ceiling of
The specific focus is on the investigation of the transient the chamber helped minimize the pressure buildup due to
solid–liquid interface movement and the associated the volumetric expansion of the PCM upon melting [39].
convection heat transfer in the melted region. The heat transferred through the open top prevented the
heat buildup in the chamber and hence simulated the
condition of a continuous heat transfer in a real thermal
2. EXPERIMENTAL SETUP storage as the heat continued to transfer from the heat
source towards the boundaries of the storage domain.
2.1. Thermal energy storage chamber
2.2. Thermal energy storage media
Experiments were conducted in a thin rectangular chamber
that served as the PCM storage. A schematic and A mixture of fine paraffin wax and copolymer alloys in
photograph of the experimental setup are shown in the form of milk-white pellets, commercially available
Figure 1(a) and (b), respectively. The PCM chamber has as ‘Polyfin’, was used as the PCM in this study. Various
the inside dimensions of 100 mm horizontally (L), thermo-physical properties of the PCM as per published
100 mm vertically (H), and a depth of 12 mm (W). An literature are listed in Table I. One of the key features
optically clear cast acrylic plate (8 mm thick) cut into of ‘Polyfin’ for its suitability for the present research is
a U-shaped structure formed the shape of the cavity that it becomes transparent once melted, which was a
(Figure 2a). All three sides of this U-shaped plate were very useful and crucial feature for accurately imaging
25 mm wide. To form the front and back walls of the the melting process and tracking the solid–liquid
chamber, one 5-mm-thick plain clear glass pane and an interface. In addition, it is safe to handle and its melting
acrylic sheet of the same thickness with the same cross temperature is in the safe range of operation in the lab

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

environment. It is to be noted that paraffin wax has been 2.3. Heat source
widely used in experimental research studies on PCMs
[29,32,40–42]. Very small amount of silver-coated As mentioned earlier, a U-shaped HTF tube acted as the
hollow glass sphere having an average diameter of 9- heat source in this study. The HTF (hot air) continuously
13 μm was used along with the PCM as the tracer passed through the tube at a controlled flow rate and
particles to investigate the behavior of the molten liquid temperature. In order for the pressure fluctuations in the
flow through imaging. The volume change of the wax in HTF to be minimized, the incoming compressed air from
the liquid stage was estimated to be approximately 10% the laboratory supply line was initially passed through a
from the solid state. settling tank to dampen pressure fluctuations. Downstream

Figure 1. (a) Schematic diagram of the experimental setup. (b) Photograph of the experimental setup. The U-tube heat source is shown
inside the phase change material (PCM) chamber. DAQ, data acquisition. [Colour figure can be viewed at wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

of the air settling tank, a pressure regulator was employed (Zesta ZEL-9100) to precisely control the temperature of
to control the pressure of the air in the system. The air was the HTF fluid. The accuracy of the PID controller was
then passed through a flowmeter to control its flow rate within ±2°C. The air flow rate was maintained at
before passing through the heater (Figure 1). The 40 L/min. The accuracy of the flow meter was estimated
controlled air was then heated while passing through an as ±5%. Four different controlled temperatures of the
air heater (Zesta ZA0017) equipped with a PID controller HTF were used as inlet temperatures (150°C, 175°C,

Figure 2. Schematic of the phase change material (PCM) chamber. (a) Isometric view. (b) Schematic diagram. Locations of the
thermocouples are marked with black open circles. HTF, heat transfer fluid. [Colour figure can be viewed at wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

Table I. Thermo-physical properties of phase change material at 25°C (VWR CA 27900268) [43,44].

Thermal conductivity
Melting point Specific Specific heat Kinematic viscosity Latent heat of fusion Thermal diffusivity
o (W/m/K) 2 2
( C) gravity (kJ/kg/K) (m /s) (kJ/kg) (m /s)
6 8
55 0.92 2.890 Solid Liquid 5.50 × 10 180 7.985 × 10
~0.24 ~0.18

200°C, and 225°C) by adjusting the heater controller, (Kessler 10/30 ST Jointed Thermometer) was used as the
which provided four different input heat fluxes of 3450, reference. The calibration was conducted over a
4370, 5020, and 5840 W/m2, respectively. temperature range from 90°C to 0°C with increments of
about 10°C between each reading. All calibration curves
2.4. Temperature data showed almost linear relationship. The uncertainty of
temperature measurements from TCs was estimated as
A total of 28 T-type thermocouples (T30-2-507; Zesta ±0.4%.
Engineering Ltd., Toronto, Ontario, Canada), hereinafter
referred to as TC, were used to measure the temperatures 2.6. Phase change material chamber
at various locations in the experimental setup, shown in insulation
Figure 2(b) as small black open circles. Out of these 28
TCs, two TCs were placed in direct contact with the air flow As mentioned earlier, the front wall was made of a clear
to measure its (HTF) temperatures at the inlet and outlet of glass pane. This was required for this study because the
the PCM chamber. The temperature on the surface of the clear glass pane allowed optical access to image the
HTF tube inside the chamber was measured at 11 different melting process inside the chamber by a high-resolution
locations along the tube length. Out of these 11 TCs, 10 camera. This was the only uninsulated wall of the chamber,
TCs were affixed on the surface of the two vertical legs (five and hence, some heat loss occurred through this glass pane.
TCs on each leg)) with an equal spacing of about 20 mm Therefore, it was necessary to ensure that this heat loss
between them, and the other TC was fixed in the middle from the front wall did not influence the melting behavior
of the curved part of the U-shaped tube (Figure 2b). All inside the chamber. For this purpose, another set of
these 11 TCs were affixed at the backside of the tube to experiments was conducted under the same conditions, in
avoid any imaging obstructions. For measuring the which the front glass pane was also covered with the same
temperature inside the PCM domain, 15 TCs were arranged insulation. Note that only temperature measurements were
in an array format (five rows and three columns), with one carried out in this set of experiments because of no optical
column each on the left, right, and middle of the U-tube access. The temperature data obtained from this set of
(Figure 2). The left and right columns were located 14 mm experiments were compared with the temperature data
from their respective sidewalls. The center TCs’ column from the corresponding cases with the uninsulated front
was located along the vertical centerline of the chamber glass pane. The results show that the PCM temperature
and tube, at a distance of 50 mm from each sidewall. The within the domain at each heat flux case was slightly
vertical distance between each TC row was also kept at higher for fully insulated chamber than for the uninsulated
20 mm, and they were at the same vertical height as that front glass pane, as expected. The difference in the mean
of the tube surface TCs (Figure 2b). The bottom TCs’ temperatures for the two chamber configurations was on
row was located approximately 5 mm above the curved average 7.5%. Because the melting process was transient
surface of the HTF tube near the bottom of the chamber. in nature, to further confirm that the melting behavior
All TCs in the PCM domain were inserted individually into was similar, we also compared over the entire melting
the chamber through the insulated acrylic back wall. period for both insulated and uninsulated cases, the
The temperature data from all 28 TCs were recorded temperature profiles at different locations within the PCM
simultaneously at a rate of 3 Hz via data acquisition cards domain. The results show that the temperature profiles
(TC modules: NI-9214 and NI-9211) controlled by the for both insulated and uninsulated cases were very similar,
LABVIEW software. For accuracy and similarity to be hence confirming that the uninsulated pane had no
ensured, the temperature data recording for all considerable influence on the transient melting behavior.
experimental cases was started 1 min prior to the beginning
of the heating process and continued 5 min after the PCM 2.7. Image acquisition and image
was completely melted. processing

2.5. Calibration of thermocouples A 4-megapixel high-resolution charged-coupled device


camera (Flare 4M180-CL) with a resolution of
Calibration of all TCs was accomplished by using an 2048 × 2048 pixels was used to capture the images of the
insulated hot water bath. A high-accuracy thermometer phase change process and to track the solid–liquid

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

interface and the flow behavior of the melted PCM. The location, the local heat transfer coefficient was computed
camera was connected to an image acquisition system using the equation
(DVR express core; IO Industries, London, Ontario, Canada)
00
to record images. The camera was controlled via the DVR q ¼ h ðT s  T bulk Þ (2)
express CoreView software installed on a PC. The field of
00
view of the camera was set at 94 mm × 94 mm. Two 13-W where q is the heat flux assumed to be equal to the average
LED lights were used to enhance the image quality. The heat flux through the HTF tube, Ts is the local surface
lights were placed more than 50 cm away from the front temperature of the HTF tube, and Tbulk is the local bulk
wall of the chamber. Considering the power, distance, temperature of the melted PCM. Note that the tube surface
and nature of light emitted by an LED, the radiation effects temperature and bulk liquid temperature were computed as
on the PCM chamber wall were assumed to be negligible. the average from all corresponding TCs that were
For each run, images were captured from the beginning of immersed in the liquid PCM in each zone.
the melting process until the PCM was completely melted.
The camera frame rate was set at 40 frames per second 2.9. Interface detection
(40 Hz) for different experimental runs. The stored images
were transferred from the DVR core to an external Tracking the solid–liquid interface and detecting its form
storage media in suitable format for further processing. as the melting progressed provided an in-depth insight
for the better understanding of the underlying process.
2.8. Experimental data analysis Using an in-house algorithm in a Matlab platform, the
solid–liquid interface was detected in each image over
The heat gain by the PCM was considered equal to the heat the whole melting process. The algorithm initially
loss by the HTF passing through the PCM domain inside preprocessed raw images to increase their signal-to-noise
the chamber and was calculated from the following ratio by rescaling the gray-scale values between solid and
equation [12]: liquid phases (upper end gray-scale values correspond to
the solid PCM, and lower end gray-scale values
q_ total ¼ mc
_ p ðT in  T exit Þ (1) correspond to the liquid PCM) for accurate identification
of each phase and its transformation into a binary format
where q_ total is the heat transfer rate, m_ is the mass flow rate for the precise detection of the interface. A series of
of air, cp is the specific heat of air, and Tin and Texit are the morphological operations were performed to remove any
inlet and exit temperatures of the air (HTF). Because the noise from the data. The coordinates of the detected
TCs to measure inlet and outlet temperatures were located interface in the binary image were recorded at every spatial
approximately 1 cm off from the physical entrance and exit location, which when processed generated the actual
of the PCM domain, the heat loss from the HTF tube profile and position of the solid–liquid interface at a given
between Tin and Texit TC locations and the chamber inlet time. Because of the physical presence of various TCs in
and outlet locations, respectively, were calculated. The the PCM domain, the interface profile in the close
net heat transferred to the PCM (q_ net ) was then calculated
by subtracting the inlet/outlet heat loss, from the total heat
00
lost by the HTF. The net heat flux (qnet ) into the PCM
domain was computed by dividing ( q_ net ) by the surface
area of the HTF tube inside the domain. The uncertainty
in estimating the heat flux was on average within
approximately ±10%.
As the liquid fraction continued to increase with the
progression of melting, the local heat transfer coefficients
were computed when the melted fraction reached up to a
particular TC. Because of the nature and pattern of melting
in a U-shaped tube configuration (heat source), the local
heat transfer coefficient (h) was measured based on the
change in the vertical extent of the melted PCM in the
vicinity of the heat source. It is the same approach used
for natural convection heat transfer from vertical tubes
[40]. Hence, the local heat transfer coefficient values were Figure 3. A snap shot showing the real image of the chamber
obtained in each zone with the change in the height of the during phase change material melting for one experimental run
melted PCM. The vertical locations of TCs were 2
(heat flux of 4370 W/m ). The interface is marked as the red line.
considered as the reference lengths; that is, the local heat The dark-gray area represents the melted phase change
transfer coefficient in each zone was computed when the material, and the white area represents the solid phase
melted PCM domain reached subsequent TC within a (excluding the tube legs). [Colour figure can be viewed at
given column in the respective zone. At a given vertical wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

proximity of a TC was locally influenced. Hence, in the influence of the geometry of the heat source. The
subsequent analyses, the interface data in the locality of temperature data acquired throughout the storage chamber,
each TC were excluded. The uncertainty in detecting the along with the simultaneous imaging, provided detailed
interface was within ±2 pixels, which correspond to information about the thermo-fluidic behavior during the
±90 μm. Figure 3 shows an instantaneous image of the solid–liquid phase change process.
PCM domain. The detected solid–liquid interface in the
corresponding image is also plotted with a red line. 3.1. Instantaneous temperature fields and
melting behavior

3. RESULTS It was mentioned earlier in the experimental setup section


that the temperature was measured at 26 locations inside
The objective of this study was to study the heat transfer the chamber (11 locations on the surface of the tube and
phenomena during the phase change process and the 15 locations inside the PCM domain) to characterize the

Figure 4. (Left) Colormaps of the temperature field in the phase change material (PCM) chamber at different stages of melting. Center
area marked by black lines in U-shape profile indicates the location of the heat transfer fluid tube. (Right) corresponding image of the
PCM domain. Dark-gray region corresponds to the liquid PCM, and white region corresponds to the solid PCM (excluding the U-tube).
[Colour figure can be viewed at wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

thermal behavior of the PCM during the melting phase. As the heat transfer to PCM continued and once the
The variation of the temperature field inside the chamber melting temperature of the PCM was reached, the solid
at different stages of melting is illustrated in Figure 4 (left phase of the PCM started to melt. The U-tube surface in
side) along with the corresponding images showing the contact with the PCM naturally was at the highest
melting trends through the front glass panel (right side). temperature near the top left corner of the chamber where
Figure 4(a) shows the data soon after the beginning of the HTF entered the PCM domain. Because the HTF was
the heating process. At this stage, heat transfer is in the continuously losing heat to the PCM, the temperature of
early phase via conduction through the PCM. The heat lost the HTF decreased along the tube, which caused an
by the HTF is evident through a gradual decrease in the increase in the PCM domain temperature as well as a
tube surface temperature. The bulk PCM temperature at decrease in the tube surface temperature. Because of the
this stage is not significantly influenced by the heat transfer higher HTF and hence the tube surface temperatures, the
and the PCM domain remains in the solid phase (see the melting process initiated near the top left corner of the
corresponding image on the right). chamber (Figure 4b). As the time passed, the melted zone

Figure 4. (continued)

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

started to expand downward and horizontally. Thus, the zone started to develop just above the U-bend of the HTF
pool of melted PCM acquired the shape of an inverse cone tube in the lower mid region of the chamber and the overall
and continued to grow. temperature of the melted PCM continued to rise. The
Following the formation of the melted zone in the formation of this third zone above the tube bend was due
entrance region of the HTF, another smaller melted region to the higher contribution of buoyancy. The heat source
having a similar conical shape quickly developed around in this region was near horizontal, where the buoyancy
the HTF tube where the HTF exited the PCM domain near forces supported the transport of heat to the PCM above
the top right of the chamber (Figure 4c). This is an the tube; that is, the buoyancy forces aligned with the
unexpected trend because as the HTF loses its temperature direction of the solid–liquid interfacial front. As the
along the tube, one expects the melting front to progress melting process further continued, all three melted zones
along the same path. A plausible explanation for the continued to grow (Figure 4(d)) and eventually merged
observed trend is described as follows. As mentioned (Figure 4e). A blob of solid PCM remained in the middle
earlier, the melted zone formed in the HTF entrance zone of the U-tube, which eventually melted. The results also
started to expand horizontally and vertically, indicating indicate that the temperature gradients are stronger in the
the movement of the solid–liquid heated interfacial front. melted PCM than in the solid PCM. It is observed from
The heat transfer through this interfacial front was higher the image sequence in Figure 4 that the melting was more
because the convection heat transfer that is induced in the rapid in the PCM enclosed by the U-tube (inner zone) that
liquid PCM enhances the rate of heat transfer relative to in the region surrounding the U-tube (outer zone). Once
the conduction. Thus, the heat more rapidly transferred the PCM in the inner zone was fully melted, the melting
horizontally from the left leg of the tube at the upper end rate increased in the outer zone. The image sequence also
of the PCM towards the right leg as well as the left showed that the solid–liquid interface was nonlinear in all
sidewall. But because the heat was also being transferred three zones and its nature continued to change with the
from the right leg near the upper end, the PCM temperature growth of these zones. The interface acquired a relatively
in the vicinity of the right leg reached the melting point linear form once the PCM was fully melted in the inner
faster than the other regions of the PCM. Another zone.
interesting behavior observed at this stage was the change It is also observed that the melted zone did not extend
in the trend of the tube surface temperature, which much beneath the U-tube bend. This is likely due to the
corresponds to the similar changes in the HTF temperature reason that the heat transfer from the tube was dominated
inside the tube. As Figure 4(a) shows, the tube surface by buoyancy-driven convective motions, which were
temperature decreased gradually from the inlet to the outlet present above the tube bend. Hence, the heat transfer to
before the commencement of melting. However, once the the PCM was primarily above the bend. This further
melting began and the heat started to propagate more indicates that in a real PCM-based thermal storage, the heat
rapidly in the horizontal direction, the surface temperature source should be designed in a way that the supply heat
of the right leg near the outlet became higher than that of should also reach closer to the bottom end of the storage,
the tube on the immediate upstream side almost up to the which otherwise will not be able to effectively store heat.
tube bend at the bottom of the chamber. A plausible One option to achieve this is by adding extended surfaces
explanation for this trend is described in the succeeding or fins to the HTF tube that penetrate into the bottom layer
texts. When the PCM is melted, because of the buoyancy and induce convective motion.
effect and convective motion the warmer liquid PCM
started to rise and accumulated near the top. Furthermore,
the liquid PCM also acted as a bridge to directly transfer
heat from the left leg to the right leg, horizontally. As a
result, the temperature difference between the tube surface
and the liquid PCM is lower near the top exit than near the
bottom. Hence, the heat transfer rate near the bottom is
higher than that near the top exit. Inside the tube, the hot
air transferred heat to the tube wall. While the air
temperature decreased because of the heat loss, but
considering the smaller geometry of the setup, this
temperature drop is not very large particularly in the
section between the bottom and the exit. Hence, the
temperature difference between the air and the tube wall
near the top exit is smaller than that near the bottom. This
resulted in a slightly higher tube wall temperature near the
exit. Such trend is not likely to occur in a large setup.
As the melting further progressed with time, the melted Figure 5. Instantaneous melted fraction versus time for four
fraction continued to grow in the upper region of the PCM input heat fluxes. [Colour figure can be viewed at
chamber surrounding the two tube legs and a new melted wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

3.2. Melting rate and melt fraction of phase and right legs of the tube. The purpose was to investigate
change material the melting behavior and the associated heat transfer due
to the vertical legs of the heat source. The bottom melting
Using an in-house algorithm, we analyzed the images near the U-tube bend was not considered because the
recorded during the melting process to compute the melted interface detection and analysis would have become very
fraction (mf) in each image, which is the ratio of the melted complex. The interface was tracked up until the bottom
PCM volume to the total PCM volume in the chamber. The melting zone merges with the top melting zones. Tracking
change in the total melted fraction with time that expresses of the interface in each image allowed to analyze the
the instantaneous melting rate is plotted in Figure 5 for all transient behavior of the interface dynamics. Figure 6
four heat flux cases. As expected, the melting rate of the shows the time history of the detected interface at the heat
PCM was highest for the largest heat flux, which decreased flux of 4370 W/m2 as an example.
monotonically with a decrease in the heat flux. From the From the profile dynamics, it is clearly evident that the
graphs, it is observed that at the initial stages for a small interface movement was nonlinear in both space and time.
period of time, there was no melting at any heat flux. This The interface moved more rapidly near the heat sources as
time duration corresponds to the period during which PCM expected. The results also show that the interface
in the vicinity of the tube reached its melting temperature movement was not symmetric about a given heat source
after the HTF fluid started passing through the PCM (left or right leg); that is, the interface movement was
domain. relatively faster on the heat source facing the inner region.
From Figure 5, it is also observed that the melting rate Similarly, the interface movement was relatively faster at
was comparatively higher up until approximately 65– the left heat source, which was the heat inlet, as expected.
70% of the total PCM volume was melted and, after that, Because the HTF has to enter from one leg and exit from
the melting rate decreased. A plausible explanation for this other, this behavior is the practical reality because of
trend is described later. As seen earlier in Figure 4, the geometry of the heat source. Hence, for a better
PCM in the inner region melted first and at a higher rate characterization of this behavior, the PCM chamber was
because of the presence of two heat sources (i.e., left and divided into four separate imaginary zones as shown in
right legs of the tube). Thus, the higher melting rate Figure 7, which are denoted as zones A, B, C, and D. It
observed in Figure 5 corresponds to the melting of the is to be noted that the boundary line between zone B and
PCM in the inner region and the slower rate corresponds zone C was commonly shared by the column of five TCs
to the melting of the PCM in the outer region. vertically arranged along the centerline of the chamber
(Figure 2). Hence, the same set of temperature data
3.3. Interface profile obtained from these five TCs was used for both zone B
and zone C to calculate each zone’s parameters. Various
As shown in Figure 3, the solid–liquid interface was
thermo-physical parameters were calculated by
detected using an in-house algorithm. The algorithm was
used to detect the interface developed in the upper region
of the chamber because of the melting caused by the left

Figure 6. Time history of the solid–liquid interface position Figure 7. Schematic of the phase change material chamber
(shown at partial melting phase). The time interval between showing four separate imaginary zones marked as A, B, C, and
each interface line is 66.67 s. PCM, phase change material. D by dashed lines. [Colour figure can be viewed at
[Colour figure can be viewed at wileyonlinelibrary.com] wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

determining the local parameters first, and then the average instances when the liquid fraction reached consecutive
values were taken into account to find the global TCs embedded in the PCM domain. Furthermore, similar
parameters. to the interface detection, the local values of h were
computed up until the bottom melting zone merges with
3.4. Local convective heat transfer the top melting zones. A final value of h was calculated
coefficient (h) when the inner region was fully melted. It is to be noted
that in the moment when the central region bounded by
The convective heat transfer coefficient (h) in the liquid the inner area of the U-tube (zones B and C) was
(melted) PCM was calculated using Newton’s law of completely melted, some parts at the lower regions in
cooling [12]: zones A and D were still not melted completely. Thus, to
00   keep similarity in computations, data from only three upper
q ¼ h T Surf  T Bulk (3) TCs were considered for local h calculations.
The values of the local convective heat transfer
00
where q is the heat flux, TSurf is the average surface coefficients (h) were calculated in a transient manner as
temperature of the HTF tube that is adjacent to the liquid the melted PCM expanded for all heat flux cases.
PCM, and TBulk is the average temperature of the liquid Figure 8(a) and (b) shows the values of h for the lowest
PCM. As the liquid domain of the PCM expanded with and highest heat flux cases (3450 and 5840 W/m2),
time, the local heat transfer coefficients associated with respectively. In the plots, y is measured from the top of
the top melting zones, that is, formed by the left and right the chamber and H is the height of the chamber. Hence,
vertical heat sources (zones A, B, C, and D), at different y/H = 0 corresponds to the top of the PCM chamber. The
instances were computed using the aforementioned results show a general trend that the heat transfer
equation. The local values of h were computed at time coefficient in the liquid PCM increased with the expansion
of the melted domain in each chamber zone (A, B, C, and
D) on both sides of each HTF tube leg. This increase in the
local magnitude of h is due to two main reasons. The first is
the increase in the HTF tube contact length with the liquid
that strengthens the magnitude of the buoyancy-induced
flow, and the second is the expansion of the liquid PCM
zone that allows the growth of convective cells formed in
the liquid zone. These convective cells increase the
transportation of heat from the source to the other
boundaries of the liquid zone.
At a given heat flux, the results show a clear influence
of the given PCM zone relative to the heat source
orientation; that is, the local values of h were significantly
larger in the PCM zones within the inner region (zones B
and C) than in the outer region (zones A and D). It is found
that the local values of h in the inner region are on average
about 35% higher than the local values of h in the outer
region at both the highest and lowest heat fluxes.
Relatively larger melted zone volume and higher liquid
contact length of the HTF tube in the inner region are the
likely causes for higher h values in that region.
Comparison of Figure 8(a) and (b) shows that the
magnitude of h increased with an increase in the heat flux
in the inner region. The results also show that the variation
of h with height became more linear with an increase in the
heat flux. This is likely due to the reason that an increase in
the heat flux increases the buoyancy magnitude, which
resulted in better mixing.
Figure 8 presented the transient variation in the local h
in four chamber zones at the lowest and highest flux cases.
For the results to be further generalized, the average value
of the local h in each chamber zone is presented in Figure 9
Figure 8. Values of the local convective heat transfer coefficient for all heat flux cases. The trends are similar to that
(h) at different heights in the chamber. Results are presented for observed in Figure 8; that is, the highest values of the heat
2
two input heat fluxes, (a) 3450 and (b) 5840 W/m . [Colour figure transfer coefficient, h, are observed in zone B and then
can be viewed at wileyonlinelibrary.com] zone C, which are in the inner region. The outer region

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

gβðT S  T B Þl 3
Ra ¼ (4)
να

where g is the acceleration due to gravity, β is the


coefficient of thermal expansion of the liquid PCM, TS is
the surface temperature of the HTF tube, TB is the bulk
temperature liquid PCM domain, l is the characteristic
length (in the present case, it is the liquid contact length
of the HTF tube), ν is the kinematic viscosity, and α is
the thermal diffusivity of the liquid PCM. As the HTF tube
bounded one side of each zone, that side was used to
compute the characteristic length for the corresponding
zone. The local variations in the Rayleigh number were
calculated in the four chamber zones in the transient
manner similar to the computation of the local heat transfer
coefficient. The average values of the local Rayleigh
Figure 9. The average values of local convective heat transfer number in different zones at all heat fluxes are shown in
coefficient (h) in the four chamber zones at four input heat Figure 10. The results show the highest values of Rayleigh
fluxes. [Colour figure can be viewed at wileyonlinelibrary.com] number in zone B, which is followed by that in zone C.
The values in the outer region (zones A and D) were in
general further lower. While overall the trends in Rayleigh
(zones A and D) has almost similar magnitudes. Results number variations are similar to that of the heat transfer
also show that in each zone, the value of h increased coefficient (Figure 9), one prominent difference was in
monotonically with an increase in the heat flux. It is found zone C. The values of heat transfer coefficient in zones B
that the value of h in the inner region (zones B and C) and C were relatively comparable, indicating that the flow
increased approximately by 10% as the heat flux increased patterns in both zones are quite similar. However, the
from 3450 to 5840 W/m2, while in the outer region (zones Rayleigh number in zone C was significantly lower than
A and D), the value of h increased approximately by 5% that in zone B and approximately in the same range as
over the same heat flux range. the Rayleigh number in the outer region. A plausible
explanation for this trend is that the Rayleigh number is
primarily influenced by the fluid temperature rather than
3.5. Local Rayleigh number (Ra) the fluid flow behavior. As seen earlier in Figure 5, the
Rayleigh number (Ra) is a non-dimensional parameter that HTF tube surface temperature was significantly higher in
characterizes the magnitude of buoyancy-driven force to zone B than in zone C, hence a higher liquid PCM
viscous dissipative force in the fluid domain and is temperature in zone B, which caused a higher reduction
calculated using the following equation [12]: in the liquid viscosity. The results also show that the
Rayleigh number increased almost monotonically with
the heat flux in the chamber zones. It is observed that the
Rayleigh number on average increased by 23% in the inner
zone and 18% for the whole domain as the heat flux
increased from 3450 to 5840 W/m2.

3.6. Determination of the bulk parameters

The transient local behavior of the heat transfer


coefficient in different spatial zones is presented earlier.
The overall behavior can be characterized in a transient
manner by averaging the local heat transfer coefficient
values in different zones at a given height that
corresponds to the distance of the propagating melting
front (which is moving in a transient manner). However,
as seen in Figure 4, the PCM in the inner region (zones
B and C) was fully melted, while the bottom section in
the outer region (zones A and D) never melted. Thus,
the overall transient behavior of the heat transfer
Figure 10. Average Rayleigh number (Ra) in different chamber coefficient was characterized by averaging the local heat
zones at four input heat fluxes. [Colour figure can be viewed at transfer coefficient values in the inner region (zones B
wileyonlinelibrary.com] and C) only. The results are presented in Figure 11.

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

however, the increasing trend is nonlinear. The results also


show that the overall heat transfer coefficient increased by
approximately 10% as the heat flux increased from 3450 to
5840 W/m2.

3.7. Nusselt number (Nu) correlation

The heat transfer behavior in a given configuration during


natural convection is typically generalized in terms of the
relation between Nusselt number, Nu (a ratio between the
convective and conductive heat transfer), and Rayleigh
number, Ra. Such relationship provides an understanding
of how the convection heat transfer is influenced by the
buoyancy effects. The local Nusselt number was
computed as [12]
Figure 11. Average values of convective heat transfer
coefficient (h) at different heights of the chamber in the inner
region of the phase change material domain. Results are
Nu ¼ hl=k (5)
presented for four input heat fluxes. [Colour figure can be
viewed at wileyonlinelibrary.com] where h is the local convective heat transfer coefficient, l
is the corresponding local characteristic length (in the
present case, it is considered as the liquid contact length
The results show that the local heat transfer coefficient of the HTF tube), and k is the thermal conductivity of
continuously increased as the liquid domain continued the liquid PCM. The local Nusselt number is plotted
to expand and the heat transfer coefficient reached a versus the local Rayleigh number in Figure 13 for all heat
maximum value when the inner region was fully melted. flux cases. The results show as expected that the local
As mentioned earlier, the plausible cause is the stronger Nusselt number increased with an increase in the
buoyancy-induced flow and larger domain for the Rayleigh number. To the best of authors’ knowledge,
convective cells to grow. The plot shows a similar trend the results in Figure 13 provide, for the first time, the
of the heat transfer coefficient increase at all heat fluxes, relation between the Nusselt and Rayleigh numbers in
while the magnitude of h at a given height increased the transient melting process using a U-shaped heat
monotonically with the heat flux. The results show that source. A generalized expression for this relation is
at the lowest heat flux, the value of h increased by obtained using a power law fit to the experimental data,
40% as the vertical distance increased from y/H = 0.15 which is presented as
to y/H = 1. Over the same vertical distance range, the
value of h increased by 55% at the highest heat flux.
For the bulk behavior to be further characterized, the Nu ¼ 0:0071 Ra0:4501 ; 3:0106 < Ra < 1:5109 (6)
heat transfer coefficient values averaged over space and
time are plotted in Figure 12 at all heat flux cases. The The geometry considered in the present study
results as expected show that the overall heat transfer comprised a combination of vertical (side) heat sources
coefficient increased with an increase in the heat flux; and a bottom heat source. In the literature, a well-

Figure 13. Nusselt number (Nu) versus Rayleigh number (Ra) at


Figure 12. Convective heat transfer coefficient (h) as a function different heat fluxes. Empirical correlations obtained from Lim-
of input heat flux (q00 ). [Colour figure can be viewed at Bejan [49] and LeFevre-Ede [48] are also plotted for comparison.
wileyonlinelibrary.com] [Colour figure can be viewed at wileyonlinelibrary.com]

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

established Nu–Ra correlation is reported for heat transfer because of the additional contribution from the bottom heat
from a vertical cylinder [45–47] that was originally source. The Nusselt number values in the higher range of
proposed by LeFevre and Ede in 1956 [48]. The Rayleigh number correspond to the condition when the
correlation is presented below: PCM in the inner region was fully melted (Figure 4f). In
this condition, the buoyancy-induced convective currents
 41 from the bottom tube surface supported the flow induced
4 7RaH Pr 4ð272 þ 315 PrÞH
NuH ¼ þ (7) by buoyancy from the vertical sections of the tube and
3 5ð20 þ 21 PrÞ 35ð64 þ 63 PrÞD
played a significant role in the overall convective motion,
hence resulted in higher Nusselt number values than that
where H represents the height of the chamber, D is the predicted by Lim and Bejan’s [49] correlation because
diameter of the heat source, and the dimensionless such heat source was not present in the configuration of
Rayleigh and Prandtl numbers are represented by Ra and Lim and Bejan [49]. Comparison of the present correlation
Pr, respectively. It is to be noted that, for this correlation, with that of LeFevre and Ede [48] shows that at a given
the medium considered was a single-phase fluid. Rayleigh number, the Nusselt number values predicted
Lim and Bejan [49] also investigated a two-phase by LeFevre and Ede’s [48] correlation are higher than
system and proposed a correlation for the melting phase those by the present study. A plausible explanation for this
of a PCM where a vertical wall acted as the heat source. difference is that LeFevre and Ede’s [48] correlation
Their correlation is expressed as considers single-phase fluid in the entire domain, which
1
influenced the convective flow from the initial stage of
0:35 Ra4 heating, while in the present case, the liquid domain
Nu ¼ h i49 (8)
9 increased with time.
1 þ ð0:143=PrÞ16

These correlations are also plotted in Figure 13 for


comparison. It is observed that the present results agree 4. CONCLUSIONS
more closely with the correlation of Lim and Bejan [49]
than with LeFevre and Ede [48]. It is expected because An experimental study was conducted to investigate a
Lim and Bejan’s [49] correlation is for the phase change time-dependent heat transfer process during the melting
process with a vertical heat source, while LeFevre and phase of a PCM inside a rectangular chamber that
Ede’s [48] correlation is for single-phase convection from embedded a U-shaped heat source. The temperature fields
a vertical heat source. A close comparison of the present and the melting behavior were recorded via TCs and
results with Lim and Bejan’s [49] correlation show that imaging system, respectively, at four input heat fluxes.
the Lim and Bejan [49] correlation predicts higher Nusselt The presented results showed that the geometry of the
number in the lower range of Rayleigh number; however, heat source has a significant effect on the solid–liquid
as the Rayleigh number increases, the Nusselt number in interface dynamics throughout the melting period as well
the present geometry exceeds the Nusselt number as the temperature field. The results further show that
predicted by Lim and Bejan’s [49] correlation. This the melting rate also changed nonlinearly over the melting
difference in the trend is due to the differences in the phase. The simultaneously recorded temperature data and
geometry of the heat source. The present results in the the images were analyzed, and that enabled to compute
lower range of Rayleigh number corresponds to the various important thermo-physical parameters of the
duration when the PCM started to melt from the top and PCM during the melting process to help better understand
propagated downward and horizontally until it merges with the overall heat transfer mechanism. The results show that
the melted PCM zone emerging from the bottom. The the heat source geometry has a significant influence on the
correlation of Lim and Bejan [49] was based on the local heat transfer coefficient. The heat transfer coefficient
constant temperature condition of the vertical heat source, in the region bounded between the U-tube legs was about
while in the present case, the temperature of the HTF tube 35% higher than that in the region outside the U-tube. It is
surface was decreasing because of heat loss from the HTF also observed that the overall convective heat transfer
(Figure 4). Hence, the buoyancy forces in this case were coefficient increased rapidly at the early stage of melting
relatively weaker than those in the case with a constant and the rate of increase gradually decreased at the latter
temperature heat source. This could likely be the reason stage of melting. As the vertical distance increased
for the lower Nusselt number values in this Rayleigh from y/H = 0.15 to y/H = 1, the value of h increased by
number range. The comparison also shows that beyond this 40–55% as the input heat flux increased from 3450 to
lower Rayleigh number range, the Nusselt number in the 5840 W/m2. Over the same input heat flux range, the
present configuration started to become larger than that in Rayleigh number increased by approximately 23% in the
Lim and Bejan [49]. This is likely due to the reason that inner region and 18% in the whole domain. A new
beyond this Rayleigh number, the bottom melted zone correlation for the Nusselt number and Rayleigh number
merged with the top melted zones (Figure 4e), which is proposed to characterize the heat transfer during the
enhanced the convective currents across the domain melting phase with a U-shaped heat source.

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Bashar M. and Siddiqui K. Heat transfer during melting of a PCM by a U-shaped heat source

ACKNOWLEDGEMENTS 11. Farid MM, Khudhair AM, Siddique AR, Al-Hallaj S.


A review on phase change energy storage: materials
The authors are thankful to the Natural Sciences and and applications. Energy Conversion and Management
Engineering Research Council of Canada (NSERC) and 2004; 45:1597–1615.
the University of Western Ontario for the research support.
12. Incropera FP, Wewitt DP, Bergman TL, Lavine AS.
Fundamentals of Heat and Mass Transfer (7th). John
REFERENCES Wiley & Sons, ISBN 13 978-0470-50197-9: Hoboken,
NJ, 2011.
1. Murray RE, Groulx D. Experimental study of the 13. Holman JP. Heat Transfer (10th). Mc-Graw-Hill
phase change and energy characteristics inside a Companies Inc: New York, NY, 2010.
cylindrical latent heat energy storage system: part 2, 14. Burmeister L. Convective Heat Transfer (2nd). John
consecutive charging and discharging. Renewable Wiley & Sons: New York, NY, 1993.
Energy 2015; 63:724–734. 15. Gebhart B, Jaluria Y, Mahajan RL, Sammakia B.
2. Dinçer I, Rosen MA. Thermal Energy Storage: Buoyancy-induced Flows and Transport. Hemisphere
Systems and Applications (2nd). Wiley: Chichester, Publishing Company: New York, NY, 1988.
UK, 2011. ISBN:9780470747063. 16. Liu C, Groulx D. Experimental study of the phase
3. Viskanta R. Solar heat storage: latent heat materials, change heat transfer inside a horizontal cylindrical
volume i: background and scientific principles. In latent heat energy storage system. International
Chapter 5: Phase-change Heat Transfer, Lane GA Journal of Thermal Sciences 2014; 82:100–110.
(ed.). CRC Press: Boca Raton, FL, 1983. 17. Christiano GSS, Luiz FM. Numerical study of melting
ISBN:0849365856. of tin within a rectangular cavity including convective
4. Chiu JNW. Heat transfer aspect of using phase change effects. Proceeding of COBEM 2011, Brazilian
material in thermal energy storage applications, Congress of Mechanical Engineering, Natal, RN,
licentiate. PhD thesis, KTH School of Industrial Brazil, 2011.
Engineering and Management, Division of Heat and 18. Zhu Y, Zhang Y, Li G, Yang F. Heat transfer
Power Technology, SE-100 44 Stockholm, Sweden, processes during an unfixed solid phase change
2011. material melting outside a horizontal tube.
5. Akgun M, Aydin O, Kaygusuz K. Experimental study International Journal of Thermal Sciences 2001;
on melting/solidification characteristics of a paraffin as 40:550–563.
PCM. Energy Conversion and Management 2007; 19. Tzivanidis C, Antonopoulos KA, Kravvaritis ED.
48(2):669–678. Parametric analysis of space cooling systems based
6. Sharma A, Tyagi VV, Chen CR, Buddhi D. Review on on night ceiling cooling with PCM-embedded piping.
thermal energy storage with phase change materials International Journal of Energy Research 2012;
and applications. Renewable and Sustainable Energy 36:18–35.
Reviews 2009; 13:318–345. 20. Ismail KAR, Castro JNC. PCM thermal insulation in
7. Ettouney H, El-Dessouky H, Al-Ali A. Heat transfer buildings. International Journal of Energy Research
during phase change of paraffin wax stored in 1997; 21:1281–1296.
spherical shells. Journal of Solar Energy Engineering 21. Zhang Z, Bejan A. Melting in an enclosure heated at
2005; 127(3):357–365. constant rate. International Journal of Heat and Mass
8. Feng Y, Li H, Li L, Bu L, Wang T. Numerical Transfer 1989; 32(6):1063–1076.
investigation on the melting of nanoparticle-enhanced 22. Rajeev Rai KN, Das S. Numerical solution of a
phase change materials (NEPCM) in a bottom-heated moving-boundary problem with variable latent heat.
rectangular cavity using lattice Boltzmann method. International Journal of Heat and Mass Transfer
International Journal of Heat and Mass Transfer 2009; 52:1913–1917.
2015; 81:415–425. 23. Joseph A, Kabbara M, Groulx D, Allred P, White MA.
9. Paris J, Falardeau M, Villeneuve C. Thermal storage Characterization and real-time testing of phase-change
by latent heat; a viable option for energy conservation materials for solar thermal energy storage.
in buildings. Energy Sources 1993; 15:85–93. International Journal of Energy Research 2016;
10. Cabeza LF (Ed). Advances in Thermal Energy 40:61–70.
Storage Systems: Methods and Applications. 24. Tamme R, Bauer T, Buschle J, Laing D, Müller-
Woodhead Publishing: Cambridge, UK. ISBN:978- Steinhagen H, Steinmann W. Latent heat storage
1-78242-088-0. above 120°C for applications in the industrial process

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er
Heat transfer during melting of a PCM by a U-shaped heat source Bashar M. and Siddiqui K.

heat sector and solar power generation. International local heat source. Thermophysics and Aeromechanics
Journal of Energy Research 2008; 32:264–271. 2016; 23:553–565.
25. Nabeel SD, Khodadadi JM. Melting and convection of 37. Bondareva NS, Sheremet MA. 3D natural convection
phase change materials in different, shape containers: a melting in a cubical cavity with a heat source.
review. Renewable and Sustainable Energy Reviews International Journal of Thermal Sciences 2017;
2015; 43:449–477. 115:43–53.
26. Naterer GF. Heat Transfer in Single and Multiphase 38. Bondareva NS, Sheremet MA. Effect of inclined
System. CRC press: Boca Raton, FL, 2003. magnetic field on natural convection melting in a
ISBN:0-8493-1032-6. square cavity with a local heat source. Journal of
27. Beckermann C. A general correlation for melting in Magnetism and Magnetic Materials 2016;
rectangular enclosures. Journal of Heat Transfer 419:476–484.
1989; 111:1111–1115. 39. Mariani VC, Coelho LS. Natural convection heat
28. Gau C, Viskanta R. Melting and solidification of pure transfer in partially open enclosures containing an
metal on vertical wall. Journal of Heat Transfer 1986; internal local heat source. Brazilian Journal of
108:174–181. Chemical Engineering 2007; 24(3):375–388.
29. Diaz LA, Viskanta R. Visualization of the solid-liquid 40. Zalba B, Marin JM, Cabeza LF, Mehling H. Review
interface morphology formed by natural convection on thermal energy storage with phase change:
during melting of a solid from below. International materials, heat transfer analysis and applications.
Communication of Heat and Mass Transfer 1984; Applied Thermal Engineering 2003; 23:251–283.
11:35–43. 41. Mathematical simulation of melting inside a square
30. Jellouli Y, Chouikh R, Guizani A, Belghith A. cavity with a local heat source. Thermophysics and
Numerical study of the moving boundary problem Aeromechanics 2016; 23:553–565.
during melting process in a rectangular cavity heated 42. 3D natural convection melting in a cubical cavity with
from below. American Journal of Applied Sciences a heat source. International Journal of Thermal
2007; 4(4):251–256. Sciences 2017; 115:43–53.
31. Hsu CF, Sparrow EM, Patankar SV. Numerical 43. Himran S, Suwono R, Mansoori GA. Characterization
solution of moving boundary problems by boundary of alkanes and paraffin waxes for application as phase
immobilization and a control-volume based finite- change energy storage medium. Energy Sources 1994;
difference scheme. International Journal of Heat and 10:117–128.
Mass Transfer 1981; 24:1335–1343. 44. Ukrainczyk N, Kurajica S, Sipusic J. Thermo-physical
32. Hale NW Jr, Viskanta R. Photographic observation comparison of five commercial paraffin waxes as latent
of the solid–liquid interface motion during melting heat storage materials. Chemical and Biochemical
of a solid heated from an isothermal vertical wall. Engineering Quarterly Journal 2010; 24(2):129–137.
Letters in Heat and Mass Transfer 1978; 45. Boetcher SKS. Natural Convection from Circular
5:329–337. Cylinders. Springer publications, 2014. ISBN:978-3-
33. Ho CJ, Viskanta R. Heat transfer during melting from 319-08131-1.
an isothermal vertical wall. Journal of Heat Transfer 46. Bejan A. Convection Heat Transfer (4th). John Wiley
1984; 106:12–19. & Sons: Hoboken, NJ, 2013.
34. Gadgil A, Gobin D. Analysis of two dimensional 47. Ede AJ. Advances in Free Convection. Advances in
melting in rectangular enclosures in presence of Heat Transfer. Academic Press: New York, NY, 1967.
convection. ASME Journal of Heat Transfer 1984; 48. LeFevre EJ, Ede AJ. Laminar free convection from the
106:20–26. outer surface of a vertical cylinder. Proceedings of the
35. Yuksel N, Avci A, Kilic M. A model for latent heat 9th international congress on applied mechanics,
energy storage systems. International Journal of Brussels, Belgium, 1956; 175–183.
Energy Research 2006; 30:1146–1157. 49. Lim JS, Bejan A. The Prandtl number effect on
36. Bondareva NS, Sheremet MA. Mathematical melting dominated by natural convection. Journal of
simulation of melting inside a square cavity with a Heat Transfer 1992; 114(3):784–787.

Int. J. Energy Res. (2017) © 2017 John Wiley & Sons, Ltd.
DOI: 10.1002/er

You might also like