All India Test Series: JEE (Advanced) - 2021

ALL INDIA TEST SERIES
FULL TEST – IV
JEE (Advanced)-2021
PAPER –2
TEST DATE: 18-01-2021
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. B, C, D
Sol. Volume of liquid upto lower level of meniscus = r2h
Volume of liquid above meniscus = Volume of cylinder of radius r and height r – Volume of
2 3 1 3
hemisphere of radius r  r 3  r  r
3 3
1 3  r
So, total volume of liquid in capillary  r 2h  r  r 2  h  
3  3
For equilibrium, weight of liquid = Upward force of surface tension
 r
 r 2  h    2rT cos 
 3
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AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 2
2T cos  r
h 
rg 3
r
If we neglect in comparison to h, then
3
hrg
T
2cos 
 r
r  h   pg
3
or T  
2 cos 
For water and glass,  is very small
  0
 r
r  h   pg
3
 T  
2
2. B, C
Sol. For observing resonance paper riders are used and vibrating tuning fork is touched to sonometer
box (not with wire). When temperature increases length of prongs of tuning fork increases and
thus frequency decreases
1 T
Also, t 
2L 
1 T

2L  D2  
 4 
 
1 T

LD 
3. A, D
Sol. Let length l of the cylinder is dipped in liquid, the weight of liquid displaced by the volume of l-part
of cylinder
r 2 l g  W …(i)
where,  = density of the liquid when cylinder is further dipped through a distance x, then volume
of displaced [liquid r2(l + x)]
3 AITS-FT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021
Therefore, vertically upward force, (i.e. force of buoyance) acting on mass equals t2(l + x)g.
At situation of equilibrium, net force on the mass
F  W  r 2 (l  x)pg
 W  r 2lg  r 2 xg …(ii)
From equations (i) and (ii), we get
F  r 2pgx  kx
R  r 2g
m
The time period, T  2
k
m
 2
r 2 g
 Frequency of oscillations,
1 1 r 2 g
v 
T 2 m
4. C, D
Sol. If mg  kx  mg
When spring is taut, the acceleration of each block are same
If a2  0,T  mg
T  kx  mg kx
 a1  
m m
If mg < kx – mg, string slacks
kx  mg
and a1 
m
and a2  g
5. A, C
Sol. For upward moving elevator,
kx1  mg  ma …(i)
For downward moving elevator,

mg  kx 2  ma …(ii)
Dividing Eq. (i) by Eq. (ii), we get

g  a x1 4 2
 
g  a x2 3 2
g
 a
7
For horizontal motion of elevator, spring will be inclined at some angle as given in figure.
kx 3 cos   mg …(iii)
kx 3 sin   ma …(iv)
Squaring and adding Eqs. (iii) and (iv), we get
(kx 3 )2  m2 (g2  a2 )
m 2
x3  g  a2 …(v)
k
From Eqs. (i) and (v), we get
x3 g2  a2

x1 ga
 g2  a2 
x3   
 ga 
 
Hence, x3 = 5 mm
6. A, B, C, D
Sol. At final equilibrium, force must be equal from two side, so
pl1 A  pl2 A  pl1  pl2

In final condition, final temperature will also be same, because separator is conducting.
Conservation of moles in I and II components gives

pV p t (V1 )
 …(i)
RT RT
2p(2V) p t V2
 …(ii)
RT RT
pV
V1 
pt
4pV
V2  …(iii)
pt
V1  V2  3V
pV 4pV
  3V
pt pt
pV 5
 5  3V  p t 
pt 3
3V 12V
So, V1  , V2 
5 5
SECTION – B
7. 7
Sol. Find the network done for the process, then find heat supplied. By this you can find the value x
with the help of efficiency formula.
Total work done
Efficiency 
Total heat supplied
WAB  p( V)  nRT (isochoric process)
25
 2  300  5000 J
3
T  p 
WBC  nRT ln  f   nRT ln  i  (isothermal process)
 ti   pt 
 2  105 
 2  R  600 ln  5 
 1 10 
= 1200 R ln (2)
pT  k 
nr.T 2R  300  2 
WCA    p V K 
2 1
1 p  V1/ 2  K 
2
= –1200 R
W  600R  1200R ln(2)  1200R
W  600R[2ln(2)  1]
Heat supplied,
5R
Q AB  nCp T  2   300  1500R
2
QBC  WBC  1200R ln(2)
600R[2ln(2)  1] 12ln(2)  6
 
1500R  1200R ln(2) 15  12ln(2)
21
  1
15  12ln(2)
37
 1
15  12ln(2)
x=7
8. 3
Sol. In this problem, concept of friction as well as the concept of torque will be used. For the
equilibrium, resultant force will be zero. We well also balance the torque for the equilibrium.
F  0
  0
Under equilibrium,
FH  0  P  N  0  P  N
FV  0  N  W  0  N  W
P = W
Moment about contact point A,

P(AD) = W(GD)
P(OA – OD) = W (GD)
P
sin   …(ii)
4W
P
3
Substituting, P = w from Eq. (i)
W
sin  
4W
W 
3
3
sin  
3  4
3
   sin1
3  4
7 sin   3
9. 3
Sol. Consider a small element of radius r and width dr.
F
Normal reaction, dF   2rdr
 2
D
4
Frictional force, dF1  dF

Frictional moment, dM  rdFt  rdF
Total moment,
4F
D/2
M   dM   r 
 2rdr
O
D2
4F (D / 2)3
    2  
D2 3
FD
M N3
3
10. 2
Sol.
E2  W0  KE2 …(ii)
1
Also,   
e
KE
2
KE 2  1   1 
    6.1
KE1   2    2  1 
 6.1 
1 1
E1  13.61 12  2  2  = 10.2 eV …(iv)
1 2 
Now, ionisation energy of H-atoms,
1 1
= – E1 = 13.6 eV energy of first line in Lyman series  13.6Z 2   2  eV
1 2 
2
 10.2 Z 2 eV
 1 1 
and energy of series limit of Balmer series  13.6  Z 2  2    eV  3.4Z 2 eV
 2  
Given, 13.6  2  10.2 Z  3.4 Z
2 2
 Z=2  He+ ion
11. 1
Sol. For constructive interference, intensity (l) is maximum,
When cos = +1
The path difference at point P,
x  (SS2  SS1 )  (S2P  S1P)
dy d(d / 2)
 
D1 D2
For constructive interference,
dy d2
x    n
D1 2D2
(10 3 )(0.5 sin t)  10 3 (10 3 )2
  n
1 22

0.5 sin   t  10 6  0.25  10 6
6
 (5000  1010 )n  0.5  10 6 n
 0.5n  0.25
sin   t 
6 0.5
For the minimum value of t, n = 1
 1  
sin   t     t 
6 2 6 6
or t = 1s
12. 5
 
Sol. WAB  nCP T  nRT 
 1  1

[3p0 V0  p0 V0 ]  2pV0 
 1
Q AC  U  W
nR 1
 T   3V0 [p0  4p0 ]
 1 2
[16p0 V0  p0 V0 ] 15p0 V0
 
 1 2

56  2p0 V0 
 1
  1 
360  15p0 V0  
 2(   1) 
360 15 (   1)
 .
56 4 
7 2
12  7   7,    1 
5 f
t=5
SECTION – C
13. 00002.00
Sol. For the given area total force will be u dA
When dA is the area, then electrical force per unit area
2
1 1    2
  0E 2   0   
2 2  20  2ge0
Projection area  r 2
 2 
 Net electrical force    ( R )
2
2
 0
In equilibrium, this force should be equal to the applied force,
 2R 2 4  0
F  2
2 0 2 0
14. 00023.33
Sol.
Let x = distance between the car at the instant first bullet is fired (sat at time t = 0)
Speed of bullet, relative to ground is
Vb = u + V2 = 305+25 = 330 m/s
Velocity of bullet, relative to car A is
VbA = 330 – 30 = 330 m/s
 Time when the first bullet hits the car a is
X X
t1   …(i)
VbA 300
Distance between the car when the last bullet is fired (at time t = T0 = 20 s) is
X1  X  VAB T0  X  5  20  X  100
Time when the last bullet hits the car A is
X
t 2  T0 
VbA
X  100
 20  …(ii)
300
The interval t = t2 – t1
100
 20   23.33 sec .
30
15. 00000.75
Sol. Consider the tube + liquid inside it + Block as our system.
For equilibrium
Weight = Buoyancy
L  L
2 vg  r 2 .  g   v  r 2   g
2  2
Solving, v = 0.75 m3
16. 00002.25
Sol.
We have to find x co-ordinate of particle B. Phase difference between A and B is

5 2 5
  ( x) 
3  3
5  1.5
x   1.25m;  x B  2.25 m
6
17. 00016.80
Sol. The potential difference across 1 F and 2 F (uppermost) capacitor
must sum up to
q q/ 2 24
 6q C
1 2 5
24
 Answer is 12   16.8C
5
18. 00003.44
Sol. The cone of rays passing through the hole at A produce an elliptical spot on the floor.
The circular base having diameter BD will get projected on the floor as an ellipse.
CB = major axis = 12 cm
DB = Minor axis = 6 cm
h sin 
DB  AB( )   h  (6 cm)
sin  
DB 6 1
But sin    
CB 12 2
(6 cm)
 h
2
3 cm  180  0.5   
  0.5  radian 
0.5    180 
Chemistry PART – II
SECTION – A
19. A, B, C, D
Sol. Factual
20. A, B, D
Sol. There will be post in each possible geometrical isomer thus no-optical isomers.
21. A, C, D
Sol. Factual
22. B, C
Sol. POS in B
POS in C after even
Interchanges.
23. B, C, D
Sol. H3
H3 C C CH CH2
OH OH OH
24. B, C
Sol.
Ph CH2 N N N
Ph CH N N N
SECTION – B
25. 3
Sol. Q  H2 O2
R  O2
26. 0
Sol. [Si1O12 ]2
27. 6
Sol. c
b
a a
b X1
c
a
a b
b
b b
a a
a X1
c c X1
c
a
a a
a
c c
c b
b X1
b b X2
c
Pair of enantiomers
28. 6
Sol. CxH12  (x  3)O2  xCO2  6H2 O
At 400 K H2O is gaseous.
29. 5
Sol. Compound 1, 3, 4, 5, 6.
30. 3
Sol. Compound 2, 4, 5.
SECTION – C
31. 00033.00
Sol. X2O3
X13 Xa2 X15a O3
3  2a  5(1  a)  6  0
[balancing charges]
32. 00044.00
Sol.   U  P2 V2  P1V1
33. 00600.00
Sol. PCl5  PCl3  Cl2
2 2 2
After ‘x’ moles Cl2 is added.
2 y 2y 2 xy
2  x  y  2  y  2  y  2  (6)
x  y  6
2 y 2y 8
2 2

V V  8 / 2V
2 2y 2 y
V  2v    2V 
   
34. 00287.00
K
Sol.  0Ag  Xocl
S
Convert mol/l to g/l
35. 00054.00
Sol. Let molar mass = M
6
M  Po  20
180 6

18 M
6
M  Po  20.02
6
11 
M
36. 00020.00
Sol. H - U = ng  RT
Mathematics PART – III
SECTION – A
37. A, B, C
/ 2  /2
Sol. I1   
cos  cos2 x dx    cos   sin x  dx
2
0 0
/ 2
  
2I2  
0
2 cos   cos  cos 2x   0
2
   2 
I1  0
/ 2 / 2
I2   cos   1  cos 2x   dx    cos   cos 2x  dx
0 0

1
cos   cos t  dt
2 0
 put 2x  t
 I3
 I2  I3  0
38. B, D
Sol. The line y= mx + c mater a chord of length 2

 
a2 1  m2  c 2
from circle x2  y 2  a2
1 m 2
39. A, B, D
dy 1
Sol. y  log7  log7 x   
dx xloge x loge 7
40. A, B, D
1
Sol. Yy  X  x   X  mY   x  my   0
m
x  my
Perpendicular distance from origin  y
1  m2
dy y 2  x 2
 x 2  2xym  y 2  
dx 2xy
dy
Also x.2y.  x2  y2
dx
dt 1
Put y  t ,
2
 .t   x
dx x
41. A, C
x2 1 x2
Sol.  
I   x.ln 1  x 2 dx  ln 1  x 2 .   2

1 x 2
2x. dx
2
x2 x 3 .dx

2

ln 1  x 2   2
x 1

 x 2  1  x 2  1
I 
 ln 1  x  
2
 c
 2   2 
42. B, D
x2 9 1
Sol.  x.  1 x 2  3x  4  0 x = 4, –1
4 4 3
Points (4, 3)
 Required equation(s) of tangents are x  y = 1
SECTION – B
43. 8
1
Sol. x2  x  1  0  x  1
x
2
5
 1
   xr  r   8
r 1  x 
44. 5
Sol. Let at A, B, C f(x) is continuous but not differentiable at A, B, C. Right hand derivative is – and A
+ is left hard derivative is +.
y = x3
1 y = sgn(x)
C
–2 –1
2 3
–1 1–
A B
–2
 5 points
45. 1
x 1 y  3 z  3
Sol. Equation of line through P(1, -2, 3) and parallel to given line is   
2 3 6
1
General point online Q(2 + 1, 3 –2, –6 +3) if then point lie on plane,  =
7
 9 11 15 
Q  ,  ,
7 7 7 
4 9 36
 PQ    1
49 49 49
46. 7
2
 1 3 3
Sol. 9 x  3 x  1   32    
 2 4 4
3
x   , 1  9x  3x  1  7
4
Range of f(x) = {0, 1, 2, 3, 4, 5, 6}
47. 6
Sol. If let A denotes the event that target is hit when x shells are fired at point I.
8 1
P E1   , P E 2  
9 9
x 21 x
A  1  A  1
P    1    ard P    1 
 E1  2  E2  2
8  1  1   1 21 x 
x
PA  1    1    
9   2   9 2
 


dA d PA
2
0  x  12 0
dx dx

   12 6
2
48. 2
 
Sol.     x  sin x  dx   xdx  2 square unit
0 0
SECTION – C
49. 00400.00
100  n 200n
Sol. Am  , Gm  10 n, Hm 
2 100  n
For Am to be integer, n is even
For GM to be integer n should be perfect square
 n = 4k2
200k 2
 Hm   k 2  125,100, 75, 25
25  k 2
 k2 = 100 only satisfy.

x = 4 kx2 = 400
50. 00208.00
Sol. TTT, A, E, R, S
4!
3 like, 1 distinct  4C1   16
3!
4!
2 like, 2 distinct  4C2  1  72
2!
All for different  5 C  4!  120
4
 Total number of words = 16 + 72 + 120 = 208
51. 00000.00
3
5 3  5i  4i
2
Sol. z  3  5i 8 4  5i
3
 4i 4  5i 9
2
z  z  z  purel, real
 imaginer part of z = 0
52. 00004.00
  
a.a a.b a.c 
         2     
Sol. a  b b  c c  a   a b c   b.a b.b b.c  = 32
    
   
c.a c.b c.c 
 1
 abc 
  12  4
53. 00004.25
Sol. An P(2, 0) lie on curve – 89 + 4b – 2c + 5 = 0 ….(1)
dy
Q  0, 5   3ax 2  2bx  c
dx
dy
At(0, 5) 3 c 3 ...(2)
dx
dy
at  2, 0   0  12a  4b  3  0
dx
1 3
a   , b   , c 3
2 4
2 3 17
c ab  3    4.25
4 4 4
54. 00004.00
 
Sol. cos 2   sin   cos   3 
2 
 
2  2n    3  , n  I
2 
 
for  ve sign     2n  
 2
2n 
For –ve sign   
5 10
3 7 11 15
 , , ,
10 10 10 10
Hence four values

All India Test Series: JEE (Advanced) - 2021

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ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

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