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Experimental Effectiveness Estimation of Inhibitors on Oxidation


Degradation of Oil Impregnated Paper Insulation in Power Transformers

Article  in  i-manager s Journal on Power Systems Engineering · January 2017


DOI: 10.26634/jps.4.4.11392

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RESEARCH PAPERS

EXPERIMENTAL EFFECTIVENESS ESTIMATION OF INHIBITORS ON


OXIDATION DEGRADATION OF OIL IMPREGNATED PAPER
INSULATION IN POWER TRANSFORMERS
By
CHILAKA RANGA * ASHWANI KUMAR CHANDEL ** RAJEEVAN CHANDEL ***
* Ph.D Scholar, Department of Electrical Engineering, NIT, Hamirpur, HP, India.
** Professor, Department of Electrical Engineering, NIT, Hamirpur, HP, India.
*** Professor, Department of Electronics and Communication Engineering, NIT, Hamirpur, HP, India.
Date Received: 20/10/2016 Date Revised: 13/02/2017 Date Accepted : 15/02/2017

ABSTRACT
Power transformers are very important and expensive components of electricity transmission and distribution networks.
Though the failure rate of transformers is generally low, however, in the event of a failure huge repair costs and long
shutdown time are generally needed. The life of insulation decides the service life time of the transformers. Several
oxidation inhibitors are generally inhibited into the oil in order to improve the life time. These inhibitors reduce the
oxidation process inside the transformers insulation, and improve the dielectric strength. The present paper determines
and compares the effectiveness of 1,2,3-benzotriazole and 2,6-dibutyl-4-methylphenol inhibitors on the oxidation
degradation of mineral transformer oil subjected to higher accelerated thermal stresses. It improves the quality and the
service lifetime of the insulation in transformers.
Keywords: Transformer Oil, 1,2,3-benzotriazole, 2,6-dibutyl-4-methylphenol, Aging, Water Content, Flash Point,
Interfacial Tension, Breakdown Voltage.

INTRODUCTION transformers is generally low, however, in the event of a


Transformers are very expensive equipments of electricity failure huge repair costs and long shutdown time are
transmission system, and one of the most valuable generally unavoidable. Therefore, condition monitoring
devices in an electrical substation. Therefore, in order to (CM) of power transformers has become very essential for
have a continuity of power supply the health of these the continuous and reliable operation of such vital
devices has to be always excellent. However, the health devices [4]. CM determines the insulation degradation,
condition of power transformers mainly depends on the and facilitates the timely maintenance of the transformer.
health of their solid and liquid insulations [1]. Further, the At the same time it enhances the serviceable life of the
operating characteristics of these insulations are largely transformers.
influenced by thermal and electrical stresses. These During the past few years, a number of researchers have
stresses inside the transformers accelerate aging, and investigated the influence of thermal aging on the
reduce the overall service life time [2]. At high performance of the transformers [2-5]. These studies are
temperatures, oxidation of the insulation inside the good to determine the aging characteristics of the
transformers progresses extensively. Due to this many insulations. It has been concluded that the insulation
undesirable contaminants including solid particles and characteristics are satisfactory for new materials but
water content accumulate within the transformer oil due decline with time and temperatures. This is due to the
to oxidation [3]. Presence of these particles inside the oxidation of various components inside the transformers
transformers changes the electrical and the thermal [4]. Thus, anti-oxidants namely, 1,2,3-benzotriazole (BTA)
properties of the insulation. Though the failure rate of and 2,6-dibutyl-4-methylphenol (DBPC) are added in to

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the transformer mineral oil in order to inhibit the oxidation details the outcomes of the test results. Subsequently, the
process [6]. These additives effectively slow down the percentage improvement in the dielectric characteristics
copper ion elution and trapping radicals. BTA effectively of the inhibited samples over the uninhibited samples has
inhibits the corrosion of copper and the oxidation of been determined in section 4. Finally, the conclusions are
insulating oil. Similarly, DBPC traps the radical chain drawn in section 5.
reaction which is the main factor behind the oxidation of 1. Experimental Work
the transformer insulation [7]. Though the effect of these
1.1 Samples Preparation
inhibitors is extremely good in improving the thermal
A series of samples inhibited with BTA, DBPC and mixed
characteristics of the transformer oil, however, only a few
inhibitors were prepared in the present work to determine
research articles on the significance and effectiveness of
the oxidation degradation of the mineral transformer oil
these inhibitors have been reported in the literature [2-6].
subjected to higher thermal stresses. As mentioned
Effect of oxidation on the thermal performance of fresh
above, every sample consists of transformer mineral oil,
and field transformer oil samples has been investigated in
TUK and copper strip [12]. Detailed specifications of the
[8]. In [9, 10] it is reported that the presence of inhibitors
materials used in the samples are as specified in Table 1.
increases the useful life of the oil thereby decreasing the
Before conducting the accelerated aging tests, the four
oxidation. Although the effect of these inhibitors on
conical flasks were initially cleaned with purified water,
transformers insulation is determined over the time and
and then dried out in an air-circulated temperature oven
normal working temperatures, however, the influence of
(set at 1000C for 24 hours). This removes all traces of
these inhibitors at higher accelerated thermal stresses has
humidity from the flasks. The cleaned and dried conical
not been investigated. However, it is very important to
flasks were cooled down to room temperature, and then
determine the effect of inhibitors at higher temperatures.
filled with uninhibited fresh mineral transformer oil. Further
The reason is that the degradation rate of transformers
the oil filled and unsealed conical flasks were placed in
insulation is very high at higher temperatures [3, 11].
the temperature oven, and subjected to a temperature of
During normal operating conditions, the transformers are
900C for 24 hours. It is done to remove the moisture
generally subjected to different faults including low,
content which may get added during the preparation of
medium and high temperature faults. These faults
the test samples. Three of the samples were filled with BTA,
increase the oil temperature to a large extent (>7000C). In
DBPC and mixed inhibitors, whereas the other one is
such temperatures, the oxidation of the insulation is very
without additives. The quantity of the inhibitors as given in
high. Therefore, there is a great need to investigate the
Table 1 added in the samples has been in accordance
effect of oxidation degradation additives at higher
with the references [6, 13]. Finally, the prepared test
temperatures to determine the extent of oxidation of the
samples were tightly sealed with cork plugs surrounded
insulation and an increased service life of transformers.
with aluminum foil and Kaptan tape to avoid any ingress
Thus, the present work is an attempt in this direction.
of any outside contaminants. Details of the different
In the present paper, the effects of oxidation degradation
additives such as 1,2,3-benzotriazole and 2,6-dibutyl-4- Material/Item Specification
Transformer oil 1000ml
methylphenol on the thermal characteristics of the
Paper Thermally upgraded Kraft (TUK) – 2mill
transformers insulation have been investigated at higher Copper Strip 100mm (length) × 25mm (width) × 3mm (thickness)
accelerated temperatures. The work presented in this Conical flasks 1000ml capacity

paper has been organized as follows. Section 2 outlines Cork Rubber


0
Temperature oven (500±2) C, PID controller based
the details of the experimental setup. It includes the
Inhibitors BTA (0.66 g), DBPC (6.66 g), Mixed
samples preparation, accelerated aging process and (0.33 g of BTA+ 3.33 g of DBPC)

the different diagnostic tests of transformers. Section 3 Table 1. Detail Specifications of the Materials

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Figure 1. (a) TUK (b) Copper Strips (c) Rubber Cork (d) Kaptan Tape (e) Sample in Conical Flask
(f) Air-circulated PID Controlled Temperature Oven with Samples Placed in Conical Flasks

materials used in the samples are as given in Figure 1 (a) to increase the contents of free-ions and ion-forming
(f). particles. The significant reductions in oil BDV indicate that
1.2 Accelerated Aging the oil is no longer capable of performing its vital insulation
and cooling functions [18]. The break down voltage test
Accelerated aging tests were conducted at different
was performed as per the guidelines given in ASTM D 877
temperatures ranging from 1000C to 2200C. Initially, the
[19].
prepared samples were thermally stressed at 1000C for 72
hours. It was clearly observed from several test results that The second diagnostic test which was performed on the
the changes in insulation characteristics over the samples is interfacial tension. It determines the presence
temperatures are very significant at 72 hours [14, 15]. of polar contaminants and oil decay products [20]. These
Therefore, every test temperature was maintained up to contaminants extensively reduce the interfacial tension of
72 hours. Further, the samples were cooled down to room the transformer oil. This is due to the high affinity towards
temperature, and several diagnostic tests were water and oil molecules [21]. Generally, new mineral oil
performed. Subsequently, another set of samples was exhibits high value of interfacial tension before aging. It
prepared using the same experimental procedure, and decreases with aging and thermal stress. This test was
0
subjected to 120 C for 72 hours duration. Similarly, the performed in accordance to ASTM D971 [22].
0 0 0 0
samples were aged at 140 C, 160 C, 180 C, 200 C and Further, the samples were analyzed with another
0
220 C respectively. Each of these oil samples was important diagnostic test called flash point. It is the safety
handled and stored in accordance with ASTM D 923 [16]. property of the oil. This test provides information about the
1.3 Diagnostic Tests risk of fire [23]. It is desirable that the fresh insulating oil
should have very high flash point (i.e. >140°C) [24]. Flash
Five different tests namely Breakdown Voltage (BDV),
point decreases with thermal aging. The test was
Interfacial Tension (IFT), flash point, Water Content and
performed as per the instructions of ASTM D93-16 [25].
Ultra Violet Visible (UV-Vis) spectroscopy were conducted
on inhibited and uninhibited aged test samples. It is The forth diagnostic test which was performed on the test
mentioned here that BDV is one of the prominent samples is Columetric Karl Fischer Titrator test. It
diagnostic test which is used by the experts to assess the determines the amount of water content present within
health condition of the transformer oil [17]. The maximum the transformer oil. The water content inside the oil
voltage that can be applied across the oil without any samples increases due to heat dissipation. An increase in
electrical breakdown is called as breakdown voltage of the water content reduces the insulating properties of the
oil. Any significant reduction in BDV indicates the presence oil [26]. Excessive water content results in the breakdown
of oil degradation products, cellulose breakdown of the insulation. It ultimately creates a big loss of
products, and water content. These contaminants transformer performance and revenue loss. The water

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content measurement test was conducted in falls down by more than 50% when the temperature
accordance to ASTM D 4643-08 [27]. ranges from 1000C to 1400C. Further, the deterioration in
UV-Vis spectroscopy test was also performed on the test BDV is more than 80% at 2200C. In contrast, BTA inhibited
samples in order to determine their oxidation stability over test sample BDV decreases 40% at 1400C, and nearly
the temperature. UV-Vis test play an important role in 70% at 2200C. Similarly, BDV of DBPC inhibited sample
different power transformer condition monitoring deteriorates by 49% at 1400C, and 74% at 2200C. The
applications [28]. Spectroscopic measurements are change in BDV of oil sample having mixed inhibitors is
widely used to determine the energy levels of atoms and quite similar to that of DBPC inhibited oil sample. It is
molecules. Therefore, all the test samples were analyzed concluded here that the deterioration in BDV of
with UV-Vis Spectroscopy test. It measures the absorbance uninhibited oil sample is more as compared to that of
of ultraviolet or visible light by a sample over a range in the inhibited oil sample. This is due to the increased water
spectrum [29]. The shift in the absorbance curve to longer content and impurities over the accelerated
wavelengths indicates an increasing concentration of temperatures. The water content within the transformer oil
dissolved decay products [30]. This test was performed in propagates the creation of gaseous substances, and the
accordance to ASTM E275 [31]. presence of impurities sharply breaks these gaseous
substances. This process is continued till the breakdown of
2. Results and Discussion
the oil takes place. Thus the presence of inhibitors inside
In total thirty-two samples were prepared and thermally
the mineral oil improves its dielectric strength thereby
stressed at different temperatures, and then the above
extending the service life of transformers.
mentioned diagnostic tests were performed in
2.2 Interfacial Tension
accordance to ASTM standards. The complete
description of these tests is discussed in the subsequent Interfacial tension of inhibited and uninhibited oil samples
sub-sections. aged at different accelerated temperatures has been
determined, using the test set up shown in Figure 3 (a). The
2.1 Breakdown Voltage
changes in IFT as per the accelerated aging are shown in
Breakdown voltage test has been performed on inhibited
Figure 3 (b).
and uninhibited oil sampels. Figure 2 (a) shows the BDV test
It was observed from the test results that there is a 26%
set up, and Figure 2 (b) details the change in BDV of
reduction in IFT of BTA inhibited oil sample at 1400C,
inhibited and uninhibited oil samples which were explored
whereas it is 36% in case of BTA inhibited oil sample at the
to different temperatures.
same temperature. IFT falls down to nearly 79% from its
In uninhibited oil sample, it has been observed that BDV
rated value at 2200C for BTA oil sample. At the same

Figure 2. (a) BDV Test Set up Installed at TIFAC-CORE Centre, NIT Hamirpur (b) Variation of BDV
of Inhibited and Uninhibited Mineral Oil Samples over Accelerated Temperatures

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Figure 3. (a) IFT Test set up Installed at TIFAC-CORE Centre, NIT Hamirpur (b) Comparison of
the Change in IFT of Inhibited and Uninhibited Mineral Oil Samples with Temperature

temperature, IFT reduces to 84% in case of DBPC inhibited uninhibited oil samples is quietly high as compared to that
sample. Similarly, the deterioration in IFT of uninhibited test of the samples having inhibitors. Based on the test results,
0 0
samples is 53% at 140 C, and 85% at 220 C. These 70% reduction in flash point of uninhibited oil sample at
significant decrements in IFT of all the test samples 2200C has been observed. At the same temperature,
indicate the presence of more oxidation contaminants. 52% and 48% decrements were found in case of BTA and
Comparatively, uninhibited test samples consist of more DBPC inhibited oil samples. Significant changes were
oxidation contaminants over the temperature as observed in uninhibited and mixed inhibited oil samples. It
compared to BTA and DBPC inhibited oil samples. Also it is due to the combustible products present in the oil, and
was observed from the test results that the effect of low molecular weight hydrocarbons. The breakdown of
accelerated aging on the IFT of DBPC sample is higher as the oil at higher temperatures produces a large quantity
compared to that of samples having BTA inhibitor. of low molecular weight hydro carbons. These hydro
2.3 Flash Point carbons reduce the flash point of the oil. The changes in
IFT of mixed inhibited samples were quietly similar to that
Flash point of inhibited and uninhibited oil samples
of uninhibited oil sample.
exposed to different temperatures has been determined.
The experimental test set up of flash point is shown in 2.4 Water Content
Figure 4 (a), and the results are detailed in Figure 4 (b). It Water content present within inhibited and uninhibited
has been observed from the results that the influence of aged samples has been determined. Figure 5(a) shows
accelerated thermal aging on the flash point of the test set up of Columetric Karl Fischer Titrator which

Figure 4. (a) Flash Point Test Set up Installed at TIFAC-CORE Centre, NIT Hamirpur (b) Variation
in Flash Point of Inhibited and Uninhibited Mineral Oil Samples with Temperature

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Figure 5. (a) Columetric Karl Fischer Titrator Set up Installed at TIFAC-CORE Centre, NIT Hamirpur (b) Change in
Water Content Present in Inhibited and Uninhibited samples for Different Temperatures

determines the water content of the samples. Figure 5(b) represents the base or reference line. It has been
shows the variation in water content of inhibited and observed from Figure 7(a)-(d) that the absorbance curve
uninhibited oil samples subjected to higher accelerated shifts towards the higher wavelengths as per the
temperatures. In case of DBPC and BTA inhibited oil accelerated aging temperatures. It is due to the
samples, the water content reaches its excessive level at presence of more oxidation contaminants and sludge
2200C. Similarly, the water content in uninhibited and particles. Also a relationship exists between the areas
mixed inhibited mineral oils reaches its deteriorated level under the absorbance curves (Table 2) and the total
0
at 180 C. amount of dissolved decay products in oil.
Therefore, a substantial increase in the water content of During accelerated aging tests, UV-spectrums of inhibited
uninhibited oil samples over the accelerated oil samples occupied less area under the absorbance
temperatures was observed. Thus, the oxidation curve. Whereas UV-spectrums areas of inhibited test
degradation in BTA and DBPC inhibited oil samples is low. samples are higher, and undetermined at 2200C. It
This is due to the continuous stability loss of the oils. As a indicates the effectiveness of inhibitors in terms of
result the oil becomes decomposed and oxidized after retarding the degradation rate of mineral oil. From Table
overheating at the higher accelerated temperatures. 2, it has been observed that there is a huge amount of
2.5 UV-Vis Spectroscopy sludge formation in all oil samples at 2200C. Hence the
aging test was terminated at 2200C. The absorption curve
To determine the oxidation stability of inhibited and
of uninhibited oil sample was completely deteriorated at
uninhibited oil samples explored to accelerated
2000C. In this stage, the color of all samples was quite
temperatures, UV-Vis spectroscopy test was performed.
The experimental set up of this test is shown in Figure 6. As
discussed above, UV spectrums of different aged
samples swing towards the higher wavelengths. The
trending of UV-Vis absorbance as a function of
wavelength for different types of aged samples is shown in
Figure 7 (a) to (d).
In Figure 7, UV spectrums of the samples which were aged
at different temperatures i.e. 1000C, 1200C, 1400C, 1600C,
1800C, 2000C and 2200C are represented by numbers
from 1 to 7 respectively. The red colored horizontal line Figure 6. UV-Vis Spectroscopy Set-up Installed
at TIFAC-core Centre, NIT Hamirpur

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Figure 7. Comparison of UV Visible Spectroscopy Results of Samples having (a) without Additive
(b) BTA Inhibitor (c) DBPC Inhibitor (d) Mixture of BTA and DBPC

Sample Base Line After aging After aging After aging After aging After aging After aging After aging
at 1000C at 1200C at 1400C at 1600C at 1800C at 2000C at 2200C
Uninhibited 9.26 29.11 97.49 130.39 192.43 232.36 463.92 Undefined
BTA Inhibited 9.24 28.27 96.77 126.31 181.65 192.48 320.15 434.49
DBPC Inhibited 9.27 27.17 92.21 129.17 185.72 194.11 335.18 488.59
Mixed Inhibited 9.22 30.49 98.26 133.57 182.36 215.18 325.35 494.28

Table 2. Area U nder UV-Vis Spectrums of Uninhibited and Inhibited Aged Samples

dark, and the contaminants in oil samples were clearly properties of insulation, let xi (where i varies from 1 to 4) be
visible. Thus the BTA and DBPC inhibitors significantly affect BDV, IFT, flashpoint and water content of inhibited and
the quality of the transformers insulation. uninhibited oil samples respectively. The percentage
3. Improvement in Insulation Properties improvement in the dielectric characteristics of inhibited
mineral transformer oil over temperatures is obtained
Based on the outcomes of different diagnostic tests it has
using (1), and given in Table 3.
been concluded that addition of inhibitors into the mineral
transformer oil improves the oxidation stability and the % improvement in xi of inhibited oil =
thermal performance. Moreover, these additives provide
Average change in xi of inhibited oil sample
improved thermal stability at higher temperatures. To 100 (1)
´
Average change in xi of uninhibited oil sample
determine the percentage improvement in various

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Sample type % increment in BDV % increment in IFT % increment in Flash point % decrement in water content
BTA inhibited 118.53 121.35 112.52 85.19
DBPC inhibited 115.26 123.38 117.00 82.45
Mixed inhibited 105.09 104.06 111.65 97.11

Table 3. Percentage Improvement in Different Characterisitcs of Inhibited Oil Samples Over Uninhibited Sample

The significant improvements in BDV, IFT, flash point and transformers insulation at higher temperatures. Also it was
water content of inhibited oil samples were obtained over found that the oil sample having mixture of BTA and DBPC
the accelerated temperatures. As per the accelerated inhibitors has poor thermal characteristics as compared
temperatures, BTA inhibited sample has an average to that of BTA and DBPC inhibited samples. The inhibitors
18.53% BDV increament over uninhibited oil sample. added in the oil sample significantly improve the quality of
Whereas, DBPC and mixed inhibited oil samples have BDV the insulation, thereby improving its service life time. The
increaments of 15.26% and 5.09% respectively. Thus the present paper provides an extensive data set and a
dielectric strength of the transformers insulation was comparative analysis on accelerated thermal aging of
improved by using additives. Similarly, BTA inhibited transformer oil inhibited with BTA, DBPC and mixed
sample has an average 21.35% increment in its IFT as additives and shall be extremely important for power
compared to uninhibited sample, whereas DBPC and transformers.
mixed inhibited oil samples have 23.38% and 4.06% Acknowledgement
increments. The percentage improvements in flash point
The authors are thankful to the authorities of the
of BTA, DBPC and mixed inhibited samples are 12.52,
TIFAC–CORE Centre and TEQIP-II of NIT Hamirpur India for
17.00 and 11.65% respectively. As per the variation in
providing the necessary facilities and financial aid wide
water content, BTA, DBPC, and mixed inhibited samples
grant number NIT/HMR/TEQIP-II/Research & Development-
have 14.81%, 17.55% and 2.9% decrement over
19/2015/2157-63 to perform the experiments and
uninhibited oil samples. Finally, it has been concluded
carrying out the present research. Authors are also
that the dielectric strength of BTA inhibted oil samples is
thankful to the Himachal Pradesh State Electricity Board
good over the different temperatures, whereas, IFT and
(HPSEB), India for providing the transformer oil samples.
flash points of DBPC samples are better over the
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November 2016 - January 2017 9
RESEARCH PAPERS

(moisture) content of soil by microwave over-heating, Trans. Dielectr. lectr. Insul., Vol.22, pp.1275-1282.
ASTM D 4643-08. [30]. A. Abu-Siada, (2016). “A novel method of measuring
[28]. N. A. Bakar, A. Abu-Siada, N. Das, and S. Islam, transformer oil inter facial tension using UV-Vis
(2013). “Effect of conducting materials on UV-Vis spectral spectroscopy”. IEEE Trans. Pow. Deliv., Vol.32, No.1, pp.1-
response characteristics”. Universal Journal Electr. 13.
Electron. Eng., pp.81-86. [31]. Standard practice for describing and measuring
[29]. N. A. Bakar, A. Abu-Siada, S. Islam, and M. F. El- performance of Ultraviolet, Visible, and Near-Infrared
Naggar, (2015). “A new technique to measure interfacial Spectrophotometers, ASTM E275-01 Standard, Vol.3,
tension of transformer oil using UV-Vis spectroscopy”. IEEE No.6, pp.72-81, 2001.

ABOUT THE AUTHORS


Chilaka Ranga received his B. Tech. Degree in Electrical and Electronics Engineering from Bapatla Engineering College,
Bapatla (AP), India in 2010. He received his M.Tech. Degree from National Institute of Technology, Hamirpur (HP), India, in 2012.
Presently he is pursuing his Ph.D. in the Department of Electrical Engineering at NIT, Hamirpur (HP). His areas of interest are
Performance Evaluation and Health Assessment of Power Transformers.

Dr. Ashwani Kumar Chandel has graduated in Electrical Engineering from Kerala University. He was awarded Postgraduation
Degree from Punjab Engineering College, Chandigarh. He was awarded Ph.D. Degree from Indian Institute of Technology,
Roorkee, India in 2005. Dr. Chandel joined the Department of Electrical Engineering, National Institute of Technology, Hamirpur,
HP, India, as Lecturer in 1991, where presently he is working as a Professor and Head of the Department. His research work has
been published in various International Journals of repute including IEEE, IEE, Elsevier Science, Taylor & Francis and others. He has
worked extensively in the area of Harmonic Estimation & Elimination, Condition Monitoring of Transformers and currently his
research interest continues in these fields. He is a Fellow of IETE, Member IEEE, and Life Member of ISTE.

Dr. Rajeevan Chandel received her B.E. Degree in Electronics and Communication Engineering from Thapar University Patiala,
India, in 1990. She is a double gold medalist of Himachal Pradesh University, Shimla, India, in Pre–University and Pre–Engineering
in 1985 and 1986, respectively. She received her M.Tech. Degree in Integrated Electronics and Circuits from Indian Institute of
Technology (IIT), Delhi, India, in 1997. She was awarded Ph.D. degree from IIT Roorkee, India, under QIP scheme of Government
of India in 2005. She joined the Department of Electronics and Communication Engineering, NIT Hamirpur, HP India, as a
lecturer in 1990, where presently she is working as a Professor and has been the Head of the Department twice. She has five
MHRD, MCIT sponsored projects to her credit from the Government of India. She has over 50 research papers in International
and National Journals of repute and over 75 in Conferences. Her research interest includes Electronics Circuit Modelling, and
Low–Power VLSI Design. She is a Fellow of IETE(I), Member of IEEE and Life Member of ISTE(I), ISSS.

10 i-manager’s Journal on Power Systems Engineering, Vol. 4 l


No. 4 l
November 2016 - January 2017

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