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ICMM502
ICMM502
Sponsored by
Defence Research and Development Organisation (DRDO)
In association with
MRSI, Hyderabad Chapter
Book of Abstracts
Organized by
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ISBN: 978-93-5396-620-1
Editors:
Dr. G. Neeraja Rani, Professor, Geethanjali College of Engineering and Technology
Dr. J. Anjaiah, Professor, Geethanjali College of Engineering and Technology
Dr. P. Raju, Associate Professor, Geethanjali College of Engineering and Technology
Dr. M. Aruna Bharathi, Professor, Geethanjali College of Engineering and Technology
Conference Chair/convenor
Dr. R. S. Raju
Dr. G. Neeraja Rani
Dr. J. Anjaiah
Dr. M. Aruna Bharathi
Message
The conference aims to bring leading academicians, experts, innovative researchers and students
under one roof. The conference is a platform for intelligent minds to propel their potential for
driving technological innovation. It promotes a wonderful future for those who would like to master
Material Science.
I congratulate the team for their efforts to provide enriching experience to the participants. I hope
that the team would take the beacon of dynamism further.
Message
It is a moment of honour to announce that our college is hosting the First ever International
Conference on Multifunctional Materials (ICMM 2019), in association with MRSI, Hyderabad
Chapter from 19th- 21st December, 2019.
The rudimentary objective of the conference is to provide a platform for academicians, researchers,
engineers and industrialists to deliberate on the emerging trends in the field, sustainability and
challenges encountered pertaining to the Multifunctionality of Materials.
ICMM provides an excellent opportunity and space to the dynamic minds to learn and express their
ideas. I firmly believe that this conference would be a trend setter in arousing the curiosity of
researchers.
I would like to express my admiration and appreciation to the organizing committee for their
commendable effort. I wish the conference will pave a new path towards the best possible results
that would meet the demands of the fast growing industry.
I convey my warm greetings and felicitations to the Organizing Committee as well as the
participants.
I am delighted to know that Geethanjali College of Engineering and Technology is hosting its First
International Conference on Multifunctional Materials (ICMM 2019), in association with MRSI,
Hyderabad Chapter from 19th- 21st December, 2019.
The conference would provide a platform for researchers, scientists, faculty members to present
their innovative ideas and technological advances. In a nutshell, the conference promises to reach
greater heights of excellence.
I extend my best wishes to the Organizing Committee, delegates, participants and the team for the
success of the conference. I also congratulate the Management for initiating such pioneering step.
PT 1: Safer Multifunctional Sunscreen Active Ingredient via Native Atomic Defects Promotion – Concept to Commerce
...................................................................................................................................................................... 30
A. R. Kulkarni .................................................................................................................................................... 30
PT 2: Influence of noble metal ions on electrical and optical characteristics of non-conventional animonate glass
ceramics- possible materials for NLO and piezo-optical devices..................................................................... 31
J. Ashok and N. Veeraiah* ................................................................................................................................ 31
PT 3: Microwave Resonators with Bulk and Thin Film Solids .......................................................................... 32
K.C. James Raju ................................................................................................................................................ 32
PT 4: Indigenous Nanomaterials-Based Technologies A “Make in India” Initiative ......................................... 33
Tata Narasinga Rao .......................................................................................................................................... 33
PT 5: Thermal efficient materials for electronic applications ......................................................................... 34
J. Janardhana Reddy, V.V. Bhanu Prasad ......................................................................................................... 34
PT 6: Development of oxide based functional materials for magnetic refrigeration....................................... 35
Sunkara V. Manorama ...................................................................................................................................... 35
PT 7: Synthesis of carbon nanomaterials composites and their interfacial effects on properties ................... 36
Dr. P.K. JAIN ...................................................................................................................................................... 36
PT 8: Perspective functional electronics on a base Synergistic processes ....................................................... 37
E. N. Moos......................................................................................................................................................... 37
PT 9: Nano-carbon materials from the viewpoints of practical field electron emitters .................................. 38
1,2* 1
Masahiro Sasaki and Yoichi Yamada .......................................................................................................... 38
PT 10: Modeling and Synthesis of High-Temperature Superconductors: Problems and Perspectives ............. 39
Andrei I. Sechnoi ............................................................................................................................................... 39
IT 1: Mosquito Bite Inspired Microneedle Technology for Health care Applications ...................................... 40
Ganesh Kumar Mani ......................................................................................................................................... 40
IT 2: Studies of Conducting polymers and its applications .............................................................................. 41
Dr. M.V.N. Ambika prasad ................................................................................................................................ 41
IT 3: Metal Oxide Nanostrutures for Gas Sensing ........................................................................................... 43
K. Venkateswara Rao ........................................................................................................................................ 43
IT 4: Photonic Bandgap Crystals: Physics, Fabrication and Applications ......................................................... 44
B.V.R. Tata* ...................................................................................................................................................... 44
IT 5: Inorganic waste management: for better tomorrow .............................................................................. 45
1,2
D D Ramteke .................................................................................................................................................. 45
ICMM: 103 | Raman, FTIR and XPS Studies of Oxyfluoro -Phosphosilicate Glasses ........................................ 47
1,2 3* 1 4* 4
Vootukuru John Reddy , H. Umamaheshwari R. Padmasuwarna , Venkata Krishnaiah Kummara , Ravi Nirlakalla
.......................................................................................................................................................................... 47
ICMM: 108 | Fluorescent Trilayer OLED Device: an Electrical and Optical Characterization Based Simulation48
Arvind Sharma, Sagar Bhattarai, and T. D. Das* ............................................................................................. 48
ICMM: 109 | CONCEPT OF DEVELOPING THE MULTI FUNCTIONALFIXTURES USING MAGNET RHEOLOGICAL FLUID. 49
GANDLA UDAYASREE ........................................................................................................................................ 49
ICMM:101 | Complex permittivity and Permeability Properties Analysis of NiCuZn Ferrite-Polymer Nanocomposites
for EMI Suppressor Applications .................................................................................................................. 196
P. Raju*, Ch. Kalyani, J. Shankar, J. Anjaiah, G. NeerajaRani ......................................................................... 196
ICMM:111 | Optical Properties of Samarium doped Zinc Lithium Borate Glasses ........................................ 197
1 18 2
Kavita Hanumar , B G Hegde and N H Ayachit ........................................................................................... 197
ICMM:112 | Exploration of Lead-free Magneto-electric 0.85(Na0.49K0.9Bi0.5TiO3) – 0.15(CoFe2O4) Particulate Composite
for Sensor Application ................................................................................................................................. 198
1 2* 1*
Munendrapal , Adiraj Srinivas Saket Asthana ........................................................................................... 198
ICMM:115 | Magnetic and Dielectric Studies of Ba0.5Sr0.5Fe12O19 Prepared by Solid State Reaction Method199
1 1 1,*
V. Argish , M.G. Shalini , Subasa. C. Sahoo ................................................................................................. 199
ICMM:116 | Thermo Magneto Electric Effects in Ferromagnetic Mild Steel, Cobalt and Nickel as Core Materials in
Vertical set up: Comparative Study .............................................................................................................. 200
1* 2 3
Mandava Sridhar , G. Patrick and J. Kishore Babu .................................................................................... 200
ICMM:118 | Vegetable Assisted the Green Synthesis of Gold Nanostructures and its Nonlinear Optical Properties 201
1* 2 2
Ramya Emusani , L. Jyothi , D. Narayana Rao ............................................................................................. 201
ICMM:121 | Effect of Doping on Defect Modes of 2D Photonic Band Gap Crystals ...................................... 202
*
Saranya Narayanan, B.V.R Tata .................................................................................................................... 202
ICMM:130 | Non-linear Optical Studies of Cadmium Magnesium Oxalate Crystals Grown by Gel Method .. 203
ICMM-2019 19 Book of Abstracts
1 1 1
Mangala M Sanjeevannanavar , Jagannatha N *, and Rohith P.S. .............................................................. 203
ICMM:131 | Influence of Alkaline Earths on EPR spectra of Lithium Borate Glasses Doped with Fe (III) ions.204
1 2
Ashok Bhogi and P. Kistaiah ......................................................................................................................... 204
3+
ICMM:136 | Luminescence Characteristics of Dy Doped Borofluorophosphate Glasses for White Emission
Applications ................................................................................................................................................. 205
1 2 2 2 2 2*
Jismon Sebastian , Subash Gopi , Sreeja E , Adon Jose , Krishnapriya T , P.R. Biju ..................................... 205
ICMM:144 | Structural, Thermal and Optical Properties of 50Bi2O3-15MO-20B2O3-15Li2O (where M= Zn, Cd, Ba and
Pb) Glasses................................................................................................................................................... 206
a b a *
J. Bhemarajam, G. Upender, M. Prasad ..................................................................................................... 206
ICMM:146 | Synthesis, Structural and Magnetic Properties of Multifunctional Spinel Ferrite Nanoparticles for Data
Storage Applications .................................................................................................................................... 207
Shubhada Thorat*, Pooja Khedekar, Deepali Andhare, Supriya Patade, K. M. Jadhav .................................. 207
ICMM:154 | Structural and Optical Properties of ZnS/Graphene Nanocomposite Films Formed by Homemade Spray
Pyrolysis Unit ............................................................................................................................................... 208
1* 1 2
V.H.Choudapur , S.B.Kapatkar , N.H.Ayachit ............................................................................................... 208
ICMM:161 | Photoluminescence in KMgAlF6 ............................................................................................... 209
1* 2 1
Vartika S. Singh , P. D. Belsare , S. V. Moharil .......................................................................................... 209
ICMM:162 | Rare Earth Based Insulating Nano Crystals for Plasma Display Panels ...................................... 210
1 2 1 1 2,
P. Chandar Rao , Vishnu V. Jaiswal , G. Ravinder , C. J. Sreelatha , D. Haranath ........................................ 210
ICMM:165 | Low Temperature Synthesis, Structural, Cation Distribution and Magnetic Studies of Cobalt Ferrite
Nanoparticles .............................................................................................................................................. 211
Farha Naaz, Aqsa Samreen, Shaikh Saima Anam, Shaikh Zeba Anjum, K.M. Jadhav ..................................... 211
ICMM:167 | Magnetic and Dielectric properties of Sm and Bi Substituted Gadolinium Iron Garnet ............ 212
*
Aakansha, S.Ravi ........................................................................................................................................... 212
ICMM:168 | A Comprehensive Device Modelling Of Solid-State Dye Sensitized Solar Cell by MATLAB ........ 213
1,a 2,b 2,c
Omhari Dubey , Sarvesh K Gupta and Abhishek K Gupta ....................................................................... 213
ICMM:169 | Solid State Route Preparation, Characterization and Electrical Properties of
NiCuZnFe2O4/Paraformaldehyde Nanocomposites ...................................................................................... 214
P. Raju*, S. Rajesham, J. Shankar, J. Anjaiah, G. Neeraja Rani ....................................................................... 214
3+
ICMM:170 | Effect of Cr Substitution on Electromagnetic Properties of Nanocrystalline MgCuMn Ferrites
Synthesized by Sol-Gel Method. .................................................................................................................. 215
1* 2 2 3
T. Ramesh , D. Bhavya , K. Ruchitha Devi and S. Senthil Kumar ................................................................. 215
ICMM:171 | Theoretical Study on Structural and Optical Properties of PEO & NH4SCN based Solid Polymer Electrolyte
.................................................................................................................................................................... 216
a b
Vinay Shukla , Abhishek Kumar Gupta* , Sarvesh Kumar Gupta .................................................................. 216
ICMM:205 | Dielectric Relaxation Studies of Aqueous Diethylamine from 10MHz To 50GHz Using A Time Domain
Reflectometry .............................................................................................................................................. 217
1 1*
A.R. Deshmukh and A.C. Kumbharkhane .................................................................................................... 217
2+
ICMM:206 | Dielectric, Spectral studies of gel grown Mg Doped Copper Cadmium Oxalate Single Crystal 218
1 1* 1
Rohith P S , Dr. Jagannatha N , Pradeepkumar K V ..................................................................................... 218
ICMM:208 | Novel In-situ Synthesis of 1D ZnWO4 Nanorods Decorated 2D g-C3N4 Nanosheets For Enhanced Visible-
Light-Driven Photocatalysis ......................................................................................................................... 219
1 1 1 1, # 2, # 1,
Ravindranadh Koutavarapu , Bathula Babu , Ch. Venkata Reddy , Kisoo Yoo , Migyung Cho , Jaesool Shim * 219
ICMM:213 | Resistive Switching Characteristics of Pt/TiO 2/Al Structure under Optical Illumination ........... 220
1,2 1 1 1 1
Kiran D. More , Devidas I. Halge , Pooja M. Khanzode , Vijaykiran N. Narwade , Sumayya Begum , Shivaji G.
1 3 4 1,*
Munde , Jagdish W. Dadge , Abhimanyu S. Rana and Kashinath A. Bogle ................................................ 220
ICMM:216 | Application of Synthesized Tetragonal Structured Zirconium Oxide Nanoparticle on Victoria Blue B and
Acridine Orange Dye .................................................................................................................................... 221
1 1 2 1
Santhosh A.M , Yogendra K , Mahadevan K.M , Madhusudhana N ............................................................. 221
ICMM:222 | Enhanced Electrical Properties of Sr(Bi3.9La0.1)(Ti3.975Zr0.025)O15 Ceramic with the Doping of Nd 222
1 2 1 3
B. Mamatha *, K. Ashok , G. Neeraja Rani and A. R. James ........................................................................ 222
2+
ICMM:224 | Growth, Optical and Thermal Properties on Co Doped Copper Tartrate Single Crystals at Different
Environmental Condition. ............................................................................................................................ 223
1 1* 1
Pradeepkumar K V , Jagannatha N , Rohith P S ........................................................................................... 223
16.45- Poster Presentations ICMM-101, 111, 112,115, 116, 118, 130, 131, 136, 144, 146, 161, 162, 167, 168, 170, 205, 206, 213, 222, 224, 226,
18.00
230, 234, 235, 236, 238, 249, 250, 268, 284, 286, 289, 290, 295, 301, 401, 405, 407, 422, 432, 503, 504, 505, 519, 520, 521, 522, 531, 538,
539, 545, 608, 616, 627,631, 633, 635. 636, 740, 2105, 2111, 2128, 2131, 2145, 2146, 2147
A. R. Kulkarni
Department of Metallurgical
Engineering and Materials Science,
Indian Institute of Technology- Bombay, Mumbai-400076
Abstract
Native atomic defects promotion in ZnO nanocrystals (NCs) has immense potential for
delivering innovative solutions for many challenging societal problems. In our laboratory,we focus
on developing different process chemistry to promote atomic defects in ZnO NCs. In this talk,
emphasis will be given to our recent innovation in photoprotection by taking advantage of defects
enabled optical transitions and surface chemistry in ZnO NCs. The defects promoted ZnO NCs are
proven to be a safer multifunctional sunscreen active ingredient by eliminating harmful UVA
emission usually found in commercial ZnO. In addition to this it offers cosmetic value along with
broadband UV protection. We have scaled up the process chemistry for defect-rich ZnO NCs to yield
10's of grams and successfully developed phase transfer techniques that allow an easy formulation
development for various skincare products. Considering the application potential and advancement
offered in the area of photoprotection, a leading specialty chemical industry is associating with us
for possible technology transfer. In view of this, our experience so far in the line of translational
research for multifunctional sunscreen active ingredient will be shared.
Abstract
Sb2O3based glass ceramics are known due to their high density and high refractive index. By
adding traces of noble transition metal ions like Ag and Au, these materials find potential
applications in several photonic, plasmonic, NLO, piezo-optical devices etc. Further, by admixing a
small quantity of alkali oxides like Na2O, these materials exhibit high magnitude of ionic
conductivity and hence can also be used as electrolytes in solid state batteries. In this talk we
present, details of synthesis of Na2O-Sb2O3:Au2O3/Ag2O glass ceramics, characterization of the
samples by XRD, SEM, TEM, EDS, XPS and DSC techniques. Characterization studies indicated
samples are embedded with multiple crystallites composed of antimony ions, AuO and AgO
nanoparticles. Structural analysis is carried out by means of OA, IR, Raman and PL spectral studies.
OA spectra exhibited SPR bands. Finally, quantitative studies on dielectric properties, impedance
spectra and σac over wide ranges of frequency and temperature were performed. Observed
dispersion of dielectric parameters is discussed in the light of various polarization mechanisms.
Dipolar orientational effects exhibited by electric moduli spectra were analyzed using Cole-Cole
plots. Variation of σac in the low temperature region is discussed using QMT model. Analysis of the
results of σdc indicated SPH model is valid in high temperature region while its variation in the low
temperature region follows VRH model. THG beam and piezo-optical coefficients were found to be
the maximal for the samples mixed with small quantities of Au2O3. The positron annihilation
spectroscopy studies have indicated decrease of free volume space with increase of Au 2O3
concentration. The comprehensive analysis of the results of electrical properties (together with the
results of THG and PAS studies) indicated the samples doped with minute quantities of noble metal
oxides exhibit high conductivity and such materials are useful as solid electrolytes.
Resonators are an important component in microwave circuits used for frequency control. It
was one of the components that were difficult to miniaturize. Initially they were made with
waveguide cavities which are heavy and bulky. They could be replaced with solids with high
dielectric constant and low dielectric loss with low values of temperature coefficient of resonant
frequency. They came to be known as Dielectric Resonators. They brought down the dimension of
resonators from cm range to mm range. However for integration into miniature integrated circuits,
they were insufficient. Then the solutions found out mainly made use of the small acoustic
wavelengths in solids generated by electro acoustic conversion using piezoelectric effect. Using
piezoelectric substrates, surface acoustic wave (SAW) resonators came up. Further miniaturization
became possible once thin films of these materials were used. Resonators made with such thin
films are Film Bulk Acoustic Resonators (FBAR) and High Overtone Bulk Acoustic Resonators (HBAR).
An alternate method that has come up for microwave resonators is with micromachining. With
micromachining, it is possible to fabricate miniature mechanical resonant structures where as their
dimensions decrease, the resonant frequency will be reaching the lower GHz range. Using materials
like carbon nano tubes, the resonant frequency could reach GHz range. These miniaturized devices
are becoming more important for 5G applications as they employ large number of wireless
channels. Another area where they find increasing applications is with sensors. In this talk these
resonators will be introduced and the results generated by the author and his group will be
presented.
Keywords: Microwave Resonators; Electro acoustic resonance; Piezoelectrics; Dielectric
Resonators; FBAR.
Acknowledgements
UGC, DST, DRDO, DAE.
Reference James Raju KC, Miniaturization of Microwave Resonators, DOI:
10.31031/COJEC.2018.01.000504, COJ Electronics & Communications.
Abstract
Abstract
The continued drive for miniature electronic devices of high frequency and high power
necessitated the development of high thermal efficient materials. Thermal efficient materials
should have primary properties of high thermal conductivity and low coefficient of thermal
expansion (matching to devices) to avoid thermal shock failures and lower in density for space and
avionic applications apart from other application specified electromagnetic, electrical insulation
properties. While usual heat sinks materials for laptops are aluminium and copper, but their high
CTE, electrical conductivity are barriers for the electronic substrate applications. An overview of
different materials for high thermal conductivity is presented.
DMRL has been developing these thermally efficient materials through powder metallurgy
route by hot pressing techniques. The optimized hot pressing conditions resulted in compacts
having densities near to theoretical densities. Aluminium nitride made at DMRL density was 3.24
g/cc and the CTE 4.83 ppm/K and thermal conductivity at RT was 200 W/m.K. These compacts were
characterized for their thermal conductivity over a temperature range up to 10000 C. The
composites conductivity decreased with increasing silicon carbide content or temperature while
Copper-copper coated carbon fiber composites properties are directional. Aluminum-70% SiC
fabricated at DMRL had density 2.94 g/cc, CTE 7 ppm/K, TC 110 W/m.K.
Sunkara V. Manorama
Nanomaterials Laboratory, Polymers and
Functional Materials Division,
CSIR-Indian Institute of Chemical Technology, Hyderabad-500 007, Telangana. India.
Email: manorama@iict.res.in and manorama@csiriict.in, web site: http://www.iictindia.org
Abstract
Materials Science is a fascinating field of science encompassing the design of materials for
applications not only for devices, healthcare, medicinal products and many more. It has the
mandate to improve quality of life. Undoubtedly, research and technological advances in materials
science plays an important role in strengthening, stimulating and sustaining the economic growth of
the country. In recent years, materials research has spawned countless advances in areas such as
energy both production and storage, consumer commodities, information technologies, medicine,
defense and agricultural sectors.
Imparting multi-functionality is one of the current thrust areas of research worldwide. In this
context semiconducting oxides have been surface engineering and made suitable for diverse
applications like in gas sensors, catalysis including photocatalysis, solar cells etc. Surface
engineering also makes these inorganic oxides suitable for applications in biology and biomedical
devices. Magnetic nanoparticle based structures have been designed as MRI contarst agents, for
PDT applications etc. In another such attempt magnetic materials are being explored as energy
materails.
Abstract
E. N. Moos
Ryazan State University, Department of Physics and
Mathematics, Ryazan, Russia
Abstract
Abstract
Nano-carbon materials such as graphene, fullerene, carbon nanotubes and their related
materials are known to possess quite various and unique electronical properties. Since some of
these have intrinsic sharp shapes with high aspect ratios, resulting in extremely large geometrical
field enhancement, the effects on field emission have already demonstrated by many researchers.
In my presentation, I will introduce the unique and unrevealed field emission features of nano-
carbon materials besides their geometrical field enhancement, which are applicable for practical
field emitters, and discuss the physics behind these field emission features. Here I will focus on the
field emissions from vacuum-arc prepared carbon film, fully graphitized pencil lead and C60
adsorbed on emitter tips. (1) Amorphous carbon thin films were deposited on W and Si tips by
means of arc-discharge of graphite rods in vacuum. These tips have shown field emission features
corresponding to very low effective work functions, although the macroscopic work function of this
film remains similar to that of graphite. The origin of these features is discussed on the basis of
scanning tunneling microscopy (STM) observations [1]. (2) The simply broken and completely
graphitized edges of pencil leads also showed high currents at very low applied fields, although the
tips were not sharpened. These features can be originated from graphene on the basis of the
energy distributions of emitted electrons [2]. (3) We have observed that the C60 deposited on W
tips gives very unique field emission microscopy (FEM) patterns, that is very similar to that of large
atomic-like orbitals, corresponding to the super-atomic molecular orbitals (SAMO) [3]. This suggests
that the electron orbitals of unoccupied states can be easily visualized by using FEM, which will
open the possibility to develop electronics based on the unoccupied states.
Keywords: field electron emission; nano-carbon materials; amorphous carbon; graphene; C60
References
S. Nagashima, et al., J. Vac. Sci. Tech. B 28, C2A13, 2010.
Y. Nishiyama et al., IVNC-IVESC 2019, 22-26 July, 2019, Cincinnati, OH USA.
M. Feng, et al., Science 320, 359 2008.
Andrei I. Sechnoi
Samara University, Gymnasium No. 3, Samara, Russia
Abstract
Abstract
Always there is great demand for in vivo testing to understand more about body metabolism
to provide effective diagnosis and therapy. Currently no industrial technology available for single
cell especially for pH, temperature or other cell metabolites. Compared to conventional sensors,
research on single cell microneedle sensor is still in its infancy due to their difficulty in fabrication,
poor flexibility, toxicity, scarcity of nanomaterials, instrumentation difficulty and poor stability.
Meanwhile painless micro/nano needles have been widely used for extraction of skin interstitial
fluid, vaccine and drug delivery over the past two decades, but their potential as sensor remains
largely unexplored. Therefore, we aim to develop single microneedle-based sensor for detection of
pH and other cell metabolites in single cell. A ~4.8 µm pH sensor was fabricated and tested it in-
vivo/in-vitro sensing capability was demonstrated. High stability and sensitivity make this novel pH
sensing microneedle is a cost effective and easy fabrication tool for biological sensing especially at
the single cell level. The developed sensor exhibited the Nernstian response of -46 mV/pH. The
fabricated microneedle sensor ability is proven by in vivo testing in mice cerebrospinal fluid (CSF)
and bladder. The pH sensor reported here is totally reversible and results were reproducible after
several routine testing. This type of sensor development definitely will bring new innovative ideas
that have the huge potential for drug development while continuous metamorphosis observation.
Keywords: Microneedle; Sensor, Nanosheets, Healthcare; Mosquito bite
Acknowledgements
Authors wish to express their sincere thanks to the Micro/Nano Technology Center (MNTC), Tokai
University (Shonan Campus), Japan for their infrastructural and financial support. Also the fellow
thanks to Japan Society for the Promotion of Science for funding support (Grant ID : P19076).
Reference
G.K. Mani, K. Miyakoda, A. Saito, Y. Yasoda, K. Kajiwara, M. Kimura, K. Tsuchiya, ACS Appl. Mater.
Interfaces 9, 21651–21659, 2017
G.K. Mani, M. Morohoshi, Y. Yasoda, S. Yokoyama, H. Kimura, K. Tsuchiya, ACS Appl. Mater.
Interfaces, 9, 5193–5203, 2017
Abstract
Polymers by virtue of their light weight and greater ease of fabrication have replaced and
are continuing to replace metals in several areas of application. The idea that plastics could be
made to conduct electricity would have been considered to be absurd. Indeed, plastics have been
extensively used by electronic industry because of their very good insulating property. This narrow
perspective is rapidly changing as new class of polymers known as conducting polymers or electro
active polymers are being discovered. For more than two decades now, researchers have shown
that certain class of polymers which are conjugated (those possess extended π – conjugation along
polymer backbone), exhibit semi-conducting behavior. The discovery of doping in polymers has led
to further dramatic increase in the conductivity of such conjugated polymers to values as high as
105 Scm-1. The discovery of these conducting polymers has opened up new frontiers in material
Chemistry and Physics.
The Noble Prize of the millennium awarded to Shirakawa, Heeger and Mac Diarmaid in
Chemistry for the year 2000 for their contribution to conducting polymers, is a great recognition of
the “dawn of new plastic age”. Polyaniline (PANI) has emerged as one of the most promising
conducting polymers, because of its wide spread applications and due to the combination of unique
properties like simple preparation and doping procedure, good environmental stability, relatively
high conductivity and low cost. The increase concern about environmental protection has led to
continuous expansion in sensor development. The inorganic–organic composites containing
polymer as the organic base and Tungsten oxide, Cobalt oxide and Cerium oxide as inorganic part
have been used for studying its humidity sensing.. These composites have been synthesized by in
situ deposition technique by placing fine graded WO3, CeO2 and Co3O4 in polymerization mixture
of aniline. The results are well supported by FTIR spectral analysis, Scanning Electron Microscopy,
XRD and Conductivity measurements. High temperature conductivity measurements show thermal
activated behavior. The change in resistance with respect to percent humidity (RH) is observed. The
composites in the pellet form exhibit almost linear behavior within a chosen range of humidity
ranging between 10 and 95% RH. It is observed that PANI- WO3, PANI- CeO2 PANI- Co3O4
composites are promising materials for humidity sensors.
K. Venkateswara Rao
Centre for Nanoscience and Technology,
Institute of Science and Technology,
JNTU Hyderabad, India
Abstract
Studies on semiconducting metal oxides for high precision chemiresistive gas sensors has
attracted lot of attention because of their advantages like flexibility, low power consumption, easy
production and miniaturization for domestic and industrial applications. When these metal oxides
form various nanostructures based on the morphology variation, a significant effect on
chemisorption or physisorption process during detection of toxic gases are observed. The current
study highlights the design and mechanisms of different metal oxides nanostructures like nanorods,
nano-rice shaped, nanoflowers, and nanosheets for sensing hazardous gases. The morphology of
the synthesized nanostructures was confirmed by electron microscope. The phase and crystallite
size were elucidated using X-ray diffraction studies. The functional groups present, were verified by
Fourier transform infrared spectroscopy. The results show that sensing material and the structure
of the sensing layer plays a crucial role in analytical gas sensing characteristics like sensitivity,
selectivity, response and recovery time and optimum operating temperatures due to various factors
like surface area, porosity, uniform alignment of nanostructures and availability of active sites for
adsorption/ desorption of target gases.
B.V.R. Tata*
School of Physics, University of Hyderabad,
Gachibowli, Hyderabad-50004, India
*Corresponding author. Mobile: (+91) 9444463933;
E-mail:bvrtata@uohyd.ac.in
Abstract
Advances in the synthesis of nearly monodisperse colloidal nanoparticles have made it
possible to fabricate crystalline arrays of nanoparticles (known popularly as Colloidal Nano
Crystalline Arrays) with lattice parameters close to the wavelength of light. Light travelling through
such crystals experiences a periodic variation of refractive index, analogous to periodic potential
energy of an electron in an atomic crystal. This variation in refractive index in three dimensions with
hundreds of nanometres periodicity is responsible for photonic band structure in these crystals.
Thus these crystals are also known as photonic crystals/photonic band gap (PBG) crystals and have
several emerging applications such as Bragg diffraction devices, optical filters and switches,
photonic bio-sensors, non-bleachable display materials etc. Large single crystalline domains are
crucial for some of these applications and lithography based approaches are unrealistic. The talk
presents an overview of self-assembly methods employed in my lab for fabricating PBG crystals
using, polystyrene, silica, and stimuli-responsive poly(N-isopropylacrylamide)(PNIPAM) nanogel
particles. Issues involved in impregnating stimuli-responsive microgel particles with semi-
conductor quantum dots for fabricating photonic crystal alloys and Holographic Optical Tweezers
for fabricating seed crystals with desired symmetry and lattice constants will also be discussed.
PBG crystals are capable of manipulating the interaction of light with matter at the micro/nano
scale. This property finds several applications as bio-sensors, non-bleachable display materials,
visual strain gauges etc. and the talk presents some of these applications.
Keywords: Photonic Crystals; Photonic band gap; Colloidal Nanoparticles; Colloidal crystals
Acknowledgements
Author acknowledges my past students J.Brijitta, R.G.Joshi, D.K.Gupta, D. Karthickeyan and P.K.
Mohanty for their contributions to this area of research and for the discussions.
References
1. R. G. Joshi, D. Karthickeyan, D. K. Gupta, B.V.R. Tata, Colloids and Surfaces A: 558, 600, (2018).
2. D.K. Gupta, B.V.R. Tata and T.R. Ravindran, Applied Optics, 57, 8374 (2018).
3. D. Karthickeyan, R. G. Joshi, and B. V. R. Tata, J. Chem. Phys. 146, 224503-8 (2017).
4. B.V.R. Tata and R. G. Joshi , SMC Bulletin 6, 69 (2015).
5. B.V.R. Tata, R.G. Joshi, D.K. Gupta, J. Brijitta and Baldev Raj, Current Sci., 103, 1175 (2012).
D D Ramteke1,2
1
Universita' degli Studi di Padova, Dipartimento di
Ingegneria Industriale Edificio Ex Fisica Tecnica,
Via Marzolo, 9, 35131 Padova, Italy
2
Centre for Functional and Surface Functionalized Glass, Alexander Dubček University of Trenčín,
Slovakia
Contact: - https://ddphyvnit.wixsite.com/mysite
Abstract
Stabilization of waste is the main challenge in today’s world. The change in life style and
living standards of human beings produces billions of tons of waste every day. Stabilization of these
waste is the key demand for the environment protection. Stabilization of inorganic waste is possible
by using the glasses, but main criticism is related to costs and energy use. Also effectiveness
depends on the starting materials e.g. silica-rich waste favor the obtainment of glass, iron-rich
wastes affect the functionalities, influencing the porosity in cellular glass-based materials as well as
catalytic, magnetic, optical and electrical properties. Engineered formulation may lead to reduction
in the processing cost and energy required in the solid waste management. Stabilization of
industrial slag in the glass matrix is the best example of inorganic waste management engineering.
For the successful stabilization of inorganic waste multidisciplinary approach is crucial. Alkali
activated materials are the major step in this direction. These materials are the output of the
reaction of an alumino-silicate raw material in alkaline media (in general often referred as geo-
polymers). In alkaline aqueous media, alumino silicate compounds form ‘inorganic oligomers’
results in zeolite like gel formation. This gel consist a network of [SiO4] and [AlO4] tetrahedral
surrounded by alkali ions for the charge compensation. The alkali ions remain substantially
‘trapped’ in the gel, for an optimum Al2O3/SiO2 balance in starting materials, with the achievement
of chemically stable products. The stability can be further tested by entrapping pollutant from
industry. With entrapment of air bubble by using surfactant followed by firing, one can form cellular
glass-ceramics. Other method of waste management includes zeolite formation by using NaAlO2
and phosphoric acid based geo-polymers. These recycled product are useful in the building industry
and as a potential electromagnetic shielding.
Lanthanide (Ln3+) doped oxyfluoride glasses have been investigated for diverse applications such as
lasers, optical amplifiers, laser cooling and optical waveguides. In this work, we have prepared
bismuth-phosphosilicate glasses with the chemical composition of 50 P2O5 + 25 NaF2 + 10 SiO2 +15
Bi2O3 (PNfSiBi) by usual melt-quenching method. Structural investigations were performed through
fourier transform infrared (FTIR), Raman and x-ray photoelectron spectroscopy (XPS) for PNfSiBi
glasses. FTIR spectrum reveals the vibrational modes at 370, 412, 468, 904, 1215, 1536, 1648, 1742,
2360, 3603 and 3736 cm-1 in the range of 400 – 4000 cm-1. The laser micro-Raman unveiled different
vibrational bands centred at 531, 722, 1116, 1487, 1825, 2123 and 2646 cm-1 recorded from 100 –
3000 cm-1. Highest intense band was positioned for PNfSiBi glasses at 1116 cm-1 which is owing to
symmetric stretching of non – bridging oxygen on a Q2P tetrahedron. Elemental compositions and
binding energies of elements were explored from XPS analysis. Binding energies of PNfSiBi glasses
were obtained as 157 and 163 eV for bismuth (Bi) which situated in the 4f state (4f7/2 and 4f5/2), 100
eV for silicon (Si(2p)), 132 eV for phosphorous (P(2p)) and 1069.7 eV for (Na(1s)). From FTIR
analysis, a relatively low intensity of OH- ions in the PNfSiBi glasses could be a flexible candidate to
accommodate different Ln3+ ions to explore them for photonics applications.
GANDLA UDAYASREE
FeNi thin film has recently attracted enormous interest due to its large magneto-crystalline
anisotropy (Ku) and high saturation magnetization (MS) and acts as a viable candidate to replace
lower energy-density ferrites and Alnico magnets or rare-earth containing permanent magnets in
elevated temperature applications [1]. In this work, we report systematic investigations of tuning
magnetic anisotropy, structural, magnetic propertiesand magnetic domain structures of Fe1-
xNix(x=49-57) thin films. All the Fe1-xNixfilms were prepared by using magnetron sputtering
technique directly on Si(100) substrate kept at different substrate temperatures (TS). Crystal structure
of the films was characterized by using X-ray diffractometer (Rigaku TTRAX III 18 kW). Thickness
of the films were calibrated ex-situ using surface profilometer (Vecco Dektak 150). Room
temperature and temperature dependent magnetic properties were measured using vibrating sample
magnetometer (LakeShore VSM 7410). Magnetic domain images were analysed using Kerr
microscopy (Evico Magnetics, Ltd., Germany). Fe1-xNix films deposited at ambient temperature
exhibit weak L10 ordered structure. On the other hand, with increasingTS, the degree ofL10ordering is
enhanced up to 250 C for all the compositions.Magnetic studies reveal that the values of MS and Ku
increase progressively with increasing Fe content and exhibit a maximum of 720 emu/cc and 5.2106
erg/cc, respectively for Fe51Ni49 thin films prepared at 250C. The systematic investigations of the
effects of compositions and TS on the ordering and tuning of magnetic anisotropy and magnetic
domain structures in Fe1-xNix thin films will be presented in detail.
Keywords: FeNi films, Magnetic anisotropy, Magnetic domain
Dr. M. Lakshmi*
*
Vidya Jyothi Institute of Technology, Aziznagar Gate, C.B.Post, Hyderabad,
Telangana-500075, India.
Mobile: (+91) 9000207926; E-mail: lakshmimamilla@vjit.ac.in Please
Abstract
insert
photograp
The series of Cr-Zn and Cr-Co nanoferrites bearing the general chemical composition Cr x Zn
h of the
Fe2−x O4 and Cr x Co Fe2−x O4 (0 ≤ x ≤ 0.5) were successfully synthesized by sol–gel method.
presentingThe
prepared samples were annealed at 900 °C temperature for 3 hours. The aim of author. the present
comparative analysis was to investigate the impact of Cr 3+ ion substitution on the structural
properties of Cr–Zn and Cr-Co nanoferrite systems. Various characterization techniques such as
XRD, FTIR, SEM, TEM, etc. were used to investigate the structural properties of both nanoferrite
samples. XRD patterns of the both ferrite samples provide information about the existence of single
phase spinel structure.The average crystallite size was found to be ranging from 24–34 nm and 56-
75nm in case of Cr-Zn and Cr-Co ferrite systems respectively. The analysis revealed that with the
increase in Cr- concentration (x), the average crystallite size decreased graduallyin Cr-Zn ferrite
system but decreased non-linearly in Cr-Co ferrite system.FTIR spectra show that the bands υ1
and υ2 are found to shift towards the higher frequency side with substitution of Cr3+ ions. SEM and
TEM micrographs demonstrated that nanoparticles with narrow size distribution were obtained.
The results indicated that the amount of Cr contents significantly influenced the crystal morphology
and structural properties of both Cr-Zn and Cr-Co nanoferrites.
A series of glasses were prepared by melt quenching method in the glass system
10LiF-40Li2O-20RO-30Bi2O3 where R= Mg, Ca, Sr & Ba. XRD analysis has confirmed that the
samples are X- ray amorphous.The glass samples are characterized byopticalabsorption, Raman and
Fourier transform infrared spectroscopy(FTIR). Density of glass samples were measured using
Archimedes principle. It was found that, the densities of the glass increased in the order of MgO <
CaO < SrO < BaO as expected from the relative masses of the alkaline-earth ions. IR spectra of all
glass samples exhibited number of absorption peaks. With the introduction of LiF, the band at 865
cm-1 which is assigned to the symmetrical stretching vibrations in the BiO3 pyramidal units decreases
in intensity and the band at around 490 cm-1 shifts to lower wave number which can be due to the
formation of Bi-F bonds. From Raman spectra of the present glasses it can be observed that with
introduction of alkaline earth oxides from MgO to BaO into the present glasses, the intensity of the
bands corresponding to Bismuthate units [BiO3 and BiO6] decreases form BaO to MgO. This is also
conformed from the present IR spectra, where the intensity of the bands decreases with the
introduction of alkaline earth elements from BaO to MgO.
Key words: Glasses, MDSC, FTIR, Optical Absorption, Alkaline earth Oxides.
Keywords: Internet of Things; renewable energy; Energy utilization; Smart homes; Renewable
resources
M Vinod
Please insert
Abstract photograph of
the presenting
In today’s world rival combat is a crucial aspect in any nation’s security. The countrywide
author.
security
mainly depends on soldiery, naval, air force and a vibrant role is played by soldiers. This system will
be beneficial for soldiers, who encompass in undertakings or in special actions. In rival terrain, our
territorial army not only have to deal with the physical risk, but also with load and exhaustion caused
by prolonged processes or even due to lack of doze. So, for their security persistence we need a tool
to remote soldier performance and health monitoring. And, in this project a device is instigated by
means of biosensors for health nursing purpose. This system permits GPS (Global positioning
systems) tracking of these soldiers. It is probable by M-Health. It can be well-defined as mobile
computing, communication technologies, medical sensors for health maintenance. In this system,
smart sensors are attached to the body of soldiers for detection and prevention. This is applied with a
particular server system for broad agility. This server will furnish the affinity to the server at the base
station with the use of wireless assembly. Individual soldier also has a GSM (Global system for
Mobile communication) module that permits to interconnect with the base station if any wounds
noticed. As quick as any other soldier cross the rival borders it is tremendously tough for the soldiery
base station to distinguish the particular or predicted location as well as the health condition of all the
soldiers. In our project we have come up with an idea of tracking soldier and this tool is implemented
by means of biosensors for health monitoring purpose as well as to stretch the condition status of the
soldier all through the war for their safety.
Keywords: GPS- Global Positioning System, GSM- Global System for Mobile Communication, M-
Health – Mobile Health
S. Harivardhagini
1
CVR College of Engineering, Ibrahimpatnam, 501510,India
Mobile: (+91) 9985147962; E-mail: harivardhagini@gmail.com
Abstract Please
insert
Driving while either intoxicated or drunk is dangerous and drivers with high blood alcohol
photogra
ph of the
content or concentration (BAC) are at greatly increased risk of car accidents, highway injuries and
presentin
vehicular deaths. Every single injury and death caused by drunk driving is totally preventable.
g author.
Although the proportion of crashes that are alcohol-related has dropped dramatically in recent
decades, there are still far too many such preventable accidents. Unfortunately, despite great
progress, alcohol-impaired driving remains a serious national problem that tragically affects many
victims annually. At present drunken drivers have increased enormously and so is the deaths due to
drunken drivers. The main reason for driving drunk is that the police are not able to check every car
and even if they catch any one the police can be easily bribed. So, there is a need for an effective
system to check drunken drivers.
In this paper an alcohol detection system is designed and implemented. Apart from sensing
the alcohol, the ignition of the fuel is regulated by a sensor circuit. The sensor circuit is used to detect
whether alcohol was consumed by the driver recently. This design also consists of sensor which is
used to check whether alcohol is consumed while driving. The effects of drinking and driving are
always risky and can often be lethal. A prototype is also designed which detects the amount of
alcohol taken by the person. When the amount of the alcohol is reached to a threshold limit
(Dangerous/maximum) it automatically turns off the combustion engine of the vehicle with buzzer
indication and simultaneously with a LED indication.
Keywords: High blood alcohol content or concentration (BAC); alcohol detection system; ignition
interlock system; alcohol sensor
Please insert
Abstract photograph of
the presenting
The glasses of the composition 30 CaF2 – (10-x) Sb2O3 – x Y2O3 – 60 B2O3:author.
1 Ho2O3 (Where
x = 0, 5 and 10 mol%) are prepared. Prepared samples characterized by elastic, TL, UV and PL
technique. The values of density ( = 2327 Kg/m3), elastic modulus (Y= 21.98 GPa) and micro
hardness (H= 2.138 GPa) suggest that the sample Sb5Y5 exhibiting largest mechanical strength
(strongly interlinked covalent structure). The TL reports of the sample Sb5Y5 exhibiting good shape
symmetry factor (𝒖 = 0.524) and low AE’s (E𝛕 = 1.201, E𝛅 = 1.223 & E𝛚 = 1.239) under 30 min of
UV - irradiation might be good TL asset.Judd-Ofelt parameters are additionally projected. Which are
found to be best (Ω2 = 10.56 x 10-22cm2, Ω4 = 2.47 x 10-22cm2 and Ω6 = 2.88 x 10-22cm2) for the
sample Sb5Y5 might be good optical asset. The radiative evolutions, corresponding to the emissive
transition 5S2 → 5I8assessed by PL technique. The evaluations are found to be best (At = 3229s-1, τrad
= 181μs, β = 96.1 %) for the sample Sb5Y5 might be good radiative resource.
Keywords: Micro hard ness; trap depth parameters; J-O parameters:
Abstract
Eu3+ and Tb3+ activated Ba2SiO4 phosphors have been synthesized by using high temperature
conventional solid state reaction method. All synthesized phosphors are characterized by X-ray
Diffraction (XRD), Energy Dispersive Spectroscopy (EDS), Scanning Electron Microscope (SEM),
Fourier-Transform Infrared Spectroscopy (FTIR) and Photoluminescence Techniques (PL). The X-
ray diffraction patterns of the sample are indexed as orthorhombic structure. Elements are present in
the composition are Ba, Si, O, Eu and Tb as confirmed from EDS. In the photoluminescence
studies,Ba2SiO4:Eu3+phosphor exhibits strong emission peak at 611 nm and Ba2SiO4:Tb3+phosphor
exhibits high intense emission peak at 546 nm under UV excitations. These peaks may be attributed
to the transition 5D0 →7F2 of Eu3+ ions and transition 5D4 →7F5 of Tb3+ ions.The intensity of intense
peaksare increasing with Eu3+ concentration increases as well asthe high intense emission peak is
moderated from blue region to green region with Tb3+ concentration increases. Based on these
results, these phosphors may be useful as red and green phosphors in the lamp as well as displays.
Keywords: Barium Orthosilicate Phosphor,X-ray Powder Diffraction (XRD), Energy Dispersive
Spectroscopy (EDS) and Photoluminescence (PL).
Acknowledgements: We would like acknowledge to DST-SERB, New Delhi and OU-DST-PURSE-
II PROGRAMME for providing financial assistance to carry out this work and also thanks to Head,
Department of Physics, Osmania University, Hyderabad for providing research facilities.
Herein, we report the structural and electrical properties of nickel ferrite nanoparticles induced by
gamma ray irradiation. Nickel ferrite NiFe2O4nanoparticles were synthesized in nanocrystalline form
using sol-gel auto combustion route. The obtained nanoparticles were sintered at 500ºC for 6 h and
used for structural and electrical characterizations. These characterizations were made before and
after gamma irradiation. Single phase formation and nanocrystalline nature was confirmed through
X-ray diffraction analysis. The intensity, crystallite size and other structural parameters were
changed after gamma irradiation. The electrical properties such as DC electrical resistivity were
measured using two probe technique before and after gamma irradiation. The results of DC
resistivity measurements suggest that nickel ferrite nanoparticles exhibit semiconducting behaviour
obeying the Arrhenius relation. The observed changes in structural and electrical properties after
gamma irradiation may be attributed to creation of defects.
Keywords:Nickel ferrite nanoparticles, sol-gel auto combustion, XRD, Gamma irradiation.
Acknowledgements
One of the authors Pooja Khedekar is thankful to Government Institute of Science, Aurangabad for
gamma radiation facility.
Sumalatha M1, Shravan kumar Reddy S4, Sreenath Reddy M2, a, Suresh
Sripada3, Venkat Reddy P1, Gopal Reddy Ch2,Yadagiri Reddy P2 and
Raghavendra Reddy V5
1
Sreenidhi Institute of Science and Technology, Hyderabad-501301
2,
Department of Physics, Osmania University Hyderanbad-500007
3
JNTUH College of Engineering, Nachupally, Jagityal-505501
4
Chaitanya Bharathi Institute of Technology, Gandipet, Hyderabad-500075 Please insert
5
UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indoor-452001
photograph of
the presenting
*Corresponding author. Mobile: (+91) 9849936509; E-mail:marrisr@gmail.com
Abstract author.
Ferrites are familiar for their ferrimagnetic properties and exhibits significant amount of magneto-electric
coupling in composite form. The effect of sintering temperature on structural and electrical properties of
inverse spinel structured cobalt ferrite (CoFe2O4) is presented in this paper. The samples (CoFe2O4) were
synthesized through well known sol-gel method and sintered at different temperatures 1000oC, 1300oC and
1400oC for 6 hours. Rietveld refinement of X-ray diffraction (XRD) patterns confirms the phase purity of the
samples and found that samples were formed inverse spinel cubic structure with space group fd3min single
phase. There is a noticeable decrease in lattice parameters (a, b and c) and volume with the increase of
sintering temperature from 1000oC to 1400oC. Micro structure of the samples was understood through SEM
images. P-E loop and leakage current density measurement results were corroborated with the microstructure
of samples.
Acknowledgements
One of the authors Mrs. M. Sumalatha, is thankful to DST for providing the financial assistance through
PURSE project.
335K
1.5
340K
M(emu/g)
345K
1.0
350K
355K
360K
0.5
0.0
0 1000 2000 3000 4000 5000
H (Oesterd)
Using these isotherms Arrott plot (H/M versus M2) the magnetic entropies were deduced.
Relative cooling power, RCP has been estimated using maximum magnetic entropy and found to be
comparable with earlier reports.
Acknowledgements: GL thanks DST SERB for funding the project TAR/2018/000366 and all
authors are grateful to Director CSIR-IICT for the support.
Magnetic Induction Spectroscopy (MIS) is a nondestructive testing technique that could be applied in
different areas of engineering, technology, and other applied sciences. The MIS system consists of
three main parts: electrical signal generation instrumentation (ESGI), electromagnetic interface
(EMI) system and object under test (OUT). The MIS technique is found promising for different fields
of applications such as biomedical engineering, industrial engineering, defence and securityand so
on, but the design of an ESGI needs to be studied in detail. As the MIS system is a non-contact
material characterization system, the signal to noise ratio (SNR) of the system is found to be reduced
for unwanted interference. Therefore, for an MIS system, the design of the ESGI is very crucial. The
works presenting the detail design aspects of the ESGI of an MIS system are still required to be
explored. This paper has presented the design, development, and testing of a low-cost MIS
instrumentation. Along with the mathematical modelthe electromagnetic system, MIS
instrumentation is developed with two windings of suitable turns using enameled copper wires of
required cross-sectional areas. The variable voltage multifrequency function generator developed to
generate the magnetic field lines is used to excite the primary coil. The voltage developed at the
secondary winding due to the Faraday’s electromagnetic induction principle is acquired to sense the
permeability of the different materials placed as the core of the electromagnetic interface. The SNR
has been studied for different amounts of voltages and frequencies of the electrical excitation applied
at primary winding. The advantages and limitations of the system have been described along with the
future work and possible applications of the system.
Acknowledgements
Research support has been provided by NIT Durgapur (NITDgp), West Bengal 713209, India.
Abstract
Semiconducting oxides have been extensively studied for application as gas sensing materials
becauseof their ability change their electrical resistance in response to the concentration of target gas
in its contact.Tungsten trioxide (WO3) belonging to this class of materials has other interesting
features such as different morphology and crystalline structures that could be effectively tailored to
design a material for efficient gas sensing. Ethylene (C2H4) gas, a vegetal hormone produced in most
plant tissues plays a major role in the initiation of ripening of fruits. Uncontrolled ethylene
production over a period of time could lead to the damage of the stock and hence warrants its
detection. With this objective, the present work describes the synthesis of tungsten oxide (WO3)
nanoparticles and their response towards the ethylene sensing. A facile hydrothermal synthesis
method using sodium tungstate dihydrate as the precursor is described. X-ray powder diffraction
(XRD), field emission scanning electron microscopy (FESEM) and energy dispersive spectroscopy
(EDS) respectively establish the monoclinic crystal structure with flake-like morphology of WO3.
Figure 1. The XRD in Figure 2 shows the evolution of the structure post 500oC calcinations after the
hydrothermal synthesis at of 160oC. The gas sensing studies supported with XPS findings and the
systematic study of structure and morphology evolution led to elucidation of the formation
mechanism and probable sensing mechanism.
Figure 1 FESEM of WO3 after calcinationsFigure 2 PXRD data before and after calcination
Acknowledgements: All the authors are grateful to Mrs.Y.Swarnalatha and B.Arun Kumar for their
relentless analytical support.
*For Correspondence
Email: manorama@csiriict.in and manorama@iict.res.in
D.Ravinder1*, G.Naveena2
1
Department of Physics,Osmania University, Hyderabad- 500007, India
2
Department of Physics, Osmania University, Hyderabad- 500007, India
Acknowledgements
The authors are very grateful to DST-SERB, New Delhi for financial support.
1
Swami Ramanand Teerth Marathwada University, Nanded-431606, India
2
St. John College of Engineering and Management, Palghar-401404 India
3
Solapur University, Solapur-413001, India
4
Yeshwant College, Nanded -431606, India
Y1-XVO4: Eux-y 3+: Pry3+ with x = 6 mole % and y = 0, 2, 3 ,4, 5, 6, mole % phosphors have
been prepared by solid state reaction. The dopant Eu3+ concentration was optimized along with the
co-dopant Pr3+ concentration in the yttrium vanadate host lattice with the help of photoluminescence
(PL) spectra. The phosphors have displayed red color under UV source. Pr3+ acts as quencher and
quenching effect of co-dopant Pr3+ on Red Emitting Yttrium Vanadate Phosphor Doped with Eu(III)
using luminescence Studies on Y1-XVO4: Eux-y 3+ : Pry3+ systems are presented in detail in this paper.
The emission intensities were determined and the relative fluorescence intensities have been
estimated. The richness of the red color is verified by determining the chromaticity coordinates (X,
Y) from the CIE standard charts.
Acknowledgements
We acknowledge Director NMRL for computational resource and financial assistance to conduct this
research work.
Abstract
The SEM photographs on HITACHI S-4700 FE-SEM for Composite Solid Electrolytes 0.25Ba(NO3)2-
0.75KNO3, 0.19Ba(NO3)2-0.81KNO3,0.05Ba(NO3)2-0.95KNO3 and DSC(DSC-60-SHIMADZU)plots of
Ba(NO3)2,KNO3 and their composit systems of 0.62Ba(NO3)2-0.38KNO3, 0.37Ba(NO3)2-0.63KNO3,
Abstract
The nano-sized InyCoSb3 skutterudites (y = 0.0125, 0.025, 0.0375 and 0.0625) were synthesized by
solvo-/hydrothermal method at 240 0C for 24 hours. The surface morphology of as-synthesized
samples analyzed by Field Emission Scanning Electron Microscope (FESEM) shows nanoparticles
with size of around 50 nm depicting narrow size distribution and Electron X-ray diffraction
spectroscopy (EDX) spectrum confirms the purity of the In-filled CoSb3 nanomaterials. The powder
X-ray diffraction (pXRD) pattern reveals all the compositions showing diffraction peaks indexed to
cubic phase of CoSb3 with Space group Im . However, no significant variation in the pXRD pattern
of In filled CoSb3 as compared to pure CoSb3justifies the successful filling of voids in cage-like
structure of CoSb3 with Indium. FTIR spectra of In filled CoSb3 presents vibration modes below
1000 cm-1 corresponding to Co-Sb bonding and Cobalt complex. A significance of In filling into
CoSb3 structure is also evident. A wide absorption has been witnessed from UV region to large part
of visible region, hence indicating the effect of nanoparticle, agglomeration and filling.
Keywords:Skutterudites; Solvo-/hydrothermal; Nanostructure; Filling; Optical properties.
Synthesis of nanomaterials with desired properties and applications is one of the most popular areas
of research in the field of science and technology. The broadly adopted approaches for the synthesis
of nanomaterials are – (i) Top-down and (ii) Bottom-up approach. Out of these two approaches,
chemists prefer bottom-up approach for the synthesis of nanomaterials because of less expensive,
better control and more parameters which provide a variety of products with different properties and
applications. Radiation induced synthesis which comes under bottom-up approach exploits the
interaction of radiation (both high as well as low energy) with the solvent media to generate highly
reducing free radicals to induce the synthesis process. The advantages of radiation induced synthesis
over the other methods are: (i) Minimal use of potentially toxic chemicals (as reducing, capping and
cross-linking agents), (ii) Low energy consumption, (iii) Simple reaction scheme, (iv) In-situ
sterilization of product if required and (v) Dose dependent morphology of nanomaterials. In this
regards, the mechanistic approach for the radiation induced synthesis of different nanomaterials like-
CdSe and Si QDs which involve both high energy (radiation chemical) and low energy
(photochemical) using different capping agents in aqueous solution have been discussed. In radiation
chemical method, the radicals are generated upon radiolysis of water (H•, OH•, eaq-) after interaction
of high energy e-beam or gamma rays which will react with the solute molecules to generate
reducing radicals. On the other hand in photochemical method, low energy photons (UV) directly
interact with the solute molecules for the generation of reducing radicals e.g.- generation of 2-
hydroxy propyl radicals ((CH3)2C•OH) in acetone and 2-propanol in aqueous solution.
Acknowledgements
The author acknowledges DAE for research funding and MLR Institute of Technology for supports.
Novel bio-inspired nanoarchitectured materials with surface functionalized properties have potential
applications in various fields. Polymeric porous nanomaterials/particles/capsules are taking as a
challenging task for surface porosity as payload for anticancer drugs and nanomedicines for drug
delivery and cancer theranostics [1]. The hybrid of bio-inspired SiO2NPs, ZnONPs along with
biodegradable, biocompatible and bio-safe (3B) polymers can help to design and develop potential
carrier nanomaterial for biomedical and biotechnological applications.The metal (AuNPs/AgNPs) in
combination of 3B polymers can easily functionalized and nanomaterial or particle or capsule surface
profile can be modified based in the applications [2]. The active functional groups present in the
polymers lead to the self-assembly followed by the net-work formation capabilities. The interactions
between polymer and inorganic, organic and metal nanoparticles has been examined through the
following characterization tools FTIR, SEM, FE-SEM, AFM and TEM for functional groups, size,
shape, morphology, surface profile. The BET surface area, porosity and specific surface area of
nanoparticles. The nanomaterials/capsules with size of ~100 to 200 nm (in diameter) has been
engineered and used to develop nanoformulations for cancer therapeutics.
Acknowledgements
The author Dr.Jakeer Husain gratefully acknowledges the financial support from VGST Program.
MEMS based actuator and scanning mirror is device that steers and reflects incident light by
angular rotation of the mirror itself. It finds applications in optical MEMS (OMEMS), digital light
projector, optical switch, adaptive optics, communications, signal sensing, and confocal microscopes.
For single axis scanning, the mirror itself provides the required angular rotation, while most of the
biaxial scanning micro mirrors have a gimbal configuration. Electrostatic actuation is commonly
being used because of ease of fabrication and work on the principle of electrostatic forces between
pairs of movable and fixed electrodes. Parallel plate type tip-tilt/scanning mirror is commonly being
used for smaller mirror dimensions (up to 2mm). For larger mirror diameter (>2mm), the desired
scan angle leads to large gap between the electrodes, which increases the driving voltage drastically
and leads to bulky driver controller. To reduce the driving voltage, the straight torsion springs which
connect the mirror to the gimbal are replaced by comb structures. In this paper, design, simulation of
electrostatic actuation based parallel plate comb type two axis tilt scanning micro mirror is described.
The effect of comb structure on pull-down voltage and resonant frequency is studied.
Keywords: Micro Eelectro Mechanical systems (MEMS), Electrostatic actuator, Scanning micro-
mirro, Adaptive optics.
Acknowledgements
Authors would like to thank STIC Cochin for their support in characterization of nanostructures.
Structural, elastic and optoelectronic properties of materials are important to identify their
applications in technology. In the present paper LiMgF3 is investigated to obtain these properties
using the highly accurate full-potential linearized augmented plane wave (FP-LAPW) method. The
exchange correlation effects are included through the generalized gradient approximation (GGA) and
modified Becke-Johnson (mBJ) exchange potential. The structural optimization of LiMgF3 is
compared with previous results and is found to be in good agreement with those results. The
predicted band structure shows an indirect (M-Г) bandgap of 6.1 eV. The elastic properties such as
elastic constants, anisotropy factor, shear modulus, Young’s modulus, Poisson’s ratio are calculated
and based on these calculations it is found that this compound is elastically stable and brittle in
nature. The contribution of different bands to the band structure is analyzed from the total and partial
density of states curves. Optical properties like real and imaginary parts of dielectric function,
refractive index, extinction coefficient, reflectivity, energy loss function, conductivity and absorption
coefficient are presented. Based on the optical properties of the compound, it is predicted that
LiMgF3 is suitable for optoelectronic devices.
Acknowledgements
Author Sagar Bhattarai is the fellowship recipient of TEQIP-III Fellowship for carrying out his PhD
research work on organic solar cell at NIT Arunachal Pradesh.
In this work, eco friendly simple modified ultrasonication-cumbustion method has been
adopted to synthesize Zinc Oxide Nanoparticles using naturally available Vitis vinifera fruit and
Aegle marmelos L. leaves extracts.8.91 g of zinc nitrate, 10 ml of each extract and 10 ml of distilled
watermixture was taken in a round bottomed flask and stirred for 30 min to get clear solution. Then
the mixture was kept for ultrasonication at a frequency of 22 KHz for 30 min at a temperature of
353 K. Then the solution was heated in the muffle furnace for the combustion process for about 20
min at 633 ± 5 K. to get ZnO Nanopatrticles. The synthesized Zinc Oxide Nanoparticles showed
hexagonal wurtzite crystalline phase confirmed by Powder X-Ray Diffraction patterns. Scanning
Electron Microscope gives images of Surface morphology of the synthesized Nanoparticles. The
Energy Dispersive X-Ray Spectroscopy gives elemental composition of the prepared Nanoparticles.
From Ultra-Violet-Near Infrared studies,energy band gap calculated which is correlate with the
reported literature. Fluorescence emission studies shows the prepared ZnO Nanoparticles emissions
are in the blue region useful in optoelectronic devices and light emitting diodes.The red and green
fluorescence emissions can be further enhanced by choosing suitable europium rare-earth dopants.
Acknowledgements
Author Dr. Daruka Prasad B would like to acknowledge the VGST , Government of Karnataka for
funding towards the project.
Graphene oxide (GO) is a promising material for energy storage device applications.
Modified Hummers method (MHM) was used to prepare GO films from graphite flakes by Sol-Gel
method. With the aid of bridging agent dimethyldichlorosiline fine GO films were prepared. Fourier
transform and infra-red (FTIR) spectrum of the GO thin film possess absorption bands at 461, 594,
670, 803, 1020, 1243, 1457, 1544, 1627, 2850, 2926 and 3429 cm-1. A sharp OH- absorption band
was revealed at 3429 cm-1. Two vibrational bands were noticed in the laser micro Raman spectrum
for pure graphite flakes at 1578 and 2718 cm-1. However for GO five Raman vibrational bands were
unveiled centred at 413, 1344, 1597, 2697 and 2945 cm-1. Among these bands, 1344 cm-1 was
assigned to D-band and 1597 cm-1 was assigned to G-band to the GO films. Compared to D-band, G-
band was dominant in the GO films. Several times of centrifugation and ultra-sonication process
have aided to obtain more intense of G-band. 2D and D + G bands were also revealed in the GO
films. X-ray diffraction (XRD) analysis was confirmed that a sharp peak at 10.64 degrees leads to the
GO thin film.
T S C Nataraj1 M. Meikandan2
1
Assistant Professor, Department of Mechanical Engineering, Vignana Bharathi
Engineering College, Hyderabad, India
Research Scholar, Vel-Tech University, Chennai
(tscnataraj@gmail.com), Ph: +91 8309740042.
2
Assistant Professor, Department of Mechanical Engineering,Vel-Tech
University,Chennai.
(mmeikandan@veltech.edu.in), Ph : +91 9490907989.
Abstract
The energy consumption in worldwide has been increasing rapidly, due to increase in world
population. This energy consumption growth is apparently impacting on the environment and the
society. This has accelerated the development and deployment of Renewable Energy Sources (RES)
harvesting technologies and facilities. The global electricity production by RES by the end of 2016 is
accounted to 24.4%. This increase in RES has highlighted the next big challenge, storage of energy
when demand is lower than the supply. There are many energy storage technologies existing from
decades. Battery technologies have the highest cost reduction potential at the moment. Battery
technologies are delivering significant advances in a wide range of industries, from electrical
vehicles to renewable power. From the discovery of electrical energy, there is a great need to store
the electrical energy generated for use on demand. Energy Storage Systems (ESS) is used to store the
excess electricity when a power production is greater than consumption. ESS play very important
role for off-grid storage applications to back up Renewable Energy such as Solar and Wind power,
used by people who live or work in remote areas. Electrical energy can be stored in different forms
including Electrochemical- Batteries, Kinetic Energy-Flywheel, Potential Energy-Pumped Hydro,
and Compressed Air (CAES). This paper gives the current state of battery storage technologies, its
main challenges, its applications and actions for future.
Keywords:Energy Storage Systems (ESS), Electric Vehicles (EVs), Renewable Energy Sources
(RES), Lithium-ion battery, Lead-acid battery.
a) b)
Fig.1 – a - Capacitor connection; b- capacitor section and condenser paper for extra insulation
between sections
Keywords: Condenser paper, Insulation, Capacitor.
All Here with we reported a detailed synthesis of Fe/Cr co-doped Copper oxide nano particles with a
simple and inexpensive wet chemical method. The pure and Fe, Cr substituted CuO nanoparticles
was prepared with sol-gel chemical method are expedient for industrial application. The preliminary
X – ray diffraction and Rietveld refinement study revealed a pure crystallinity nature with
monoclinic crystal with C2/c phase. The average crystallite size was calculated by Scherrer’s formula
in order of 21 nm and further observation indicates with increase concentration crystalline size
increases. The scanning electron microscopy (SEM) images indicate particles are in 20-30 nm range.
The Raman spectroscopic study indicates the existence of molecular groups in the CuO nanoparticles
with the doping of Cr and Fe.
Keywords: CuO Nano particles, Sol – gel method, Crystallite size and Particle size.
Acknowledgements
The authors would like to thank UGC-DAE Consortium, Mumbai Centre, India for providing
experimental facilities and financial support under UGC-DAE, CRS-M-216-Sponsored Project
Scheme.
Please insert
Abstract pho
Renewable energy sources like solar and wind as Distributed Generation (DG) systems can
be made available to meet local power demand. Natural disasters mostly damage the distribution
system. Under these conditions it is necessary to supply power to emergency services like hospitals.
If DGs are available, these can be used to supply the load. To meet the maximum demand the
optimal use of available DGs is required. An optimization problem is formed using cost functions of
renewable energy sources and it is solved using Linear Programming method (LP) in MATLAB.
tograph of the
Problems with reproductive power, despite its purpose to the environment, continue to be associated
presenting
with its operation and reliability. The production and weather condition of someauthor.
renewable energy
sources, such as wind and solar power generators are determined. Due to this intermittent nature,
power generated by these sources is highly variable in nature and cannot be considered as dispatch
able. As a consequence, the power supply must be maintained or backed up by alternate volatile
power sources such as diesel generator, battery or fuel cell. In this paper, three generation systems
like solar, wind and diesel systems are considered and an optimization problem is formed using cost
functions of these DGs.
Keywords: Optimization, Linear Programming Method, Reduced Gradient Method, Cost function.
Acknowledgements:
I thank TEQIP-II, JNTUHCEH for providing necessary infrastructure.
Abstract
The copper zinc tin sulfide (CZTS) is a widely studied absorber material for thin film solar cells.
Recently, CZTS have found suitable for counter electrode (CE) material in Dye sensitized solar cells
Please
(DSSCs) due to high cost of Pt.In this paper, we propose pulsed laser deposited CZTS on florin-
doped tin oxide (FTO) conducting substrate as efficient counter electrode and studied the thickness
effect on the performance of the DSSC.X-ray diffraction(XRD) and Raman spectroscopy reveal the
formation of single phase kesterite CZTS with (112),(220) and(312) planes confirms the single phase
CZTS as evidenced by weak and strong Raman modes at 285,337 and 352cm-1 . The influence of the
thickness of CZTS samples on the catalytic performance of DSSCs was also investigated. The electro
catalytic ability and electrochemical properties of the CZTS CEs were studied by cyclic voltammeter
(CV), electrochemical impedance spectroscopy (EIS), and Tafel plot. The performance of DSSCs
with various thickness of CZTS CEs was measured usingJ–V curves. The DSSC based on CZTS
insert photograph of
counter electrodes deposited with the thickness of 300 nm showed maximum solar-to-electrical
the pres
power efficiency of 3.98%. The results indicated the potentiality of CZTS to replace Pt CE (5.55%)
in DSSC.
enting author.
Fig. J-V curve voltage Vs current of different thickness of CZTS counter electrodes with Pt..
Acknowledgements
Researchers of the Low Temperature Laboratory and Cryogenics, especially, Er. P. Saravanan for the
supply of cryogens from UGC-DAE CSR Indore, M. P. are thanked for their help.
Abstract
Acknowledgements
The authors gratefully acknowledge University Grants Commission Networking Resource Centre,
School of Physics, University of Hyderabad, for giving the Opportunities to use the Research lab
facilities to carry out the above work.
In India ample source of alternative energy is available, 65% population of India lies in rural
area and only 30% of rural area have a grid connected electricity. Their situation becomes
impoverished in summer time due to frequent load shedding. In this paper our aim is to design SOFC
and diesel based hybrid system that will cater domestic as well as irrigation need in a remote located
village. Design and modeling of Solid Oxide Fuel cell (SOFC) is discussed for the distributed
generation applications. Modeling and simulations are carried out in MATLAB Simulink platform.
Solid oxide fuel cells operate at temperatures near l0000C, these are highly efficient heat and electric
power source. Modeling of SOFC is done by using Nernst equation. In that the output power of the
fuel cell can be controlled by controlling the flow rate of the fuels used in the process. The fuel cell
source is integrated with diesel generator and battery hybrid energy system.
Abstract
This paper reports on the enhancement of heat transfer by the usage of nanofluid in place of
conventional fluids like water, oil, etc, in the double pipe heat exchanger. The heat exchanger is used
to transfer the thermal energy between two or more phases, such as solid, liquid or gas, at different
temperature and in thermal contact. The nanofluid is prepared by using silica nanoparticles, with
distilled water as the base fluid. In place of conventional water, the prepared nanofluid is applied in
the heat exchanger as the cooling liquid. A double pipe heat exchanger is modeled and meshed using
the ANSYS software.The heat transfer characteristics of nanofluid in the heat exchanger was
analyzed using ANSYS Fluent software. Finally, the CFD results obtained are compared with the
experimental results. Based on the results, it can be observed that the addition of nanoparticles to the
base fluid leads to significant enhancement of heat transfer characteristics.
Keywords: Silica Nano Particles, Double Pipe Heat Exchanger, Nano Fluid, CFD Analysis.
Abstract
Zinc borate glasses mixed with different concentrations of Ta2O5, Nb2O5 and ZrO2 were
crystallized. The prepared samples were characterized by XRD and SEM techniques. The results of
these measurements have indicated that the bulk samples are entrenched with Zn3Ta2O8 [1],
columbite ZnNb2O6 [2]and ZnZrO3 [3] (tetragonal/cubic) crystal phases, respectively, with varying
sizes and concentration depending upon the content of dopant transition metal oxides. The dielectric
breakdown strength (DBS) of these materials was measured in air medium at ambient temperature
along with dielectric properties viz., dielectric constant, loss tangent, electric moduli, electrical
impedance and a.c. conductivity over wide ranges of frequency and temperature. The analysis of the
results has suggested that the glasses doped with 3.0 mol% of Ta2O5 exhibited the highest insulating
strength, while for Nb2O5 and ZrO2 mixed glass ceramics value of DBS is found to increase with
increase of concentration of these two metal oxides. The highest values of DBS were measured to be
18.34, 17.49 and 18.92 kV/cm, respectively, Ta2O5, Nb2O5 and ZrO2 mixed zinc borate glass
ceramics. The reasons for such high DBS were identified and reported. Finally, it is concluded that
these glass ceramics are suitable as insulating layers in the screens of display panels.
D. Saritha*
1
Chaitanya Bharathi Institute of Technology, Department of Chemistry, Hyderabad–500075,
India
Nano CompositesNiO and GDC20 were synthesized as X (NiO) +1-X (Ce0.8Gd0.2O2-δ) where
(X = 40& 45 wt. %) for intermediate or low temperature operating solid oxide fuel cells (SOFC).
For composite anode materials, NiO and GDC20 nano powders were mechanically mixed and
calcined from 600 oC to 750 oC. Samples were pelletized and sintered at 1300oC. Systematic study of
structure, purity, phase and structural parameters of anode samples were carried out by XRD and
SEM. Mechanical strength of anode composites were estimated by Vickers micro-hardness and
observed that microhardness of composites are varying from 5.09Gpa to 5.52 Gpa. Electrical
properties D.C conductivity and A.C conductivity of anode composites were computed using four
probe method and impedance analyser respectively. The A.C conductivity and their activation
energies of the anode samples (compositions X = 40& 45 wt.%) were computed from RT to 500 oC
with the impedance data and the conductivities are found 2.95 x10-3 S/cm and 7.53 x10-3
S/cmrespectively at 500oC (frequency 5 MHz) .The activation energies of A.C conductivity have
observed that decrease with increase in frequencies.
Keywords: SOFC; Anode; nanocomposite. D.C conductivity and A.C conductivity
Acknowledgements:
The authors are thankful to the Department of metallurgical engineering and material science, IIT
Bombay and Professor S.S Bhoga, Department of physics R.T.M University Nagpur for providing
experimental support.
Microwave Assisted Solvothermal (MAS) processing offers fast and conformal deposition of
nanocrystalline ferrites films on a Si-chip in a CMOS-compatible manner [1].Briefly, selected
metalorganic precursors, dissolved in a chosen mixture of polar organic solvents, transforms into the
desired nanocrystalline ferrite thin film under the influence of µ-wave irradiation and adheres well to
the substrate submerged in solution. Nanocrystalline manganese zinc ferrite (MZF), deposited via
MAS process,exhibited great potential to meet the requirements of upcoming 5G technology devices
– enhanced Q-factor of an on-chip inductor by 30% at C-band (4-8 GHz) [2]. However, MAS
process, still in its infancy thus has not been thoroughly studied/established parametrically. This lack
of understanding renders suboptimal reproducibility of the physical and magnetic characteristics of
the deposited film. This work explores the effect of precursor solution preparation protocol on the µ-
waveheating mechanism, thus, impacting film deposition rate. Keeping constant deposition
parameters (deposition time, µ-wave power) throughout, a key pre-deposition step, sonication time –
required to dissolve the solute precursors into the polar solvent was systematically varied to
investigate its effect on reproducibility of the deposited film.It was evidenced that the pre-deposition
sonication time of the solution affects the quantity of the volatile solvent in the solution which
subsequently changessolution’s effective tan(δ), thereby affecting film quality as heating rate
changesduring irradiation. To affirm the impact of solution’s tan(δ), solvents with different tan(δ)
were mixed at different proportion before irradiation. The deposition rate varied from 10-120 nm/min
by increasing the sonication time (30-75 min). Moreover, it was evinced that high deposition rate
yields relatively rough and porous film with delamination tendency. Effect of solution loss-tangent
on the deposition rate of ferrite film deposited via MAS process is systematically investigated here
for the first time thus providing a strategy for tuning deposition rate via MAS process in general
while achieving desired film characteristics.
Keywords: Microwave-assisted solvothermal (MAS) process; loss-tangent; sonication time;
deposition rate
Abstract
Cryogenic treatment has been recognized by a few methods for expanding apparatus life of
numerous cutting instrument materials, hence enhancing efficiency essentially. However genuine
components which ensure better instrument execution are as yet questionable. Concentrates on
cryogenically treated HSS instruments demonstrate microstructural changes in material that can
impact device lives. However little research has been done on other cutting apparatus materials.
Cryogenic treatment of carbides presently can't seem to be widely contemplated. This work expects
to contemplate the impact of cryogenic treatment on M2 and D2 steels. It is an extension for subzero
process and It is the latest technology. The objective of this lecture is to explain the basic
transformation of structures and the conversion of retained austenite into martensite and martensite
into tempered martensite which in turn include the properties like longer part life, minimize failure
because of cracking, enhanced warm properties, better electrical properties including less electrical
protection, lessened coefficient of friction, minimal creep and walk, enhanced evenness, and less
demanding machining. This retained austenite into martensite is the most important type of
transformation i.e. transformation requires diffusion for the changes in crystal structure to occur. The
effect of cryogenic process, subzero process, other heat treatment process and the types of heat
treatment furnaces structural changes in heat treatment process are studied.
Heart disease or advanced heart failures is one of the serious causes of death. Due to
availability of low volumes of donor hearts, there has been an ongoing development of Mechanical
Circulatory Support (MCS): Ventricular Assist Devices (VADs) and total heart replacement by Total
Artificial Hearts (TAHs) for over 60 years [1].
Mechanical circulatory frameworks had seen three phases of advancement. The first
generation of MCS devices were largely mechanical devices and had pulsatility in their action, but
were highly cumbersome, unreliable due to small fatigue cracks and required an external pneumatic
power and control. Smaller and continuous flow devices are the second generation MCS devices.
Because of compact sizing they were suitable for implantations and were more durable than the first
generation devices. Problems like pump thrombosis prompted the development of non-contact, type
of devices leading to the development of third generation devices, where the pumps magnetically
levitate over a magnetic field and have no contact with the blood. Manufacturing of these
electromagnetic devices for implantation has to adhere to the constraints of space and weight [2-3].
With the advent of new Bio-materials, additive manufacturing is reportedly playing a significant role
in biomedical industry such as anatomical models for surgery training/planning, rehabilitation,
dentistry, customized implants, drug delivery devices, tissue engineering, and organ printing [4].
Cardiologists and Cardio surgeons reported complex and patient specific interventional and surgical
planning with the help of additive manufacturing techniques [5]. Additive manufacturing reported for
electromagnetic and electronic components had yielded considerably good performance [6]. The
authors had mathematically implemented a control algorithm for introducing pulsatile flow by
modulating the speed of a BLDC motor for VADs and TAHs. This paper explores the feasibility of
constructing VADs and TAHs using additive manufacturing techniques.
Acknowledgements
This work is funded by Jawaharlal Nehru Technological University Hyderabad under TEQIP – III
scheme.
This paper addresses thermovibrational convection in a thin porous layer permeated by a nanofluid.
The criteria for the onset of convection are found when the layer is heated from the bottom . A
stability analysis based on the method of small perturbations is performed using normal mode
assumption. The critical values of the governing parameters are found with the help of the Mathieu
functions. The emerging instabilities of synchronous and subharmonic types and the transition
between them are examined.
Keywords: Convection; Porous medium; Instability.
Abstract
The properties of hypoeutectic iron of HCWCI containing 25 wt. %Cr-2.5 wt. %C were
investigated after destabilisation heat treatments, cooling (slow and fast cooling) to ambient
temperatures, their influence on the structure and hardness was investigated using X-ray diffraction,
element distribution analysis and hardness tests with 28 references. The experimental results show
that appropriate heat treatments contribute to a significant improvement on the mechanical properties
of selected alloy of HCWCI. The results are discussed in terms of the change in volume fraction of
retained austenite phase at the different destabilisation heat treatment temperatures.
Keywords: white cast iron; high chromium white cast irons; (Cr,Fe)7C3 carbides; secondary (Cr,Fe)23C6
carbides.
Reference
1. F. Nyokong and X. Pan, “A Review on Usage of High Chrome White Cast Irons in South
Africa,” Tamil Nadu, India, 2019.
2. T. X. L. D. Y. H. B. a. D. K. Chung R. J., “Microstructure Refinement of Hypereutectic
High Chromium Cast Irons Using Hard Carbide-Forming Elements for Improved Wear
Resistance,” Science Direct, vol. 301, pp. 695-706, 2013.
3. C. Mahlami and X. Pan, “Main challenges and developments of high manganses steel
castings based on service life,” 71st World Foundry Congress, Bilbao, Spain, 2014.
4. C. Mahlami and X. Pan, “An overview of high manganese steel casting,” 71st World
Foundry Congress Bilbao, Spain, 2014.
5. G. Nelson, “Influence of Microstructure on the Corrosion and Wear Mechanisms of High
Chromium White Irons in Highly Caustic Solutions,” Dissertation / School of Mechanical
Engineering, Adelaide, South Australia , 2010.
6. C.S Mahlami; X Pan, Mechanical properties and microstructure evaluation of
manganese steel alloyed with vanadium, FCSPTC international conference, Andhra
Pradesh, India, 2017, pp227-236.
Armour materials are important in defence applications for providing protection against different
threats. Quenched and tempered high strength steels are the primary choice for armour in battle tanks
and armoured vehicles. Understanding the penetration mechanism of projectiles in to the target plate
during ballistic impact plays a crucial role in the design and development of any armour. This paper
presents the ballistic performance of high strength low alloy armour steel against high hardness steel
projectiles of 7.62 mm and 12.7 mm caliber at normal angle of impact.The deformation mechanism
of the target material against both type of projectiles have been analyzed. Main interests are focused
on the microscopic observations and micro-hardness measurements adjacent to the crater holes
formed by the impact of both types of projectiles. It is observed that the extent of material
deformation increases with higher caliber of the projectile. Microstructural analysis of the crater
region exhibits material deformation along with shear band induced cracking. The ballistic behavior
of the steel is compared with the ballistic behavior of rolled homogeneous armour steel.
Keywords: High strength low alloy steel; Ballistic evaluation; Adiabatic Shear bands.
Acknowledgements
The authors wish to acknowledge DRDO, Government of India for financial support and The
Director, DMRL for his encouragements to carry out this work.
Ethylene acrylic acid co-polymer is a water-based polymer coating solution is used on cotton
bleached fabric [Fig 1]. The polymer coating solution is applied by roller method as well as by
exhaust method. The developed fabric is then cured and dried in an oven with a temperature ranging
from 60-90oC.Fabric stiffness properties is an important property that influence the drape of the
fabric. In this research work, the scanning electron micrographs of coated fabrics are captured to
ascertain the changes that occur after coating with ethylene acrylic acid co-polymer solution.
Thermal properties of these coated fabrics are analyzed using their DSC thermographs. The
composition graphs and finger print output of ethylene acrylic acid polymer coating is also analyzed
using FTIR results. The results of mechanical fabric stiffness properties of coated fabrics show
increased stiffness and good thermal properties in fabric after application of coating solution.
Fig 1: Materials used for surface treatment of cotton fabrics using ethylene acrylic acid co-polymer solution
KEYWORDS: Functional Textiles, Ethylene acrylic acid co-polymer, Stiffness property, Thermal
properties of fabrics, DSC thermographs
The Solid state reaction of BaTiO3 formation from a mechanically Activated BaO-TiO2
system has been investigated. A simple soft chemical method of synthesizing barium titanate nano
powders is described here, which is simple and cost effective, where titanium dioxide was taken as a
source of titanium, and BaO was obtained by Solution combustion synthesis of Ba(NO3)2 and
CH4N2O (as a fuel). An equi molar mixture of BaO and TiO2 powders was activated in a planetary
ball mill in a continual regime for 0, 30, and 90 min, and treated at a speed of 300rpm. The effect of
the milling on the phase formation was investigated by XRD method, EDAX, Particle Size Analyzer,
SEM, UV Visible Spectroscopy and Raman Spectroscopy.
Keywords: Ba(NO3)2 and CH4N2O (as a fuel), XRD, EDAX, SEM, UV Visible Spectroscopy and
Raman Spectroscopy, ball milling method.
Composite Materials are most commonly used in aerospace applications due to its light
weight and high strength. Manufacturing and testing of this composite material are expensive. The
analytical methods are best alternative for this problem. In this analysis simply supported composite
plate analytical procedure was implemented to evaluate the deflections and stresses. Composites are
good at tensile properties and weak in compressive properties. So, there is a need in evaluating the
buckling strength of the composite plate. The buckling strength of the composite plate was evaluated
by varying the lamination orientation and lamination sequence. In this analysis Graphite/epoxy,
Glass/ epoxy and Kevlar Epoxy lamina properties are considered. Lamination scheme and fiber
orientation play a vital role on deflection and stresses. Buckling load is maximum when the graphite/
epoxy layers are at the middle. A parametric study was carried to know the bending and buckling
behaviours of the Hybrid composite plates
Keywords: Simply supported Plate; Laminated Composites; hybrid Composites; Static Analysis;
Bucking analysis
Keywords:Deep Drawing; LDH test; Erichsen test; Limiting drawing ratio; Olsen test
Acknowledgements
The author would like to thank Dr. Suresh Akella, Principal and the management of Sreyas Institute
of Engineering and Technology for supporting in creating the research facilities for metal forming
tests in the Department laboratories.
1. Department of H&S, J.B Institute of Engineering and Technology, R.R Dist, Hyderabad-500075.
2. Department of H&S, Institute of aeronautical Engineering, R.R Dist, Hyderabad-500043.
3. Departments of Physics, University College of Science, Saifabad, Osmania University, Hyderabad-500004
4. Departments of Physics, Annamalai University, Chidambaram (TN) -608002
5. Department of H&S, Anurag Group of Institutions, Medchal Dist, Hyderabad-500 088.
6. Department of ECM, J.B Institute of Engineering and Technology, R.R Dist, Hyderabad-500075.
7. Department of P.G Studies and Research in Physics, Gulbarga University, Gulbarga-585105, India.
Acknowledgements
I would like thank VNRVJIET civil engineering department for the infrastructure they provided for
the project and would like to express my gratitude to Sri M.Siva Prasad for helping us in testing and
my project teammates Vooha Chowdary C and Abhilash K for their help in project.
Acknowledgements
I would like to express my deep gratitude toDr. Roy Johnson, Scientist-G and Associate Director,
ARCI –Hyderabad and Dr Y Srinivasa Rao, Scientist F, Centre for ceramic processing, ARCI-
Hyderabad for their timely help in my active research on this topic.
Polysialate composites are a new class of high performance materials due to their excellent
inherent high temperature resistance, low density and ease of manufacturing. These properties also
suggest that polysialate composites have a high temperature resistance, environmental friendliness,
light weight suitable for structures of both aerospace and motorsport applications. The foremost
requirements of these applications are high temperature resistance, low density, good structural
properties and ability to form complex geometries at low lead times. The polysialate matrix based on
polymineral resins, has ease of manufacturing using conventional polymer composite lay-up, and
allowing complex geometries to be fabricated. The most widely used polysialate matrix materials
reinforced with silicon carbide fibres material havebeen studied in this work for their flexural
strength over a representative temperature range. The three point bending test simulation analyses
were performed according to ASTM standard on these polysialate composites. The simulation
analysis results revealed that flexural strength of polysialate composites were stable over a
representative temperature range of 200OC to 600OC.
Keywords: Polysialate composites; flexural strength; three point bending test.
Acknowledgements
The Electrical properties and transport mechanism of the Ni/polyvinyl alcohol (PVA)/n-Si
metal-insulator-semiconductor (MIS) type heterojunction was investigated by the I-V measurements
at room temperature. The evaluated result of MIS heterojunction has a higher rectification ratio with
low leakage current compared with Ni/n-Si metal-semiconductor (MS) junction. The calculated
barrier height of MIS type heterojunction [0.80 eV (I-V)/0.88 eV (Cheung’s)/0.81 eV (Norde’s)]
increases compared with the MS junction [0.70 eV (I-V)/0.74 eV (Cheung’s)/0.72 eV (Norde’s)].
The ideality factor values were evaluated using thermionic emission theory and were found to be
1.09 for the MS junction and 1.35 for the MIS type heterojunction. The series resistance (RS),
ideality factor values extracted for the MS junction and MIS type heterojunction using Cheung's
functions were calculated to be 171 Ω, 1.24 and 3345 Ω, 1.43. The series resistance values were also
extracted from H (I) versus I plot and were found to be 459 Ω for MS junction and 15669 Ω for the
MIS heterojunction. Furthermore, the surface potential versus forward voltage curves of the MIS
heterojunction yielded a Schottky barrier height of 0.77 eV which is higher than 0.68 eV attained for
the MS junction. In conclusion, it was elucidated that the intentionally deposited PVA(Polymer)
insulating layer at the interface of Ni/n-Si it is influenced the electrical properties of the fabricated
Ni/PVA/n-Si MIS type heterojunction.
Keywords: PVA insulating layer; heterojunction Barrier height; Ideality factor; Series resistance;
Surface potential.
Acknowledgements
Authors would like to acknowledge DRDO for funding out the experiments.
Epoxy/glass composites reinforced with micro boron carbide (B4C) made by hand lay-up method.
The effect of micro B4C powder on dry sliding wear behaviour of epoxy/glass composites was
studied. Taguchi method was used to design the experiments and analyse the results. Incorporation of
B4C filler resulted in improvement of wear resistance of composites by 25.9%. The percentage
influence of selected composite parameters are 28%, 70.97%, 0.82% respectively, for filler content,
fiber volume percentage, and fiber orientation. The deformation mechanisms under dry sliding wear
were investigated using SEM photographs. The study of effects of selected machine parameters i.e.
load, speed, and sliding distance on weight loss of composite consisting of 2.5 wt% of B4C, 31.5
vol% of glass fiber, and 45˚ fibers orientation revealed that there is 53.19%, 27.81%, 15.60%
influence on wear loss.
Keywords: Epoxy-glass composites; boron carbide; sliding wear, Taguchi method, ANOVA
Acknowledgements
We acknowledge and give credit to MHRD for this research work carried out in NIT Warangal.
Acknowledgements
The authors wish to express their sincere thanks to JNTUH for the financial support through the
project JNTUH/TEQIP-III/CRS/2019/Physics/04.
Ion beam synthesis technique is used as one of the important tools for synthesis and processing of
nanostructures used in semiconductor device industries. The major challenge is not only to make the
devices smaller in size but also to optimize the synthesis process. Subsequent modification and/or
doping of these nanostructures (e.g. semiconductor nanowires) using low energy (kilo-electron-volt,
KeV) ion beams can significantly enhance their functional (optical, electronic and magnetic)
properties. These properties can strongly differ from the respective bulk counterparts due to the high
surface-to-volume ratio of the nanostructures. Ternary intermetallic compounds involving Fe and Co
are the most interesting due to their unique crystallographic structures and chemical phases. These
compounds exhibit remarkable magnetic, electronic and thermal properties. Various alloy thin films
involving Fe, Co, and Si have been formed using the chemical vapor deposition method. However,
there is not much research done on the synthesis of self-assembled Fe-Co-Si alloy Nano system using
ion implantation. In this study, we will be reporting the simulated and experimental results of 50 keV
energy Fe and Co ion irradiated Silicon wafers at various fluence. The simulation result shows that
for 50 keV ion-implanted in Si, both the Fe and Co ion concentration is saturated at a fluence of
2×1017 atoms/cm2 and higher. The Synthesized samples were annealed at different temperatures to
obtain various Fe-Si phases. The results show that for lower annealing temperature, Iron rich phases
are formed but for higher annealing temperature Iron based silicides are formed. We will report the
results from the subsequent implant of Fe and Co both at 50 keV [1]. We will also report the X-Ray
diffraction (XRD), Scanning Electron Microscope (SEM), and X-ray Photoelectron Spectroscopy
(XPS) measurements of the implanted substrate both as-implanted and after thermal annealing in
order to investigate the formation of various crystal structures in Silicon. We will report the results of
the similar dual ions implant in Si nanowire. Implanting ions into nanowires can modify their
properties and annealing the implanted nanowire at different temperatures can facilitate the formation
of various alloys in the nanowire. Finally, in this study, we will report the output results of various
ion-solid interaction simulation codes for Fe or Co ion-implanted into Si nanowires, which can be
utilized for the synthesis of ternary metal-silicon alloy nanostructures.
Keywords: Ion Implantation; Nano System; XRD; Thermal Annealing; XPS.
Acknowledgements: We would like to thank UNT High-Performance computing center
(https://hpc.unt.edu/) for providing computing time for the simulation.
Abstract
Milling is the most common form of machining process used in the production of
moulds/dies, due to the high tolerances and surface finishes by cutting away the unwanted material.
Please
The selection of Pre-hardened steel (P-20) is widely used in production of moulds/diesinsert
because of
photograph
less wear resistance and are used for large components. Due to extensive use of highly automated
of the
machine tools in the industry, manufacturing requires reliable models and methods for the prediction
presenting
of output performance of machining processes. author.
The major objective of the present study is experimental analysis of machining parameters in
end milling for surface roughness by considering the input parameters such as cutting speed, feed
rate, axial-depth of cut, radial depth of cut and nose radius using taguchi’s orthogonal array.
Keywords: Taguchi’s orthogonal array; P20 Steel; surface roughness; cutting speed; feed rate.
Acknowledgements
The authors hereby thank Mr. Durgesh Nadig, Senior Scientific Officer, Indian Institute of Science
Bangalore, India for his suggessions. Authors also acknowledge the support of Dr. Parthoghosal,
Scientist F, DMRL Hyderabad, India for analysis.
Acknowledgements
The authors thanks to Dr. M. Sudarshan and Staff of the UGC- DAE Consortium for Scientific
Research centre, Kolkata, India, for providing the facilities at their Trace Elemental Laboratory for
carry out the EDXRF experimental work.
Acknowledgements
We thank TEQIP and VGST (GRD-242 and GRD-441) for the financial support.
Acknowledgements
Authors like to acknowledge the National College, Jayanagar, Bengaluru and Center for Nano and
Materials Science for their constant support for this research.
L. Srinivasa Rao1*, Ch. Sai Phani Kumar2, K. Aruna Prabha2, C.D. Naidu1
1
Centre for Nanoscience and Technology, 2Department of Mechanical Engineering,
VNR Vignana Jyothi Institute of Engineering and Technology, Bachupally, Nizampet
(S.O), Hyderabad, Telangana, Pin- 500 090, India.
Li2O-B2O3 glasses were synthesized doping with TiO2 and co-doping with TiO2 as well as
ZnO nanoparticles by melt-quenching method. The samples were labelled as LB1, LBT2 and LBTZ3.
The XRD patterns of the prepared glass samples have shown two amorphous halos at small values of
2θ (≈ 22o and 45o) are attributed to the short-range periodicity of the glass network due to non-
bridging oxygens (NBOs). The FTIR spectra of the glasses have exhibited prominent bands due to
the trigonal BO3 units, tetrahedral BO4 structural units and bending vibrations of B–O–B linkages.
Also, absorption bands were clearly seen due to stretching vibrations of O-H bonds of moisture in the
glass samples. The rigidity of the samples follows order: LB1> LBT2> LBTZ3. The ESR spectrum of
the glass sample LBTZ3 has exhibited a spectral line centered at about g ≈1.94. The addition of ZnO
nanoparticles into the glass matrix leads to convert the non-magnetic glass sample into a magnetic
glass material; because some of Ti4+ ions may be converted as Ti3+ ions in the melt-quenching
process. Thus, we expect that these materials can find the potential applications such as solid state
electrolytes and magnetic sensors etc.
Keywords: ZnO nanoparticles, Oxide glasses,X-ray diffraction studies, FTIR spectra, EPR spectra.
Acknowledgements
Authors would like thank management of VNR VJIET, Hyderabad for sanctioning this project under
CNST establishment grant (File no. 17/VJ/1274).
Salavadi Stalin1*, Avula Edukondalu2, M.A. Samee3, Sair Md. Taqiullah4, SyedRahman1
1
Department of Physics, Osmania University, Hyderabad, India.
2
Department of Physics, University college for Women, Koti, Hyderabad, India.
3
Department of Physics, University college of Technology, Osmania University, Hyderabad, India.
4
Department of Physics, College of Science, Jazan University, Saudi Arabia.
*Corresponding author. Mobile: (+91) 9666670558; E-mail: stalinsmily@gmail.com
Abstract
Abstract
Among all transition metal dichalcogenides (TMDs), MoS2 shows very unique conducting
and optoelectronic properties, which makes it the most suitable material for fabricating real-time
sensors and atomically thin transistors. By chemical modifications, the MoS 2 can be made more
useful in the field of various gas sensors, biosensors, optoelectronic devices. In this study we present
a novel facile method to grow 2-D MoS2 thin films by electrochemical deposition technique. We
have successfully grown MoS2thin films on ITO substrates through functionalization of MoS2 nano-
flakes in the presence of monochloroacetic acid (MCA). The functionalization of trigonal prismatic
MoS2 flakes with carboxyl group was achieved through sonication of MoS2 solution in DI water in
the presence of MCA and KOH. Due to weak van der Walls force between the sulphur-sulphur layers
of MoS2 flakes, ultrasonic vibrations can easily intercalate the MoS2 flakes, creating sulphur
vacancies at the two outer side surfaces and further saturated by Cl atoms of the MCA, forming
composites of MoS2-COOH. The as grown composites were then driven through linear sweep
voltammetry on an ITO glass plate to form the MoS2 thin film by controlling the sweeping cycles.
The growth of the thin film was confirmed by the cyclic voltammetric current responses, which show
the corresponding change in oxidation peak currents after the deposition of COOH-MoS2 thin film on
the ITO substrates. It was further observed that the charge transfer decreases with the increase in
thickness of the thin films as expected from the thick MoS2 semiconductor. These 2D MoS2 can be of
immense use in designing new types of real-time semiconducting biosensors, gas and
electrochemical based sensors, and atomically thin 2D transistors.
Acknowledgments:
We would like to thank the Department of Science and Technology (DST), India for full financial
support of this research work with grant no.- ECR/2016/000818.
Acknowledgements
The authors gratefully thank Prof. C.Radhakrishnamurthy and Prof. K.GopalkishanRao of Central
Instrumentation Centre (CIC), Kakatiya University, Warangal for providing experimental facilities.
Abstract
The D-gun sprayed Cr3C2-NiCr coatings on three different superalloys when subjected to cyclic
oxidation in air at 900 oC for 100 cycles were found to be successful in maintaining its adherencey
with the substrate superalloys. The oxide scales were also found to be intact and there is no
indication of any spalling in all the cases. A saving in overall cumulative weight gain for Cr3C2–
NiCr coated superni 75, superni 718 and superfer 800H with respect to the bare alloys tend to be of
the order of 37.3%, 26.3% and 19.6% respectively. The Cr3C2–NiCr coating after exposure to air
oxidation showed the presence of mainly oxides of Cr in the upper region of the scale. In the
subscale region, the phases revealed were oxides of Cr and Ni, and their spinels, below the subscale
region, Ni-rich splats remained un-oxidised and provided protection to the superalloys against high
temperature oxidation.
The vast populations of countries with burgeoning economies increasingly require environmentally-
friendly day-to-day methods of energy generation. Most of the traditional methods rely on
petroleum-combustion systems which produce significant quantities of exhaust, causing serious
health conditions and air pollution. The increasing interest in renewable energies has highlighted the
centrality of catalytic metal nanoparticles (NPs) in sustainable energy-conversion technologies
including photocatalytic water splitting and polymer-electrolyte membrane fuel cells (PEMFCs).
Ethanol fuels, which can be produced via biochemical routes including fermentation, are of growing
importance to establish the desirable petroleum-free economy. However, ethanol fuels are still
precluded from broad use except as an additive to petroleum for traditional combustion systems
primarily because of the lack of efficient catalysts which promote complete oxidation of ethanol at
low temperatures to fully extract chemical energy without heat loss. To address this, we report that
Platinum based intermetallic nanoparticles (NPs) with early 3d metals (Nb, Zr and Ta)1-3, which are
materialized for the first time via a wet-chemistry route, exhibit substantially high performance
toward the complete electro-oxidation of ethanol at room temperature. The electro-oxidation of
ethanol fuels catalyzed by the TaPt3 NPs is accompanied by no toxic exhaust and is more energy-
efficient than combustion systems, allowing populations to improve their quality of life and reduce
the impact of their emissions on the global environment.
Keywords: Intermetallic Nanoparticles, Pt3Nb, Pt3Zr, Pt3Ta, Ethanol Electrooxidation.
In this paper, we report an extremely low cost and highly efficient method for fabrication of
visible light photo-detector using nano-crystalline lead sulfide (PbS) thin film. The film was
fabricated on 300 GSM paper via spray pyrolysis technique at 100 0C. Structural and morphological
analysis of the film confirms the nano-crystalline nature of PbS with size ~ 50 nm and uniform
coating of PbS on paper. Photo-detector devices are prepared by drawing contacts using 4B pencil on
the film by keeping a gap of 1 mm between electrodes. Photo-detection property of a nano-crystalline
PbS thin film under visible light illumination show linear I-V suggesting low resistive contact
between graphite electrode and PbS film. The photo-sensitivity measurements reveal excellent
sensitivity of ~ 103 at 20 V. For this graphite/nano-PbS/paper photo-detector, the best rise and decay
time is observed to be 7 and 16 ms, respectively. This simple and low cost fabrication method results
in highly stable and sensitive photo-detectors device, which have fast response and decay time.
Keywords: Nano-crystalline; PbS; spray coating; photo-detector, fast response and decay time
Abstract
Friction stir welding (FSW) was invented for the welding of dissimilar metals are difficult to weld by
other conventional welding method as fusion welding. FSW is a solid state joining welding technique
in which material undergoes intense plastic deformation at elevated temperature. Development of
FSW is considered to be most significant for the industry of automobile, aircraft and aerospace etc.
The joining of dissimilar metals is difficult by using traditional methods of welding because of inter
metallic compounds like Magnesium and Aluminium alloys. In order to enhance the joint strength,
The Friction stir welding is used which is a solid-state welding process. It is used to weld dissimilar
metals (or) unweldable metals.In this paper, review of dissimilar metals is presented by considering
the importance of the properties of friction stir welded joint of dissimilar metals.
Acknowledgements
One of the authors is thankful to TEQIP-III of REC Ambedkar Nagar for providing the financial
assistance for the project. Authors are also thankful to Dr. Sri Siva Kumar, Associate Professor,
Department of Chemical Engineering and Material Science Programme, IITK, for providing the
experimental facility.
Abstract Please
insert
The Activity deals with an automated article allocation and implementing actual administration photog
(pick
raph of
and place) for called items application apprentice system. It synchronizes the movement of automatic
the
arm to aces the altar affective on a agent belt. It aims in classifying the color (black, red, green, blue)
presen
and shaped altar (circular, aboveboard shaped preferable) which are advancing on the agent ting by
author.
acrimonious and agreement the altar in its corresponding pre-programmed location. Thereby
eliminating the terrestrial plan done by human, accomplishing accurateness and acceleration in the
work. The proposed arrangement makes use of avant-garde Raspberry Pi processor and aswell USB
camera to faculty the called altar affective on the conveyer belt.
The altar are sensed application an USB camera. When the article appears abreast to its around again
the arrangement captures an angel and fed as ascribe arresting the Raspberry Pi processor for added
implementation. The Raspberry Pi processor checks the captured angel from the predefined abstracts
abject like appearance and blush of the object. When the article detected matches with the called
appearance like blush and admeasurement again it activates the automatic arm motors application
interfacing circuits. The basal firmware for the Raspberry Pi is accounting in PHP/Python language.
The arrangement uses DC motor for the movement of conveyer belt and servomotor for automatic
arm gripper to aces the altar of corresponding blush and appearance from the anchored area at
accurate direction.
The Raspberry Pi is a low cost, credit-card sized computer that can be acclimated in electronics
projects. It is a able little accessory that enables humans of all ages to analyze computing, and to
apprentice how to affairs in languages like Scratch and Python. It’s able of accomplishing aggregate
you’d apprehend a desktop computer to do, from browsing the internet and arena high-definition
video, to authoritative spreadsheets, word-processing, and arena games.
Keywords: USB- Universal Serial Bus, DC- Direct Current, PHP- Personal Home Page
My project is about data logger using PIC micro-controller. When transporting the goods
from one place to another place or storing the goods in a certain place, the components should work
perfectly according to our application. Sometimes due to room temperatures also we can observe a
change in the component readings. So in that cases, data logger systems will be helpful. By using
those data log systems we can calculate temperature and humidity parameters. Then these readings
will be stored in a memory location so that these readings will be helpful for the future purpose. In
this type of temperature and humidity based data loggers, along with real time clock it will carry out
the measurements also.This project shows you how to get the temperature and humidity values for
particular components which are kept in a certain room or area or during the shifting process along
with the real time clock. Here we are measuring various weather parameters like temperature
humidity, time and date and all these process will be done by using PIC microcontroller. For this, we
require sensors for getting temperature and humidity values and a real time clock is used to get real
time. We can retain previous values also by using previous records. Finally, we can display these
parameters on the LCD display and save the records so that we can access the previous records. For
this storage we can use controller memory or else externally also we can connect a memory called
SD-card.
Keywords: IDE- MicroC pro for PIC, Simulation- Proteus software, PIC18F6527 microcontroller,
SHTxx sensor, Real Time Clock, 20*4 LCD- Display.
Due to physics based modelling parameter extraction with the compact model is fast. With very less
extraction effort, the compact model fits the dc current and capacitance characteristics accurately.
Keywords: Compact model, macro model, insulated-gate bipolar transistor, parameter extraction.
Abstract
Abstract
In mild of the present state of affairs of the metro cities and other large cities, girls protection
has emerged as one of the maximum crucial requirements in our country. In this international of
advanced era and clever electronics it's miles required to have a easy and value-powerful safety
machine that facilitates the sufferers for the duration of unforeseen dangers. This challenge covers
descriptive details about the design and implementation of prototype for an electronic machine
whichhastheabilitytoserveasaprotectionwearinsidethecomingyears.Thedeviceincludesa transfer,
ARM7, Wi-Fi module (ESP2866), GPS module (Neo6M), buzzer, Vibration sensor . The
predominant working of this undertaking is that every time a woman senses risk, all she has to do, is
to maintain at the button of the tool. Once the tool is activated, it tracks the region of the girls the use
of GPS (Global Positioning System) and sends place using Wi-Fi (wi-fi fidelity), to a server inside
the police control room. Here using electric powered shock for whilst she is in threat for safety. The
main gain of this system is that this tool small and clean to carry. The use of state-of- the-art
additives guarantees accuracy and makes it reliable.
Keywords: Smart grid, micro grid, battery energy storage system, BESS, renewable energy sources, hybrid
power, solar energy, lead acid and lithium ion batteries.
Acknowledgements
I would like to express my special thanks of gratitude to Dr.M.Sushama, Professor, Department of Electrical
and Electronics Engineering, JNTU Hyderabad for her support and cooperation in doing this paper.
Abstract
The goal of this project is to develop advanced signal control strategies for mobility, safety, and
environment based on connected vehicle data, i.e., real-time information on vehicles’ location, speed
and characteristics as well as communication to the signal control infrastructure. This document is
the final report for the project. It describes the findings from the literature review on existing
adaptive signal control systems, their features and operational experiences from their
implementation. Several performance measures are proposed for evaluating signal control
algorithms, and procedures for estimating the performance measures from connected vehicle data
were developed using statistical techniques and kinematic wave theory. We developed and tested
through simulation a number of control strategies to improve mobility: queue spillback avoidance,
control for congested networks, and dynamic lane allocation. The results indicate that the proposed
strategies improve the traffic performance. We also developed strategies for improving intersection
safety with emphasis on avoidance of red light running (RLR) related collisions. A prototype in-
vehicle driver speed advisory system for minimum fuel consumption and emissions was also
developed. Field tests show that the prototype system achieved significant fuel savings.In addition,
when an ambulance approaching the junction, it will communicate the traffic controller in the
junction to turn on the green light. This module uses Zigbee modules on CC2500.
Emotions play a very important role in our day to day life. Emotions are the natural physiological
response of the human bodywhich can be recognized by the facial expression. In the proposed system
research has been done in the field of Human Computer Interaction (HCI). The entire project is
divided into three majorsteps i.e. face detection, facial featureextraction and classification. In the
firstphase face detection has been done using Haar Cascaded frontal face algorithm. The system
detects and crops the lip region forfurther classifications, then the features areextracted into
vectorized form. Extracted features are compared with traineddatabase using Logistic Regression.
The main hardware used in this project is Raspberry pi with linux based OS toneglect the drawbacks
of personal computer and for better picture quality 8MP USB Camera is used.
Keywords: HCI- Human Computer Interaction, 8MP USB Camera.
Electricity is essential for daily life of the people and also for strengthening the economy.
Over the past few years, the electric power industry, in many countries, has undergone significant
changes in the total installed generation capacity using both conventional and non-conventional
energy sources. Despite of this remarkable progress, economy is still facing an enormous need to
meet the growing demand of electricity thereby increasing the competition offering opportunities to
number of generating companies, to deliver the electric power with same local service, same local
quality, and same local load delivery. This rapid increase in the power generation from various
emerging integrated energy sources are becoming a challenge to the existing transmission network.
Considering calculation accuracy and time this paper proposes two different computational
approaches viz.,(i)Neural networks Radial Basic Function(RBF) ,(ii)Monte Carlo simulation to
continuously compute Available Transfer capability (ATC) of a IEEE 14 bus transmission test
system to withstand the contingencies more efficiently in case of load change and line outages to
give accurate results so as to upgrade it in a deregulated transmission network. The results of the two
proposed techniques are compared to obtain accuracy for optimization in a deregulated environment.
Acknowledgements
Sincere thanks to the authors for their kind co-operation and support in completion of paper.
Dr. J.S. Sudarsan1, Jyesta.W2, Jaisal.D2, Dr. V. Sri hari3, Pola Vamshi4*
1
Asst. Professor, School of Construction Management,
2,4
PG Students Advanced Construction Management, National Institute of Construction
Management (NICMAR), PUNE – 411045,
3
Professor, NICMAR, Hyderabad 500101, India
*Corresponding Author. Mobile: (+91)9642602396; E-mail: vamship32@gmail.com Please
Abstract insert
photogr
aphsignifies
The different types of human exercises particularly those recognized with development, of
the
outflow of ozone depleting substances, greenhouse emissions that outcome into an Earth-wide
presenti
temperature boost and environmental change. This affects nature and leads to imbalance
ng in the
author.
environment and ecosystem. Henceforth it has turned out to be important to reduce dangerous
atmospheric changes by some sustainable mitigation processes. In all the greenhouse gases, CO2 is
the main compound that adds to a worldwide temperature alteration. Thus it is fundamental
responsibility for every person to control the carbon outflow by understanding the concept of
sustainable development.
Carbon footprint estimation for an institutional and residential building was done separately for each
component of structure or as a whole organization. The reason for this investigation includes
distinguishing proof and examination of different emission inventories and the measure of carbon
transmitted by them regarding an institutional structure and the residential building materials also
assessed. Furthermore this study examines the current methodologies and approaches to estimate
carbon footprint in an institutional building and residential building in Karnataka.To ascertain the
status of carbon emission in the residential building materials a study was carried out in a proposed
residential structure. It was concluded that the existing institutional building is carbon positive and
also the amount of carbon emission by building materials used in the residential building also
contribute to carbon footprint results to carbon positive. So as to lessen the emission and to convert
the institutional structure and the residential building materials from carbon positive to carbon
negative, general mitigation measures are recommended and by implementing the same how much
carbon emissions also reduced was discussed .This research study also helps in creating awareness
about the impact of amount carbon emissions happening in an institutional building due to different
activities among the students, faculties and other public/Stake holders.
Keywords: Greenhouse effect, Carbon foot print estimation, Institutional building, Carbon positive,
Carbon Negative.
Keywords: MHD; Jeffrey fluid; Thermal radiation; Element Free Galerkin method.
Abstract
Highly flexible, secured and bi-directional communicationinfrastructure for power system data
exchange is the stepping stone for the success of smart grid vision. Traditionally, wired
communication is the first choice for monitoring, protection and control systems. With advent in
communication technologies, the wireless technologies have also emerged as potential contender for
data communication in various industrial applications. Wireless technologies have distinct
advantages over wired in terms of higher mobility, lower installation cost and faster deployment
among others. The deployment of wireless technologies for monitoring and control systems of Smart
Grid namely WAMS has been largely unexploited area. This paper devises a systematic approach
that identifies the communication requirements of WAMS, defines the capability of various wireless
technologies such as Wireless LAN (WLAN), Wi-Max, Wi-Fi, GSM, GPRS etc. based on
performance criteria and selects the potential wireless communication technologies for WAMS based
on closest match. The WAMS communication requirement specifications have been arrived based on
Indian Smart Grid case studies. The paper also discusses the challenges and hence opportunities
associated withimplementation of wireless technologies for Smart Grid.
In the current research car tracking optimization (CTO) technique is introduced to solve the optimal
power flow problem in an electrical network.With the introduction of new adaptive global velocity
updating method and local speed updating method, the CTO technique is capable to find the optimal
solution. IEEE 30-bus system with different objective functions are considering in the present work
to validate the effectiveness of the proposed algorithm. The attained results are compared with the
results in the existing literature. These results proved that the demonstrate that the CTO algorithm
provide better results in comparison to the other algorithm methods.
Keywords: Optimal Power Flow, Fuel Cost, Evolutionary Algorithm, Car Tracking Optimization
Technique
In recent years, due to the consumers need to electricity with the least outages and the highest
reliability, power continuity of the electrical systems have been highly regarded by companies in the
electrical distribution field. Complexity in the process of distribution automation and manually
restoration mechanism in modern distribution networks cause longer duration of outages and make
the need to a reliable model for automatic fault location, isolation and service restoration (FLISR)
process necessary. In this study, a mathematical model of the FLISR process in a distribution
network is presented based on formal methods. The proposed model correctness has been
investigated by evaluating its important properties consisting liveness, reachability and deadlock
free.
Keywords: Distribution automation; fault analysis; automation; reliability.
Acknowledgements
I would like to express my special thanks of gratitude to Dr.M.Sushama, Professor, Department of
Electrical and Electronics Engineering, JNTU Hyderabad for her support and cooperation in doing
this paper.
I would like to express my profound sense of gratitude indebtedness to Ch. Kavitha, student,
Department of Electrical and Electronics Engineering for her valuable cooperation at each and every
phase of the work.
Abstract
As brass materials are having high strength and high resistance towards corrosion, along with
high thermal and electrical conductivity, these were the reasons for their wide usage in the industry
as engineering materials. Although they have good appearance, they can also be shaped easily.
Anyhow, fusion welding of brass is a difficult task, as during the process of fusion welding zinc
evaporation has been a major concern which these alloys which affects its chemical and physical
properties. Many researchers have been working for the new methods as problems due to fusion
welding are not getting solved in case of brass. In this scenario Friction stir welding is one of the
novel methods to solve these problems. Then, experimental investigations were needed in this
domain. Although decent research works have been reported on FSW of Aluminium, copper and
their alloys, but constrained work has been done in case of brass. This research aims to determine the
optimum parameters for FSW of brass and corrosion test, tensile test, environmental tests, surface
morphology and surface metallurgy results has been examined on the obtained weld joints.
Keywords: FSW, Brass, Tensile strength, Surface integrity, Surface morphology, Corrosion test.
Abstract
A novel design of optical directional coupler switch with S-bend waveguides on LiTaO3
platform has been designed with R-Soft CAD tool and the same is simulated by Beam
propagation method(BPM) for light propagation analysis. The simulation results of optical
directional coupler switches are reported. We observed that the directional coupler (DC) switch
has lower insertion losses and higher extinction ratios with variation in waveguide parameters such
as, wavelength, waveguide gap, and length of the device. Simulation results designate that the
switching efficiency for TE and TM modes with extinction ratio about 3dB when the
waveguide gap is 3.5μm for both the polarization modes and insertion loss is 13dB with same
waveguide gap in TE mode and 16dB in TM mode at 1550 nm wavelength.
Abstract
This paper addresses free convection heat transfer in a square cavity filled with ethylene glycol
nanofluid containing (Fe3O4) in porous square cavity in the presence of thermal radiation. The top
and bottom horizontal walls of cavity are considered adiabatic, while the vertical walls are kept at
constant temperatures. The governing partial differential equations are solved by Galperin’s Finite
element method of weighted residual scheme. Numerical results are computed for certain pertinent
parameters: Rayleigh number (10-1000), radiation parameter (0.1-1) and nanofluid volume
fraction(0.1-0.5). The overall investigation of variation of streamlines, isotherms and Nusselt
numbers is presented graphically. To examine the accuracy, the present results are compared with the
available results and found to be in good agreement.
Keywords: Ethylene Glycol; Nanofluid; Fe3O4; Porous square cavity; Thermal Radiation,
A voltage-controlled oscillator (VCO) [1] is one of the key parts of electrical impedance
spectroscopy (EIS) [2] system which measures the electrical impedance of a material at different
frequency points within a particular bandwidth to study its frequency response. EIS instrumentation
[3] needs a function generator to generate an alternating voltage signal which is, generally, converted
into a constant amplitude current signal to inject it to the sample under test (SUT) and the sample
impedance is estimated by measuring the surface potential developed. On the other hand, the voltage
signal is also, sometimes, directly injected to the SUT to measure its electrical impedance from the
current signal developed due to the voltage applied. An automatic EIS instrumentation essentially
needs an automatic sinusoidal voltage generation at different frequencies which is generally obtained
by a VCO controlled by a microcontroller or any other electronic controlling unit such as PC based
Data Acquisition systems [4]. In this paper an Arduino UNO [5] based Multifrequency-VCO (Mf-
VCO) is developed for EIS studies. The VCO is developed with function generator circuits which
generates the sinusoidal voltage signal at different frequencies by changing the value of few passive
components connected to the IC as the frequency controlling components. The frequency controlling
components are connected to the VCO through an analog multiplexer circuits (AMC) operated by the
digital signals to generate the signals with required frequency values. The digital signals are
generated in Arduino board through its digital I/O pins and fed to the AMC to control the frequency
generation in VCO. The digital signal generation and AMC operation are assessed by LED based
digital signal evaluator (LED-DSE) to assure the connectivity of the passive components and
frequency control. Results show that the Mf-VCO is suitable for EIS studies of biological samples
within a wide bandwidth
Acknowledgements
Please acknowledge the funding authorities and other research supports.
Abstract
Epilepsy is a brain disorder or an abnormal activity of the central nervous system in which the human
brain malfunctions for a certain period of time, causing unusual behavior, sensations, and sometimes
loss of awareness or seizures. An epileptic seizure, which is caused by the inconsistent electrical
activity of the brain, is found as a period of unusual symptoms excessive or synchronous neuronal
activity in the brain. Noninvasive detection of epileptic seizures is an important role with many
advantages in medical science to assist doctors to diagnose and treat the patient. EEG based epileptic
seizure detection is a fast technology that generally combines electronic instrumentation and the
signal processing algorithm. In this paper, an EEG acquisition system (EAS) has been developed
with a multi-stage amplifier and filter blocks. The instrumentation is studied, tested and evaluated
with low voltage, low-frequency periodic signals generated with a function generator developed with
Wien Bridge oscillator circuit. The instrumentation has also been studied with the EEG-like signals
simulated by a virtual instrumentation (VI) developed with NI MyDAQ controlled by a LabVIEW
based graphical user interface (GUI). The instrumentation noise response is studied by measuring the
SNR of the circuit blocks using the test signals with and without noises. The SNR is obtained at each
stage of the circuit blocks and the overall SNR of the EAS instrumentation is measured and
compared. Results, obtained from the experimentation conducted with the real periodic signal as well
as the EEG waveforms simulated by VI, show that the developed EAS is suitable for acquiring and
amplifying the EEG signals and suitable for detection of epileptic seizure.
Acknowledgements
Research support has been provided by NIT Durgapur (NITDgp), West Bengal 713209, India.
Biological tissues are developed of a three-dimensional array of the cells surrounded by the
extracellular matrix. Biological cells consist of a nucleolus floating within a sap like intracellular
material called cytoplasm containing cell organelles. The intracellular matrix is enclosed by an
envelope called a cell membrane composed of a protein-lipid-protein bi-layer structure. In the plant
cells, there is an another envelope called cell wall over the cell membrane. The cell wall is developed
with a comparatively rigid material to make a solid structure for plant tissues. Under an alternating
electric excitation, all the biological tissues, both the animal tissues and plant tissues, exert a complex
bioelectrical impedance which is a function of tissue materials as well as the applied signal
frequency. Due to the difference in the anatomical structural and material compositions, the
impedance models differ in tissue type. Moreover, it is obvious that the equivalent cell models of
plant cell and animal cell are different. Due to the variation in their single-cell model, the frequency
response of the electrical bioimpedance of the animal cell and plant cells. Consequently, the
impedance responses of animal and plant tissues are found remarkably distinguishable. The present
paper investigates the electrical impedance response of the biological cells with electrical impedance
spectroscopy (EIS). The animal and plant cell models are developed in Matlab and the EIS studies
are conducted for their single-cell structures. Complex bioimpedance and their phase angles are
calculated within a wide frequency range and the Nyquist plots are analyzed by estimating the real
and imaginary part of the bioimpedance. Comparative studies are also conducted for the multicell
model of both the animal and plant tissues.
Keywords: Biological tissues,biological cells, cell membranes, bioelectrical impedance, animal cell
model, plant cell model, electrical impedance spectroscopy (EIS).
Acknowledgements
Research support has been provided by NIT Durgapur (NITDgp), West Bengal 713209, India.
1
Department of Mathematics, CMR Technical Campus, Kandlakoya, Telangana ,India 501401
2
Department of Mathematics, GITAM University, Hyderabad, Telangana, India 502329.
3
Department of Mathematics,B V Raju Institute of Technology,Narsapur, Telangana, India 502313.
Corresponding authors:1.mswethamaths@gmail.com; 2.drbalasiddulu.malga@gitam.edu
Abstract
This paper studies the effects of viscous dissipation, chemical reaction and heat
generation/absorption on unsteady MHD Casson fluid flow over an exponentially accelerated
vertical plate embedded in porous medium with ramped wall temperature and ramped surface
concentration. By introducing the similarity variables, the dimensional governing equations are
converted to non-dimensional form and solve numerically by using Galerkin Finite element method
and expressions for velocity, temperature and concentration profiles are obtained.
The change of velocity, temperature and concentration profiles effected by the following parameters
such as Prandtl number(Pr), Casson parameter (√), permeability parameter (k), Schmidt number
(Sc), Grashof number (Gr, Gm), chemical reaction parameter R, heat generation / absorption
(H),Eckert number (Ec) and results are presented graphically and discussed quantitively.
Keywords: Finite element method, chemical reaction, Eckert number, Casson parameter, heat
generation/ absorption.
Smart interactions among the smart grid, aggregators and EVs can bring various benefits to all
parties involved, e.g., improved reliability and safety for the smart gird, increased profits for the
aggregators, as well as enhanced self benefit for EVcustomers. The impact of plug-in electric
vehicles (PEVs) integrated into a powerdistribution system based on voltage-dependent control. The
gasoline gate situation has many peopleturning to electric vehicles as a more environmentally
friendly option, especially in smart communityareas. The proposed PEVs model was developed as a
static load model in powerdistribution systems under balanced load conditions.The topology of the
proposed charger consists of the bidirectional ac/dc and buck–boost dc/dc converters, where it can
operate in four quadrants in the active-reactive power plane with the capability of harmonic
compensation. Based on the PQ theory, the active and reactive power that includes average and
oscillatory components obtained, based on the demand of nonlinear/linear loads and EV battery. In
this paper presents the design of a single-phase electric vehicle (EV) on-board bidirectional charger
with the capability of power conditioning based on its control in charging/discharging active power
based on the demand of EV battery/network or load. The proposed approach was validated and
implemented in softwarepackages like MATLAB/OPALRT or etc to integrate the fidelity of the
physical simulation and the flexibility of the numerical simulations.
Keywords: Plug-in Electric vehicles; smart charging; PQ theory, EV battery; Physical simulation.
Acknowledgements:
The authors would like to express highest gratitude to the Faculty of Electrical and
Electronics Engineering, CVR College of Engineering for providing the effective facilities and
efficient learning environment in conducting the research. The research is supported by the
research grant of JNTU-TEQIP3 Collaborative Research Proposal “Multi-agent system for Energy
Management of Renewable and Alternative Energy in Domestic Cooking” of Rs 2, 15,000 Lakhs.
Heat and mass transfer on the unsteady two dimensional MHD flow through porous medium
under the influence of uniform transverse magnetic field in a rotating parallel plate channel. A
mathematical model is developed for unsteady state situations using slip conditions. Analytical
expressions for the velocity, temperature and concentration profiles, wall shear stress and rates of
heat and mass transfer have been obtained and computationally discussed with respect to the non-
dimensional parameters.
Keywords: MHD; rotating channels; porous medium; heat and mass transfer.
Ternary transistion metal sulfides are promising electrode materials due to its low
electronegativity and high conductivity, higher electrochemical activity in compare to transition
metal oxides and single metal sulfides. In this research work, ZnCo2S4 nanoparticles have been
successfully prepared through a simple, cost-effective hydrothermal synthesis method for high
performance supercapacitors. The resulting samples were carefully characterized by X- Ray
Diffraction (XRD), Scanning Electron Microscope (SEM) with Energy Dispersive X- Ray Analysis
(EDX), Transmission Electron Microscope (TEM), and X-Ray Photoelectron Spectroscopy (XPS)
respectively.The electrochemical measurements were systematically applied to investigate the
performance of the ZnCo2S4 nanomaterials electrodes. The supercapacitor performance of ZnCo2S4
nanoparticles presented an obvious enhancement in specific capacity and cycling stability.
Electrochemical impedance spectroscopy result illustrated that the prepared sample possesses a much
lower charge transfer resistance. The experiment proved that the ZnCo2S4 nanoparticles are
promising electrode materials for next generation of energy storage devices.
Zn(NO3)2
TERNARY
CO(NO3)2
+6H2O +6H2O (SC METAL
(NH2)2), SULFIDES
CALCINATION
Acknowledgements
Please acknowledge the funding authorities and other research supports.
Acknowledgements
The author, S. J. Margarette is thankful to UGC for providing aid through Maulana Azad National
Fellowship, New Delhi, India.
N. Sangeetha1, P. Vickraman*
1
Solid State Ionics Lab, Department of Physics, The Gandhigram Rural Institute -
Deemed to be University, Gandhigram-624 302, Dindigul District, Tamil Nadu, India
The emergence of multiferroic materials has recently paved a way for theirengrossing
applications invarious devices such as spintronics, memory, sensors and photovoltaics [1]. Bismuth
ferrite(BFO) materialappears to be a potential candidate especially for memory and photovoltaic
devices owing to its intriguing features like low optical bandgap (2.08 - 2.7eV), large remnant
polarization(90 µC/cm2) and co-existence of different ferroic orders [2,3]. However, the practical
application of this material is still hindered due tothe inherent limitations which include large leakage
current density and pure phase formation of BFO compound. Keeping this view in mind, we have
successfully synthesized the pure phase of BFO nanoceramics by adopting low temperature sol - gel
synthesis route and studied the effect of annealing temperature and time on thestructural,
morphological, optical and dielectric properties of these ceramics. The as-prepared samples were
calcined at 400oC and subsequently annealed at various temperatures (500oC, 550oC, 600oC) for
different durations (2h, 4h, 6h). Interestingly, the sample annealed at 550oC for 2h almost yielded
pure phase of BFO ceramics and the average crystallite size of these ceramicscalculated based on
Williamson-Hall method was found to be increasing with both increase in annealing temperature and
duration. The infrared spectra (FTIR) recorded for all these samples exhibited strong absorption
bands in the range of 400-600 cm-1 which corroborated the perovskite structure of BFO
nanoceramics. The microstructural analyses have revealed the existence of granular shaped grains
with negligible porosity in all the samples studied. However, the samples annealed at higher
temperatures for longer duration showed the agglomeration of the grains in the scanning electron
micrographs. The optical bandgap was determined for all the samples prepared under various
annealing conditions by using Kubelka-Munk method. It is interesting to note that the value
ofbandgap of these ceramics could be tuned as a function of annealing temperature andduration. For
instance, the value of the optical band gap obtained for the pure sample annealed at 550oC for 2h was
found to be 2.08 eV. The dielectric properties of pure BFO nanoceramicswere carried out by using
LCR meter in the frequency range of 20Hz - 1MHz at 300K and the dielectric constant was found to
decrease with increase in frequency.Therefore, the tailoring of physical properties of BFO
nanoceramics in the present work by aforementioned thermal treatment parameterscould be
beneficial for designing memory as well as photovoltaic devices.
Keywords: Multiferroics; Bismuth ferrite; Bandgap; Dielectric properties
Acknowledgement
We acknowledge DST - SERB for funding this project and also BITS - Pilani, Hyderabad campus for
providing infrastructural facilities to carry out this work.
ICMM-2019 187 Book of Abstracts
ICMM: 2125 | Silver Nanoparticles on Modified Flexible Substrates for
Electronics Applications
Gurumurthy S. C.1*, Anju Jolly1, Koduri Ramam2, Shridhar Mundinamani3, B. SNagaraja4
1
Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher
Education, Manipal -576104, India
2
Departamento de Ingeniería de Materiales (DIMAT), Facultad de Ingeniería (FI),
Universidad de Concepción (UdeC), Concepción, CHILE.
3
Department of Physics, Siddaganga Institute of Technology, B H Road, Tumakuru-
572103,India
4
Department of Physics, NMAM Institute of Technology, Nitte, Udupi- 574110,
Karnataka, India
Acknowledgements
Authors would like to thank Dr. Mohan Rao K, Manipal Institute of Technology for extending the
lab facilities to carry out the research work.
Acknowledgements
Authors thankfully acknowledge IIT(ISM), Dhanbad for providing research facilities.
Acknowledgements
M. Gurulakshmi is thankful to DST-INSPIRE for awarding JRF, financial support through IF
160564. M. Raghavender thanks SERB, DST (Grant No. EMR/2016/007049) for financial support.
The LiNi0.8-xZnxCo0.1Mn0.1O2 (x = 0.0 and 0.05) cathode materials are synthesized by the
sol-gel auto-combustion method. The structure, morphology and bonding nature of the synthesized
materials are characterized by XRD, FE-SEM with EDS and FT-IR studies. It is observed that the
lattice constant values for the Zn substituted layered materials are increasing than the base material
LiNi0.8Co0.1Mn0.1O2. As a result, more Li+ could be inserted/extracted. The charge/discharge curves
of the synthesized materials with the current rates of 0.1C between 2.6 V and 4.8 V is shown at room
temperature. The charge/discharge capacities for the first and second cycles are 176.1/162.7 and
163.7/150.3 mAh/g−1 respectively with capacities of 92.4 % and 91.81 % respectively.
Over the past two decades, multiferroic materials in its composite forms have been an
important topic of research with a variety of applications such as low-power sensors, energy
harvesting devices, memory devices, magnetic refrigeration etc., have been investigated.In this work,
a tri-layer laminates of Fe75Ga25-(Ba0.85Ca0.15)(Zr0.1Ti0.9)O3-Fe75Ga25 has been fabricated and their
magnetoelectric properties were studied for energy harvesting applications. For this purpose, a lead
free piezoelectric (Ba0.85Ca0.15)(Zr0.1Ti0.9) ceramic powder has been prepared through solid state
reaction method and sintered at 1500oC for 5hr. Its structure has been confirmed with XRD analysis.
The Ferroelectric hysteresis loops were measured with a Prof 5.8 μC-cm-2 has been recorded.
Samples were poled at 1 kV for 10 minutes and piezoelectric charge coefficient (d33) values were
found to be in the range of 200 to 260 pC/N. On the other hand,Fe75Ga25 alloy was prepared by
powder metallurgy route by maintaining the proper Fe and Ga ratio’s and confirmed its A2 phase
structure. Magnetostriction of ~140 µ-strains has been achieved in this alloy. Finally, a tri-layer
laminate structure consisting of Fe75Ga25-(Ba0.85Ca0.15)(Zr0.1Ti0.9)-Fe75Ga25 has been made with the
thickness of 1mm each and with a diameter of 12 mm. Magnetoelectric measurement were
performed and showed a ME coefficient of 13 mV/Oe-cm. The results are discussed and compared
with the literature.
Acknowledgements
The authors thank Group Head and staff of Advanced Magnetics Group, DMRL forthe support.
Authors also thank Director, DMRL for giving the necessary permission to publish this work.
Bhupesh G. Nemmaniwar
Department of Physics Digambarrao Bindu Arts, Commerce and Science College,
Bhokar, Dist. Nanded – 431605(MS) India.
Mobile No. 9423306864, E-mail –bhupesh.nemmaniwar@rediffmail.com
Abstract
The dielectric relaxation measurements in the frequency range of 10 MHz to 30 GHz and at
temperature range of 0 °C to 25 °C using a picosecond time domain reflectometry technique have
been carried out over entire concentrations of binary mixtures 2-Chloroaniline with 2-
methoxyethanol. The complex dielectric permittivity spectra of 2- CA with 2-ME binary mixture
were fitted using Havriliak–Negami equation. The static dielectric constant and relaxation time for
all concentrations were obtained using least square fit method. The principal relaxation time is small
if compared to that of corresponding aniline/alcohol binary mixtures this may be due to the hydrogen
bonding ether oxygen in the 2-CA/2-ME system. The results are interpreted in terms of
heterogeneous interactions among the unlike molecules due to hydrogen bonding.
Keywords: Dielectric Permittivity, Dielectric loss, Relaxation time, Static dielectric constant, 2-
Chloroaniline with 2-Methoxyethanol.
Acknowledgements
Authors are thankful to School of Physical Science Swami Ramanand Teerth Marathwada
University, Nanded for availing the laboratory facility. We also thank Prof. Kumbharkhane A.C. for
the discussion and help full suggestion.
Abstract
We report pressure induced structural, topologicalphase transitions and Fermi surface in MTe
(M = Ca, Sr, Ba) compounds under high pressure using first principles calculations based ondensity
functional theory. CaTe[1], SrTe[2] and BaTe compounds undergo first order structural
phasetransition from NaCl-type (B1) to CsCl-type (B2) phase at 24.2, 14.7, 4.9 GPa respectively and
are consistent with the experimental observations [3].Electronic structure of MTe compounds were
calculated using Tran Blaha-modified Becke Johnson(TB-mBJ) potential and its new
parameterizations. The calculated band gaps are improved using TB-mBJ and itsnew
parameterization when compared to standard LDA/GGA functionals [4]. MTe compounds are found
to be indirect band gap semiconductors at ambient conditions and becomes semimetal upon further
compression. The high pressure B2 phase of (Ca/Sr)Te and BaTe are found to be node-line and
Dirac semimetals, respectively.
Keywords: High pressure, Topological phase transitions and Semimetal.
Acknowledgements
The authors would like to thank RGUKT Basar for the computational facilities.
magnetization (Ms) increased whereas coercivity decreased with the decrease in measuring
temperature. The highest Msvalue of 84 emu/g was observed at 60K and the highest coercivity of
3.12 kOe was observed at 300K. Dielectric studies were done at different temperature. Dielectric
constant and resistivity decreased with the increase in frequency whereas ac conductivity increased
with frequency.
Fig.1. (a) XRD pattern and (b) M-H Loop of Ba0.5Sr0.5Fe12O19 annealed at 1200°C.
The voltage induced in the coil (solenoid or inductor) depends on number of turns of coil, rate of change
of flux and permeability of core material. It was observed that the induced voltage in a coil can be
further increased, if the temperature of ferromagnetic core material is increased. The variation of
Please insert
inductance and effective resistance of the coil in the presence of heated ferromagnetic cores and
photograph
Coefficient of induced voltage,Coefficient of permeability for different ferromagnetic core
of materials
the are
presenting
also measured. All these parameters were measured for ferromagnetic Mild Steel, Cobalt and Nickel as
author.
core materials in horizontal setup and vertical set up. In this paper variation of induced voltage,
inductance, effective resistance of the coil and Coefficient of induced voltage, Coefficient of
permeability in the presence of heated ferromagnetic Mild Steel, Cobalt and Nickel as core materials are
measured and reported in the vertical setup as comparative study.
Acknowledgments
This research was supported by Basic Science Research programme through the University Grant
Commission (UGC - BSR), India.
Abstract
The growth of Cadmium Magnesium Oxalate (CMO) crystals were achieved successfully by
gel technique. The effect of various parameters such as specific gravity of Sodium Meta
silicate(SMS), concentration of oxalic acid solution, concentration of reactants cadmium chloride and
magnesium chloride, gel set time of the crystals have been studied. The study of FTIR spectrum
reveals the presence of various bands of functional groups. The study of UV-Vis spectrum shows that
optical transparency of the grown crystals. The absorption co-efficient and energy band gap were
discussed and reported.
Acknowledgements
Authors are thankful to Mangalore University for Sanction of fellowship, PURSE and USIC for
providing laboratory facility.
Jismon Sebastian1, Subash Gopi2, Sreeja E2, Adon Jose2, Krishnapriya T2,
P.R. Biju2*
1
Sacred Heart college, Thevara, Ernakulam, 682013, India
2
School of Pure and Applied Physics, M G University, Kottayam, 686560 India
*P.R. Biju. Mobile: (+91) 9446316179; E-mail:prb.mgu@gmail.com
Abstract Please
insert
3+
The present work reports structural and luminescence studies on Dy doped
photograp
h of 2O
borofluorophosphate (BFPDY) glasses prepared with the chemical composition of (40-x)B the
3 +
presenting
30P2O5 + 10ZnF + 10K2O + 10BaO + xDy2O3, where x = 0.1, 0.2, 0.5 and 1 mol% by melt
author.
quenching technique. The structural and optical properties of the prepared glasses were analysed by
means of XRD, FTIR, UV-Vis absorption spectroscopy and photoluminescence emission and
excitation spectra. XRD results confirm the amorphous nature of glass and FTIR studies reveals the
presence of various stretching and bending vibrations of different structural units within the sample.
The optical absorption spectrum has been recorded at room temperature and different absorption
transitions were obtained and it is found that the transition via 6H15/2→6P7/2 is more prominent. From
the absorption spectrum, optical band gap energy, nephelauxetic ratio (β) and the bonding parameter
(δ) were determined. Excitation spectrum was recorded in the region 300-500 nm by monitoring
emission at 572 nm and characteristic excitation bands were observed. The band at 348 nm arising
through the transition 6H15/2→6P7/2 shows maximum intensity. The photoluminescence spectra of the
filled glasses have been recorded at an excitation wavelength of 348 nm and the spectra contain two
intense emission bands in the blue (483 nm) and yellow (572 nm) regions and a weak band in the red
region (663 nm). Concentration dependent variations in emission intensities were analysed. It is
observed from the emission spectra that the luminescence intensity increases with the increase in
Dy3+ ion content up to 0.5 mol% beyond that it decreases due to luminescence quenching. The Y/B
intensity ratio by varying the concentration of Dy2O3 is also studied. The emission intensity were
characterized through Commission International d’Eclairage (CIE) 1931 chromaticity diagram to
explore its suitability for white light emission applications.
Keywords: Nephelauxetic ratio; Luminescence quenching; Y/B intensity ratio; CIE color
chromaticity coordinates
Abstract
The glasses with the composition 50Bi2O3-15MO-20B2O3-15Li2O (where M= Zn, Cd, Ba and
Pb) were prepared by conventional melt quenching method. The glasses were characterized using X-
ray diffraction (XRD), Fourier Transform Infrared (FTIR), Differential Scanning Calorimetry (DSC)
and optical absorption. XRD patterns of the glasses confirmed the amorphous nature of the glasses.
FTIR showed that the glass networks consist of bismuthate and borate groups. The glass transition
temperature (Tg), onset crystallization temperature (To) and thermal stability (∆T) of all the glasses
were determined from DSC. The optical absorption studies revealed that the cut-off wavelength (λc)
decreases while optical band gap energy (Eopt) and Urbach energy (∆E) values increases with MO
content. Refractive index (n) evaluated from Eopt was found to decrease with varying of MO content.
The physical parameters such as density (ρ) molar volume (Vm), oxygen packing density (OPD),
optical basicity (Λ), molar refraction (Rm) and metallization criterion (M) were evaluated and
discussed.
Keywords: Glasses, FTIR, DSC and Optical absorption
Abstract
In the present communication, we report the synthesis of pure cobalt ferrite nanoparticles using sol-
gel auto combustion method in which glycine was used as a fuel. The prepared nanoparticles were
characterized structurally by means of X-ray diffraction technique. The analysis of the XRD pattern
reveals the formation of single phase cubic structured compounds. The structural parameters like
lattice constant, X-ray density, Unit cell volume etc all are in good agreement with the literature
values. The crystallite size obtained through Debye-Scherrer’s formula found to be in nanometer
dimension exhibiting the nanocrystalline nature of the prepared samples. The magnetic properties
were investigated using pulsed field hysteresis loop tracer at 300K. The saturation magnetization
(MS) show significant enhancement as compared to bulk counterpart. The values of other magnetic
parameters like coercivity, remenance magnetization, magneton number etc obtained through M-H
hysteresis plot show the prepared multifunctional cobalt ferrite can be used for data storage
applications..
Keywords: Cobalt ferrite nanoparticles, sol-gel auto combustion, XRD, M-H plot.
Acknowledgements
One of the authors Shubhada Thorat is thankful to Solapur University, Solapur for X-ray diffraction
facility.
Acknowledgements: This work is supported by Research and Development cell, B.V.B. College of
Engineering and Technology, Hubballi, under Capacity building projects. Authors thank K.L.E
Technological University and B.V.B.C.E.T., Hubballi for providing financial support.
Farha Naaz, Aqsa Samreen, Shaikh Saima Anam, Shaikh Zeba Anjum, K.M.
Jadhav
Dr. Babasaheb Ambedkar Marathwada University, Aurangabad.
*Farha Naaz, Mobile no.: 8830756447, E-mail: farahnaaz0225@gmail.com
Abstract
Herein, we report the low temperature synthesis of multifunctional spinel cobalt ferrite (CoFe2O4)
using sol-gel auto combustion method, in which dextrose was used as a fuel. The reaction was carried
out at sufficiently low temperature of 110 degree celsius to obtain nanoscale particles of cobalt ferrite.
The obtained nanoparticles were structurally characterized by X-ray diffraction (XRD) technique using
CuK-alpha radiation. The XRD pattern show the reflections which belongs to cubic spinel structure. The
single phase formation and nanocrystalline nature was analyzed through XRD analysis. The crystallite
size estimated from the most intense peak (311) was of the order of 22 nm confirming the
nanocrystalline nature of the prepared samples. Using the XRD data, i.e. interplanner spacing (d) and
corresponding Miller indices the lattice constant (a) was calculated. The other structural parameters like
X-ray density, unit cell volume, strain etc. were also estimated through XRD data. The values of all the
structural parameters are well matches with the literature values. The cation distribution was estimated
using X-ray intensity ratio calculations, which confirms the inverse spinel structure of prepared cobalt
ferrite. The magnetic properties were investigated using pulsed field hysteresis loop technique. A typical
M-H curve recorded at room temperature reflects the magnetic nature of the cobalt ferrite. The saturation
magnetization (Ms) show enhanced value as compared to bulk cobalt ferrite. However, low value of
coercivity (Hc) was observed for the present sample indicating the superparamagnetic behaviour. The
observed magnetic behaviour was explained on the basis of Neel’s model.
Keywords: Low temperature synthesis, sol-gel auto combustion, cobalt ferrite, cation distribution,
magneticproperties.
Acknowledgements
The authors extend their sincere thanks to UGC-SAP Programme (F.530/16/DRS-I/2016 (SAP-2)
Dt. 16-04-2016) and DST-FIST (Project NO. SR/FST/PSI-210/2016 (C) dtd.16/12/2016) for providing
financial support.
Aakansha, S.Ravi*
Department of Physics, Indian Institute of Technology Guwahati, Guwahati-781039,
Assam, India
Fig 1: (a) ZFC and FC plots of Gd1Sm2Fe5O12 sample. (b) ε' as a function of T for different applied frequencies
(100 Hz to 100 kHz) for Gd2Bi1Fe5O12 sample. Inset shows the plot of modified Curie-Weiss law in the
temperature range of 558 K to 598 K at f = 200 Hz.
Abstract
In this investigation, the structural and electrical properties of nanocomposites of NiCuZn ferrite
(NCZ) and paraformaldehyde (PFD) synthesized by solid state mixing route are reported. Synthesized
nanomaterials have been characterized by FT-IR and TGA techniques. FT-IR results confirm the presence of
NCZ and PFD in the samples. The DC conductivity measurements have been investigated. The dielectric
constant ε’ and dielectric loss ε’’ were found to increase as the PFD content increased to 50% and to decrease
as the PFD content further increased. A dielectric cole-cole diagram can be obtained by plotting the dielectric
loss ε’’ against the dielectric constant ε’. The colecole diagram is generally used for studying the dielectric
polarization characteristics by following the variation of dielectric loss ε’’ with dielectric constant ε’. From
this work, it is possible to deduce interfacial polarization and dipolar polarization from dielectric cole-cole
plots.
The magnetodielectic properties such as initial permeability, hysterisis loop and dielectric
permittivity properties of the solgel synthesized MgCuMn ferrites with Cr3+ substitution were
investigated. The XRD patterns of the as synthesized powders reveal that the phase purity of the
powders with crystallite sizes are in the range of 15-40nm. FT-IR spectra further giving the support
to phase formation. The powders were densified at 1050°C/4hr by conventional sintering method.
The AFM patterns reveal that the microstructures of the samples are less than 500nm. Complex
permittivity and permeability spectra were undertaken with in the frequency range of 10 kHz-1.8
GHz. From these results, it is found that the initial permeability value decreases with increase of cr
substitution. The complex permeability spectrum indicates that the resonance frequency due to
domain wall oscillation is at a frequency above 20 MHz for all the samples. The hysterisis loop
parameters were calculated and we observe these parameters were decrease with higher Cr3+
substitution.
Keywords: Ferrite, Microwave Hydrothermal, XRD, FT-IR, complex permittivity and permeability.
Acknowledgements
The instrumental facility from the Department of Science and Technology, New Delhi in School of
Physical Sciences, SRTMU Nanded is gratefully acknowledged (Project no. DST PROJECT-
SB/S2/LOP-032/2013).
Acknowledgements
The authors are thankful to the scientific officer DST-PURSE laboratory Mangalore University,
Chairman Department of studies in Physics Mangalore University, Director USIC Mangalore
University, Director Innovation Centre MIT Manipal and The Director STIC Cochin for providing
facilities for the characterization and technical support to carry out the work.
Zirconium oxide with the tetragonal phase was prepared from zirconium nitrate and urea by solution
combustion method. Nano-photocatalyst zirconium oxide was investigated by XRD, SEM-EDAX,
TEM, UV absorbance spectroscopy and specific surface area analysis. The distribution size of ZrO2
found to be <17nm and was confirmed by XRD and TEM studies. Further ZrO2 nano-photocatalyst
confirms tetragonal phase by XRD. EDAX reveals the presence of Zr and O. The efficiency of ZrO2
nanoparticles in the photodegradation of victoria blue B and acridine orange dye under sunlight was
investigated.
In the present manuscript, we are reporting the complex dielectric permittivity of glycerol / n-
methyl-2-pyrrolidone (NMP) binary mixtures of different concentrations in the in the microwave
frequency range 20 MHz-20 GHz at different temperatures. The dielectric relaxation times of the
binary mixtures are analysed by using the Havriliak-Negami equation. The ordering nature of the
molecular dipoles is discussed by evaluating the Kirkwood correlation factor(geff) and stability of the
system by thermodynamic parameters. The experimental dipole moments of the pure and equimolar
binary system are determined by using Higasi’s method and compared with the theoretical dipole
moment values obtained from DFT/B3LYP methods. Mean molecular polarizability (αM) of the
system is calculated from the Lippincott δ function potential model and compared with the Lefevre
method. The molecular interaction between glycerol / n-methyl-2-pyrrolidone (NMP) binary
mixtures are discussed in terms of hydrogen bonding and dielectric parameters.
Keywords: Dielectric permittivity; relaxation; DFT; hydrogen bonding; mean molecular
polarizability.
Acknowledgements
The authors gratefully acknowledge University Grants Commission Networking Resource Centre,
School of physics, University of Hyderabad, for giving the opportunity to use the Research lab
facilities to carry out the above work.
Acknowledgments
Authors (S.B.K and N.H.A) thank K.L.E.Technological University for providing funding assistance
through TEQIP grants.
Abstract
Please insert
Relaxation property is always matter of interest for the frequencydependent study photograph of
of the ferroelectric
the presenting
materials. The Nyquist plot of the impedance data provides the information about the relaxation phenomena.
author.
Often, in solids instead of a single relaxation time a distribution of the relaxation times is found, which arises
from the different mechanisms. Usually, the relaxation times is varied by substitution and its influence is
studied on the basis of the compositional effect, but the impact of the size of the dopant is rarely
analysed.1Fundamentally, the substituted cations affect the crystal structure of the host material, which
modulates the relaxation phenomenon. In the current study, the Rb substituted lead free Na0.5Bi0.5TiO3
(perovskite structure, ABO3 type) is chosen as its A-site is compositionally disorder due to the presence of the
differentcations with dissimilar radii. The samples are prepared through the solid state sintering method.2 The
mismatch of the A-site cation radii is quantified through the size variance ( 2 ). The imaginary part of the
complex impedance ( Z ) vs itsreal part ( Z ) are plotted for all samples to verify the response of the grain and
grain boundariesand effect of the 2 on the relaxor nature. At the higher temperature (500°C) single semi-
circular arcs are formed by the materials for lowest and highest 2 values. Interestingly, two semi-circular
arcs are observed for the material for highest 2 value at lower temperature (below 300°C). The second circle
is associated with the different relaxation time of the dipolar entity, which may be generated due to the
substitution of the Rb1+. This observation proves that cation size mismatch creates the variation in the
relaxation times at the lower temperatures. The cation size mismatch also modulates the contribution of the
grain boundary to the impedance property. The real part of impedance of the 4 mol %, substituted
Na0.5Bi0.5TiO3 is enhanced by 4 times than pure Na0.5Bi0.5TiO3, which fortifies its performance as a capacitor
and energy storage device.
Keywords: Relaxation time; size mismatch; lead free ferroelectric.
Raju B. Katti1, V.K Pattar2, K.R Sardar Pasha3, N. Hanumantha Raju4, V.C Veeranna
Gowda4*
1
Department of physics, K.L.E Society’s, S. Nijalingappa College, Rajajinagar, Bangalore-560010, India
2
Department of physics, B.G.S.R &D Centre, SJC Institute, Chikkkaballapur-562101, India
3
K. R Sardar pasha, Research Scholar, Rayalaseema University, Kurnool, Andra Pradesh-518007, India
4
Department of physics, N. Hanumantha Raju, Maharani’s Science College for Women, Bangalore-560001,
India
4
Department of physics, V.C Veeranna Gowda, Maharani’s Science College for Women, Bangalore-560001,
India
*Corresponding author. Mobile: (+91) 9741118016; E-mail: vcvgowda@gmail.com
Abstract
In the present study europium doped lead-boro-tellurite glasses were prepared by melt
quenching method. The oxygen packing densities have been calculated and were used to elucidate
the variation in the density and glass transition temperature. Borate glasses exhibit BO3 and BO4
structural entities with oxygen atoms. These two structural units of the boron cations gets modified in
the process of formation of various borate species in the form of diborate, triborate, metaborate,
tetraborates[1]. These different structural entities of the boron network bring down the local crystal
field around Eu3+ ions and exhibits structural dependent optical properties finds various photonic
applications [2-4].
The optical properties have been examined using UV-visible absorption spectra. The optical
band gap energy found to decrease with the increase of Eu3+ ions. The addition of lead oxide to
borate glass provides additional non-bonded oxygen coordination to Pb2- ions. The addition of TeO2
significantly reduce the higher phonon energy of the borate glasses. The local symmetry offered by
the boro-tellurite glass network reveals the splitting of the 5D07F1 transition into three components.
These telluroborite glasses containing Pb2+ ions possess unusual optical properties like higher
refractive index and low phonon energy which reduces the multi-phonon relaxation, de-excitation
between rare-earth ions energy levels and to enhance the quantum efficiency of luminescent
transition of the trivalent rare earth ions [5]. The non-linear variation in the optical properties was
considered to depend on the electronic polarizability of oxide ions and is owing to the creation of
non-bridging oxygen in the lead borate glass network.
Keywords: Optical properties; Rare earth oxides; Borate glasses; Electronic polarizability.
Enhancing the thermal conductivity of a heat transfer fluid with the incorporation of
nanomaterial is a widelyknown technique to achieve an efficient cooling system where such fluid,
incorporated with nanomaterial is popularlyknown as nanofluid. However, the complexities in
synthesizing the desired nanomaterials and difficulties inincorporating them to the heat transfer fluid
due to their poor dispersion ability opens up huge scope for carrying outfurther research in this field.
Therefore, in the current work, we report, a simply synthesized amorphous carbonnanotubes (ACNT)
and alumina (Al2O3) nanoparticle based nanocomposite that can easily disperse in engine oil (a
classof heat transfer fluid) and can significantly improve its thermal conductivity. In our work,
ACNTs with the length of ⁓ 4μm and diameter of ⁓ 200 nm was synthesized by simple solid state
reaction method whereas alumina nanoparticles withthe dimension of ⁓ 50 nm were separately
synthesized by sol-gel method. Then the nanocomposite was prepared bysimply mixing them in
liquid medium, followed by drying. Structural characterizations were carried out through x-
raydiffraction, field emission scanning electron microscopic and high resolution transmission
electron microscopic studies.The nanofluid was formulated by dispersing the nanocomposite in the
base fluid (engine oil) with variation in loadingand subsequently thermal conductivity was measured
by Transient Hot Wire (THW) method. The maximumimprovement in the thermal conductivity of ⁓
20% was obtained with 0.04 vol. % of nanocomposite loading. So, all inall, it can be stated that
ACNT and alumina naoparticle based nanocomposite was successfully prepared and itsapplication in
enhancing thermal conductivity of engine oil has successfully been shown.
Keywords: Amorphous carbon nanotube; alumina nanoparticle; nanofluid; thermal conductivity.
Acknowledgements
Department of Science and Technology, Govt. of India.
University with Potential for Excellence (UPEII), Govt. of India.
University Grants Commission (UGC), Govt. of India.
Cubic Li7La3Zr2O12 garnet electrolyte is the most studied solid electrolyte material due to its high
ionic conductivity (10-4 S/cm) and large electrochemical stability window. It is difficult to stabilize
the cubic phase of Li7La3Zr2O12 at room temperature without any doping element. Doping of
different supervalent cations at the lithium and zirconium sites to stabilize the cubic phase of
Li7La3Zr2O12 electrolyte has been studied by different research groups. Here Ce substituted
Li7La3Zr2O12has been prepared by solid state reaction method in different compositions. The
structural and electrochemical properties of as prepared electrolyte have been studied by powder
XRD and AC impedance spectroscopy. The conductivity values obtained for Ce doped
Li7La3Zr2O12are considerably low as compared to pure cubic Li7La3Zr2O12 electrolyte which may be
due to the lower ionic radii of cerium as compared to lanthanum.
Keywords: Lithium ion batteries; solid state electrolytes; cations, ionic conductivity.
Abstract
The synthesis of silver nanoparticles (AgNPs) has drawn attention over the past few years owing to
their physico-chemical and optical properties. In the present investigation synthesis of AgNPs using
Punicagranatum peel extract was mediated under microwave irradiation. The duration of microwave
irradiation and concentration of AgNO3 and Punicagranatum peel extract were optimized for the
better yield of AgNPs.Under all optimized conditions, the zeta potential, average diameter and
polydispersity index of AgNPs synthesized were -30.5 mV, 10±2 nm and 0.224 respectively.
Phytochemicals present in the extract help to reduce silver salt to metallic silver and act as a
stabilizer in the synthesis of AgNPs. The synthesized AgNPs are characterized by routine analytical
techniques like UV-visible, FTIR, XRD, DLS and TEM. The synthesized AgNPs not only showed
good catalytic activity in the reductions of p-nitrophenol, Methylene Blue and Congo red, but also
showed antibacterial activity against gram positive and gram negative bacteria.
Keywords: Microwave, Punicagranatum, Silver nanoparticles, Antibacterial properties, Catalytic
activity.
Acknowledgements
All the authors thanks to Department of Chemistry, Palamuru University and Department of
Chemistry, Osmania University for providing infrastructure and other necessary facilities. The
authors would like to thank STIC, Cochin, India for extending their TEM facility.
In the last few decades, nano Zirconia has attracted great attention because of its versatile
applications in the diversified areas like catalyst support, as insulator in transistors for nanoelectric
devices, solid oxide fuel cells, optoelectronic, piezoelectric and nanocomposite devices .In the
present study ,We report hydrothermal synthesis of nanozirconia quantum dots exhibiting variable
photo luminescence at different excitation wavelengths. Nano Zirconia quantum dots were prepared
by single step hydrothermal synthesis followed by reduction of Zirconyl Oxy chloride
(ZrOCl2.8H2O) solution with wet leaf extract of Syzigium cumini (S.cumini) in absence of surfactant
and a base, which opens a new avenue for designing novel luminescent nano Zirconia quantum dots.
The ultraviolet-visible spectrum of the aqueous medium containing zirconia nanoparticles showed an
absorption peak at around 262 nm. Powder X-ray diffraction showed that the particles are crystalline
in nature, with an average size of ~2.06nm comprising tetragonal ZrO2 structure. Photoluminescence
Spectra has shown a sharp visible emission peaks at 730 nm and 603 nm, broad emission peaks at
450 nm ,500 nm,520 nm and 580 nm at varying excitation wavelengths ranging from 300-400nm
.The most needed outcome of this work will be the development of pure nano quantum dots using
the plant extract which contains different flourophores, greatly used in bio-medical, opto electronic
and electro chemical sensing applications.
Acknowledgements
DST, INSPIRE AORC Fellowship is greatly acknowledged for providing financial assistance.
To meet the growing demand of food in the developing nation like India, which is the second
largest populated country in the world and need much focus on the increase in crop production to
feed such a huge population? To meet this demand of food, researchers need to focus on the
development of eco-friendly agricultural production technologies. Nanoparticulate material delivery
to plant technology also holds the promise of controlled release of agrochemicals and site targeted
delivery of various micronutrients needed for improved productivity, plant disease resistance,
efficient nutrient utilization and enhanced plant growth. Nanoparticles mediated plant growth has the
potential for improved agricultural productivity.
In this study, microwave assisted phytosynthetic magneto sensitive magnetite nanoparticles had
been synthesized from aqueous Hibisus Rosasinensis leaf extracts, which acted as a reductant
and stabilizer simultaneously. The phytosynthetic magnetite nanoparticles acts as a nanofertilizer
which enhances the seed germination (hydroponics) in Eleusine coracana (Finger Millet) commonly
called as Ragi seeds. The nanomagnetite particles are characterized by XRD, SEM, FTIR and TEM.
The Nano Magnetite Fe3O4 visualizes enormous beneficial aspects in enhancing growth performance
(seed germination) in terms of root length and shoot length of Eleusine coracana (Finger Millet)
seeds.
Fig.1. Eleusine coracana seed germination (a) on day-2 and (b) day-6
Keywords: Magneto-Sensitive Magnetite, Hibiscus rosasinenis, Eleusine coracana, Seed
germination, Hydroponics
Acknowledgements
The author greatly acknowledged the Gitam Deemed to be University, Bangalore for the support.
Nanofluids have a great attention because it has an enormous potential to improve the
efficiency for heat transfer systems owing to its high thermal conductivity. For any nanofluid to be
usable in heat transfer applications, the main concern isits thermal conductivity. In this work, iron
oxide nanoparticles were synthesized using cost-effective chemical method. The nanostructured iron
oxide were characterized by various characterization techniques viz., X-ray diffraction (XRD),
Scanning Electron Microscope (SEM) etc. The iron oxide based nanofluids of different
concentrations in the range 0.02%, to 0.2% were prepared.The size of nanoparticles used was 20nm.
A comprehensive correlation of ultrasonic velocity and thermal conductivity is proposed based on
theory and experimental observations. The effect of concentration on ultrasonic velocity,
compressibility and thermal conductivity thereby was studied. Such approach can be useful in
studying the relationship between various prepared nanofluids such as ultrasonic velocity, thermal
conductivity, electrical conductivity, compressibility etc.
Acknowledgements
This work has been supported by UGC-DAE Consortium for Scientific Research, Mumbai Centre,
India in the form of a collaborative research scheme (CRS) through project number CRS-M-289.
AKB thanks support from INSA under its Senior Scientist scheme.
Glass samples with composition (35- X) B2O3 - (40 +X) PbO - 25 TiO2 (where X= 0, 2.5,5,
7.5 and 10 mol %) were prepared using conventional quenching technique. These glass samples were
converted to glass ceramics by following two stage heat treatment schedule. The density (ρ) values of
glass ceramic samples are higher than those of corresponding glass samples. It was observed that
there was good correlation between the density and Coefficient of Thermal Expansion (CTE) results
of the glass–ceramics. The XRD results in the glass ceramics revealed the formation of tetragonal
lead titanate (PbTiO3) as a major crystalline phase and lead borate (PbB2O4) as minor crystalline
phase. The microstructure of glass ceramic samples contains nano crystallites of lead titanate
embedded in a borate glass matrix.
Keywords: Glass; Glass Ceramics; Thermal Expansion, SEM.
a) b)
Fig.1 – Equivalent paper-oil insulation scheme: a - to calculate the voltage on the oil layer; b - to
calculate the dielectric loss in insulation.
The increase in the dielectric constant of the paper is accompanied by an increase in the tension in the oil
layers of paper and oil insulation, which promotes the development of discharges in these layers and facilitates
the breakdown of the insulation. As a result, the effect of paper density has a different effect on the short-term
and long-term strength of the insulation. In determining the short-term strength, the influence of the first factor
prevails, which contributes to its increase with increasing paper density. For example, by increasing the
density of paper from 0.7 to 1.3 g/cm3, the electrical strength of sheet insulation (flat samples) increases by
60%.However, in determining the long-lasting strength, partial breakdowns in the oil layers lead to
considerable destruction of the insulation. In this case, as the paper density increases, the breakdown strength
is reduced and the insulation life is shortened.
In situations like natural disasters and fault conditions it becomes difficult to supply
the power from conventional energy resources to the loads that are connected to the
secondary distribution network. Often it requires that the Distribution Energy Resources
(DERs) are connected to the secondary distribution network. In situations like fault on grid side
or to feed power from distributed resources to secondary network loads, the secondary network
should be isolated from the grid. In order to switch the loads from grid side to DERs and to
prioritize the loads, it requires control strategies. In general, the control uses the under
frequency, negative sequence currents and impedances of the fault line as parameters.
The algorithm is proposed for Low Voltage (LV) DC distribution system is difficult to
obtain control by frequency, negative sequence currents as parameters.
This paper proposes a technique by using voltage, current and active power of the
network as parameters for islanding loads in LVDC distribution system. An algorithm is
proposed using Adaptive Neural Fuzzy Inference Systems (ANFIS) to generate boundary
conditions for the outputs that are produced from the control unit for intentional islanding of
loads in LVDC distribution system.
Keywords: DERs, Solar Photo Voltaic (PV) Module, LVDC, Intentional Islanding, ANFIS
Controller.
Acknowledgements:
I thank TEQIP-II, JNTUHCEH for providing necessary infrastructure.
Conventional multi crystalline silicon wafers used in photovoltaic applications offer low
electrical conversion efficiencies due to various loss mechanisms. The challenges, such as photon
absorption, charge separation and carrier collection, in conversion of photon energy to electrical
energy using PV cells, can be influenced by coating the active surface of the cell with nano materials
as anti-reflection coating. Carbon Nano Tubes (CNTs)in combination with TiO2are having superior
electrical conductive properties that can be used in many other applications apart from photo voltaic
application. TiO2 is prepared using a two step sol-gel method using titanium isopropoxide as
precursor. Single walled CNTs is grown using chemical route synthesis.CNTs and titanium dioxide
nano particles prepared using this simple and scalable method offers good photo-electrochemical
properties. Both CNTs and TiO2 are spray coated on bare multi-crystalline silicon solar cell. The
extensive surface area of CNTs due to their vertical alignment and excellent anti reflective properties
of TiO2 are useful in tuning the band gap energy of the AR coating with reduced recombination rate
and enhanced photocurrent. Characteristic studies on these CNTs and TiO2are to be conducted for
enhanced conversion efficiencies of multi crystalline silicon solar cells compared to bare and SiN
coated mc-Si cells.
Keywords: Bi-Zn nanoferrites; sol-gel combustion method, AC conductivity and dielectric constant,
cole-cole plot, and spreading factor.
Abstract
Supercapacitors are new energy storage devices with unique features such as high power
density, high capacitance and a long life than batteries. Finding supercapacitive materials with high
energy density with good rate capability is still challenging. Here, we have synthesized MnWO4
nanostructure by facile hydrothermal method and studied their supercapacitive properties. The
structural and morphological analysis and measurements were done using x-ray diffraction, scanning
electron microscopy, energy dispersive x-ray diffraction. Asymmetric supercapacitor was fabricated
with graphite as anode and MnWO4 as cathode on carbon cloth substrate and studied its
electrochemical properties using 1 M Na2SO4 as the electrolyte. The effect of potassium iodide (KI)
addition to electrolyte on electrochemical properties was studied. Maximum specific capacitance of
450 F/gm was achieved with capacitive retention 85% for 5000 cycles for three electrode system.
Energy density without KI was 51 Wh/kg which is increased by addition of KI to 99 Wh/kg.
In this work, we present the synthesis and characterization of nanoparticles suitable for
semiconductor applications using a simple and economical sol-gel process. ZnO-CuOis the potential
material because of its high thermal stability and low cost. Properties of the ZnO-CuO
nanocomposites are size dependent and when the particle size is reduced to the nanometer scales it
shows some novel properties. Sol-Gel method is a good method to synthesis ultrafine metallic oxide
nanocomposites and has been widely used for preparing nanoparticles at very low temperatures.
Nano-structured ZnO-CuO has been characterized by using various techniques like XRD, SEM, and
DSC-TGA. The phase transformation was investigated by an X-ray diffractometer (XRD). The
microstructure was characterized by a scanning electron microscope (SEM). DSC-TGA analysis was
used to investigate the thermal properties of the material.
Keywords: ZnO-CuO; Sol-Gel method; XRD; SEM; DSC-TGA.
Acknowledgements
We thank Dr. Shilpa Chakra, Head of the Dept., Dept. of Nanotechnology, and JNTUH for allowing
performing the experimental work under internship.
In this work the impact of various concentrations of dopant ion on the structural and optical
properties of Manganese doped ZnS Quantum Dots (Mn ZnS QDs) in presence of a capping agent
has been investigated. Mn ZnS QDs with various concentration of Manganese were prepared by
simple, water based chemical precipitation method. The prepared Quantum Dots were characterized
by various techniques like X-ray diffraction spectroscopy (XRD), Scanning electron microscopy
(SEM), UV-vis. Spectroscopy, FT-IR spectroscopy; diffuse reflectance spectroscopy (DRS) and
Fluorescence spectroscopy (PL). The results revealed that the surface morphology, size and optical
properties of the Mn ZnS QDs were varied by dopant ion concentration. With increase in
concentration of dopant ion the absorption edge is shifted to lower wavelengths, as clear from the
obtained UV-vis. spectra of samples. FT-IR and PL results confirmed the incorporation of
Manganese into ZnS crystal structure, and XRD results showed that Mn ZnS nanoparticles
crystallized in a zinc blende structure without any impurity. PL intensity of the Mn ZnS QDs were
compared, and Mn ZnS QD (Mn 1mM) was found to have the highest PL intensity. In the
Photoluminescence spectra for the undoped ZnS QDs a blue peak at 450nm is obtained and for the
manganese doped ZnS QDs an orange peak centered at 598nm is observed in addition to blue
emission.
Keywords: Quantum dots, band gap, absorption edge.
Acknowledgements
Financial assistance is provided by UGC(under FDP scheme),Government of India is greatfully
acknowledged.
Niharika Chourasiya1*, Arun Kumar Singh, Aksh kumar Verma and Ashish
Verma
Dr. Harisingh Gour Vishwavidyalaya, Sagar (M.P.), 470003, India
Acknowledgements
Authors are grateful to UGC-DAE Consortium, Indore (M.P.) India for XRD characterization and
Dr. Harisingh Gour Vishwavidyalaya, Sagar (M.P.) India, for financial support during the research.
The study of topological semimetals and insulators have become a keen interest in the field of
solid-state physics which are known to possess properties that enhances the performance of a
thermoelectric (TE) material1,2. In our study, we have performed ab initio calculations on non-
centrosymmetric ternary Half-Heusler (HH) compound, LiAuTe. The presence of spin-orbit coupling
results in the s-p band-inversion near the Fermi level and thus may be categorized as topological
semimetals. To understand its TE performance, transport properties are studied using Boltzmann
transport theory. The relatively lower value of lattice thermal conductivity of LiAuTe than other
conventional ternary compounds3, improves its performance as a potential TE material. Thus, the
findings may create more opportunities in experimentally realizing HH alloys as TE materials.
Keywords: Thermoelectric materials; ab initio calculations; Half-Heusler
Acknowledgements
We would like to thank MHRD for the award of research fellowship and also IIT Ropar for
providing the High Performance Supercomputing facility and research support.
Abstract
P. Rambabu1,2*, V. Kanchana1
1
Department of Physics, IIT Hyderabad, Kandi, Sangareddy- 502285, T. G., India.
2
Department of Pure and Applied Physics, Guru Ghasidas Vishwavidyalaya, Koni,
Bilaspur-495009, India.
*Corresponding author. Mobile: (+91) 9074508220; E-mail:ph17resch01004@iith.ac.in
Abstract
Half metallic ferromagnetic materials have applications in spintronic devices because of their high
spin polarization. Spin gapless semiconductors belong to the class of half metals that have fully spin
polarized carriers at the Fermi level so that they exhibit large magnetoresistance and low spin
relaxation (Gilbert damping). Here in we report the electronic structure, magnetic exchange coupling
properties of LiMgPdSn-type spin gapless CoFeCrGa material through First principles calculations.
Also CoFeCrGa/ GaAs/CoFeCrGa magnetic tunnel junction is constructed and its spin transport
properties are calculated based on the density functional theory combined with non-equilibrium
Green’s function methods as implemented in QuantumATK package.
BiFeO3 is one of the well-known room temperature multiferroics among all multiferroics. Its
high ferroelectric Curie temperature (TC = 1103 K), magnetic Neel temperature (TN = 643 K) and the
coupling between spin and charge in it attracts many researchers since several years. However, the
potential of BiFeO3 in device applications is limited due to the presence of oxygen vacancies and
Fe2+/Fe3+ ions. It is impressed the researchers that the substitution of elements at A-site and/or B-site
effectively tackles these issues and improves the insulating character properties. In this work, BiFeO3
(BFO), Bi0.9Ho0.1FeO3(BHFO) and Bi0.9Ho0.1Fe0.95Sc0.05O3(BHFSO) compounds are prepared by
using convention solid state reaction method. The detailed experimental procedure can be found
elsewhere. Phase analysis of the prepared compounds is examined by X-ray diffractometer
(Panalytical X’pert Pro). The temperature and frequency variation of impedance and dielectric
properties are investigated by using Wayne Kerr 6500B impedance analyser. The X-ray diffraction
patterns of BFO, BHFO and BSFSO compounds are crystallized in R3c rhombohedral crystal
structure. However, a small phase percentage of orthorhombic structure with Pnma space group is
evidenced in BHFO and BHFSO compounds which is also confirmed from the Rietveld refinement
using Fullprof software. The grain and grain boundary resistances at different temperatures are
analysed using complex impedance studies. The activation energies obtained from the temperature
variation of grain and grain boundary resistances and ac conductivity data follow Arrhenius
equations. The obtained activation energies clearly indicate that the co-substitution of Ho and Sc
improves the insulating character of BFO. The enhanced dielectric properties are also observed in the
co-substituted BFO compound.
Keywords: Multiferroics, impedance studies, dielectric properties.
Spectroscopy is the interaction between matter and electromagnetic radiation, which is useful in the
determination and characterisation of various chemical composition existing in the material. Present
paper, focuses on predicting the extent of thermal damage on hydrated Portland Cements (PC), using
Fourier Transform Infrared Spectroscopy (FTIR). The hydrated specimens of Portland Pozzolana
Cement (PPC) and Ordinary Portland Cement (OPC),were subjected to temperatures ranging from
27 °C - 800 °C, for aninterval of every 100 °C was analysed. Variation in the absorbance peaks
obtained from FTIR, is correlated with the Thermal analysis (TA). At temperatures beyond 400 °C,
reduction in the absorbance values at wavenumbers of 3430 – 3440 cm-1 of Ettringite phase for PPC
and OPC specimenswas observed. However, in OPC specimens, an increase in the absorbance values
of Portlandite phase at wavenumbers ranging from 3640 – 3645 cm-1 was observed. The phase
changes taking place in the PC specimens observed using FTIR, are in good agreement with the mass
loss and heat flow plots obtained from Thermal Analysis. Therefore, it can be concluded that FTIR
analysis is suitable test method in predicting the thermal damage of concrete specimen.
Acknowledgements
The authors acknowledge the help provided for thermal analysis test at CAM-NIT-Warangal.
Scientists and technologists attracted towards natural fibers like banana, cotton, coir, sisal, hemp and
jute for the application civil structures and consumer goods. It was identified the electrical resistance,
thermal and acoustic insulating properties for possessing of these natural fibers in composites.
Natural fibers have many benefits co
mpared to artificial fibers, as an example less density, less weight; low cost, specific properties and
they are recyclable and biodegradable. There aren’t any skin effects because of high strength and
stiffness, renewable. In alternative manner, there also are some limitations, as an example less
thermal stability and wetness uptake. several of them studied a major improvement in propertiesof
hybrid composites with reinforced with glass fiber in resin contenthowever it’s naturally hazard with
usage of this glass fiber content. There are many publications on review of fiber reinforced
composites, a notable research has been done on natural fiber polymer composites but research on
jute, hemp, hybrid of jute fiber and hemp fiber, hybrid (jute/hemp) fiber with SiC particulates as
filler at specific extent fractions primarily.
In this paper, hybrid (hemp and jute) fiber reinforced epoxy matrix composites were fabricated by
using hand lay-up technique of different weight percentage of hybrid fiber and SiC particulates as
filler have been studied and their thermal properties such as density, Thermal gravimetric analysis
(TGA) and Differential Scanning Calorimetry (DSC) by which we can know thermal stability of the
composites
Keywords: Natural Fibers, Hybrid fibers, SiC, Thermal properties, Hand Lay-up Technique.
Now a day’s waste becoming an environmental impact globally, the focus of the researchers
have to admin the problem caused by the waste. As a part of its bio-degradable materials research is
a necessary task used for automotive applications. Natural fibers mostly known as extracted fibers
from plants which are available in large scale may solve the requirements of industrial components
as well as automotive needs. The replacement of plastics with natural fiber components is one good
choice to avoid large dump of thermo and thermo setting plastics. To attain the standards of solving
desires of plastic thing replacements researches wished within the vicinity of natural fibers to obtain
the comparative properties of plastics. To expand composites with good mechanical, chemical
amendment of fibre achieved to reduce the hydrophilic conduct of fibers and the absorption of
moisture. There are many publications on review of fiber reinforced composites, a notable research
has been done on natural fiber polymer composites but research on jute, hemp, hybrid of jute and
hemp fiber, hybrid (jute/hemp) fiber with SiC particulates as filler at specific extent fractions
primarily based polymer composites are uncommon.
In this paper, hybrid natural fiber reinforced epoxy matrix composites were fabricated using
hand lay-up techniquewith different percentage of hybrid fiber and SiC filler have been studied and
their mechanical properties such as tensile strength, compressive strength, flexural strength and
hardness have been reported. It is observed that the tensile and compressive strength increases with
hybrid fiber reinforcement and SiC filler. Failure mechanism of hybrid fiber composites has been
discussed using scanning electron microscopy.
Keywords: Natural Fibers, Hybrid, Mechanical properties, hand layup Technique.
The contamination of water bodies in the surroundings is due to the accumulation of toxic organic
pollutants such as pesticides, herbicides, dyes etc. The degradation of these pollutants are difficult
due to their severe interactions with the solvents. There are several photocatalyst synthesized for the
better degradation of these organic pollutants and severe toxic organic dyes. In this paper, an
efficient and a simple photocatalyst is prepared based on less toxic lanthanum and bismuth
nanoparticle. The synthesized binary composite consist of lanthanum and bismuth, which provides
well degradation for these pollutants. The structural identification of the synthesized binary
composite is done by FT-IR and PXRD and themorphological peculiarity of the nanocomposite is
done by using SEM and TEM analysis. The weight % optimization of the binary nanocomposite is
done by using UV spectroscopy. The results of photocatalytic studies reveal that the highest
photocatalytic activity and stability were obtained for the binary composite with (47% La) and it can
be used to oxidize 81% of methylene blue within 120 minute. The successful photodegradation of the
insecticide acepahte can be effectively done by using the synthesized binary composite. The
mechanism of the photodegradation involves the effective transfer of electrons from the valence band
of Bi2O3 to the conduction band of La2O3. The photodegradation efficiancy of the nanocomposite is
analyzed by using Total Organic Carbon (TOC) analysis.
Keywords: Pesticides, herbicides, photocatalyst, nanocomposite
Acknowledgements
The present work was supported by DST-PURSE PII (SR. 417 & SR. 416 dated 27-2-2017) and
Mahatma Gandhi University, Kottayam, Kerala, India.
Aqsa Samreen, Farha Naaz, Shaikh Saima Anam, Shaikh Zeba Anjum, K.M.
Jadhav
Dr. Babasaheb Ambedkar Marathwada University, Aurangabad.
Abstract
Recently, magnetic nanoparticles are of current interest in biomedical applications. The present
paper deals with the synthesis of cobalt ferrite nanoparticles and their characterizations.The synthesis
was carried out using well known sol-gel auto combustion technique. Dextrose was used as chelating
agent/fuel in the synthesis process. The functionalization was carried out using oleic acid as a coating
agent. The phase purity and structural properties were investigated using X-ray diffraction technique
at 300K. The analysis of X-ray diffraction data proves the formation of single phase cubic structure.
The crystalite size obtained through Debye-Scherrer’s formula indicates the nanocrystalline nature
of the prepared samples. The other structural parameters like lattice constant, X-ray density etc. are
in reported range. The magnetic properties like saturation magnetization, coercivity etc. were studied
using pulsed field hysteresis loop tracer technique. The measurements were taken at room
temparature. The M-H plot shows typical ferrimagnetic behaviour with superparamagnetic nature.
The obtained values of crystalite size, lattice constant, saturation magnetization, coercivity,
remenance magnetization and remenance ratio all are excellent and are most suitable for biomedical
applications (Magnetic Hyperthermia). The studies related to induction heating are in progress.
Keywords: Cobalt ferrite nanoparticles, XRD, M-H plot, Hyperthermia
Abstract
Crushing and grinding are widely used in mining, mineral processing, cement making, and
coal power generation. The mechanical components that contact with materials being processed are
working under the conditions of high abrasion and impact. How to reduce the wearing damages and
prevent from the cracking failure of the mechanical parts is one of the crucial challenges facing the
operations of many industries, involved crushing and grinding processes. Whit cast irons, and
specifically high chromium white cast irons, have been developed and deployed worldwide for
making mechanical components of crushing and grinding machines due to the combination of high
wear resistance and good mechanical strength. The paper is aimed to give an overview on the white
cast iron alloys, and particularly high chromium white cast iron alloys with 28 references, including
their classifications, their standard specifications in USA, China and Australia, their main usages and
new developments.
Keywords: white cast iron; high chromium white cast irons; high wearing resistant alloys; crushing
and grinding
Reference
7. F. Nyokong and X. Pan, “A Review on Usage of High Chrome White Cast Irons in South
Africa,” Tamil Nadu, India, 2019.
8. T. X. L. D. Y. H. B. a. D. K. Chung R. J., “Microstructure Refinement of Hypereutectic
High Chromium Cast Irons Using Hard Carbide-Forming Elements for Improved Wear
Resistance,” Science Direct, vol. 301, pp. 695-706, 2013.
9. C. Mahlami and X. Pan, “Main challenges and developments of high manganses steel
castings based on service life,” 71st World Foundry Congress, Bilbao, Spain, 2014.
10. C. Mahlami and X. Pan, “An overview of high manganese steel casting,” 71st World
Foundry Congress Bilbao, Spain, 2014.
11. G. Nelson, “Influence of Microstructure on the Corrosion and Wear Mechanisms of High
Chromium White Irons in Highly Caustic Solutions,” Dissertation / School of Mechanical
Engineering, Adelaide, South Australia , 2010.
12. C.S Mahlami; X Pan, Mechanical properties and microstructure evaluation of manganese
steel alloyed with vanadium, FCSPTC international conference, Andhra Pradesh, India,
2017, pp227-236.
Abstract
High chromium white cast irons (HCWCI) are widely used as abrasion resistant materials in
cement manufacturing, mineral processing and slurry pumping industries. Their high resistance to
wear in these demanding situations stems from the presence of hard eutectic (Cr,Fe)7C3 carbides in
their microstructures. In this context, the properties of hypoeutectic iron of HCWCI containing 25 wt.
%Cr-2.5 wt. %C were investigated after destabilisation heat treatments, cooling (slow and fast
cooling) to ambient temperatures, their influence on the microstructure was investigated. For
characterization of the hypoeutectic iron of HCWCI, several experimental tests were performed
using the following laboratory equipment: light optical microscope, scanning electron microscope.
The amount of retained austenite also depends on the alloying additions in the melt during melting
processes, destabilisation temperatures, soaking time and the cooling rates during heat treatment
processes.
Keywords: white cast iron; high chromium white cast irons; high wearing resistant alloys; microstructure
Reference (part)
13. F. Nyokong and X. Pan, “A Review on Usage of High Chrome White Cast Irons in South
Africa,” Tamil Nadu, India, 2019.
14. T. X. L. D. Y. H. B. a. D. K. Chung R. J., “Microstructure Refinement of Hypereutectic
High Chromium Cast Irons Using Hard Carbide-Forming Elements for Improved Wear
Resistance,” Science Direct, vol. 301, pp. 695-706, 2013.
15. C. Mahlami and X. Pan, “Main challenges and developments of high manganses steel
castings based on service life,” 71st World Foundry Congress, Bilbao, Spain, 2014.
16. C. Mahlami and X. Pan, “An overview of high manganese steel casting,” 71st World
Foundry Congress Bilbao, Spain, 2014.
17. G. Nelson, “Influence of Microstructure on the Corrosion and Wear Mechanisms of High
Chromium White Irons in Highly Caustic Solutions,” Dissertation / School of Mechanical
Engineering, Adelaide, South Australia , 2010.
18. C.S Mahlami; X Pan, Mechanical properties and microstructure evaluation of manganese
steel alloyed with vanadium, FCSPTC international conference, Andhra Pradesh, India,
2017, pp227-236.
Acknowledgements
I would like to thank Nalla Malla Reddy Engineering College, for providing all facilities for this
project and special thanks to Dr. N. Sujan Rao and Dr. TVMSR Bhushan for their value input and
technical support for this project. .
The objective of the current work is to estimate the maximum displacement and energy
absorption capacity of fascia and body in white structure during crash. The details of the Fascia and
body in white structure are taken from Honda Accord Model. The crash tests are performed on fascia
considering the Dual Phase 600 Steel, TI6AL4V alloy and Acrylonitrile Butadiene Styrene (ABS)
Plastic materials. The fascia crash test is performed as per United States New Car Assessment
Programand and Roof crush test is performed as per federal motor vehicle standards 216.
Deformation and energy absorption capacity during crashing have been analyzed by using finite
element solver LS-DYNA. The results show that, the energy absorption capacity of Dual Phase 600
Steel is greater than that of TI6AL4V alloy and Acrylonitrile Butadiene Styrene (ABS) Plastic during
the fascia crash test. In case of roof crush test, resultant displacement of Dual Phase 600 steel is less
compared to TI6AL4V Alloy. This analysis helps in selection of material which can minimizes the
damage during vehicle accidents.
Keywords: Fascia; FEM; LS-DYNA.
X-ray mass attenuation coefficient of Niobium compound is measured in the energy range from
18.317 keV to 19.668 keV around the k-edge using Scanning EXAFS Synchrotron radiation Source.
The observed values are compared with the theoretical predictions XCOM and FFAST. The results
and discrepancies obtained are discussed.
Acknowledgements
The authors acknowledge their thanks to Nirmalagiri College, Koothuparamba, Biogenixresearch
Centre, Thiruvananthapuram and SAIF, Cochin for providing facilities for characterization. They are
also thankful to KSCSTE, Thiruvananthapuram.
Abstract
A Series of complex blended polymer films of poly (vinyl alcohol) (PVA) and poly (ethylene
glycol) (PEG) with doping of various concentrations of active Sm3+ ions (1-5 mol %) were
synthesized by the mechanism of solution casting technique. From the analysis of X-ray diffraction
(XRD) and FTIR spectra, the structural analysis and molecular level interactions were observed,
which results in reduction of the poly crystalline nature of the blended films. Scanning electron
microscopy (SEM) studies reveals the uniform dispersion and coordinated complexes formation over
the surface. Thermo gravimetric analysis (TGA) and differential scanning calorimetric (DSC)
analysis are used for examination of thermal behaviour of the polymer blends, which shows
enhancement in their thermal degradation and strength. The complex miscible polymer blends
(PVA+PEG) doped with 5.0 mol % of Sm3+ ions are acting as a prominent host material for
designing and development of opto electronic and luminescent devices.
Keywords:Polymer blend; Solution-casting; Poly Crystalline;Coordinated Complexes.
Acknowledgements
The authors thank to Department of Physics K.L.S.G.I.T., India, Department of Applied Physics,
Defence Institute of Advanced Technology, India, Department of Chemistry, Govindram Seksaria
Science College, India, Department of Physics, RCU, India.
Ismayil1*, Swathi1
1
Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher
Education, Manipal, Karnataka - 576104, India
Phenol red dye doped Carboxymethyl Cellulose biodegradable polymer films of different
dopant concentrations were prepared by conventional solution casting method. The optical properties
of these films for different Phenol red concentration were investigated using UV-Visible
spectroscopy and the fluorescence spectroscopy and the corresponding microstructure behavior of
the polymer matrix have been studied using SEM and XRD techniques. UV-Visible study shows that
new peaks emerged at around 270nm and 440nm for doped films. Optical absorption increases with
increasing dopant concentration. The variations of optical energy band gap, Urbach energy upon
doping were studied. Optical energy gap of the sample shifted from 5.21eV to 4.21eV upon doping.
The variations of optical dielectric constant and refractive index with wavelength of the doped films
have also been studied. XRD study reveals the fact that there is anincrease in amorphousnessand also
reduction in the inter chain distance within the polymer matrix.Photoluminescence study show that
the fluorescent quenching takes place upon doping due to increase in the free volume size. The
change in the microstructure and hence the modification in the physical properties of the polymer
composite films are correlated.
Keywords:Polymer microstructure; free volume; structure-property relationship.
Acknowledgements
We thank Dr. Sangappa Y, Professor, Department of Physics, Mangalore University for extending
UTM facility.
In material science for different applications purpose research and development wise various
materials tried starting from small to big molecules which includes inorganic as well as organic
polymers. Especially some of the thrusting areas like non-linear optics (NLO), light emitting diode
(LED), liquid crystal display (LCD), field effect transistors (FET) and solar cell are still under
demand for various applications like optical communication, optical data storage, energy harvesting
etc.To fulfil the demand various novel polymeric materials based on polyamide, poly(methyl
methacrylate), polyimide and polyurethane etc have been synthesized in especially for NLO and
LCD applications. For NLO and LC materials, having donor and accepter containing moietieswhich
are attached through conjugation to some extent plays important role to achieve the desirable
properties. In the present paper we have synthesized donor-acceptor-donor based NLO polymer
containing carbazoles by using Knoevenagel condensation reaction. The polymer is found to be fully
soluble in high polar solvents like dimethyl formamide and dimethylsulphoxide. By using GPC and
tetrahydrofuran as a solvent, the molecular weight is found to be 5000 g/mol. Thermal analysis
exhibited thermal stability of the polymer up to 400oC and glass transition temperature (Tg) at 214oC.
The non-centrosymmetry in the film was induced by corona poling for second order NLO property
Computational study indicated that the total charge is located at the centre of the molecule in HUMO
case whereas in the case of LUMO the charge is spreads out from the centre of the molecule.
Keywords:Nonlinear optics,Carbazole, Thermal analysis, Poling,Computational study.
Abstract
Ferromagnetic Shapememory Alloys offers prospects for novel applications that make use of
new mechanism for converting between magnetic and mechanical energies,due to the unique
combination of large displacements and fast mechanical response. Structural transformation varies
between Austenite and Martensitic phase. These structural transformation temperatures are sensitive
to the preparation parameters and conditions. We have prepared a sample of Co-Ni-Al alloy system
(Co40Ni33Al27) by arc melting and annealed at 1373K/24h and 1473K/72h. The sample was
characterized by XRD, resistivity, & magnetization. Interestingly annealing temperature and stress
affects on magneto transport and elastic properties respectively1. TM has increased due to annealing.
Austenite to Martensite phase transformation shifts to above room temperature for annealing at
1473K/72h and hence we can largely control the shape memory effect of this alloy by annealing2.
Room temperature resistivities are increased by a factor of 3 due to higher temperature annealing
prolonged annealing brought in more disorder in the system and affected the electronic transport
properties. The elastic behavior of the sample annealed at 1373K/24h, in presence of stress of 7.42
MPa the transition temperature is lower than the temperatures found in magnetization and resistivity
measurement.
Keywords:Sound velocity 1; Internal Friction 2; Ferromagnetic Shape Memory Alloy 3.
Acknowledgements
BRK acknowledges the support extended by DST videproject grant no. SR/FTP/PS-108/2009
and the Directors of S. N. Bose Center and T.K.R. College of Engineering and Technology for
allowing the collaboration work. Dr. S. Pandianand J. Arout Chelvane are acknowledged for the help
extended in making the samples, SH thanks TWAS – Bose fellowship.
The present work was supported by DST-PURSE PII (SR. 417 & SR. 416 dated 27-2-2017).
This paper provides details regarding the preparation, optical absorption, emission and FTIR
spectral studies on Dy3+ doped Li2O-CaF2-Al2O3- B2O3- SiO2 glasses. Absorption spectrum reveals
different bands and it analyzed by the use of JO-theory. Emission spectra of the samples display two
4
transitions F9/2→6H15/2, 4
F9/2→6H13/2, a clear enhancement is observed with increase the
concentration of Dy2O3 ions. The CIE coordinates is measured for these glasses it demonstrates that
the glasses produce bright white light, which are appropriate for the improvement of the laser
materials and white light LED's.
Keywords:Optical absorption, emission, JO-theory, FTIR
The Crystallization process of Xanthan Gum Bio Polymer is studied by Differential Scanning
Calorimetry (DSC) at different heating rates (2,4,6,8 and 10 K/min) under non isothermal
conditions. Four iso-conversional (Flynn-Wall-Ozawa, Tang, Straink ,Kissinger-Akahira-Sunose and
Ortega)approaches are utilized to determine the activation energy of crystallization (Ec) and Avrami
exponent (nα ) . The transformation of amorphous phase to crystalline form is discussed.
Keywords:Non-isothermal method;Iso-conversional; Crystallization kinetics; Biopolymer;
Activation energy.
Acknowledgements
We thank Central Salt and Marine Chemical Research Institute (CSMCRI), Bhavnagar,
Gujarat 364002, India for helping DSC experimental work.
Khan Faizan*, Shaikh Junaid, Farha Naaz, Aqsa Samreen, Shaikh Saima Anam,
Shaikh Zeba Anjum, Pravina P.Pawar.
Dr. Babasaheb Ambedkar Marathwada University, Aurangabad.
Mobile: (+91) 8485803926; E-mail:khanfaizan3926@gmail.com
Abstract
Acknowledgements:
The authors extend their sincere thanks to UGC-SAP Programme (F.530/16/DRS-I/2016 (SAP-2) Dt.
16-04-2016) and DST-FIST (Project NO. SR/FST/PSI-210/2016 (C) dtd.16/12/2016) for providing
financial support.
Reference
1. L. Wang, X. Wang, J. Cheng, P. Ning, Y. Lin, Appl. Surf. Scie., 439, 213-221, 2018.
2. E. Pakdel, W.A. Daoud, S. Seyedin, J. Wang, J.M. Razal, L. Sun, X. Wang, Coll. Surf. A:
Physicochem. Engin. Asp., 552, 130-141, 2018.
3. I.N. Ivanenko, T.A. Dontsova, I.M. Astrelin, V.V. Trots, J. Water Chem. Technol., 37(1), 14-20,
2016.
4. T. Dontsova, I. Ivanenko, I. Astrelin, Nanoplasmonics, nano-optics, nanocomposites, and
surface studies: Springer Proceedings in Physics, 167, 275-293, 2015.
In the last two decades there has been a lot of interest in the development of alternative renewable
energy sources [1]. Particularly thermoelectric materials have witnessed a renewed interest since
thermoelectric effect can be used to convert thermal energy into electrical energy; they provide an alternative
for power generation from waste heat and also can be used for refrigeration. The efficiency of thermoelectric
S 2
materials is given by the dimensionless figure of merit (ZT) defined as ZT Where S,,& T are the
T
Seebeck coefficient, electrical conductivity, thermal conductivity and absolute temperature respectively.
Therefore excellent thermoelectric performance require a high power factor as well as low thermal
conductivity.
Since the initial observation of high thermoelectric performance in SnSe in 2014 in the temperature
range 723-923 K[2], there have been a large number of research papers on SnSe samples[3]. Favourable
thermoelectric properties in SnSe are not limited to higher temperature phase but can also be obtained in low
temperature phase by suitable doping. Now doping in SnSe can be done either at cation site or anion site.
Singh et al[4] tried Al, Cu, Pb and In as dopants at Sn site and synthesized Sn (1-x)MxSe in the polycrystalline
form. Their study showed that Cu doped SnSe alloys resulted in enhancement of ZT and could work as a
potential and cost effective TE material. Since it has been seen that SnSe in single crystal form gives a better
thermoelectric performance[5], it was thought worthwhile to grow Cu doped SnSe in single crystalline form.
The SnSe crystals doped with copper were grown by DVT-Direct Vapour Transport technique having no
transporting agent. The present paper describes a complete structural characterization of the as grown samples.
For structural analysis, X-ray diffraction data of pure and Cu doped SnSe samples have been recorded using
Phillips Xpert MPD, Holland in the 2 range of 25 to 63 with scanning speed of 3 per minute employing
CuK radiation with =1.5405 A. All the X-ray peaks have been indexed and it is seen that the grown
crystals possess an orthorhombic crystallographic phase. The lattice parameters have been calculated using the
relation 1 h k l The calculated values match with the values reported in the literature. The unit cell
2 2 2
2 2 2
d a b c2
volume has been evaluated using V = abc. Parameters such as crystallite size D, lattice strain and dislocation
density have been determined with the following formula k , 2 and 15 Where β2 is the
t
cos 2 4 tan t
integral half width, k is a constant equal to 0.90, is wavelength of incident X-rays(0.1540 nm), is Bragg
angle.
The elemental analysis for chemical stoichemetry has been done with the help of EDAX spectra. The
spectra clearly show the presence of all the elements in nearly stoichiometric proportion. The X-ray diffraction
analysis is directly supported by electron diffraction patterns taken from the as grown samples. Scanning
Electron Microscopy has been used to study the growth mechanism which is responsible for the growth of
grown samples of SnSe and SnSeCu. The implications of all the results have been thoroughly discussed.
Acknowledgements
Authors are hearty grateful to Head, Dept. of physics, Sardar Patel University, V.V. Nagar for providing the
necessary research facilities.
Keywords: friction stir welding; temperature profile; polygonal pin profiles; dissimilar materials.
Acknowledgements
The author is grateful to the University Grants Commission, Delhi for the financial support through a
R&D project (MRP-7019/16(SERO/UGC)). The author wishes to acknowledge the help rendered by
Dr. Gopa Dutta, Director R&D and Management of Vignana Bharathi Institute of Technology,
Ghatkesar, Hyderabad to carry out this work.
K. Ramesh1
1
Assistant Professor, Department of Chemistry, Chaitanya Bharathi Institute of Technology (A),
Gandipet, Hyderabad-500075, India
*Corresponding author. Mobile: (+91) 9849116946;E-mail:ramscbit@gmail.com
Abstract
During the past two to three decades, there has been green revolution in the field of chemical
research all over the world to prevent environmental pollution and the use of nonvolatile solvents,
which are essential ingredients in a large number of organic synthesis protocols. More specifically
removal of organic solvents in chemical synthesis is important in the drive towards benign chemical
technologies. Encouraged by these results, Polyethylene glycols (PEGs) have been applied here as
efficient additives in these reactions under solvent free conditions. Poly ethylene glycol (PEG)
supported Hunsdiecker–Borodin reactions were conducted with certain α, β-unsaturated acids in the
presence of metal nitrates such as ferric nitrate and manganese nitrate under solvent free (solid state)
and mineral acid free conditions. The reactants were ground in a mortar with a pestle for about 30
minutes. The aromatic acids underwent nitro decarboxylation and afforded β-nitro styrene derivatives
in very good yield while α, β-unsaturated aliphatic carboxylic acids gave corresponding nitro
derivatives. Addition of PEG accelerated rate of the reaction enormously. Reaction times
substantially decreased from several hours to few minutes followed by highly significant increase in
the product yield. Among the several PEGs used in this protocol, PEG-400 has been found to be
more effective than other PEGs.
Keywords: Metal Nitrate, Poly ethylene glycols, Hunsdiecker –Borodin reaction, α, β-unsaturated
carboxylic acids.
In this work, we report fabrication of high quality visible light photo-detector based on
uniform nano-crystalline cadmium sulfide (CdS) thin film deposited on glass substrate using spray
pyrolysis technique. Structural, morphological and chemical analysis of the film confirms nano-
crystalline nature of CdS thin film with ~ 30 nm crystallites and uniform coating of CdS on glass.
Finger electrodes were made on the film using Ag paste. Photo-detection property of nano-crystalline
CdS thin films was tested under visible light illumination. For photo-detection, the response of
incident light in terms of photo-current was monitored when exposed to different wavelengths
ranging from 420 to 700 nm. The fabricated device showed significant photo-detection at lower
operating voltage (2 V) for low power (< 10 mWcm−2) light. Time response measurements at
different wavelength show ultra-fast response and decay time and high photo sensitivity at low bias
voltage.
Keywords:Nano-crystalline; CdS; spray coating; photo-detector, ultra fast response and decay time
Thin film materials are the key elements of photonic, electrical and magnetic devices. Using
the thin film produced from powder material allows easy incorporation for various applications as
because the change in properties of materials and size reduction. A co-precipitation method was used
to prepare the CNT blended Ce doped TiO2 photocatalyst. Thin film of CNT blended Ce-TiO2over a
perspex substrate was prepared using a simple drop-casting method. The structural analysis was
carried out using X-ray diffraction (XRD). The elemental and optical analysis was carried out using
energy-dispersive X-ray spectroscopy (EDAX) and Photoluminescence (PL) studies respectively.
The hydrogen production activity was determined form the data obtained from gas chromatograph.
The thin film of CNT blended Ce-TiO2 was prepared using 1 mg of powder form of CNT blended
Ce-TiO2 catalyst which is coated on perspex substrate (1.25 cm x 3.75 cm). Hydrogen production
activity was studied using simulated sulfide solution. The results had shown that the highest
hydrogen production value of 1850 µmol h-1g-1for thin film whereas the same amount of CNT
blended Ce-TiO2 powder showed very less hydrogen production of 83 µmol h-1g-1. From the above
results it is inferred that the thin film form outperformed the particulate form in the order of
magnitude. This is because of the increased surface area of thin film materials and less recombination
rate of charge carriers.
Keywords:Co-precipitation method; Gas chromatograph; surface area; thin film materials
Acknowledgements
The authors gratefully acknowledge Hindustan Institute of Technology and Science, Chennai and
CSIR-National Chemical Laboratory, Pune for the laboratory facilities and other research supports.
Acknowledgements
The authors gratefully acknowledge Hindustan Institute of Technology and Science, Chennai and
CSIR-National Chemical Laboratory, Pune for the laboratory facilities and other research supports.
The composition of Anthracene and Lead Titanate is prepared using Solid State reaction
method.Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C14H10, consisting of three
fused benzene rings. It is a component of coal tar. Lead (II) titanate is an inorganic compound with the
chemical formula PbTiO3. It is the lead salt of titanic acid. Lead (II) Titanate is a yellow powder that is
insoluble in water. At high temperatures, lead Titanate adopts a cubic perovskite structure. The samples of
Anthracene Lead Titanate composites of suitable mixture ratio are prepared using Solid state reaction
method.TheCrystal structure of the calcined powders and also sintered ceramics were analyzed using XRD(X-
ray diffraction). The microstructure of the sintered ceramics has been investigated by using SEM(scanning
electron microscopy).The dielectric constants were calculated for different mixture ratios and at different
temperaures are reported in this paper. It was observed that an increasein temperature there is a change in the
dielectric constants has also been reported in this paper
Keywords:Anthracene, Lead Titanate, dielectric properties, SEM,XRD,. Solid State Method, Perovskite,
PAH, microstructure.
N.V.Bharadwaj1*, Dr.P.Chandrasekhar2,Dr.M.Sivakumar
1
Geethanjali College of Enegineering and Technology, Hyderabad, 501301,India
2
MGIT, Hyerabad, 500075, India
3
Gudlavalleru Engineering College,Gudlavalleru, 521356, India
*Corresponding author. Mobile: (+91) 9492030271; E-mail:bharadwaj23@gmail.com
Please
Abstract
insert
photogra
The design of induction motor for Electric Vehicle application is different from that of
ph of the
conventional induction motor, which is used in various drive applications. The performance
presenti
ng
parameters of an induction motor depend on various design parameters including electrical and
author.
mechanical. In this paper study of various parameters such as core axial length, stator inner diameter
and rotor outer diameter is done. The effect of these parameters on induction motor characteristics is
studied using analytical method. The analysis is done one two different induction motors and their
performance is compared.
Keywords:Electric Vehicle; Induction Motor; Design Parameters.
Acknowledgements
I thank Geethanjali college management for the support.
Spacers are important component in the Gas Insulated systems. Most of the dielectric strength
breakdown and surface flashover cases were due to spacer failures. Non uniform electric field
distribution along the surface of the spacer and high field stress at triple junctions are reasons for
these failures. Accurate modelling of the Spacer geometry is required for a better stress spread as it
enhances the life of the component. Seldom stress control by means of shape modelling results in
difficulties like moulding and fabrication.In this paper, a Polymeric Insulator is designed for a Single
phase GIS for reduction of electric field stress. Electric field calculations for Nitrades, Oxides and
Carbides type nano composites are computed and the reduction of electric field sress is done with the
insertion of metal inserts.
Identification of approximate model of the physical systems can be achieved by fitting the
data. In this paper particle swarm optimization algorithm (PSO) is used for linear and polynomial
curve fittings. Data generated from the known models and curve fitting is done by PSO using reverse
engineering mechanism at the initial stage. In this process of curve fitting, two types of inertia
mechanisms are used in PSO for getting better results. Later, real time financial series forecasting is
considered for validating the PSO estimated regression models. Results shows the dynamic inertia
weight strategy based PSO yields better fitting and avoids additional decisions on control parameters.
Solid state lithium ion conductors are being extensively investigated in the hope of
developing materials with high ionic conductivity, good electrochemical stability and useful
mechanical properties. Such materials have many applications in energy storage and other
electrochemical devices. Lithium ion conducting glasses have advantages over, for example, polymer
based systems, in that conduction can be solely attributed to the lithium species. It has been reported
that , the glass composition containing lithium in borosilicate network gives good conductivity. TiO2
is reported to increase the glass forming ability. Hence TiO2 is added to three different lithium
borosilicate compositions. In the present work, titanium oxide containing lithium borosilicate glasses
have been synthesized by conventional quenching technique.
The XRD was done for all glass samples to conform their amorphous nature. Transport
number measurements were carried out to determine the contribution of ions to the total electrical
conductivity of the glasses. Electrical conductivity (σ) of these glasses has been studied by dielectric
impedance analyzer as a function of frequency at different temperatures in the range 480 to 650 K.
Glass transition temperature Tg for the glasses has been determined by using DTA. The density of all
glass samples has been determined.
It has been observed that the electrical conductivity increases with increasing content of TiO2
which can be attributed to the modification of the structure by the addition of larger titanium ions. A
good correlation has been obtained between the electrical conductivity, activation energy, density
and Tg values. It has been also reported that, there is a very good correlation of lithium fraction,
glass transition temperature and ionic conductivity observed in these glasses
Keywords:lithium borosilicate; TiO2; glass transition temperature; conductivity; lithium fraction
Acknowledgements
One of the authors (NSS) wishes to express sincere thanks to Dr. V. K. Deshpande for providing
research facilities at V. N. I. T., Nagpur
e insert
*Corresponding author. Mobile:, Telephone: (+91) 9908325596; E-mail:arunabharathi916r@gmail.com
photograph of
ABSTRACT the presenting
author.
A high voltage, high power and stable non toxic cathode materials is gaining attention due to
increasing demand for Li-ion battery (LIB) for use in Battery Electrical Energy Storage (BEES)
system. This paper explains the preparation of a thermally stable high voltage LiMn1.5Cu0.5O4
spinel synthesized using Citric Acid Modified (CAM) microwave assisted sol-gel method. The
synthesized sample was characterized using XRD, SEM, HRTEM, EIS and CV. Our powder XRD
analysis shows that the sample has a pure single phase and possessed a good crystallization in the
range of 20-30 nm. The lower weight loss (<10%), as observed from TG/DTA graphs, represents the
nano crystalline LiMn1.5Cu0.5O4 material is thermally stable. The electrochemical studies show single
phase behaviour in the potential range of 4 to 5 V potential region with a good cycling property. The
impedance spectra obtained from the electrode, made out of this material, has semi circles in a high
and intermediate frequency range representing lower charge transfer resistance that enhances the life
cycles of battery. The morphological studies exhibit homogeneous particle distribution in nanoscale.
This uniform distribution is attributed to the microwave treatment, which shortened the synthesizing
time and has overcome the agglomeration of particles. This kind of morphology is very essential for
both the high specific capacity and good cyclebility. Further, the smaller particle size results faster
diffusion of Li to produce effective charge transfer that results in the capacity of the nanostructured
material. Therefore, the nanostructured LiMn1.5Cu0.5O4 is well suited cathode material for LIB
applications in BEES systems.
Abstract
In this paper we present a new approach to the construction of a transition matrix associated
with first order matrix system of differential equations. This method is unique and is applicable to all
problems that arise in control systems and the tedious calculations so far existing in literature will be
condensed to less than half.
Acknowledgements: The authors would like o thank CNST of JNTUH Institute of science and
Technology, kukatpally for providing lab facilities and encouraged to carry out research project.
Abstract
B2O3-ZnO-Na2O-Li2O (BZNL) based glasses containing silver nano particles (Ag NPs) were
prepared by melt-quenching technique. Four reducing agents such as Bi2O3, As2O3, Sb2O3, SnO were
separately used to reduce Ag+ ions into Ago atoms in the form of nano particles. The glasses were
characterized by XRD, FTIR, DSC, Optical absorption and Raman spectroscopy. The amorphous
nature of the prepared glasses was confirmed through XRD and SEM measurements. The EDS
spectra showed that all the added elements were present in the respective glasses. The vibrational
features of various functional groups like stretching vibrations of B–O linkages in BO4 tetrahedral,
asymmetric stretching vibrations of B–O bond in BO3 trigonal units and vibrations of Zn–O bonds
from ZnO4 groups were identified by FTIR and Raman spectroscopy. From optical absorption studies
it was observed that as prepared samples except SnO did not show characteristic surface plasmon
resonance (SPR) band of Ag. Therefore, all the samples were heat treated at 500oC in accordance
with DSC thermogram to form Ag nano particles and were confirmed by optical absorption spectra.
It was observed that the doping of SnO to BZNL-Ag glass system could assist the growth of silver
nano particles.
Abstract
The polymer blend composites of PANI with PVDF/KDP have been synthesized by
polymerization method. The different polymer blend of PANI with PVDF/KDP composites are
obtained by adding 10, 20, 30, 40 and 50 wt% of KDP were added with PVDF of 1N concentration
during PANI synthesis to get the polymer blend of PANI with PVDF/KDP composites. The
synthesized samples of PANI and polymer blend of PANI with PVDF/KDP composites polymer
were characterized by using X-Ray diffraction (XRD). The dielectric properties such as dielectric
constant, dielectric loss and AC conductivity for the composites of polymer blend of PANI with
PVDF/KDP composites at different weight percentages are studied as a function of frequency in the
range 5Hz–35MHz at room temperature. It is found that the dielectric permittivity decreased
exponentially at lower frequency region up to 180 Hz and then the dielectric permittivity remains
constant at higher frequency region as the frequency increased. It is also observed that the dielectric
permittivity decreased as the weight percentages of KDP increases in PVDF with PANI. AC
conductivity increased for PANI, polymer blend of PANI with PVDF/KDP composites at 10, 20, 30
and but for 40 and 50 wt% it is decreased.
Keywords: polymer blend of PANI with PVDF/KDP dielectric constant, dielectric loss and A.C
conductivity, KDP.
1
Department of ECM, J.B Institute of Engineering and Technology, R.R Dist, Hyderabad-500075.
2
Department of Physics, J.B Institute of Engineering and Technology, R.R Dist, Hyderabad-500075.
3
Department of EEE, GodutaiWomens f Engineering College, Sharananagar, Kalaburagi, India 585102
4
Department of PG Studies and Research in Physics, Gulbarga University Gulbarga-585105, India.
.
* Corresponding author. Dr. M.V.N. Ambika Prasad, Tel.: +91 9448405817.
E-mail address:prasad1_amb@rediffmail.com
Abstract
Cadmium oxide doped in polyaniline (CdO /PANI) composites were prepared with various
weight percentages by in situ polymerization method using aniline, ammonium per sulfate, and CdO
as starting materials. The temperature& frequency dependent conductivity behavior of PANI / CdO
composites have been studied. The formation of PANI and PANI / CdO composites with regards to
the structural and microstructural properties of the materials were investigated by XRD and SEM
techniques. The DC conductivity of Pure PANI and its composites have been measured in the
temperature range from 30°C to 160°C. The variation of σac with frequency obeys power law except
a small deviation in the low frequency region and the σac increases with increase in CdO
concentration.
1
High Performance Computing Lab, Department of Physics, Indian Institute of
technology(Indian School of Mines), Dhanbad, Jharkhand, 826004, Indian.
Molecular adsorption of hydrogen in lithium decorated smallest fullerene (C20Li2) has been
carried out within the framework of density functional theory (DFT) at B3LYP/6311+G(d,p) level.
Hydrogen molecules were added sequentially till no more hydrogen molecules could accommodate
by the C20Li2. The global reactivity descriptors such as, electronegativity (χ), hardness (ɳ), and
electrophilicity (ω) were calculated to confirm the kinetic stability of the clusters. It has been
observed that the C20Li2 clusters could hold maximum of eight hydrogen molecule with average
adsorption energy in the range 0.11 - 0.06 eV/H2 resulting in gravimetric density of 5.98 wt% which
is in accordance with the target set by US Department of Energy (US-DOE) for optimal hydrogen
adsorption. The average adsorption energy value and the distance between Li atom and hydrogen
molecules indicates the process to be physisorption type. Topological analysis using Bader's quantum
theory of atoms in molecules (QTAIM) concluded that the interaction between H2 and Li atom to be
closed shell type with ρ < 0.20 a.u with positive corresponding to ionic or van der Walls bonds.
Thermochemistry calculations were carried out to calculate the Gibbs free energy corrected average
adsorption energy which reveals the feasible adsorption temperatures and pressures. The desorption
temperature were calculated using Van’t Hoff equation.
Keywords: DFT, Fullerene, QTAIM, Hydrogen storage, Thermochemistry.
Acknowledgements
We thankfully acknowledge Indian Institute of Technology (Indian School of Mines), Dhanbad for
providing all research facilities.
Upconversion Er3+/Yb3+ co-doped CeO2 submicron sized particles synthesized through classical
hydrothermal method for development of dye sensitized solar cells1 (DSSC). The insertion of
upconverter CeO2:Er3+/Yb3+ into photoelectrode (PE) by spin coat method evidenced power
conversion efficiency (PCE) of 6.91 %, JSC = 15.8%, VOC = 0.62 and FF = 0.7 using platinum free
counterelectrode (CE) made with SnS through spray coat method. The test device performance is
further optimized by introduction of carbon particles into SnS CEs. The results are compared with
the standard platinum based DSSC (8.32 %) and evaluated varies photovoltaic parameters.399
Keywords: Upconverter DSSC, Pt-free SnS counterelectrode, LiI effect, Bifunctional CeO2: Er/Yb.
Acknowledgements
A.Meenakshamma is thankful to SERB, DST for awarding JRF and financial support through
EMR/2016/007049. M. Raghavender thanks SERB, DST (Grant No. EMR/2016/007049) for
financial support to carry out this work.
In this paper the effect of magnesium (Mg) substitution in lithium (Li) site of spinel lithium titanate
(Li4Ti5O12, LTO) anode materials for lithium-ion batteries (LIBs) is extensively studied. The anode
materials based on the formula Li4-xMgxTi5O12 (x=0 and 0.2) are prepared by conventional ceramic
method at 850° C for 16h. Their phase formation processes, crystal structures, morphology, elemental
analysis, cation distribution and electrical properties were studied using XRD, SEM, EDX, FT-IR and
CIS characterization techniques. The X-ray diffraction (XRD) studies revealed the exact structure of
the material which belonged to cubic spinel group with Fd-3m space group. The phase morphological
features and grain size distribution were found using scanning electron microscopy (SEM) and the
grainsize was found to be in the range 0.9-1.1μm. The FT-IR results revealed the structure of the oxide
lattice built of MO6 (M= Li, Mg and Ti) as tetrahedra and octahedra. The electrical impedance studies
showed the material to exhibit excellent conductivity which was found to be 2.8×10-5 S/cmat ambient
temperature for frequency ranging from 20 Hz to 1MHz.
High voltage electric utilities are hindered with certain difficulties like high stress distribution and
insulation damage that are needed to be taken care for reliable operation of the system. In a Gas
Insulated bus duct, high field stress along the spacer surface especially at the contact point of the
conductor, insulator and gas (called triple junction) is a major factor affecting the insulation strength.
Research studies of shaping the spacer were found effective in controlling the stress distribution but
found to be complicated in real time application. In this paper, functionally graded materials of post
type spacer with different permittivity are proposed for controlled field stress distribution at the
spacer surface. Electric field calculations for three gradings namely grading to high, grading to low
and U shape are done. Properly shaped metal inserts are incorporated to have a uniform stress
distribution along the spacer.
High voltage power equipments are becoming more dense and subjected to high stress leading to
insulation failure. Insulator design plays a vital role in improving the reliability of the system. In GIS
the solid supporting structures called spacers are vulnerable to more stress and their design is of
concern. The point of contact of the conductor, gas and spacer called the triple point junction in Gas
insulated bus duct is highly stressed region and is responsible for major insulation failures.
Switchgear design in GIS needs thorough field distribution at the supporting structures called
spacers, which is important for healthy operation of the system. In this paper, U – Type graded
material is taken for Disk type spacer with different permittivity for controlling field stress
distribution at the spacer surface. Electric field calculations for three gradings namely grading to
high, grading to low and U shape are done and compared.
Cu-Cd-Er ferrite nano particles having the compositional formulaCu Cd Erx Fe2-x O4
(Where x=0.001, 0.0015, 0.0020) was synthesized by CGAC method (Citrate-Gel Auto
Combustion). The structural properties were carried out by X-ray diffraction (XRD) and Scanning
Electron Microscopy (SEM) . XRD studies are revealed that the structure of these nanoparticles are
conformed with the single phase cubic spinal structure. The crystallite size lies in the range 21.0-42.8
nm. The lattice parameter has been calculated from d-spacings and interpreted on the basis of ionic
radius. The observed results can be explained on the basis of erbium composition.
Keywords: CGAC method (Citrate- Gel Auto-Combustion), Ferrite Nano particles, XRD, SEM and
FTIR.
Abstract
Recent advances in nanoscience have paved way for magnetic nanoparticles (MNPs) to be
used for water purification. In this study, magnetic nanoparticles were introduced due to their
impressive properties like high adsorption capacity and high extraction efficiency, high surface area
to volume ratio (even for particles less than 30nm in size), ability of magnetic immobilisation and
generation of oxidative stress in microbial contaminants thereby leading to heavy metal adsorption
and anti microbial activity. The MNPs were synthesized by chemical co-precipitation method. The
results showed high bacteria removal efficiency (99.5%), removal of heavy metals (Cu, Cr, As, Pb)
from acqueous system to a much better extent. It is suggested that MNPs are worth applying as this
technique is simple, cost effective and reusable. The toxicity test suggested that no significant
genotoxicity or cytoxicity existed in water treated with few MNPs (poly-allylamine hydrochloride)
showing they are biocompatible, whereas research on environment effect of few MNPs (iron oxide)
has to be addressed.
Keywords: Magnetic nanoparticles, bacteria, adsorption, extraction, surface area, heavy metals,
toxicity, cost effective, environment, biocompatible.
Acknowledgements
The authors extend their sincere thanks to UGC-SAP Programme (F.530/16/DRS-I/2016 (SAP-2) Dt.
16-04-2016) and DST-FIST (Project NO. SR/FST/PSI-210/2016 (C) dtd.16/12/2016) for providing
financial support.
In this work, we report the synthesis of TiO2 nanotubes (TNTs) using hydrothermal method
and incorporated MWCNT insitu to make a hybrid nanocomposite of TiO2 - MWCNTs. The as-
synthesized TiO2 - MWCNTs composite structural, optical, elemental analysis was characterized by
using different techniques such as X-ray diffraction (XRD), UV-visible spectroscopy, and energy
dispersive spectroscopy (EDAX), elemental mapping. The morphology and formation of TiO2 -
MWCNTs composite nanotubes was confirmed from electron microscopy techniques viz., field
emission scanning electron microscope (FE-SEM) and high-resolution transmission electron
microscope (HR-TEM). The effect of concentration of MWCNTs in TiO2-TNTs photoanode was
investigated on the performance for dye-sensitized solar cells (DSSCs) application. The performance
of DSSCs were evaluated by measuring photocurrent voltage (I-V) characteristics and
electrochemical impedance spectroscopic (EIS) and found that the power conversion efficiency of
DSSC depends on the concentration MWCNT in the photoanode. DSSC fabricated using 6 wt % of
MWCNT with respect to TiO2 containing nanocomposite as photoanode has shown high power
conversion efficiency (PCE) of 1.99%.
Keywords: TNTs; MWCNT; Photoanode; DSSCs.
In dye-sensitized solar cells, binder used in fabrication of semiconductor photo anode layer
plays a significant role on the surface morphology of the anode film, which has impact on the overall
performance of the DSSCs devices. In this work, two synthetic polymers (poly (vinyl alcohol)
(PVA), poly (vinylpyrrolidone) (PVP)) and their blends (1:1, 1:3, 3:1) are used as a binder and
investigated their effect on the efficiency of the cell. DSSC devices are fabricated using commercial
TiO2 nanopowder as photoanode anode, N719 dye, Idolyte HI-30 as electrolyte and Plastisol T as
counter electrode. Among DSSCs fabricated, the sample prepared with pure PVP as binder shows
the highest power conversion efficiency of 1.87%, short-circuit photocurrent density and open-circuit
voltage of 10.14 mA/cm2 and 0.56 V, respectively.
Keywords: DSSCs; PVA; PVP; XRD; SEM.
Acknowledgments
The authors are grateful to the Department of Science and Technology of New Delhi (DST -
DST / INSPIRE Fellowship / 2014 / IF 140988) in India who provided funds for young researchers
and Dr. M. Raghavender, Assistant professor, Dept of Physics, Yogi vemana University, Kadapa to
providing solar simulator.
Abstract
3
d eff . 10 23
m 2V 2 which shows effect of streaming colloids. The colloidal grains (CGs) in
diffusive semiconductor plasmas found to bemodifying the characteristic and alter the optical and
physical properties of the material.
Keywords: Colloids; Modulational Instability (MI); strain dependent dielectric constant (SDDC);
Diffusive Semiconductor Plasmas.
In this study, the synthesis and characteristic results of Zirconia (ZrO2) nanoparticles was discussed.
Synthesis of ZrO2 nanoparticles was done by Sol-Gel method to achieve controllable particle
morphology. Zirconia nanoparticles have a number of excellent properties such as high strength,
fracture toughness, wear resistance, hardness and chemical resistance. ZrO2 nanoparticles was
characterized by Fourier Transform Infrared Spectroscopy (FTIR), UV-visible Spectroscopy ,
Particle Size Analyzer(PSA) and X-ray Diffraction (XRD). we can further use these nanoparticles as
effective anti-corrosion agents when composited with PANI.
Graphical Abstract :
Acknowledgements :
This work was supported by Centre for Nanoscience and Technology, Institute of Science
Technology, JNTU Hyderabad. The first author would like to acknowledge AICTE for TEQIP-III for
R&D support.
Acknowledgements
The authors would like to thank their sincere appreciation to the Center for Nano science and
Technology, IST, JNTUH for providing the research facilities.
Abstract
In this work Nano SiO2 nanoparticles were synthesized using Sol-Gel technique. As synthesized
particles are been analyzed by varying the parameters (aging time, pH etc.) that affects the particle
size and hydrophobicity, hydrophilicity nature and UV light reflectance properties are also been
varied under controlled conditions. Nano SiO2 nanoparticles and thin films are been analyzed using
different characterization techniques like Fourier Transform Infrared Spectroscopy (FTIR), UV-
visible Spectroscopy, Particle Size Analyzer (PSA) and X-Ray Diffraction (XRD), Contact angle
measurement. Hydrophobic nature is been analyzed over different substrates.
Center for Nano Science and Technology, Institute of Science and Technology, JNTU
Hyderabad, India
Conductive inks are a recent progress in electronics and have a promising future applications
in flexible electronics and smart applications. Due to low melting temperature, low price and high
conductivity, copper nanoparticles have great potential to substitute conductive polymers, silver and
gold nanoparticles and others in conductive inks. Here we developed a new, simple and green
method to synthesize copper nanoparticles, which have the average size of around 92 nm and show
remarkable ability to prevent oxidation. Various characterization techniques like X-Ray Diffraction
(XRD), Particle Size Analyzer (PSA), UV Visible Spectroscopy, Fourier Transform Infrared
Spectroscopy (FTIR) were carried out. Using the copper nanoparticles for conductive ink, the
resistivity of the copper conductive films was 18.9µΩ•cm which was just about tentimes higher than
bulk copper's resistivity. The proposed approach to synthesize copper nanoparticles for high
performance conductive ink presents potential applications in flexible electronics.
Keywords: Copper Nanoparticles; conductive inks; electrical conductivity; flexible electronics; inks
Acknowledgements
The first author would like to acknowledge AICTE for GATE Fellowship and TEQIP-III for R&D
support.
Acknowledgements
Authors are grateful to the financial support from the management of Hindustan University through
CENCON. One of the author Veena thanks, the research funding from Dongguk University though
QSRC.
Keywords: Silver nanoparticles; thin films; optical microscopy; room temperature; sensitivity.
Acknowledgements
This work was supported by Manipal Academy of Higher Education, Karnataka and Jawaharlal
Nehru Technological University ( JNTU), Hyderabad.
1
Department of Physics, 2Department of ECE
Geethanjali College of engineering and technology, cheeryala, Hyderabad, Telangana, India-501301
*Corresponding author email: neerajarani@gmail.com
Abstract
Acknowledgments
Authors are grateful to the financial support from Defence Research and Development Organisation -
DRDO.
Website: yamtoinstruments.org