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4 Pressure-Volume Graphs Independent Task v1.1
4 Pressure-Volume Graphs Independent Task v1.1
Pressure-Volume Graphs
Independent Study Task
Let’s Go
turn to
portrait
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Press the buttons
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If the buttons
don’t work, try
opening in a
different app
Really, don’t scroll
Press the buttons
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If the buttons
don’t work, try
opening in a
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Pressure-Volume Graphs
moments car
batteries hydraulics
of inertia engines
Not quite right…
The correct answer involves gases expanding,
contracting and changing temperature…
Go back
Pressure-Volume Graphs
Let’s go
Ideal Gas Law Recap
The ideal gas law;
pV = nRT
Go back
Not quite right…
pV = nRT
n is the number of moles of gas
R = 8.31 J mol-1 K-1 the gas constant
Go back
Not quite right…
An ideal gas has no inter-molecular forces
Go back
Ideal Gas Law Recap
-298K 298K
-273K 323K
273K 423K
Not quite right…
Convert 25oC in to Kelvin…
Go back
Ideal Gas Law Recap
1 x 105 Pa 1 x 108 Pa
1 x 106 Pa 1 x 109 Pa
1 x 107 Pa 1 x 1010 Pa
Not quite right…
I thought you might
have a familiarity with
this one.
Go back
Ideal Gas Law Recap
1 x 105 Pa 1 x 108 Pa
1 x 106 Pa 1 x 109 Pa
1 x 107 Pa 1 x 1010 Pa
Not quite right…
Now you are just guessing.
Bad lobster
Go back
Ideal Gas Law Recap
pV = nRT
A sealed balloon changes pressure, volume and
temperature. It changes from p1 V1 T1 to p2 V2 T2
V1 V2 p1V1 p 2V2
= =
T1 T2 T1 T2
Not quite right…
pV = nRT
nR is a constant as the amount of gas stays the same
Go back
The First Law of Thermodynamics
Q is positive if heat
energy is transferred
to the system
Q = ∆U + W
W is the work done by
∆U is the internal energy change, it the gas, it is positive if
is positive if the gas gains kinetic the gas expands
energy i.e. temperature increases
OK
The First Law of Thermodynamics
Q is positive if heat
energy is transferred
to the system
Q = ∆U + W
W is the work done by
∆U is the internal energy change, it the gas, it is positive if
is positive if the gas gains kinetic the gas expands
energy i.e. temperature increases
∆U = 200J ∆U = -200J
∆U = 800J ∆U = -800J
∆U = 1200J ∆U = -1200J
Not quite right…
Q = ∆U + W
Q = 1000J W = -200J
Go back
Isothermal Processes
Q = 0 so ∆U = -W
∆U = 0 so Q = W
W = 0 so Q = ∆U
Not quite right…
Q is positive if heat
energy is transferred
to the system
Q = ∆U + W
W is the work done by
∆U is the internal energy change, it the gas, it is positive if
is positive if the gas gains kinetic the gas expands
energy i.e. temperature increases
Go back
Isothermal Processes
pV = nRT
p1 p2
= p1V1 = p2V2
V1 V2
p1 p2 V1 V2
= =
T1 T2 T1 T2
Not quite right…
pV = nRT
p1V1 p2V2
=
T1 T2
Go back
Isothermal Process Graphs
p1V1 = p2V2 = constant =nRT
p p
y = k/x
V V
Red line
Blue line
Directly proportional
Not quite right…
pV = nRT
Go back
Adiabatic Processes
Q = ∆U + W
Q = 0 so ∆U = -W
∆U = 0 so Q = W
W = 0 so Q = ∆U
Not quite right…
Q is positive if heat
energy is transferred
to the system
Q = ∆U + W
W is the work done by
∆U is the internal energy change, it the gas, it is positive if
is positive if the gas gains kinetic the gas expands
energy i.e. temperature increases
Go back
Adiabatic Processes
∆U = - W
change in internal energy = - work done
𝛾 𝛾
p 1V1 = p 2V2
Go back
Adiabatic Process Graphs
Isothermal process: pV = constant
Adiabatic process (for hot air): pV1.4 = constant
p
Red line
Blue line
Yellow line
Pink line
Not quite right…
Isothermal: p = k/V
Adiabatic: p = k/V1.4
Go back
Constant Pressure Processes
W = p∆V
p
V1/T1 = V2/T2
p1V1 p2V2
=
T1 T2
Q = ∆U + W
W = p∆V
Go back
Constant Volume Processes
p
Work done, W = 0
The first law; Q = ∆U + W becomes Q = ∆U
p ∝ 1/T
Not quite right…
The internal energy U of an ideal gas depends only
on the temperature
p1 p2
=
T1 T2
Go back
Units
pressure x volume
Nm-3.m3 ≡ N
Nm-2.m3 ≡ Nm
Nm-3.m3 ≡ J
Nm-3.m2 ≡ J
Not quite right…
Look carefully and try again…
Go back
Units
pressure x volume
Nm-2.m3 ≡ Nm
Nm ≡ J
Correct
OK
Work done from p-V graphs
Recall that for constant pressure, work
done is the area under the graph
p
W = p∆V
Area =
work (J) V
In general:
p
W = p(V) dV
Area =
work (J) V
OK
Work done from p-V graphs
Engine cylinders go through engine cycles as they rotate and
pistons move in and out, gases burn and are exhausted etc
OK
Work done from p-V graphs
Go back
Work done from p-V graphs
Correct!
– =
Subtracting the areas gives the work done per engine cycle.
OK
p-V diagrams
E to X
F to X
G to X
H to X
None
Not quite right…
p 1 V1 pV
= 2 2
T1 T2
Go back
Not quite right…
p 1 V1 pV
= 2 2
T1 T2
Go back
Not quite right…
p 1 V1 pV
= 2 2
T1 T2
Go back
Not quite right…
p 1 V1 pV
= 2 2
T1 T2
Go back
Correct!
p 1 V1 pV
= 2 2
T1 T2
OK
p-V diagrams
Go back
Not quite right…
Go back
Not quite right…
Go back
Correct!
BLAST OFF
The air valve is forced out by the water pressure and the air in
the bottle expands. The expanding air forces the water out of
the neck of the bottle at high speed; this provides the thrust
that lifts the bottle high into the air.
OK
Estimate the work done by the expanding air
75 ± 5 J
150 ± 10 J
300 ± 10 J
330 ± 10 J
Not quite right…
Each square;
0.5 x 105 x 0.5 x 10-3
= 25J
Go back
p-V diagrams
A→ B isn’t isothermal
Not quite right…
For an isothermal process;
Go back
p-V diagrams
Go back
What is the work done for a full cycle A→B→C→D→A?
B C C B
+ –
A A
B C C B
+ +
A A
B C C B
+ –
A A
Not quite right…
Go back
More help
please
+ –
=
Go back
Q /J W /J ∆U /J
A→B -188
B→C +235 67
C→A +168
A→B→C→A +47 0
Q = 0J
Not quite right…
A→B is an isothermal process so ∆U = 0
Q = ∆U + W
Go back
Q /J W /J ∆U /J
B→C +235 67
C→A +168
A→B→C→A +47 0
∆U = 0J
Not quite right…
A→B is an isothermal process so ∆U = 0
Q = ∆U + W
Go back
Q /J W /J ∆U /J
B→C +235 67
C→A +168
A→B→C→A +47 0
∆U = 0J
Not quite right…
Use the first law of thermodynamics
Q = ∆U + W
Go back
Q /J W /J ∆U /J
C→A +168
A→B→C→A +47 0
Q = 0J
Not quite right…
B→A is isothermal but C→A is steeper, suggesting
it is adiabatic
Go back
Q /J W /J ∆U /J
C→A 0 +168
A→B→C→A +47 0
∆U = 0J
Not quite right…
Use the first law of thermodynamics
Q = ∆U + W
Go back
Q /J W /J ∆U /J
A→B→C→A +47 0
Q = 0J
Not quite right…
Use the first law of thermodynamics
Q = ∆U + W
Go back
These questions have lots of guidance hiding
behind the wrong answers. Try one…
You Choose
AQA Equation Sheet
Bring it on
The Carnot Cycle
Go back
The Carnot Cycle
How to use the other areas to work out the shaded area?
Go back
The Carnot Cycle
Work = p(V) dV
pVγ = constant
pV = nRT
OK
The Carnot Cycle
c
Work = p(V) dV
b
c
Work = constant 1/Vγ dV
b
Go back
The Carnot Cycle
nR nR
W= (pc/Vc – pb/Vb) W= (TH –TL)
γ–1 γ–1
nR nR
W= (1/TH –1/TL) W= (1/TL –1/TH)
γ–1 γ–1
Not quite right…
Does this help?
Go back
The Carnot Cycle
Well done, you have found the work done in adiabatic
processes 2 & 4 – this is the trickiest bit of algebra in the
Carnot Cycle
nR
W2 = (TH –TL)
γ–1
a
1
b
4
2 TH
d 3 TL
0 c
0 V
Here the high temperature TH and the low temperature TL are temperatures as measured on an ideal
gas thermometer, that is
pV
T = .
NR
One cycle of the Carnot engine acts as follows:
• Leg 1: Isothermal expansion at high temperature. As the gas expands, it lifts a big pile of sand —
that is, it does work |W1 |. We’ve seen that expansion normally sends the temperature down. To keep
the same temperature, the gas must absorb heat |Q1 | from its surroundings.
• Leg 2: Adiabatic expansion. As the gas expands, it lifts a big pile of sand — that is, it does work |W2 |.
The expansion sends the temperature down. Because it’s adiabatic, no heat is absorbed or ejected.
• Leg 3: Isothermal compression at low temperature. As the gas contracts, it lets down a small pile
of sand — that is, work |W3 | is done on the gas. We’ve seen that compression normally sends the
temperature up. To keep the same temperature, the gas must eject heat |Q2 | into its surroundings.
• Leg 4: Adiabatic compression. As the gas contracts, it lets down a small pile of sand — that is, work
|W4 | is done on the gas. The compression sends the temperature up. Because it’s adiabatic, no heat
is absorbed or ejected.
1
|Q1| expand |W1|
at temperature TH
compress
at temperature TL
|Q3| |W3|
Overall, the gas absorbs some heat and ejects some heat. The gas does some work and some work is
done on it. The “net work done by the gas” is the work done by the gas minus the work done on the gas.
We’re interested in getting as large a net work as possible for a given amount of heat absorbed. That is,
we’re interested in getting a large
net work done by gas |W1 | + |W2 | − |W3 | − |W4 |
efficiency = = . (1)
heat absorbed by gas |Q1 |
(James Watt had a similar measure that he called “duty”: the work in foot-pounds generated by a bushel
of coal. I actually prefer the name “duty” to “efficiency”, but we’re stuck with “efficiency”.)
To find the relevant quantities, remember that the work done by a quasistatic fluid is
Z
p(V ) dV.
[[This formula applies only if the gas can be considered at equilibrium while the volume is changing. If there
are currents in the gas, then one cannot even define a pressure in the way we’ve been using the term! Such
currents will generally result in internal friction which throws off the work and heat calculations we’ll do
soon. If the piston experiences friction rubbing against the cylinder walls, then the force will not be the same
as pressure × area. In short, this calculation will find the efficiency of an “ideal engine” using the working
fluid of an “ideal gas”. Real engines with friction and currents and so forth will be less efficient.]]
2
Leg 1: On this isothermal expansion leg, the temperature is TH so
N RTH
p(V ) = . (2)
V
The work done by the gas is then
Z b
W1 = p(V ) dV
a
Z b
N RTH
= dV
a V
Z b
dV
= N RTH
a V
b
= N RTH ln(V )
a
Vb
= N RTH ln (3)
Va
Remember that Vb > Va , so this quantity is positive, as expected. (In leg 1, the gas does work by lifting
something.)
The heat absorbed merely counteracts the effect of the work done, so
(This derivation relies upon the already-stated fact that the energy of a given sample of an ideal gas is a
function of temperature alone, not of temperature and volume.)
Leg 2: On this adiabatic expansion leg, the pressure and volume are related through
Before I calculate the work, I’m going to find a relation between temperature and volume that will turn out
to be useful later:
pb Vbγ = pc Vcγ
pb Vb Vbγ−1 = pc Vc Vcγ−1
N RTH Vbγ−1 = N RTL Vcγ−1
γ−1
TH Vc
= (6)
TL Vb
We’ve already said that an increase in volume will result in a decrease in temperature (for example, in
releasing air from a bicycle tire), and this equation tells us quantitatively what that temperature change is.
3
With this piece of bookkeeping out of the way, we go ahead and find the work done by the gas:
Z c
W2 = p(V ) dV
b
Z c
1
= constant γ
dV
b V
c
1
= constant V (−γ+1)
−γ + 1 b #
"
1 constant constant
= −
−γ + 1 Vcγ−1 Vbγ−1
" #
1 pc Vcγ pb Vbγ
= − γ−1
−γ + 1 Vcγ−1 Vb
1
= [pc Vc − pb Vb ]
−γ + 1
1
= N R [TL − TH ]
−γ + 1
NR
= (TH − TL ) . (7)
γ−1
Once again, and again as expected, this quantity is positive.
Leg 3: In the isothermal compression leg, the calculation of work done by the gas is performed exactly
as it was in leg 1, but of course with different variables plugged in. Referring to equation (3) we find
Vd
W3 = N RTL ln . (8)
Vc
Because Vd < Vc , this quantity — the work done by the gas — is negative. The work done on the gas is
Vd Vc
|W3 | = −N RTL ln = N RTL ln . (9)
Vc Vd
Leg 4: In the adiabatic compression leg, the calculations are performed exactly as they were in leg 2,
but of course with different variables plugged in. Referring to equations (6) and (7) we find
γ−1
TL Va
= (11)
TH Vd
and
NR
W4 = (TL − TH ) . (12)
γ−1
As expected, this quantity is negative and
NR
|W4 | = −W4 = (TH − TL ) . (13)
γ−1
4
With all of the relevant quantities known we can go ahead and calculate the efficiency
|W1 | + |W2 | − |W3 | − |W4 | |W2 | − |W3 | − |W4 |
efficiency = =1+ .
|Q1 | |Q1 |
But our calculations show that |W2 | = |W4 |. (In retrospect, this is obvious for an ideal gas. We didn’t
need to evaluate W2 and W4 . But lots of things are obvious in retrospect. I am not ashamed.) Using our
calculated values for |W3 | and Q1 , we find
We seem to have found the final answer. But there’s one more simplification that can be performed.
Comparing equations (6) and (11), we find
γ−1 γ−1
TH Vc Vd
= =
TL Vb Va
so
Vc Vd
=
Vb Va
or
Vc Vb
= .
Vd Va
The two natural logs in the expression for efficiency are equal!
Our final result for the efficiency of an ideal Carnot engine using an ideal gas as a working fluid is the
remarkably simple
TL
efficiency = 1 − . (14)
TH
This efficiency is independent of the details concerning volume and depends only on the two temperatures
concerned. To get a high efficiency (always a good thing) one wants the highest possible TH and the lowest
possible TL .