3.

29 Sucrose derivatives
Eastman SAIB-100
PARAMETER UNIT VALUE
GENERAL INFORMATION
Name Eastman SAIB-100
CAS # - 27216-37-1
EC number - 204-771-6
Composition 100% sucrose acetate isobutyrate
Acronym SAIB
Empirical formula C40H62O19
Formula

Molecular mass daltons 832-856

RTECS number - WN6550000
Chemical class sucrose derivative
PHYSICAL PROPERTIES
State - viscous liquid
Odor - odorless
Color - light yellow
Color, Platinum-cobalt scale - <200
Boiling point o
C 288
Acid number mg KOH/g <0.2
Refractive index at 20oC - 1.454
Saponification value mg KOH/g 104-107 g/eq
Solubility (diluents) soluble in most alcohols, vegetable oils,
flavoring oils, animal fats, and vegeta-
ble-based waxes
Solubility in water at 25oC g/l negligible
Solubility in water at 25 C o
wt% 0.1
Specific heat at 100 C o
- 1,674.72
Specific gravity at 25oC - 1.146
Surface tension at 25oC mN/m 28.0
Vapor pressure at 20 C o
kPa 1.30E-06
HEALTH & SAFETY
NFPA classification Flammability 1
Health 0
Reactivity 0

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 706

3.29 Sucrose derivatives
Eastman SAIB-100
PARAMETER UNIT VALUE
HMIS classification Flammability 1
Health 0
Reactivity 0
Carcinogenicity IARC, OSHA, NTP: no ingredient of this
product present at levels greater than or
equal to 0.1% is identified as probable,
possible or confirmed human carcinogen
DOT class not regulated
TDG class not regulated
ICAO/IATA class not regulated
IMDG class not regulated
Flash point o
C 260/227
Flash point method - COC/TCC
Hazardous combustion products Carbon monoxide, carbon dioxide
Agency rating, listed TSCA USA, DSL Canada, AICS Aus-
tralia, MITI Japan, ECL Korea, IECSC
China
Animal testing, acute toxicity, Rat oral LD50 mg/kg 25600/sucrose
acetate isobutyrate
Animal testing, acute toxicity, Mouse oral LD50 mg/kg 25600/sucrose
acetate isobutyrate
Animal testing, acute toxicity, Rat dermal LD50 mg/kg 22000/sucrose
acetate isobutyrate
Exposure, personal protection Safety glasses, protective clothing
based on chemical resistance data,
chemical-resistant gloves, general and
local exhaust ventilation.
First aid, eye Rinse cautiously with water for several
minutes. Remove contact lenses, if
present and easy to do. Continue rins-
ing. If eye irritation persists: Get medical
advice/attention.
First aid, inhalation Remove to fresh air. If not breathing,
give artificial respiration. If breathing is
difficult, give oxygen. If irritation persists,
obtain medical advice.
First aid, skin Wash off with soap and water.
ECOLOGICAL PROPERTIES
Aquatic toxicity, Daphnia magna, 48-h LC50 mg/l >1.11/sucrose
acetate isobutyrate
Aquatic toxicity Fathead minnow, 96-h LC50 mg/l >1.82/sucrose
acetate isobutyrate

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 707

3.29 Sucrose derivatives
Eastman SAIB-100
PARAMETER UNIT VALUE
Chemical oxygen demand g/g 1.63/sucrose
acetate isobutyrate
Partition coefficient, log Kow - 6.00/sucrose
acetate isobutyrate
USE & PERFORMANCE
Manufacturer Eastman Chemical Company
Outstanding properties Delivered from a natural, renewable
sources, Eastman Sustane SAIB MCT
(sucrose, a natural sugar) Improved wa-
ter resistance, enhanced gloss, resistant
to air oxidation, low viscosity, reduced
evaporation rate of aroma chemicals,
improved emulsion stability. Used in lip-
stick and make-up can improve its wear
properties and adhesion and flexibility.
Compatible with large number of resins,
plasticizers, oils, humectants used in
cosmetic.
Recommended for products cosmetics: lipstick, lip gloss, mascara,
foundation, concealer, etc.

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 708

Eastman SAIB-90

PARAMETER UNIT VALUE

GENERAL INFORMATION
Name Eastman SAIB-90
CAS # 126-13-6, 27216-37-1 or 137204-24-1,
73398-61-5
EC number - 204-771-6
Composition 89.5-90.5% sucrose acetate isobutyrate,
<10% ethyl alcohol, <1 methyl isobutyl
ketone, 0.5% methanol
Acronym SAIB
Empirical formula C40H62O19
Formula

Chemical class sucrose derivative

Mixture - yes
PHYSICAL PROPERTIES
State - viscous liquid
Odor - ester
Color - yellow
Color, Platinum-cobalt scale - <200
Boiling point o
C 105
Acid number mg KOH/g <0.2
Solubility (diluents) soluble in most alcohols, esters (amyl
acetate, ethyl acetate, isobutyl acetate),
vegetable oils, flavoring oils, animal fats,
and vegetable-based waxes
Solubility in water at 25oC g/l negligible
Specific gravity at 25 C o
- 1.1
Vapor density - 1.5
Vapor pressure at 20oC kPa 5.32
Viscosity at 25 C
o
mPas 770
HEALTH & SAFETY
HMIS classification Flammability 3
Health 2
Reactivity 0
Carcinogenicity isobutyl methyl ketone IARC 2B:
possibly carcinogenic to humans

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 709

Eastman SAIB-90

PARAMETER UNIT VALUE

DOT class Flammable liquids, n.o.s. (ethanol,
methanol) 3, ll. Shipping descriptions
may vary based on mode of transport,
quantities, package size, and/or origin
and destination.
TDG class
ICAO/IATA class Flammable liquid, n.o.s. (ethanol,
methanol) 3, ll. Shipping descriptions
may vary based on mode of transport,
quantities, package size, and/or origin
and destination.
IMDG class FLAMMABLE LIQUID, N.O.S. (ethanol,
methanol) 3, ll. Shipping descriptions
may vary based on mode of transport,
quantities, package size, and/or origin
and destination.
Autoignition temperature o
C >402
Flash point o
C 17.1
Flash point method - TCC
Hazardous combustion products Carbon monoxide, carbon dioxide
Agency rating, listed TSCA USA, DSL Canada, AICS Aus-
tralia, MITI Japan, ECL Korea, IECSC
China
Hazardous ingredients, labelling Flammable liquids, n.o.s. (ethanol,
methanol)
Animal testing, acute toxicity, Rat oral LD50 mg/kg 25600/sucrose
acetate isobutyr-
ate, 10470/ethanol,
5628/methanol,
2000/methyl
isobutyl ketone
Animal testing, acute toxicity, Mouse oral LD50 mg/kg 25600/sucrose
acetate isobutyrate
Animal testing, acute toxicity, Rabbit dermal mg/kg >15800/ethanol,
LD50 17100/methanol,
>10/methyl isobutyl
ketone
Animal testing, acute toxicity, Guinea pig dermal mg/kg 22000/sucrose
LD50 acetate isobutyrate
Animal testing, acute toxicity, Rat dermal LD50 mg/kg 22000/sucrose
acetate isobutyrate
Animal testing, acute toxicity, Rat inhalation, mg/m3 64000ppm/4H/
LC50 methanol,
<4000ppm/isobutyl
methyl ketone

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 710

Eastman SAIB-90

PARAMETER UNIT VALUE

Effect of exposure, eye (human) May irritate and cause redness and
pain.
Effect of exposure, inhalation (human) Avoid inhalation of vapor or mist. In high
concentrations, vapors and spray mists
are narcotic and may cause headache,
fatigue, dizziness and nausea. Narcotic
effect.
Effect of exposure, skin (human) May irritate and cause redness and
pain.
Effect of exposure, swallowing (human) May be fatal if swallowed/isobutyl methyl
ketone
Exposure, personal protection Safety glasses, protective clothing
based on chemical resistance data,
chemical-resistant gloves, general and
local exhaust ventilation.
First aid, eye Rinse cautiously with water for several
minutes. Remove contact lenses, if
present and easy to do. Continue rins-
ing. If eye irritation persists: Get medical
advice/attention.
First aid, inhalation Remove to fresh air. If not breathing,
give artificial respiration. If breathing is
difficult, give oxygen. If irritation persists,
obtain medical advice.
First aid, skin Wash off with soap and water.
NIOSH, REL mg/m3 ST325/methanol
OSHA, PEL mg/m3 260/methanol;
1900/ethanol,
410/isobutyl methyl
ketone
ACGIH, TLV ppm 200/methanol,
1000/ethanol,
20/isobutyl methyl
ketone
NIOSH, REL ppm 20/isobutyl methyl
ketone
OSHA, PEL ppm 1000/ethanol, 100/
isobutyl methyl
ketone
ECOLOGICAL PROPERTIES
Aquatic toxicity, Green algae, 96-h EC50 mg/l 275/72H/ethanol
Aquatic toxicity, Bluegill sunfish, 96-h LC50 mg/l 15400/methanol
Aquatic toxicity, Daphnia magna, 96-h LC50 mg/l 4300/24H/isobutyl
methyl ketone

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 711

Eastman SAIB-90

PARAMETER UNIT VALUE

Aquatic toxicity, Daphnia magna, 48-h LC50
Aquatic toxicity Fathead minnow, 96-h LC50
BOC/COD ratio
Biological oxygen demand, 5 days
Biological oxygen demand, 20 days
Chemical oxygen demand
USE & PERFORMANCE
Manufacturer
Outstanding properties
Recommended for products
Recommended applications
mg/l >1.11/sucrose
acetate isobutyrate
mg/l >1.82/sucrose
acetate isobutyrate
% 54.6/methanol
g/g 0.770/methanol,
1.94-2.06/isobutyl
methyl ketone
g/g 1.260/methanol
g/g 1.63/sucrose
acetate isobutyr-
ate, 1.99/ethanol,
1.44/methanol,
2.16-2.46/isobutyl
methyl ketone
Eastman Chemical Company
Derived from a natural, renewable
source (sucrose, a natural sugar).
Improved adhesion to fingernails, chip
and scratch resistance, leveling of
brush strokes, increased film flexibility.
Decreased evaporation rate of fragrance
ingredients. Excellent solubility and
compatibility with solvents, polymers,
and modifiers. Low volatility over a wide
temperature range. Nonyellowing; stable
to UV light exposure. Increased water
resistance of films. Enhanced gloss.
Compatible with large number of resins,
plasticizers, oils, humectants used in
cosmetic.
nail lacquers
used in various types of coatings such
as lipsticks and nail lacquers. It can pro-
vide coatings of higher non-volatile con-
tent, resulting in lower solvent require-
ments and greater coverage (increased
film deposition per application). At levels
up to 15% in some polymers, SAIB has
minimal effect on surface hardness.
High levels of SAIB provide flexibility
and reduce the glass transition tem-
perature of the film-former. Used as a
modifying extender for film-formers such
as nitrocellulose and cellulose esters

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 712

Eastman SAIB-90

PARAMETER UNIT VALUE

Food approval (FDA) 175.105; 175.300; 175.390

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 713

Eastman SAIB-90EA

PARAMETER UNIT VALUE

GENERAL INFORMATION
Name Eastman SAIB-90EA
CAS # 126-13-6, 27216-37-1 or 137204-24-1,
73398-61-5
EC number - 204-771-6
Composition >90% sucrose acetate isobutyrate in
10% ethyl acetate
Acronym SAIB
Empirical formula C40H62O19
Formula

Chemical class sucrose derivative

Mixture - yes
PHYSICAL PROPERTIES
State - viscous liquid
Odor ester/3.9 ppm odor threshold
Color - light yellow
Color, Platinum-cobalt scale - <200
Boiling point o
C 78
Melting point o
C -83
Acid number mg KOH/g <0.2
Solubility (diluents) soluble in most alcohols, vegetable oils,
flavoring oils, animal fats, and vegeta-
ble-based waxes
Solubility in water at 25oC g/l negligible
Specific gravity at 25oC - 1.11
Vapor pressure at 20 C o
kPa 111
Viscosity at 25oC mPas 935
HEALTH & SAFETY
HMIS classification Flammability 3
Health 1
Reactivity 0
Carcinogenicity no data available
DOT class Ethyl acetate solution 3, ll
ICAO/IATA class Ethyl acetate solution 3, ll
IMDG class ETHYL ACETATE SOLUTION 3, ll

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 714

Eastman SAIB-90EA

PARAMETER UNIT VALUE

Flash point o
C 21.5
Flash point method - TCC
Hazardous combustion products Carbon monoxide, carbon dioxide
Agency rating, listed TSCA USA, DSL Canada, AICS Aus-
tralia, MITI Japan, ECL Korea, IECSC
China
Hazardous ingredients, labelling Ethyl acetate solution
Animal testing, acute toxicity, Rat oral LD50 mg/kg 25600/sucrose
acetate isobutyrate,
5600/ethyl acetate
Animal testing, acute toxicity, Mouse oral LD50 mg/kg 25600/sucrose
acetate isobutyrate
Animal testing, acute toxicity, Rabbit dermal mg/kg 20000/ethyl acetate
LD50
Animal testing, acute toxicity, Guinea pig dermal mg/kg 22000/sucrose
LD50 acetate isobutyrate
Animal testing, acute toxicity, Rat dermal LD50 mg/kg 22000/sucrose
acetate isobutyrate
Animal testing, acute toxicity, Rat inhalation, mg/m3 6000ppm/6H/
LC50 ethyl acetate
Effect of exposure, inhalation (human) Avoid inhalation of vapor or mist. High
vapor concentrations may cause drowsi-
ness.
Effect of exposure, skin (human) Prolonged or repeated skin contact may
cause drying, cracking, or irritation.
Effect of exposure, swallowing (human)
Effect of repeated or overexposure (human) Prolonged or repeated skin contact may
cause drying, cracking, or irritation.
Exposure, personal protection Safety glasses, protective clothing
based on chemical resistance data,
chemical-resistant gloves, general and
local exhaust ventilation.
First aid, eye Rinse cautiously with water for several
minutes. Remove contact lenses, if
present and easy to do. Continue rins-
ing. If eye irritation persists: Get medical
advice/attention.
First aid, inhalation Remove to fresh air. If not breathing,
give artificial respiration. If breathing is
difficult, give oxygen. If irritation persists,
obtain medical advice.
First aid, skin Wash off with soap and water.
OSHA, PEL mg/m3 1400/ethyl acetate

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 715

Eastman SAIB-90EA

PARAMETER UNIT VALUE

ACGIH, TLV ppm 400/ethyl acetate
OSHA, PEL ppm 400/ethyl acetate
ECOLOGICAL PROPERTIES
Aquatic toxicity, Daphnia magna, 48-h LC50 mg/l >1.11/sucrose
acetate isobutyrate
Aquatic toxicity Fathead minnow, 96-h LC50 mg/l >1.82/sucrose
acetate isobutyrate
Biological oxygen demand, 5 days g/g 1.240/ethyl acetate
Biological oxygen demand, 20 days g/g 1.240-1.430/
ethyl acetate
Chemical oxygen demand g/g 1.63/sucrose
acetate isobutyrate
USE & PERFORMANCE
Manufacturer Eastman Chemical Company
Outstanding properties Improved adhesion to fingernails, chip
and scratch resistance, leveling of brush
strokes, increased film flexibility, gloss
enhancement. Compatible with large
number of resins, plasticizers, oils,
humectants used in cosmetic.
Recommended for products cosmetics (nail lacquers), lacquers,
coatings, textiles
Recommended applications used in various types of coatings such
as lipsticks and nail lacquers. It can pro-
vide coatings of higher non-volatile con-
tent, resulting in lower solvent require-
ments and greater coverage (increased
film deposition per application). At levels
up to 15% in some polymers, SAIB has
minimal effect on surface hardness.
High levels of SAIB provide flexibility
and reduce the glass transition tem-
perature of the film-former. Used as a
modifying extender for film-formers such
as nitrocellulose and cellulose esters

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 716

Eastman Sustane SAIB MCT

PARAMETER UNIT VALUE

GENERAL INFORMATION
Name Eastman Sustane SAIB MCT
CAS # 126-13-6, 27216-37-1 or 137204-24-1,
73398-61-5
EC number - 204-771-6
Composition 80% sucrose acetate isobutyrate,
20% medium chain triglycerides
Acronym SAIB
Empirical formula C40H62O19
Formula

Chemical class sucrose derivative

Mixture - yes
PHYSICAL PROPERTIES
State - viscous liquid
Odor - odorless
Color - light yellow
Color, Platinum-cobalt scale - <200
Acid number mg KOH/g <0.3
Solubility (diluents) dissolves rapidly in many flavoring oils
and solvents
Solubility in water at 25oC g/l negligible
Specific gravity at 25oC - 1.1
Viscosity at 25 C
o
mPas 5,000
HEALTH & SAFETY
HMIS classification Flammability 1
Health 1
Reactivity 0
Carcinogenicity no data available
DOT class not regulated
TDG class not regulated
ICAO/IATA class not regulated
IMDG class not regulated
Flash point o
C 99/246
Flash point method - TCC/Setaflash CC
Hazardous combustion products Carbon monoxide, carbon dioxide

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 717

Eastman Sustane SAIB MCT

PARAMETER UNIT VALUE

Agency rating, listed TSCA USA, DSL Canada, AICS Aus-
tralia, MITI Japan, ECL Korea, IECSC
China
Animal testing, acute toxicity, Rat oral LD50 mg/kg 25600/sucrose ac-
etate isobutyrate
Animal testing, acute toxicity, Mouse oral LD50 mg/kg 25600/sucrose ac-
etate isobutyrate
Animal testing, acute toxicity, Guinea pig dermal mg/kg 22000/sucrose ac-
LD50 etate isobutyrate
Animal testing, acute toxicity, Rat dermal LD50 mg/kg 22000/sucrose ac-
etate isobutyrate
Exposure, personal protection Safety glasses, protective clothing
based on chemical resistance data,
chemical-resistant gloves, general and
local exhaust ventilation.
First aid, eye Rinse cautiously with water for several
minutes. Remove contact lenses, if
present and easy to do. Continue rins-
ing. If eye irritation persists: Get medical
advice/attention.
First aid, inhalation Remove to fresh air. If not breathing,
give artificial respiration. If breathing is
difficult, give oxygen. If irritation persists,
obtain medical advice.
First aid, skin Wash off with soap and water.
ECOLOGICAL PROPERTIES
Aquatic toxicity, Daphnia magna, 48-h LC50 mg/l >1.11/sucrose
acetate isobutyrate
Aquatic toxicity Fathead minnow, 96-h LC50 mg/l >1.82/sucrose
acetate isobutyrate
Chemical oxygen demand g/g 1.63/sucrose
acetate isobutyrate
USE & PERFORMANCE
Manufacturer Eastman Chemical Company

Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing 718

Eastman Sustane SAIB MCT
PARAMETER
Outstanding properties
Recommended for products
Recommended applications
Databook of Adhesion Promoters/Copyrights 2018; ChemTec Publishing
UNIT VALUE
Delivered from a natural, renewable
sources Eastman Sustane SAIB MCT
(sucrose, a natural sugar) Improved wa-
ter resistance, enhanced gloss, resistant
to air oxidation, low viscosity, reduced
evaporation rate of aroma chemicals,
improved emulsion stability. Used in lip-
stick and make-up can improve its wear
properties and adhesion and flexibility.
Compatible with large number of resins,
plasticizers, oils, humectants used in
cosmetic.
cosmetics: lipstick, lip gloss, mascara,
foundation, concealer, etc.
used in various types of coatings such
as lipsticks and nail lacquers, effective
in cosmetics, hair care and skin care
applications. It can provide coatings of
higher non-volatile content, resulting in
lower solvent requirements and greater
coverage (increased film deposition per
application). At levels up to 15% in some
polymers, SAIB has minimal effect on
surface hardness. High levels of SAIB
provide flexibility and reduce the glass
transition temperature of the film-former.
Used as a modifying extender for
film-formers such as nitrocellulose and
cellulose esters.
719