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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr.

Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S

Sri Chaitanya IIT Academy., India.


A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office – Madhapur – Hyderabad
SEC: Sr. Batch-1_Ph-II JEE-MAIN Date: 28-11-2020
Time: 07.00 Am to 10.00 Am PTM-02 Max. Marks: 300
KEY SHEET
MATHEMATICS
1 3 2 4 3 1 4 2 5 4
6 2 7 4 8 3 9 1 10 2
11 3 12 3 13 1 14 3 15 1
16 3 17 4 18 4 19 1 20 2
21 19 22 5 23 2 24 81 25 9

PHYSICS
26 1 27 2 28 3 29 3 30 1
31 3 32 2 33 2 34 2 35 4
36 3 37 1 38 1 39 1 40 4
41 1 42 3 43 4 44 2 45 3
46 0001.39 47 0008.57 48 0015.00 49 0277.35 50 0079.00

CHEMISTRY

51 2 52 3 53 4 54 1 55 2
56 1 57 4 58 3 59 3 60 3
61 4 62 3 63 2 64 3 65 3
66 4 67 3 68 1 69 4 70 2
71 01 72 10 73 6 74 2 75 3

Sec: Sr. Batch-1_Ph-2 Page 1


SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S

SOLUTIONS
MATHEMATICS
1. Solution : (3)
1 1 1
x 4 sin    x 2 x sin   
as x   x   x  lim  x  lim  x x
3
x  1 x x  1
1
x3
1
sin  
 x  1
1 x
  1 0
x
 lim     1
x  1 0  1
1
x3
2. Solution : (4)
Since f ( x) is continuous at x  0
1  cos 4 x
 lim f ( x)  lim f ( x)  f (0)  LHL  lim f ( x)  lim
x 0 x 0 x 0 x 0 x2
2
4
  8 LHL  f (0)  a  8
2
3. Solution : (1)
1 1 1 1 1 1
x 2  2cos ec t , y 2  2sec t  x 2 y 2  2cos ec t , 2sec t x 2 y 2  2cos ec t  2sec t
x 2 y 2  2 /2 x 2 y 2  K diff wrt x ;
dy  x dy  dy  y
2 xy 2  x 2 2 y  0 2 xy   y  0  
dx  dx  dx x
4. Solution : (2)
Case I ) If f ( p)  5 is true then f (q)  5 will also be true thus it is not possible
Case II ) If f (q)  5 is true

5
p
10
q
r 15

f ( p)  5 should be false & f (r )  10 should be false


 f (r )  10 will be true f (q)  15 & f ( p)  5 thus contradicts
Case III) f (r )  10 is true
f ( p)  5 should be false
f (q)  5 should be false

Sec: Sr. Batch-1_Ph-2 Page 2


SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
Then true statements will be
f (q)  5, f (r )  15, f ( p)  10 Hence f 1 (5)  q

tan 4
tan 4 x 2 0
4 tan 5 x 4 tan 5
 4
5. Solution : (4) lim    lim   2    1

x  5 
2
x  5 
2
5
2 3
 since continuous of x   / 2 K  1 K 
5 5
 
6. Solution : (2) lim  x  x  x  x 
x 
 
x x x x x x x
Rationalising  lim  lim
x  x 
( x x x  x) ( x x x  x)
1  x 1/2 1
 lim 
x 
( 1  x 1  x 3/2  1 2

 x3 x2 
7. Solution : (4) lim  2  
x  3 x  4 3x  2 

x 3 (3x  2)  x 2 (3x 2  4)
   form  lim
x  (3 x 2  4)(3x  2)
2 x3  4 x 2 2
 lim 3 2

x 9 x  6 x  12 x  8 9

1
    log x
8. Solution : (3) lim  tan   log x  
x 1
 4 
lim     1 lim 1  tan(log x )  1
1 form  e x 1  tan   log x   1 .  e x 1   1 .
 4   log x  1  tan(log x)  log x
lim 2  tan(log x ) 1 lim 2 tan(log x ) 1
 e x 1 .  e x 1 .
1  tan(log x) log x log x 1  tan(log x)
lim  1  2
 e x1 2(1)   =e
1 0 
9. Solution : (1)
 sin(sgn( x))   sin1
RHL  lim    lim  0
x0
 (sgn( x ))  x0  1 
 sin(sgn( x))   sin( 1) 
LHL  lim    lim    lim  sin1  0
x0
 (sgn( x))  x0  ( 1)  x0
10. Solution : (2)

Sec: Sr. Batch-1_Ph-2 Page 3


SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
3
sin x and e x are not differentiable at x  0 and x is differentiable at x  0 .
 a  0, b  0, c  R
11. Solution : (3)
1
h a sin  
f (h)  f (0)  h   lim h a1 sin  1 
f '(0)  lim  lim  
h 0 h h 0 h h0
h
Thus limit does not exist If a  1  0  a  1
1
None  lim f ( x)  lim x a sin    0, if a  0
x 0 x 0
 x
Thus a  (0,1]
12. Solution : (3) y 2  P ( x)
dy
2 y  P '( x) ……………(1)
dx
2
 dy  d2y
Again difference w.r.t. x 2    2 y 2  P ''( x)
 dx  dx
2
 P '( x)  d2y
From (1) 2    2 y dx 2  P ''( x)
 2 y 
2
 P '( x)  d2y
 2y  P ''( x ) 4 y 3 d y
2
 2 P( x )  ( P ')( x)) 2
2 2 2
2y dx dx
2
3 d y 1 2 d  3 d2y  1
2y  P ( x )  P ''( x )  ( P '( x )) 2  y   P '( x ) P ''( x )  P ( x ) P '''( x )
dx 2 2 dx  dx 2  2
d  3 d2y  1 1
2 y 2 
 P '( x) P ''( x)  P ( x) P '''( x )  2 P '( x) P ''( x )  P ( x) P '''( x )
dx  dx  2 2
13. Solution : (1)
2 2
1/ h
e 1/ h  0 
f ( x) is continuous at x  0 f '(0 )  lim  
lim 1/ h 2  
h 0 h h  0
e 
 1/ h 
2

Apply L’ Hospital Rule  lim


h 0 1/ h 2 3
f '(0 )  0  f '(0 )  0
e (2 / h )
Thus f ( x) is differentiable at x  0
14. Solution : (3)
 lim  f ( x)  1 g ( x) lim tan x  sin x
1 form x0  e x0 cos ecx
 e x0 1  sin x
lim 1  cos x
 e x0  e0  1
cos x (1  sin x)
15. Solution : (1) f ( x  y )  f ( x  y)
x y ( x y )
a a a  a ( x y )
x y
a x .a y  a 4 .a 4 a x .a y
   
2 2 2 2

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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
y x y
x y
a (a  a )  a (a a ) y
( a  a )( a  a  y )
x x y
2 f ( x )2 f ( y )
    2 f ( x) f ( y)
2 2 2
16. Solution : (3)
 1 1  1 1
      
 x x
   x x
RHL  lim x e LHL  lim x e  0  LHL  RHL  f (0)
x 0 x0
0
 f ( x) is continuous at x  0
f ( h)  f (0) h e 0  0
LHD  lim  lim 1
h 0 h h 0 h
h e   0
RHD  lim 0 LHD  RHD
h 0 h
f ( x) is not differential at x  0
17. Solution : (4)
 sin  x 
 ; x  R  [0,1)
f  x     x
 0 ; 0  x 1

sin  x 
RHL  lim 0  0 LHL  lim
x 0 x0  x
sin( 1)
  sin   LHL  RHL  lim f ( x ) does not exist
( 1) x 0

18. Solution : (4)


y  f ( f ( f ( x)))  ( f ( x))2
differentiate wrt x,
dy
 f '( f ( f ( x))). f '( f ( x)) f '( x)  2 f ( x) f '( x )
dx
dy
At x  1  f '( f ( f (1))). f '( f (1)) f '(1)  2 f (1) f '(1) =33
dx
19. Solution : (1)
2 cos x  1
 lim ( / 0)
x  / 4 cot x  1
Use L’ hospital form

 lim
2( sin x)


2 1/ 2  
1
x  / 4  cos ec 2 x
( 2) 2
2

Since continuous of x  xlim f ( x )  f ( / 4)  K  1/ 2
4  / 4
20. Solution : (2)
n n
 1 
 2 K  2  n(n  1) cot 1 (1  n(n  1))  tan 1  
K 1 K 1  1  n(n  1) 
23
 tan 1 (n  1)  tan 1 (n)   (tan 1 (n  1)  tan 1 (n))
n 1

 (tan 2  tan 1)  (tan 3  tan 1 2)  ....  (tan 1 (24)  tan 1 (23))


1 1 1

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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
 24  1  1  23   1  23    1  25   25
 tan 1    tan    cot  tan     cot  cot    
 1  (24)(1)   25    25     23   23
21. Solution : (19)
ax
We know f ( x)  x
a  a
1  39   2   38 
Then f ( x)  f (1  x )  1  f    f   1 f   f   1
 40   40   40   40 
 19   21 
f   f   1
 40   40 
1  2   39  1
We need f    f    ... f   f 
 40   40   40  2
20 1
39 terms 19 pairs + middle term 1  1  .....  f    f  
40 2    
1 1
 19  f    f    19
2 2
22. Solution : (5)
f ( x)  [sin x  cos x ], x  (0, 2 ) is integer at
 3 5 7
x  0, , , , Hence five points of discontinuity
2 4 4 4
23. Solution : (2)
1
f (0)  1 f '( x)  3 x 2  e x / 2 .
2
g ( f ( x))  x g '( f ( x )) f '( x )  1
1
Put x  0 g '( f (0)). f '(0)  1 g '(1)    1 g '(1)  2
2
24. Solution : (81)
2cos2 x
 12 1 1 1

t  2 cos x  3 cos x  4 cos x  ........  9 cos x 
2 2 2

x  /2
 
1 1 2cos 2 x
 
2  2  cos x  3  cos2 x
2

t (9)      .....  1  t 81[1]0 =81


x  /2  9  9  x  /2
 
25. Solution : (9)
Since f ( x) is continuous at x  0
 t f ( x)  f (0)  finite value
x 0

sin 3 x  P sin 2 x  Q sin x


 t
x 0 x5
Use L’ Hospital Rule
cos 3 x  2 P cos 2 x  Q cos x
 t  3  2 P  Q  0 …….(1)
x 0 x4
9 sin 3x  4 P sin 2 x  Q(  sin x)
L’ Hospital Rule  t  0 / 0 form
x 0 20 x 3
27 cos 3 x  8 P cos 2 x  Q cos x
Use L’ Hospital Rule  t  27  8 P  Q  0 …………..(2)
x 0 60 x 2
Sec: Sr. Batch-1_Ph-2 Page 6
SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
Use the above equations
3  2 P  Q  0 27  8 P  Q  0
We get P  4, Q  5  4 P  5Q  4( 4)  5(5)  16  25
PHYSICS
26. Solution.[1]
Y

Field of view

S X

45º H
H

H H
H 2H H
45º
45º
I Y'
4H

from Geometry
H
   tan   I    450
H
    I n YY '  I   tan 45º     1
YY '  IY '  4 H
Hence XY  4H – 2H  2H
27. Solution [2]
v OM ( x )  vIM ( x )  3 – 4  v I( x ) – 4  v I( x )  3
v OM ( y )  vIM ( y )  4 – 5  v I( y ) – 5  v I( y )  4
v OM ( z )  – vIM ( z)  5 – 8  – v I( z )  8
^ ^ ^
 v I( z )  11 v I  3 i  4 j  11 k
28. Solution [3] The object (Candle) should lie between f and 2f of concave mirror, in
order to get real, magnified and inverted image an wall.
There fore concave mirror should be placed beyond 3m so that candle lies in
between f & 2f.
3m

F O 2F
I

4.5 m

29. Solution [3]

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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S

A OB F
15 cm

Point object oscillating between A & B


uB   14.8 cm  uA   15.2 cm
uB  f uA  f
vB  & vA 
uB  f uA  f
14.8  10 15.2  10
vB  vA 
14.8  10 15.2  10
 – 30.8 cm           –  29.2 cm
vB – v A  30.8 – 29.2  1.6 cm.
uA – uB  15.2 – 14.8  0.4 cm.
vB  v A 1.6
m    4
uA  uB 0.4
Hence amplitude of image  m  u
 4  2 mm  8 mm.
30. Solution [1]


Deviation produced by prism


    µ  –  1  A  1.5 – 1  4º        2º
31. Solution [3]
For minimum deviation,  i    e,  r    r '
 r     r '     A  2r    A

i e
r r'

By Snell's law, sin 45º  2 sin r


1
sin r   r  30º  A  2  30º   60º
2
Minimum deviation, m  i  i – A  90º – 60º  30º
32. Solution.[2] f  15 cm .

O I1

20 cm
5 cm

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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
In absuce of convex mirror I1 is the image formed by convex lens. Since mirror is at
distance 5 cm from lens So I1 is at distance
60 – 5 = 55 cm. From convex mirror. Now final image I2 is formed at O it self,
means rays after reflection from mirror incident on mirror normally. Therefore I1 is
centre of curvature.
Hence R1 = 55 cm.
lens
object screen

x D–x
D = 60 cm
33. Solution.[2]
Refer to answer No. 3, the two positions of object for which lens forms its image
on the screen are
D  D2 – 4Df D – D2 – 4Df
x  and x 
2 2
Shift in position of lens
 D – D2 – 4Df   D – D 2 – 4Df 
     D2 – 4Df   20   given 
 2   2 
   
D(D – 4f )  20 60(60 – 4f )  20  400  60  60  –4f 
40 320 320 40
4 f  60 –  ;f   cm
6 6 64 3

 2

1 

34. Solution [2]


Net deviation  1      2
(clockwise) (clockwise)
 ( – )  ( – )  2 ( – )
35. Solution [4]

O I1 I2

t
 1 d
Here I1 I2  d  t  1 –   t 
    –1
36. Solution [3]

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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
t

Optical path difference  x      µt  –  t 


2
x     µ  –  1 t    (  1)t

Inet  I I  2  cos ( ) Inet  2I  2I cos
       2 (  1)t 
Inet  2I  2.cos2   Inet  4I cos2   Inet  4I cos2 
 2   2    2 
At   1, I0  Imax  4I as  ,   and cos2  
and then cos 2   So, correct options is, (C) I first  and then  .
37. Solution [1]
y

4 at x = 

B x
4 3 2  at x = 
 = 0
Maximum path difference  4
maximum occurs at x  4, 3, 2, , 0
Now, first term and last term excluded.
So three maxima.
38. Solution [1]
P
R
x
 
5cm T S

D = 12 cm
QR  (TS)2  PQ2  122  52  13 cm
PR = 12 cm x  QR – PR  13 – 12  1 cm

for first minima x    2x  2x1 cm  2cm
2
39. Solution [1]
Path difference due to slab should be integral multiple of  or x    n
n
or ( – 1) t  n n  1, 2, 3,.. t 
 –1
 
For minimum value of t, n = 1 t    2
 – 1 1.5 – 1
40. Solution [4]
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The condition for minima (dark fringes) is
d 
yn    (2n  1) For two wavelengths 1 and 2 , we get
D 2
d 1 d 
yn    (2n  1) ym    (2n  1) 2
D 2 D 2
For yn  ym we get  2n  1 1   2m  1  2
2n  1  2 560 7 7m  1
   This gives n
2m  1 1 400 5 5
The possible values are n1  3, m  2, n2  10, m2  7 and So on.
Area where the minima of both wavelengths coincides is the area of total
darkness. The width of this area is
1D  1  D  1 1D 400  10 –9  1 (10 – 3)
y   n2    1  n1    (n1 – n2 )   2800  10 –5 m  28 mm
d  2 d  2 d 10 –4
41. Solution[1]
For whistle,   2 rotations/sec
 2  2 rad / s  4 rad / s  4 rad / sec
V  R  4 1  4m / s
B

Listener

A
Maximum frequency will be heard by listener when source is at point A and minimum
frequency will be heard when source is at point B.
 V   V   max V  4 
nmax    nmin    
 V  4   V  4   min V – 4
42. Solution[3]
Final position
 198 m 264 m/s Initial
264 m/s  198 m position

600m
264 cos 

O
198
cos   0.31337
399204
The frequency heard by crew in initial position
 v 
v'  v 
 v  v S cos  
 340 
 1  
 340  264  0.31337 
 1.321 KHz
Frequency heard by crew in final position
 v 
v ''    
 v  v S cos  
 340 
 (1)  
 340  264  0.31337 

Sec: Sr. Batch-1_Ph-2 Page 11


SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
 0.804 KHz
Change in apparent frequency
 v '' – v '
 1.321 – 0.804  0.517 KHz
 520 Hz

43. Solution [4]


A
T1
T1
B P
T2

For equilibrium of pulley P,


T1 T1

T2
2T1  T2
T1 T2
 v1  ;v 2 
A A
v1 T1 1 1
  
v2 T2 2 2
h
44. Solution[2] We know that 
mv
When v is increased , then  is decreased.
Further,   D
d
As  is decreased, fringe width is also decreased
45. Solution [3]Since IP  I0cos2  , we get
2
IP 1   1
  cos2  cos 
I0 4 2 2 2
  2 2
   x …(1)
2 3 3 
where x  d sin
Substituting in (1) we get,
Sin      sin1   
3d  3d 
46. Solution: 0001.39

f  1.5 m, u  14.8  108 km  14.8  1011 m


1 1 1 1 1 1 1 1 1
      v 1
  .5 m
v u f v 1.5 14.8  1011 v 1.5 14.8  1011

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SRI CHAITANYA IIT ACADEMY, INDIA 28-11-2020_ Sr. Batch-1_Ph-2 _JEE-MAIN_PTM-02_KEY &SOL’S
v image size 1.5 image size
m  –   
u object size 14.8  1011 13.8  109
1.5  13.8  109
Image size   1.39cm
14.8  1011
47. Solution : 0008.57
Consider observer in elevator.
Consider free body diagram. of blocks A and B,
N T
arel

T arel

A
mg mg ma0 (pseudo)
For motion of A, T  marel …(1)
For motion of B, mg  m a0 – T  marel ..(2)
g  a0
1   2  mg  ma0  2marel arel     
2
1 2 1
Using, S  ut  at S  0 6  
2
 6  0.2   12 cm
2 2
At t  0.2 sec, u  30 cm, f  – 12 cm
1 1 1 1 1 1 30  12
Using     v  –  – 8.57 cm
v u f v 30 12 42
Required distance  8.57 cm
48. Solution : 0015.00
After refraction at convex lens, image is formed at focus of convex lens. For it to
emerge parallel focus of concave lens must coincide with that of convex lens.
d  fconvex – fconcave  20 – 5  15cm

49. Solution : 0277.35


Stress  F/ A
Fmax
Breaking stress    6     108 Nm–2
A
  7800 kg m–3

T
Now, speed of transverse waves  v 

F F F Fmax F  1
  v      v max    max  .
m/ A /  A A  A  

6  108
  277.35 m / s
7800
50. Solution: 0079.00
Tension in wire AB has to support a weight of  3.2  3.2  g N

 TAB   6.4 g
Tension in wire CD has to support a weight of 3.2 g
 TCD  3.2g

 Speed of transverse wave pulse in AB


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TAB 6.4g
    64  10  0.8   79 m / s
AB 10  10 –3

CHEMISTRY
51. Solution: Mass of one nucleus = volume of nucleus  density
Atomic weight 4
 r 3  d
Avogadro number 3
9 4
For F nucleus 23
 (5  10 13 )3  d
6.023  10 3
d = 6.02  1013 g ml-1  (2)
52. Solution: ROH + CH3MgI  CH4 + Mg
1 mole 1 mole
w ROH
So gas produced is CH4 nCH  112  nROH  4
22400 MWKOH
22400
MW  4.12   103  82.4 g  (3)
112
53. Solution: The compound must contain at least one oxygen atom.
So, a minimum of 1 g atom of oxygen will be present in 1 g molecule i.e., 1 mole of
the compound.
If M is the mol.wt. of the compound then since 16 is the atomic mass of oxygen
so minimum of 16 g of oxygen will be present in M g of the compound
Thus, % of oxygen  16  100 or 3.2  16  100 or M  500  (4)
M M
54. Solution: Normality = Molarity  Valence factor
Normality
 Molarity =
Valence factor
mo. wt. of oxalic acid
Valence factor for oxalic acid =
Eq. wt. of oxalic acid
02
Molarity   0.01 Number of millimoles = 0.01 100
2
Number of moles  0.001
 No. of oxalic acid molecules =0.001 6.023  1023 =6.023  1020  (1)
55. Solution: Moles of CaO  1.62
56
1.62 1.62 3.21
 Moles of CaCl2   Mass of CaCl2   111  3.21 gm  %   100  32.1%
56 56 10
56. Solution: .(1)
57. Solution: (4)
58. Solution: (3)
59. Solution: (3)
60. Solution: (3)
61. Solution: (4)
62. Solution: .(3)
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PV  780.4  17.4   119.7
63. Solution: (2) Number of moles of H2  n     5  103
RT 760  1000  0.0821 293
Let equivalent weight of metal be E, then equivalsents of metal = equivalents of He
0.275
 moles of H2  2  2  5  10 3  E  27.52
E
64. Solution:  Meq  weight  1000  50   weight  1000
Eq.wt. 56
 Weight of KOH  2.80 g  (3)
65. Solution: Mass of a drop of water  0.05  1  g    0.05 g
0.05
No. of moles of water =
18
No. of water molecules = 0.05  6.023  1023
18
1 water molecule certain 8 neutrons
0.05 0.05  8
  6.023  1023 molecule certain  6.023  10 23 neutrons
18 18
= 0.1338  10 = 1.338  10  (3)
23 22

66. Solution: Let us first solve this problem by writing the complete balanced
reaction. 3BaCl2 + 2 Na3PO 4  Ba3 (PO 4 )2  + 6NaCl
3
We can see that the moles of BaCl2 used is times the moles of Na3PO4 .
2
3
 So, to react with 0.2 mol of Na3PO4 , the moles of BaCl2 required would be 0.2   0.3 .
2
Since BaCl2 is 0.5mol, we can conclude that Na3PO 4 is the limiting reagent. Therefore,
1
moles of Ba3 (PO4 )2 formed is 0.2   0.1 mol.  (4)
2
67. Solution: The 'n' factor of KMnO4 is 5 while that of K 2Cr2O7 is 6. So for the same
number of moles, K 2Cr2O7 will have greater equivalence than KMnO4 .  (3)
68. Solution: (1) Let atomic weights of P and Q be ‘a’ and ‘b’ respectively.
 Molecular weight of P2Q3  2a  3b
and molecular weight of PQ2  a  2b   2a  3b   0.15  15.9 , and
 a  2b   0.15  9.3 Thus, a  26, b  18
69. Solution: (4) CaCO3  2HCl  CaCl2  H2O  CO 2
100  0.88
44 gm CO 2  100 g CaCO3 0.88 g CO 2   2.0 g CaCO3
44
2
% purity   100  50%
4
70. Solution:

Balanced equation is 2VO  3Fe2 O3  6FeO  V2 O5


2 5.75
Initialmoles  0.0298  0.0359 0 0
67 160
 0.0359  2 
Final moles  0.0298   0 (0.0359  2) (0.0359  1)
 3 
 Moles of FeO formed  0.0359  2
Weight of FeO formed  0.0359  2  72  5.18 g
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Here, the limiting reagent is Fe 2O3
x gm
 1000mL
40 gm
71. Solution : (01) Molarity   0.1
250mL
 x  1 gm of NaOH
72. Solution: (10) Let the volume strength of H2 O2 be x
According to the question
 meq. of H2O 2  meq. of KMnO 4
x 15.8
 280    1000
5.6 158 / 5
15.8  5
 50x   1000
158
50 x  5 00  x  10
55.2
73. Solution: (6 ) Mass of Fe2O3 =  1   0.552 g
100
0.552
Moles of Fe 2O3 =  3.45  103
160

Equivalents of the oxidant = n  0.0167  17  2.84  10 4 n


1000
(n is the ‘n’ factor of the oxidant)
Since on adding Zinc dust to the Fe2O3 solution all the Fe+3 will become Fe+2 , moles of
Fe2+ in 100 mL =3.45  10-3  2 = 6.9  10-3
 Equivalents of Fe2+ in the 25 mL that is reacting with oxidant
6.9  103
  1.725  103
4
 according to the Law of Equivalents =1.725  10-3 = 2.84  10-4 n
1.725  103
n   6.07  6
2.84  10 4
74. Solution (2)
75. Solution (3)

Sec: Sr. Batch-1_Ph-2 Page 16

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