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(Main) : Computer Based Test (CBT)
(Main) : Computer Based Test (CBT)
2021
COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 17 March, 2021 (SHIFT-2) | TIME : (3.00 p.m. to 6.00 p.m)
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SUBJECT: CHEMISTRY
PART : CHEMISTRY
Single Choice Type
This section contains 20 Single choice questions. Each question has 4 choices (1), (2), (3) and (4) for its answer,
out of which Only One is correct.
1. For the coagulation of a negative sol, the species below, that has the highest flocculating power is:
(1) PO 34– (2) Na+ (3) Ba2+ (4) SO 24–
Ans. (3)
Sol. For anion coagulation cation is used. Higher the charge on cation greater is its flocculation power.
2. The functional groups that are responsible for the ion-exchange property of cation and anion exchange
resins, respectively, are:
(1) –NH2 and –SO3H (2) –SO3H and –NH2 (3) –SO3H and –COOH (4) –NH2 and –COOH
Ans. (2)
Sol. Cation exchange resin contain RSO3H.
Anion exchange resin contain RNH2.
3. Nitrogen can be estimated by Kjeldahl's method for which of the following compound?
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
5. One of the by-products formed during the recovery of NH3 form Solvay process is:
(1) Ca(OH)2 (2) NaHCO3 (3) CaCl2 (4) NH4Cl
Ans. (3)
Sol. In Solvay process CaCl2 is obtained along with NH3 as by product.
OCH3
In the above reaction, the structural formula of (A), "X" and "Y" respectively are:
–
N2+Cl– N2+OCH3
O H H
(1) , CH3 — C—H, HCl (2) ,
H O H , HCl
OCH3 Cl
–
N2+Cl– N2+OCH3
H H O
, , CH3 — C—H , H2O
(3) (4)
H O H , H2O
OCH3 Cl
Ans. (1)
+ –
N2Cl OCH3
C2H5OH
Sol. + CH3–CHO + HCl + N2
(A) (B)
OCH3
(C7H7) N2ClO
(P)
7. The set of elements that differ in mutual relationship from those of the other sets is:
(1) Li – Mg (2) B – Si (3) Li – Na (4) Be - Al
Ans. (3)
Li Be B C
Na Mg Al Si
Sol.
Li & Na are alkali metal but Li, Mg & Be, Al & B, Si have diagonal relationship.
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
8. The common positive oxidation states for an elements with atomic number 24, are:
(1) +1 and +3 (2) +1 to +6 (3) +1 and +3 to +6 (4) +2 to +6
Ans. (4)
Sol. 24Cr = [Ar]3d54s1
11. Choose the correct statement regarding the formation of carbocations A and B given.
+
CH3 — CH2—CH2—CH2 + Br
"A"
CH3—CH2—CHHBr
+
CH3 — CH2—CH—CH3 + Br–
"B"
So, Carbocation (B) is more stable and formed relatively at faster rate.
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
13. The set that represents the pair of neutral oxides of nitrogen is:
(1) NO and N2O (2) NO and NO2 (3) N2O and NO2 (4) N2O and N2O3
Ans. (1)
Sol. Neutral oxide NO & N2O
Acidic oxide N2O3, NO2, N2O4
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
Enzyme A
17. C12H22 O11 H2O C2H12 O6 C6H12 O6
Sucrose Glu cos e Fru cos e
Enzyme B
C 6H12 O 6 2C 2H5 OH 2CO2
Glu cos e
In the above reactions, the enzyme A and enzyme B respectively are:
(1) Amylase and Invertase (2) Zymase and Invertase
(3) Invertase and Amylase (4) Invertase and Zymase
Ans. (4)
Invertase
Sol. (a) Sugar Glucose + Fructose
Zymase
(b) C6H12O6 2C2H5OH + 2CO2
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
Ans. (1)
Sol. (a) Sucrolose - Artificial sweetner
(b) Gylceryl ester of stearic acid - Synthetic detergent
(c) Sodium benzoate - Food preservative
(d) Bithionol - Antiseptic
20. Which of the following statement(s) is (are) incorrect reason for eutrophication?
(A) excess usage of fertilisers
(B) excess usage of detergents
(C) dense plant population in water bodies
(D) lack of nutrients in water bodies that prevent plat growth
Choose the most appropriate answer from the options given below:
(1) (C) only (2) (D) only (3) (A) only (4) (B) and (D) only
Ans. (2)
Sol. Theory based
21. On complete reaction of FeCl3 with oxalic acid in aqueous solution containing KOH, resulted in the
formation of product A. The secondary valency of Fe in the produce A. The secondary valency of Fe in
the product A is________. (Round off to the Nearest Integer).
Ans. (6)
KOH
Sol. FeCl3 + oxalate [Fe(C2O4)3]3–
Secondary valency = 6
O
C O
22. Cl
+ C6H5NHC6H5 C6H5 —C—N—(C6H5)2
Consider the above reaction. The percentage yield of amide product is____________(Round off to the
Nearest Integer). (Given: Atomic mass : C : 12.0 u, H : 1.0 u, N : 14.0 u, O : 16.0 u, Cl : 25.5 u)
Ans. (77)
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
O
Sol. O
C
Cl
+ C6H5NHC6H5 C6H5 —C—N—(C6H5)2
0.140 0.388
0.210 g
140.5 169
1 0.210
= 0.001 = 0.002
0.001 273
= 0.769
% yield = 76.9 %
77%
23. The total number of C–C sigma bond/s in mesityl oxide (C6H10O) is (Round off to the Nearest Integer)
Ans. (5)
O
Sol. mesityl oxide
Number of C–C bond bond in mesityl oxide is 5.
24. Consider the reaction N2O4(g) 2NO2(g). The temperature at which KC = 20.4 and KP = 600.1,
25. KBr is doped with 10–5 mole percent of SrBr2. The number of cationic vacancies in 1 g of KBr crystal
is______ 1014. (Round off to the Nearest Integer).
[Atomic Mass : K : 39.1 u, Br : 79.9 u NA = 6.023 × 1023]
Ans. (5)
Sol. For every Sr2+ ion, 1 cationic vacancy is created. Hence number of Sr 2+ ion = number of cationic
vacancies. Since mole percentage of SrBr2 doped is 10–5 to that of total moles of KBr. Hence number of
10 –5 1
cationic vacancies = × × NA
100 119
1
× 10–7 × 6.023 × 1023 = 5.06 × 1014
119
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
26. In the ground state of atomic Fe(Z = 26), the spin-only magnetic moment is________ × 10–1 BM. (Round
off to the Nearest Integer).
[Given : 3 = 1.73, 2 = 1.41]
Ans. (49)
Sol. 26Fe = [Ar]3d64s2
No. of unpaired electrons = 4
µ= n(n 2) BM
= 4( 4 2) = 24
= 2 3 2 = 2[1.73 × 1.41]
= 4.8786 BM
= 48.78 × 10–1 BM
27. The number of chlorine atoms in 20 mL of chlorine gas at STP is _____10 21. (Round off to the Nearest
Integer). [Assume chlorine is an ideal gas at STP R = 0.083 L bar mol–1 K–1, NA = 6.023 × 1023]
Ans. (1)
28. The reaction 2A + B2 2AB is an elementary reaction. For a certain quantity of reactants, if the volume
of the reaction vessel is reduced by a factor of 3, the rate of the reaction by a factor of ______ (Round
off to the Nearest Integer).
Ans. (27)
Sol. Let initial concentration of A & B is a & b
Rate = K[A]2 [B2]1
2 1
a b
r1 = K
V V
2 1
3a 3b
r2 = K
V V
r2
= 27
r1
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| JEE MAIN-2021 | DATE : 17-03-2021 (SHIFT-2) | PAPER-1 | OFFICIAL PAPER | CHEMISTRY
29. A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of
another solution which contains 18.1 weight percent of a non-electrolytic solute A. The molar mass of A
is______u. (Round off to the Nearest Integer). [Density of water = 1.0 g cm–3]
Ans. (85)
= 1+ [5–1]0.4 = 2.6
18.1 1000
Molality of unknown compound solution =
Msolute 81.9
iKb × m1 = kb × m2
18.1 1000
2.6 × 1 =
Msolute 81.9
Msolute = 85
30. A KCl solution of conductivity 0.14 S m –1 shows a resistance of 4.19 in a conductivity cell. If the same
cell is filled with an HCl solution, the resistance drops to 1.03 . The conductivity of the HCl solution is
______ × 10–2 S m–1. (Round off to the Nearest Integer).
Ans. (57)
Sol. For KCl solution
KKCl = 1 = 0.14
a R KCl
= 0.14 × 4.19
a
For HCl solution
KHCl = 1
a R HCl
1
= [0.14 × 4.19]
1.03
1
= 0.5866 × = 0.569
1.03
= 56.9 × 10–2 S m–1
57 × 10–2 S m–1
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