Industrie - TI - 2010 - e General Properties of PE PAGE 1 TO 8

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Index

Material Properties
Material Properties
General properties page 103 - 107
Specific properties page 108 - 110
Applications page 111
Pressure curves and component operating pressures page 112 - 123
Creep modulus curves page 124 - 128

Installation Guidelines
Permissible buckling pressures page 129 - 132
Behaviour at abrasive fluids page 133
Chemical resistancy page 134 - 136

Installation Guidelines
Transport, Handling, Storage page 137
General installation guidelines page 138
Machining page 139

Calculation Guidelines
Calculation Guidelines
System of units page 140
SDR, Component operating pressure page 141
Operating pressure for water dangerous media page 142
Wall thickness, External pressure, necessary stiffening for page 143 - 145
pipes with buckling strain
Pipe cross section, Determination of the hydraulic pressure page 146 - 149
loss
Flow Nomogramm page 150
Dog bone load page 151
Support distances, Support distance at fixed piping page 152 - 158

Connection Methods
systems, Change in length, Minimum straight length
Buried piping systems page 159 - 160

Connection Methods
General standard, Application limits page 161 - 162
Heating element butt welding, pressure test page 163 - 173
Non-contact butt welding (IR-welding) page 174
Heating element socket welding page 175 - 178
Double Containment Piping

Electrofusion welding page 179 - 184


Hot gas welding page 185 - 188
Extrusion welding page 189 - 191
Detachable joints page 192

Double Containment Piping System


General Information page 193 - 194
Connection System page 195 - 197
Leakage Detection System page 198
Installation page 199 - 201
Approvals and Standards

Approvals and Standards


3rd party control and standards page 202 - 203

German page 1 - 102


Material Properties

Properties
Material Properties
Material
General properties of PE Advantages of PE
(Polyehylene)
z UV-resistance (black PE)
As a result of continuous development of PE z Flexibility
molding materials, the efficiency of PE pipes and z Low specific weight of app. 0,95g/cm3
fittings have been improved considerably. This fact z Favourable transportation (e. g. coils)
has been taken into account by the introduction of z Very good chemical resistance
new international standards (ISO 9080, EN1555, z Weathering resistance

Installation Guidelines
EN12201), which lead to higher permissible z Radiation resistance
operating pressures. z Good weldability
z Very good abrasion resistance
Polyethylene (PE) for pressure pipe applications is z No deposits and no overgrowth possible
no longer classified by its density (for example PE- Due to less frictional resistance less pressure
LD, PE-MD, PE-HD) as it is now divided into MRS- z Losses in comparison with e. g. metals
strength classes. z Freeze resistance
z Resistant to rodents
In comparison to other thermoplastics PE shows z Resistant to all kinds of microbic corrosion
an excellent diffusion resistance and has therefore
been applied for the safe transport of gases for Polyethylene type PE 100
many years.
The new classification is based on the minimum These materials can also be described as

Calculation Guidelines
required strength (MRS), which has to be applied polyethylene types of the third generation (PE-3)
for designing long-term loaded PE pipes operating resp. also as MRS 10 materials.
at a temperature of +20°C for at least 50 years. This is a further development of the PE materials
Thus the first-generation pipes are named PE32, which shows by a modified polymerisation process
PE40 and PE63 and the second-generation pipes an amended mol mass distribution. Therefore PE
PE80, the third-generation are named PE100.The 100 types have a higher density and by this
figures stand for the MRS values in bar. Expressed improved mechanical properties comes a raised
in megapascal the design stresses for PE80 and stiffness and hardness. Also the creep pressure
PE100 pipes will consequently be 8,0 and 10,0 and the resistance against rapid crack propagation
MPa. are also increased.
Consequently, this material is suitable for the
production of pressure pipes with larger diameters.
Other essential advantages of this material are the In comparison to usual pressure pipes out of PE

Connection Methods
UV-stability (if its black coloured), and the flexibility with less wall thicknesses the corresponding
of the molding material ("flexible piping system"). pressure rating will be achieved.
Physiological non-toxic Modified polyethylene PE 80-el
(Polyethylene, electro-conductable)
With respect to its composition polyethylene
complies with the relevant food stuff regulations Due to the electro-conductibility, PE 80-el is often
(according to ÖNORM B 5014, Part 1, BGA, KTW used for the transport of easy combustible media
guidelines). or for the conveying of dust as for these piping
PE pipes and fittings are verified and registered systems, a connection to earth can be performed.
regarding potable water suitability according
DVGW guideline W270.
Double Containment Piping

Behaviour at radiation strain H H


Pipes out of polyethylene may be applied across C C
the range of high energy radiation. Pipes out of PE
are well established for drainage of radioactive H H n
sewage water from laboratories and as cooling water
piping systems for the nuclear energy industry.
The usual radioactive sewage waters contain beta
and gamma rays. PE piping systems do not become Chemical structure of polyethylene
radioactive, even after many years of use.
Also in environment of higher radio activity, pipes
out of PE are not damaged if they are not exposed
APP-Rovals and Standards

during their complete operation time to a larger,


regularly spread radiation dose of < 10 4 Gray.

103
Material Properties
Material Properties
Material Properties

General properties of PP Advantages of Polypropylene

According to DIN 8078, three, different types of z low specific weight of 0,91g/cm3
polypropylene are recognised: (PVC 1,40g/cm3)
Type 1: PP-H z high creep resistance
(homopolymere) z excellent chemical resistance
Type 2: PP-B z TiO2 pigmentation
(block-copolymere) z high resistance to ageing by thermal stabilizing
Installation Guidelines

Type 3: PP-R good weldability


(random-polymere) z excellent abrasion resistance
z smooth inside surface of the pipes, therefore
By copolymerisating with ethylene special z no deposits and no growth over possible due
properties are achieved as in PP types 2 and 3, which to less frictional resistance
result in an improved processability (e.g. lower z less pressure losses in comparison with e. g.
danger of shrinkage cavitation at the injection metals
molding process) and higher impact strength of the z non-conductive, therefore the structure is not
products in comparison to PP-H. affected by tracking currents
z very good processable thermoplastic
PP-R and copper (e. g. by deep drawing)
z PP is a bad conductor of heat - therefore in
In direct contact with copper and PP-R deteriorates, most cases, no thermal insulation is required
Calculation Guidelines

especially at higher temperatures, the physical for hot water piping systems
properties of PP-R. Due to the accelerated thermal
oxidation, heat ageing is faster. General properties of Polypropylene
(Standard types)
Physiological non-toxicity
Behaviour at radiation strain
With respect to its composition, polypropylene
complies with the relevant food stuff regulations At an absorbed dose of < 10 4 Gray polypropylene
(according OENORM B 5014 Part 1, FDA, BGA, KTW piping systems can be applied without essential
guidelines). resistance decrease.
At a higher energy rays than 10 4 Gray it may
AGRU pipes, sheets and round bars are made of come to a temporary resistance increase due to
nucleoid PP-H (Beta (β)-PP) since the middle of the cross-linking of the molecular struc-ture. But at
Connection Methods

seventies. durable radiation strain, it comes to a rupture of


Fittings are also produced out of PP-R (poly- the molecular chains and therefore by the damage
propylene-random-copolymere) since the end of of the material to a serious resistance decrease.
the seventies.
Both types have been stabilized against high
temperatures and are the best suited materials for
the production of pressure piping systems. Behaviour at UV-radiation

In comparison to other thermoplastics such as PE- Grey polypropylene pipe lines are not UV-stable
HD and PVC, PP shows a thermal stability up to so they must be adequately protected. As effective
100°C (short-time up to 120°C for pressureless protection against direct solar radiation, a protection
systems). layer (AGRU-Coating) or an insulation is possible.
Double Containment Piping

It is furthermore possible to compensate the arising


PP shows good impact strength in comparison to damage of the surface by a corresponding wall
PVC. The impact strength depends on temperature, thickness addition as the damage only occurs on
increases with rising temperatures decreases with the surface (according to the DVS standard 2210-
falling temperatures. 1). The wall thickness addition may not be less than
2 mm, a maximum expected operating period of
10 years has to be taken into account.
H H As polypropylene is not equipped with light-stable
colour pigments normally, it may come to a change
C C
of colour (fading) by long-time weathering.
H CH3 n As an alternative a high-temperature-resistant, black
PP material can be used. The black PP material is
stabilized against UV radiation for 10 years.The
APP-Rovals and Standards

application conditions should be clarified with the


Chemical structure of PP technical engineering department.

104
Material Properties

Properties
Material Properties
Material
General properties of PP Differences to standard types of PP

General properties of modified PP PP-R, black:

On account of the most specific requirements (Polypropylene-random-copolymere, black


arising in the construction of piping systems for coloured)
the chemical indu-stry and in apparatus engineering The essential advantage of this black coloured
flame retardant and electro-conductive special material type is the UV resistance for an operating

Installation Guidelines
types have been developed. period of 10 yaers, which is not available with grey
For example static charging due to the flow of fluids PP.
or dust can arise at the operation of thermoplastic However there is an insignificant decrease of the
piping systems. Electro-conductable polypropylene impact strength.
types have therefore been developed in order to
enable a connection to earth can be performed. PP-B 2222, grey:

By supplement of additives, these modified PPB 2222 is a polypropylene block copolymer grey
properties are achieved. But there result alterations coloured similar to RAL 7032 (pebble grey).
of the mechanical, thermal and also chemical The product is characterized by its excellent impact
properties in comparison to the standard type. properties, as well as a high heat stability and
extremely high extraction stability.
It is therefore necessary to clarify all projects with

Calculation Guidelines
our technical engineering department.
PP-R, natural:
Physiological properties
(Polypropylene-random-copolymere, natural)
Modified PP types (flame-retardant resp. electro- As PP-R natural contains no colour additives, it is
conductable PP) correspond in their composition applied mainly for high purity water piping systems.
due to the supplement of additives n o t to the However this material is not UV resistant.
relevant food stuff regulations and may therefore
not be used for potable water pipes and in contact PP-s:

(Polypropylen-homopolymere, flame-retardant)
Due to the higher stiffness of PP-s, it is well suited
for ventilation and degassing pipes as well as for

Connection Methods
flue lining systems. It may not be used for outdoors
applications due to the missing UV stabilization.

PP-R-s-el:

(Polypropylene-random-copolymere, flame
retardant, electro-conductive)
This material reconciles the positive properties of
the flame retardant and electro-conductable PP
types. It is therefore due to safety reasons mostly
applied for the transport of easy ignitable media
Double Containment Piping

and replaces often expensive stainless steel


ductings.

There is however a reduced impact strength of


PP-s-el as well as a slightly amended chemical
resistance (see page 119).
APP-Rovals and Standards

105
Material Properties
Material Properties
Material Properties

General properties of PVDF Advantages of PVDF


(Polyvinylidene fluoride)
z wide temperature range, high heat deflection
temperature
PVDF is an extremly pure polymer and contains in
comparison with a lot of other plastics no stabilizers z very good chemical resistance, even in
connection with high temperatures
UV-, Thermostabilizers, softener, lubricants or
flame-retardant additives. Its particular suitable for z good resistance against UV- and γ-radiations
therefore high ageing resistance
ultra-pure water constructions and for the transport
Installation Guidelines

of clear chemical liquids in the semi-conductor z excellent abrasion resistance (low friction
coefficient)
industry. Due to its chemical inertness, reaction
against most media is nearly impossible. z very good anti-friction properties
z good mechanical properties
Pipes and components out of suitable standard z excellent insulaing characteristics in
connection with very good electrical values
types fulfil the high demands of the semi-conductor
industry; e. g. they are in the position to maintain z flame retarding
the specific resistance of deionizationed ultra-pure z physiologically non-toxic
water over 18 MΩcm. z good and easy processing

PVDF is a halogen and also offers an excellent fire


PVDF offers with its properties an ideal protection without flame-retardant additives.
compromise, in connection with a very easy During combustion of PVDF only a slight amount
Calculation Guidelines

processing and an advantageous price-performance of smoke development arises. But like every other
ratio. organic substance also PVDF is inflammable and
in adequate ambient temperature PVDF is
Polyvinylidene fluoride (PVDF) is a thermoplastic inflammable.
and has the following typical properties:
- easy processing Solubility
- good weldability
- good heat formability The PVDF-homopolymere swells in high polar
solvents e.g. acetone and ethylacetat and is soluble
PVDF is distinguished by its high mechanical in polar solvents, e.g. dimethylformamide and
strength and the very good chemical resistance, dimethylacetamide.
even for applications in the presence of critical
chemical media in the high temperature range.
Connection Methods

H F
C C
H F n

Chemical structure of PVDF


Double Containment Piping
APP-Rovals and Standards

106
Material Properties

Properties
Material Properties
Material
General properties of ECTFE Advantages of ECTFE
(Ethylenechlorotrifluorethylene)
z wide temperature application range (thermal
resistance up to short-term 150°C).
ECTFE has a unique combination of properties,
which results due to its chemical structure - a z good resistance against UV- and γ-radiation,
therefore favourable ageing resistance.
copolymere with a changing constitution of
ethylene and chlorotrifluorethylene. z flame retardent (UL 94-V0-material) - oxygen
index 60

Installation Guidelines
Physiological properties z excellent abrasion resistance
z extreme good chemical resistance against
most technical acids, alkalies and solvents as
ECTFE is suitable for the safe application of products
well as in contact with chlorine.
in continuous contact with food stuff accoringg to
"BGA Deutschland". For avoiding every influence z excellent insulating properties in connection
with very good electrical values
of smell and taste it is recommended to clean the
food with water which has direct contact with z physiological non-toxic
ECTFE parts. z very good surface slip characteristics

Reproduction of microorganisms on ECTFE


Thermal properties
The surface of a product out of ECTFE is
ECTFE has a remarkable resistance against
unfavourable to the proliferation of microorganisms
decomposition trought heat, intensive radiation and

Calculation Guidelines
- as with glass. This conclusion is the result of an
weathering. For a long time it is resistant against
examination which has been executed within the
temperatures up to 150°C and it is one of the best
framework of a test of the HP-suitability of ECTFE.
plastics with a good resistance against radiation.
Due to these properties, ECTFE is applied in the
food and drug industry and for ultra-pure water
Resistance against the weathering
ranges.
ECTFE shows only a slight change of the properties
or apperance weathering in the sunlight. Reaped
weathering tests showed a remarkable stability of H H F F
the polymers particularly the elongation at break,
C C C C
which is a good indicator for the polymer-
decomposition. Even after 1000 hours in a "Weather H H Cl F n
- Ometer" with xenon-light the important properties

Connection Methods
are hardly influenced.
Chemical structure of ECTFE
Radiation resistance

ECTFE shows an excellent resistance against


different radiations. It has even good values after
irridation with 200 megarad cobalt 60.

Mechanical properties

ECTFE is a solid, very impact resistant plastic, which


hardly changes its properties over a wide range of
Double Containment Piping

temperatures. Besides the good impact strength


ECTFE has a good breaking strain and a good
abrasion behaviour. To emphasize is also the good
behaviour by low temperatures, especially the high
impact strength.
APP-Rovals and Standards

107
Material Properties
Material Properties
Material Properties

Specific material properties PE

Property Standard Unit PE80 PE100 HDPE-el


Density at 23°C ISO 1183 g/cm3 0,94 0,95 0,99

Melt flow index ISO 1133 g/10min


MFR 190/5 0,9 0,3
Installation Guidelines

<0,1
MFR 190/2,16
MFR 230/5
T012 T003 T001
MFI range ISO1872/1873

Tensile stress at yield ISO 527 MPa 20 25 26


Elongation at yield ISO 527 % 10 9 7
Elongation at break ISO 527 % >600 >600
Impact strength unnotched at +23°C no break no break
ISO 179 kJ/m2
Mechanical
Properties

Impact strength unnotched at -30°C no break no break


Impact strength notched at +23°C 12 16 5,0
2
Impact strength notched at 0°C ISO 179 kJ/m
Calculation Guidelines

Impact strength notched at -30°C 4,5 6 3,0


Ball indentation hardness acc. Rockwell ISO 2039-1 MPa 36 46
Flexural strength (3,5% flexural stress) ISO 178 MPa 18 24
Modulus of elasticity ISO 527 MPa 750 1100 1150
Vicat-Softening point VST/B/50 ISO 306 °C 63 77 83
Heat deflection temperature HDT/B ISO 75 °C 60 75
Properties
Thermal

Linear coefficient of thermal expansion DIN 53752 K-1 x 10-4 1,8 1,8 1,8
Thermal conductivity at 20 °C DIN 52612 W/(mxK) 0,4 0,4 0,43
Connection Methods

UL94 94-HB 94-HB


Flammability --
DIN 4102 B2 B2 B2
Specific
>1016 >1016 ≤10
8
VDE 0303 OHM cm
volume resistance
Properties
Electrical

>1013 >1013 ≤10


6
Specific surface resistance VDE 0303 OHM
relative dielectric constant
DIN 53483 -- 2,3 2,3
at 1 MHz
Dielectric strength VDE 0303 kV/mm 70 70
Physiologically non-toxic EEC 90/128 -- Yes Yes No
Double Containment Piping

FDA -- -- Yes Yes No


UV stabilized -- -- carbon black carbon black carbon black
Colour -- -- black black black

Note: The mentioned values are recommended values for the particular material.
APP-Rovals and Standards

108

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