EDTA Problems

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Engineering Gnenvouy ~ 1 1.32 i 1 of an rater requires 18 ml oO) 100 ml of @ sample of » mi of the same EDTA ie yg of 100 ml of standard EDTA solution ritratton solution was rege CaCO, per litre. Calculate hard water contain mple in ppm hardness of water Sal [B.D.U. Nov. 96;MDS.NOV.96] Given i 1 litre of std. hard water contains 1 gm of CaCO; A ie 1000ml_ of std. hard water contains 1000 mgs of CaCO3 ; = 1 ml of std. hard water = 1 mg of CaCO; 22 ml of EDTA = 100 ml of std. hard water = 100 x 1 mg of CaCO3 : 100 el a of EDTA =~ mgs of CaCO; 100 ml of sample of water = 18 ml of EDTA 00 =18 XZ5 mgs of CaCO; «8 ‘or 1000 ml of sample of water = 18 x 100... 1000 : seg: 2D 100 Hardness = 818.18 Ings/lit or ppm. 0.28 gm of CaCO; was is lution was made upto one litre | in HCl and a : istllea water. 100 ml a 1.33 above solution juired 28 mi com * req ml of EDTA solution gration. 100 ml of hard water sample required 33 bie, EDTA solution on titration. 100 ml of nee this water, after boili cooling and filtering required 10 ml of EDTA solution md jitration. Calculate the temporary and permanent harness of water. (Anna.univ. (Campus) Nov.2092) a Given 1000 ml of std. hard water contains =0.28 gm of CaCO, ie., 1000 ml of std. hard water contains = 0.28 x 1000 mgs of CaCO; = 280 mgs of CaCO, - 1 ml of std. hard water = 0.28 mg of CaCO; 28 ml of EDTA = 100 mi of the std. hard water = 100 x 0.28 mgs of CaCO; _ 100 x 0.28 mame 23 1 ml of EDTA = | mgs of CaCO3. () Total hardness 100 ml of hard water = 33 ml of EDTA = 33 x I mgs of CaCO; = 33 mgs of CaCO; 1000 f of hard water = 33 xo" 2.530 mest! (or) ppm. ardness ¢ eee = 10 ml of EDTA an (iy Permanent 100 ml of the penn fer boiling, © ic filtering reauite = 19x 1 mgs of CaCOs = 10 mgs of CaCO 10 le mgs of CaCO3 a 100 . 1000 ml of the water : = 100 mgs/lit (or) ppm. Permanent hardness : (iii) Temporary hardness (CH) r Temporary hardness =Total hardness — permanent hardness = 330-100 Temporary hardness = 230 mgs/lit (or) ppm. EDTA for thet watt of water required 25.0 ml of 0.01 M litration usi ‘ . Calculate the taint ee Eriochrome-Black-T indicator. EI [BDU.Nov.96] We know that, 1 ml of 0.01 MEDTA= Img of c. iC 25 ml of 0.01 MEDTAS Ett ’ ¢ “hy of ae oI Caco, ater requi Mlof 0, : lof 0.01

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