Liquid liquid extraction

Effect of feed ratio

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 110 90 1:1 19.8
feed and
100 ml
solvent)
15min 20.7
21.0
2(200 ml 92 208 1:2 20.8
feed and
100 ml
solvent)
20.5
20.8
3(100 ml 235 65 2:1 14.1
feed and
200 ml
solvent)
13.3
13.9

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.
S.No Time Volume of Reffinate Feed ratio Vol. used
Extract
1 (100 ml 113 87 1:1 18.8
feed and
100 ml
solvent)
15min 19.7
20.5
2(200 ml 93 207 1:2 20.9
 feed and
100 ml
solvent)
19.5
21.8
3(100 ml 20 70 2:1 14.5
feed and
200 ml
solvent)
13.8
14.7

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.
S.No Time Volume of Reffinate Feed ratio Vol. used
Extract
1 (100 ml 111 91 1:1 18.9
feed and
100 ml
solvent)
15min 18.5
20.2
2(200 ml 94 206 1:2 21.8
feed and
100 ml
solvent)
21.5
20.8
3(100 ml 236 64 2:1 13.1
feed and
200 ml
solvent)
13.5
14.1

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.
S.No Time Volume of Reffinate Feed ratio Vol. used
Extract
1 (100 ml 105 95 1:1 20.1
feed and
100 ml
solvent)
15min 20.3
 21.5
2(200 ml 98 202 1:2 22.1
feed and
100 ml
solvent)
20.9
21.5
3(100 ml 232 68 2:1 12.8
feed and
200 ml
solvent)
13.3
13.7

Effect of time:

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 105 95 1:1 22.5
feed and
100 ml
solvent)
2 (100 ml 15 minutes 110 90 1:1 18.5
feed and
100 ml
solvent)
3 (100 ml 60 minutes 112 88 1:1 19.5
feed and
100 ml
solvent)
10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 108 92 1:1 21.8
feed and
100 ml
solvent)
2 (100 ml 15 minutes 112 88 1:1 18.1
feed and
100 ml
solvent)
3 (100 ml 60 minutes 115 85 1:1 18.9
feed and
100 ml
solvent)

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 105 95 1:1 22.2
feed and
100 ml
solvent)
2 (100 ml 15 minutes 111 89 1:1 17.5
feed and
100 ml
solvent)
3 (100 ml 60 minutes 114 86 1:1 18.3
feed and
100 ml
solvent)

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 103 97 1:1 21.9
feed and
100 ml
solvent)
2 (100 ml 15 minutes 109 91 1:1 18.1
feed and
100 ml
solvent)
3 (100 ml 60 minutes 112 88 1:1 18.8
feed and
100 ml
solvent)