Liquid liquid extraction

Effect of time:

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 105 95 1:1 22.5
feed and
100 ml
solvent)
2 (100 ml 15 minutes 110 90 1:1 18.5
feed and
100 ml
solvent)
3 (100 ml 60 minutes 112 88 1:1 19.5
feed and
100 ml
solvent)

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
 titration
1 (100 ml 5 minutes 108 92 1:1 21.8
feed and
100 ml
solvent)
2 (100 ml 15 minutes 112 88 1:1 18.1
feed and
100 ml
solvent)
3 (100 ml 60 minutes 115 85 1:1 18.9
feed and
100 ml
solvent)

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 105 95 1:1 22.2
feed and
100 ml
solvent)
2 (100 ml 15 minutes 111 89 1:1 17.5
feed and
100 ml
solvent)
3 (100 ml 60 minutes 114 86 1:1 18.3
feed and
100 ml
solvent)

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 103 97 1:1 21.9
feed and
100 ml
solvent)
2 (100 ml 15 minutes 109 91 1:1 18.1
feed and
 100 ml
solvent)
3 (100 ml 60 minutes 112 88 1:1 18.8
feed and
100 ml
solvent)

10 mL of the sample of raffinate is taken for titration. Titrate the sample with 1N NaOH with
phenolphthalein indicator.

S.No Time Volume of Reffinate Feed ratio NaOH Vol.

Extract used for
titration
1 (100 ml 5 minutes 101 99 1:1 22.9
feed and
100 ml
solvent)
2 (100 ml 15 minutes 110 90 1:1 17.3
feed and
100 ml
solvent)
3 (100 ml 60 minutes 115 85 1:1 17.9
feed and
100 ml
solvent)