Kapur Classes Test / XII / Solid + Alcohol / Set- 21-A1 MM:24

1. Refractive index of a solid is observed to have the same value

along all directions. Comment on the nature of this solid. Would it
show the cleavage property? (2)

2. Gold (Atomic radius = 0.144 nm) crystallizes in a face-centered

unit cell. What is the length of the side of the unit cell? (2)

3. If three elements A, B and crystallize in a cubic solid lattice with A

atom at the corner, B atoms at cube centre and C atoms at edges
then what would be the formula of the solid ?
Show calculations. (2)

4. What is End-centred unit cell? Also give number of Lattice

Points. (2)

5. Name the most symmetrical and most unsymmetrical primitive

unit cell. (1)

6. Distinguish between : Hexagonal and monoclinic unit cell. (2)

7. Frenkel defect is not found in pure alkali metal halide. Why? (1)

8. What type of stoichiometric defect is shown by :

(i) ZnS (ii) AgBr (2)

9. Define F-centres. Mention two properties of solids which have

F-centres in the crystals. (3)

10. Write structures of the compounds whose IUPAC names are as

follows:
(i) 2,3-Diethylphenol (ii) 3-(Chloromethyl)pentan-1-ol. (2)

11. Write chemical equation for the preparation of phenol from

chlorobenzene. (2)

12 Give the equations of reactions for the preparation of phenol

from cumene. (3)