LA

PROGR
Suhu air saat percobaan (T) =
Massa jenis air pada T (ρ) =
Massa jenis asam asetat (ρ) =
Massa jenis metanol (ρ) =
Massa jenis HCl (ρ) =
Konstanta Gas Ideal (R) =
Mr CH3COOH =
Mr CH3OH =
ΔG CH3OH
o
=
ΔGo CH3OH =
ΔGo CH3COOCH3 =
ΔGo H2O =

LB.1 Perhitungan Molalitas Ekivalen H+

Konsentrasi HCl (N) Vsampling (ml)
=A53 =B53

LB.2 Perhitungan Molalitas Pelarut HCl

Kadar HCl (%) Kadar pelarut HCl (%)
=2*36,5/(C42*10) =100-A57

LA.3 Penentuan Jumlah Mol Mula-mula

Run HCl (ml)
I =B61
II =B62
III =B63
IV =B64

LA.4 Penentuan Jumlah Mol Setelah Bereaksi

Konsentrasi NaOH = B67
Run HCl (ml)
I =B69
II =B70
III =B71
IV =B72

LA.5 Penentuan Tetapan Kesetimbangan (Kc)

Konsentrasi CH3COOH (M) Konsentrasi C2H5OH (M)
=F69/E61 =H69/E61
=F70/E62 =H70/E62
=F71/E63 =H71/E63
=F72/E64 =H72/E64

LA.6 Penentuan Tetapan Kesetimbangan melalui Energi Bebas Gibbs (ΔG)

Kc praktik ΔG°
=E76
=E77
=((1*F48)+(1*F49))-((1*F46)+(1*F47))
=E78
=E79
 LAMPIRAN A
PROGRAM KOMPUTER
C38 o
C =
C39 gram/ml
C40 gram/ml
C41 gram/ml
C42 gram/ml
C43 J/mol K
C44 gram/mol
C45 gram/mol
C46 J/mol
C47 J/mol
C48 J/mol
C49 J/mol

VNaOH (ml) NaOH (N) Mol ekivalen H+ (blanko)

=C53 =D53 =E53

m pelarut (g) mol H2O

=B57*B53/100*C42 =C57/18,02

C2H5OH (ml) CH3COOH (ml) Vcampuran (L)

=C61 =D61 =(B61+C61+D61)/1000
=C62 =D62 =(B62+C62+D62)/1000
=C63 =D63 =(B63+C63+D63)/1000
=C64 =D64 =(B64+C64+D64)/1000

N
C2H5OH (ml) CH3COOH (ml) VNaOH (ml)
=C69 =D69 =E69
=C70 =D70 =E70
=C71 =D71 =E71
=C72 =D72 =E72

Konsentrasi Mol C2H5OH Konsentrasi H2O Kc

=G69/E61 =(G69+$H$61)/E61 =C76*D76/(A76*B76)
=G70/E62 =(G70+$H$61)/E62 =C77*D77/(A77*B77)
=G71/E63 =(G71+$H$61)/E63 =C78*D78/(A78*B78)
=G72/E64 =(G72+$H$61)/E64 =C79*D79/(A79*B79)

KcO teori % Ralat

=ABS((($C$83-A83/$C$83)*100)
=ABS((($C$84-A84/$C$84)*100)
=EXP(-B83/(C43*298))
=ABS((($C$85-A85/$C$85)*100)
=ABS((($C$86-A86/$C$86)*100)
F38 K
=C46/1000 J/mol
=C47/1000 J/mol
=C48/1000 J/mol
=C49/1003 J/mol

Mol CH3COOH Mol C2H5OH Mol H2O

=($C$40*D61)/$C$44 =($C$41*C61)/$C$45
=($C$40*D62)/$C$44 =($C$41*C62)/$C$45
=D57
=($C$40*D63)/$C$44 =($C$41*C63)/$C$45
=($C$40*D64)/$C$44 =($C$41*C64)/$C$45

Mol CH3COOH (sisa) Mol Reaksi Mol C2H5OH (sisa)

=((E69*$B$67)-$E$53)/1000 =F61-F69 =G61-G69
=((E70*$B$67)-$E$53)/1000 =F62-F70 =G62-G70
=((E71*$B$67)-$E$53)/1000 =F63-F71 =G63-G71
=((E72*$B$67)-$E$53)/1000 =F64-F72 =G64-G72
 LAM
HASIL PROGR
Suhu air saat percobaan (T) =
Massa jenis air pada T (ρ) =
Massa jenis asam asetat (ρ) =
Massa jenis etanol (ρ) =
Massa jenis HCl (ρ) =
Konstanta Gas Ideal (R) =
Mr CH3COOH =
Mr CH3OH =
ΔG CH3COOH
o
=
ΔG CH3OH
o
=
ΔG CH3COOCH3
o
=
ΔG H2O
o
=

LB.1 Perhitungan Molalitas Ekivalen H+

Konsentrasi HCl (N) Vsampling (ml)
2 5

LB.2 Perhitungan Molalitas Pelarut HCl

Kadar HCl (%) Kadar pelarut HCl (%)
6.14 93.86

LB.3 Penentuan Jumlah Mol Mula-mula

Run HCl (ml)
I 6
II 6
III 6
IV 6

LB.4 Penentuan Jumlah Mol Setelah Bereaksi

Konsentrasi NaOH = 2
Run HCl (ml)
I 6
II 6
III 6
IV 6

LB.5 Penentuan Tetapan Kesetimbangan (Kc)

Konsentrasi CH3COOH (M) Konsentrasi C2H5OH (M)
0.4600 0.2495
0.4814 0.2890
0.2683 0.0999
0.1200 -0.0147

LB.6 Penentuan Tetapan Kesetimbangan melalui Energi Bebas Gibbs (ΔG)

Kc praktik ΔG°
1068.7483
869.5504
4.7
4602.3533
 4.7
-65980.8492
 LAMPIRAN B
HASIL PROGRAM KOMPUTER
30 oC =
0.9949 gram/ml
1.0547 gram/ml
0.7788 gram/ml
1.1880 gram/ml
8.3140 J/mol K
60 gram/mol
 46.07 gram/mol
-3.9344E+05 J/mol =
-1.6785E+05 J/mol =
-3.2800E+05 J/mol =
-2.2859E+05 J/mol =

VNaOH (ml) NaOH (N) Mol ekivalen H+ (blanko)

5 2 10

m pelarut (g) mol H2O

5.575 0.309378468

C2H5OH (ml) CH3COOH (ml) Vcampuran (L)

5 5 0.016
4 4 0.014
3 3 0.012
2 2 0.010

N
C2H5OH (ml) CH3COOH (ml) VNaOH (ml)
5 5 8.68
4 4 8.37
3 3 6.61
2 2 5.6

Konsentrasi Mol CH3COOC2H5 (M) Konsentrasi H2O Kc

5.0332 24.3694 1068.7483
4.5410 26.6394 869.5504
4.1263 29.9078 4602.3533
3.3957 34.3335 -65980.8492

i Bebas Gibbs (ΔG)

KcO teori % Ralat
106977.9551
87020.3454
0.9981
461009.4238
0.9981
6610713.3045
303 K
 -3.9344E+02 J/mol
-1.6785E+02 J/mol
-3.2800E+02 J/mol
-2.2859E+02 J/mol

Mol CH3COOH Mol C2H5OH Mol H2O

0.0879 0.0845
0.0703 0.0676
0.309378468
0.0527 0.0507
0.0352 0.0338

Mol CH3COOH (sisa) Mol Reaksi Mol C2H5OH (sisa)

0.0074 0.0805 0.0040
0.0067 0.0636 0.0040
0.0032 0.0495 0.0012
0.0012 0.0340 -0.0001