NAME :

REGISTRATION NUMBER:
function yy=Margules(DD)
x1=[0.0174 0.0239 0.0432 0.0546 0.0786 0.0897 0.1577
0.2283 0.2930 0.3728 0.4439 0.5775 0.7096 0.7663 0.8366
0.8795 0.9435];
y1=[0.1778 0.1379 0.2420 0.3050 0.3545 0.4045 0.5381
0.6204 0.6163 0.7274 0.7543 0.8517 0.8866 0.9103 0.9317
0.9446 0.9473];
x2=1-x1;
y2=1-y1;
P=760;
T=[370.18 369.59 366.99 365.14 362.23 361.70 356.36
353.07 351.34 348.53 347.08 344.43 342.38 341.34 340.21
339.58 338.93];
A1=11.9673;B1=3626.55;C1=-34.29;
A2=11.6834;B2=3816.44;C2=-46.13;
P1sat=(exp(A1-B1./(T+C1))).*760;
P2sat=(exp(A2-B2./(T+C2))).*760;
A12=DD(1);
A21=DD(2);
G1=exp(x2.^2.*(A12+2*(A21-A12).*x1));
G2=exp(x1.^2.*(A21+2*(A12-A21).*x2));
Pcal=(x1.*P1sat.*G1)+(x2.*P2sat.*G2);
yy=sum((P-Pcal).^2);

A12=0.5;A21=0.3;
constant=fminsearch('Margules',[A12 A21]);
fprintf('A12=%6.6f,A21=%6.6f\n',constant(1),constant(2)
)
x1=[0.0174 0.0239 0.0432 0.0546 0.0786 0.0897 0.1577
0.2283 0.2930 0.3728 0.4439 0.5775 0.7096 0.7663 0.8366
0.8795 0.9435];
x2=1-x1;
y1exp=[0.1778 0.1379 0.2420 0.3050 0.3545 0.4045 0.5381
0.6204 0.6163 0.7274 0.7543 0.8517 0.8866 0.9103 0.9317
0.9446 0.9473];
T=[370.18 369.59 366.99 365.14 362.23 361.70 356.36
353.07 351.34 348.53 347.08 344.43 342.38 341.34 340.21
339.58 338.93];
A1=11.9673;B1=3626.55;C1=-34.29;
A2=11.6834;B2=3816.44;C2=-46.13;
P1sat=(exp(A1-B1./(T+C1))).*760;
P2sat=(exp(A2-B2./(T+C2))).*760;
G1=exp(x2.^2.*(A12+2*(A21-A12).*x1));
G2=exp(x1.^2.*(A21+2*(A12-A21).*x2));
Pmodel=(x1.*P1sat.*G1)+(x2.*P2sat.*G2);
y1model=(x1.*P1sat.*G1)./Pmodel;
dy1=abs(y1model-y1exp);
disp(' ')
disp(' MARGULES MODEL OF THIRD ORDER ')
disp('------------------------------------------------
-----')
disp(' x1 y1exp T(K) y1model
dy1 ')
disp('-------------------------------------------------
----')
for i=1:length(x1)
fprintf('%3.4f %10.4f %10.4f %10.4f
%10.4f\n',x1(i),y1exp(i),T(i),y1model(i),dy1(i))
end
A12=0.763261,A21=0.492682

MARGULES MODEL OF THIRD ORDER

-----------------------------------------------------
x1 y1exp T(K) y1model dy1
-----------------------------------------------------
0.0174 0.1778 370.1800 0.0917 0.0861
0.0239 0.1379 369.5900 0.1218 0.0161
0.0432 0.2420 366.9900 0.2011 0.0409
0.0546 0.3050 365.1400 0.2423 0.0627
0.0786 0.3545 362.2300 0.3167 0.0378
0.0897 0.4045 361.7000 0.3460 0.0585
0.1577 0.5381 356.3600 0.4861 0.0520
0.2283 0.6204 353.0700 0.5830 0.0374
0.2930 0.6163 351.3400 0.6480 0.0317
0.3728 0.7274 348.5300 0.7120 0.0154
0.4439 0.7543 347.0800 0.7581 0.0038
0.5775 0.8517 344.4300 0.8304 0.0213
0.7096 0.8866 342.3800 0.8907 0.0041
0.7663 0.9103 341.3400 0.9143 0.0040
0.8366 0.9317 340.2100 0.9421 0.0104
0.8795 0.9446 339.5800 0.9581 0.0135
0.9435 0.9473 338.9300 0.9810 0.0337
function yy=Wilson(DD)
x1=[0.0174 0.0239 0.0432 0.0546 0.0786 0.0897 0.1577
0.2283 0.2930 0.3728 0.4439 0.5775 0.7096 0.7663 0.8366
0.8795 0.9435];
y1=[0.1778 0.1379 0.2420 0.3050 0.3545 0.4045 0.5381
0.6204 0.6163 0.7274 0.7543 0.8517 0.8866 0.9103 0.9317
0.9446 0.9473];
x2=1-x1;
y2=1-y1;
P=760;
T=[370.18 369.59 366.99 365.14 362.23 361.70 356.36
353.07 351.34 348.53 347.08 344.43 342.38 341.34 340.21
339.58 338.93];
A1=11.9673;B1=3626.55;C1=-34.29;
A2=11.6834;B2=3816.44;C2=-46.13;
P1sat=(exp(A1-B1./(T+C1))).*760;
P2sat=(exp(A2-B2./(T+C2))).*760;
A12=DD(1);
A21=DD(2);
G1=exp(-log(x1+A12.*x2)+x2.*((A12./(x1+A12.*x2))-
(A21./(A21.*x1+x2))));
G2=exp(-log(x2+A21.*x1)-x1.*((A12./(x1+A12.*x2))-
(A21./(A21.*x1+x2))));
Pcal=(x1.*P1sat.*G1)+(x2.*P2sat.*G2);
yy=sum((P-Pcal).^2);

A12=0.4;A21=0.5;
Constant=fminsearch('Wilson',[A12 A21]);
fprintf('A12=%6.6f,A21=%6.6f\n',Constant(1),Constant(2)
)
x1=[0.0174 0.0239 0.0432 0.0546 0.0786 0.0897 0.1577
0.2283 0.2930 0.3728 0.4439 0.5775 0.7096 0.7663 0.8366
0.8795 0.9435];
x2=1-x1;
y1exp=[0.1778 0.1379 0.2420 0.3050 0.3545 0.4045 0.5381
0.6204 0.6163 0.7274 0.7543 0.8517 0.8866 0.9103 0.9317
0.9446 0.9473];
T=[370.18 369.59 366.99 365.14 362.23 361.70 356.36
353.07 351.34 348.53 347.08 344.43 342.38 341.34 340.21
339.58 338.93];
A1=11.9673;B1=3626.55;C1=-34.29;
A2=11.6834;B2=3816.44;C2=-46.13;
P1sat=(exp(A1-B1./(T+C1))).*760;
P2sat=(exp(A2-B2./(T+C2))).*760;
G1=exp(-log(x1+A12.*x2)+x2.*((A12./(x1+A12.*x2))-
(A21./(A21.*x1+x2))));
G2=exp(-log(x2+A21.*x1)-x1.*((A12./(x1+A12.*x2))-
(A21./(A21.*x1+x2))));
Pmodel=(x1.*P1sat.*G1)+(x2.*P2sat.*G2);
y1model=(x1.*P1sat.*G1)./Pmodel;
dy1=abs(y1model-y1exp);
disp(' ')
disp(' WILSON MODEL ')
disp('------------------------------------------------
-----')
disp(' x1 y1exp T(K) y1model
dy1 ')
disp('-------------------------------------------------
----')
for i=1:length(x1)
fprintf('%3.4f %10.4f %10.4f %10.4f
%10.4f\n',x1(i),y1exp(i),T(i),y1model(i),dy1(i))
end
A12=0.471147,A21=0.984822

WILSON MODEL
-----------------------------------------------------
x1 y1exp T(K) y1model dy1
-----------------------------------------------------
0.0174 0.1778 370.1800 0.1951 0.0173
0.0239 0.1379 369.5900 0.2470 0.1091
0.0432 0.2420 366.9900 0.3635 0.1215
0.0546 0.3050 365.1400 0.4145 0.1095
0.0786 0.3545 362.2300 0.4940 0.1395
0.0897 0.4045 361.7000 0.5215 0.1170
0.1577 0.5381 356.3600 0.6314 0.0933
0.2283 0.6204 353.0700 0.6909 0.0705
0.2930 0.6163 351.3400 0.7254 0.1091
0.3728 0.7274 348.5300 0.7570 0.0296
0.4439 0.7543 347.0800 0.7787 0.0244
0.5775 0.8517 344.4300 0.8148 0.0369
0.7096 0.8866 342.3800 0.8521 0.0345
0.7663 0.9103 341.3400 0.8711 0.0392
0.8366 0.9317 340.2100 0.8989 0.0328
0.8795 0.9446 339.5800 0.9193 0.0253
0.9435 0.9473 338.9300 0.9566 0.0093