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MSW - Module1 2 - GCK
MSW - Module1 2 - GCK
MSW - Module1 2 - GCK
SOLID WASTE
• All the wastes arising from human and animal activities that are
normally solid and that are discarded as useless or unwanted
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Treatment Water, wastewater, industrial treatment Treatment plant wastes, principally composed of residual
facilities processes, etc. sludges and other residual materials
Industrial Construction, fabrication, light and heavy Industrial process wastes, scrap materials, etc.;
manufacturing, refineries, chemical plants, nonindustrial waste including food wastes, rubbish,
power plants, demolition, etc. ashes, demolition and construction wastes, special
wastes, and hazardous waste
Agricultural Field and row crops, orchards, vineyards, Spoiled food wastes, agricultural wastes, rubbish, and
dairies, feedlots, farms, etc. hazardous wastes
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CHARECTERISTICS OF MSW
• If MSW is to be disposed of by landfill Little need to analyse
further
• If gas has to be collected from land fill Amount of organic matter is
important
• If recycling or material recovery or energy recovery is planned
Characterisation of waste is necessary
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Manual sampling
• The truck load which represent the average production of refuse in
the community is selected
• Before sampling the contents are thoroughly mixed
• Samples(in terms of weight) should be small enough to be analysed
but big enough to be statistical representative of MSW
• Number of samples required depends on the components under
consideration and desired precision
• Larger the article to be separated, the number of samples required to
achieve better precision will be more
• The components to be separated depends on the use of study
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MOISTURE CONTENT
• Moisture content of various components changes with time
• Important factor to be considered when the solid waste is to be
processed into fuel or when it is fired directly
• Moisture content,
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PARTICLE SIZE
• Municipal refuse is possibly the worst material for particle size
analysis but yet much of the MSW processing technology depends on
accurate description of particle size
• The size of component materials in solid wastes is of importance in
the recovery of materials especially with mechanical means
• The best way to describe the particle size of solid waste which is
composed of number of different sized particle is by means of a curve
showing percent of particle versus particle size
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ࢉ
ࢉ
ࢉ = size of component
= length
= width
= height
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WHEN THE MIXTURE OF PARTICLES IS NON-UNIFORM, THE PARTICLE SIZE IS OFTEN EXPRESSED IN
TERMS OF MEAN PARTICLE DIAMETER:
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• ARITHMATIC MEAN :
• GEOMETRIC MEAN : ீ ଵ ଶ ଷ
CHEMICAL COMPOSITION
• It is important factor to be known, for the economic recovery of
materials and/or energy from the solid waste
• Two methods of analysis are used to determine the chemical
composition of solid wastes- proximate analysis & ultimate analysis
• PROXIMATE ANALYSIS
• This is important in evaluating the combustion properties of wastes or a
waste or refuse derived fuel.
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Ultimate analysis
• This refers to an analysis of waste to determine the proportion of
carbon, hydrogen, oxygen, nitrogen and Sulphur
• The analysis is done to make mass balance calculation for a chemical
or thermal process
• Besides, ash fraction is also determined because of its potentially
harmful environmental effects, brought about by the presence of
toxic metals such as cadmium, chromium, mercury, nickel, lead, tin
and zinc
• Other metals (e.g., iron, magnesium, etc.) may also be present but
they are non-toxic
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calorimetry
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• Heat value
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DENSITY
• MSW has highly variable bulk density depending on the pressure
exerted
• The densities of solid wastes vary markedly with geographic location,
season of the year and length of time in storage. So, great care must
be taken in selecting typical values
• When MSW is placed in garbage can in loose it’s bulk density
between 90-150 kg/m3 on pushing it into the can the density reaches
180 kg/m3
• In a collection truck that compacts the refuse bulk density will be
between 450-600 kg/m3
• Once it is deposited in a landfill and compacted with machinery, it can
achieve bulk density about 700 kg/m3
• Because of highly variable nature of density MSW quantities are
almost always expressed in mass terms as kilograms or tonnes
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BIODEGRADABILITY
• Knowledge about the biodegradable fraction in an MSW is important
for deciding the treatment technique
• Methods such as composting must taken into account that there is
non-biodegradable fraction in MSW and this must be disposed of by
means other than producing useful products using biodegradation
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INDUSTRIAL WASTE
• These are wastes arising from industrial activities and typically include
rubbish, ashes, demolition and construction wastes, hazardous
wastes etc.
• Food processing wastes, boiler house cinders, wood, plastic and metal
scraps also comes under industrial wastes which are the results of
various industrial process and manufacturing operations.
• Industrial solid wastes are sources of toxic metals and hazardous
wastes, which may spread on land and can cause changes in
physicochemical and biological characteristics thereby affecting
productivity of soils.
• About 10 to 15 percent of wastes produced by industries are
hazardous and the generation of hazardous wastes is increasing at the
rate of 2 to 5 percent per year.
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WASTE SOURCE
Conversion of pig iron to steel and manufacture of
Steel and Blast furnace slag
Iron
Brine mud Caustic soda industry
Copper slag By product from smelting of copper
Fly ash Coal based thermal power plants
Kiln dust Cement plants
Lime sludge Sugar, paper, soda ash, calcium carbide industries
Mica scraper waste Mica mining areas
Phosphogypsum Phosphoric acid plant, Ammonium phosphate
Red mud/ Bauxite Mining and extraction of alumina from Bauxite
Coal washery dust Coal mines
Iron tailing Iron Ore
Lime stone wastes Lime stone quarry
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HAZARDOUS WASTE
• Wastes that pose a substantial danger immediately or over a period
of time to human, plants, or animal life are classified as hazardous
wastes
• This is due to their physical, chemical and biological or radioactive
characteristics like ignitability, corrosivity, reactivity and toxicity.
• Note that in some cases, the active agents may be liquid or gaseous
hazardous wastes. These are, nevertheless, classified as solid wastes
as they are confined in solid containers
• Typical examples of hazardous wastes are empty containers of
solvents, paints and pesticides, which are frequently mixed with
municipal wastes and become part of the urban waste stream.
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MEDICAL WASTE
• Medical wastes are wastes generated by healthcare facilities like
physician’s offices, hospitals, dental practices, laboratories, medical
research facilities, and veterinary clinics.
• The term “medical waste” can cover a wide variety of different
byproducts of the healthcare industry. The broadest definition can
include office paper and hospital sweeping waste.
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• Sharps. This kind of waste includes anything that can pierce the skin, including needles,
scalpels, lancets, broken glass, razors, ampules, staples, wires, and trocars
• Infectious Waste. Anything infectious or potentially infectious goes in this category,
including swabs, tissues, excreta, equipment, and lab cultures.
• Radioactive. This kind of waste generally means unused radiotherapy liquid or lab
research liquid. It can also consist of any glassware or other supplies contaminated with
this liquid.
• Pathological. Human fluids, tissue, blood, body parts, bodily fluids, and contaminated
animal carcasses come under this waste category.
• Pharmaceuticals. This grouping includes all unused, expired, and/or contaminated
vaccines and drugs. It also encompasses antibiotics, injectables, and pills.
• Chemical. These are disinfectants, solvents used for laboratory purposes, batteries, and
heavy metals from medical equipment such as mercury from broken thermometers.
• Genotoxic Waste. This is a highly hazardous form of medical waste that’s either
carcinogenic, teratogenic, or mutagenic. It can include cytotoxic drugs intended for use in
cancer treatment.
• General Non-Regulated Medical Waste. Also called non-hazardous waste, this type
doesn’t pose any particular chemical, biological, physical, or radioactive danger.
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UNIVERSAL WASTE
• Universal wastes are hazardous wastes that are widely produced by
households and many different types of businesses. Universal wastes
include televisions, computers and other electronic devices as well as
batteries, fluorescent lamps, mercury thermostats, and other mercury
containing equipment.
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RADIOACTIVE WASTE
Radioactive waste is waste that contains radioactive material.
Radioactive waste is usually a by-product of nuclear power generation
and other applications of nuclear fission or nuclear technology, such as
research and medicine. Radioactive waste is hazardous to all forms of
life and the environment and is regulated by government agencies in
order to protect human health and the environment.
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• Low level wastes are having short lived radioactivity and are suitable
for shallow land burial
INTERMEDIATE LEVEL WASTE
• Contains higher amounts of radioactivity and some requires shielding
• Present in resins, chemical sludges, and in metal fuel cladding
HIGH LEVEL WASTE
• Arises from the 'burning' of uranium fuel in a nuclear reactor
• Produced during reprocessing of used fuel
• For used fuel designated as high-level radioactive waste (HLW), the
first step is storage to allow decay of radioactivity and heat, making
handling much safer.
• Storage of used fuel may be in ponds or dry casks, may be at reactor
sites itself
• The most widely favoured solution for disposal is deep geological
disposal.
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E-WASTE
MINING WASTE
• Wastes that occur in several stages of the mining process and
throughout the life of the mine, from the first exploration drilling
project to the last processed material before mine closure
• Several types of waste are generated in a mine, but three types stand
out with the largest volume: waste rock, tailings and mine water.
• In some cases, the mine uses certain chemicals such as cyanide in the
processing stage. These chemicals often account for a small volume of
the total waste, but can pose a large risk due to their high toxicity.
• Depending on the composition of the waste rock, elements are
released in the atmosphere. Some may be highly toxic
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• As the ore gets processed and the valuable minerals gets separated, a
fine-grained mineral sand remains as waste, called tailings.
• The amount of tailings that remain is controlled by the percentage of
valuable minerals in the ore
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AGRICULTURAL WASTE
• Agricultural waste refers to waste produced from agricultural
operations, including waste from farms, poultry houses, and
slaughterhouses.
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WASTE
GENERATION
STORAGE
COLLECTION
TRANSFER
TRANSFER PROCESSING
AND AND
TRANSPORT RECOVERY
AND
TRANSPORT
DISPOSAL
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WASTE GENERATION
• Includes those activities in which materials are identified as no longer
being of value and are either thrown away or gathered together for
disposal
WASTE GENERATION
• Solid waste generation rates estimate the amount of waste created by
different sources over a certain amount of time (day, year, etc.)
2. Mass-volume analysis
• This is similar to load-count analysis but here mass of each load is also
recorded
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• Seasons: Seasons of the year have implications for the quantities and
composition of certain types of solid wastes.
• Containers should not have rough or sharp edges, and preferably have
a handle and a wheel to facilitate mobility.