C:\GCMSsolution\Data\Project1\Rtx 5 MS 2019\Ulyarti Sampel Minyak.

qgd 10/13/2020
Lab.Kimia Organik FMIPA - UGM
Sample Information
Analyzed by : Admin
Sample Name : Ulyarti Sampel Minyak
Sample ID :
Data File : C:\GCMSsolution\Data\Project1\Rtx 5 MS 2019\Ulyarti Sampel Minyak.qgd
Method File : C:\GCMSsolution\Data\Project1\Rtx 5 MS 2019\Atsiri.qgm
Tuning File : C:\GCMSsolution\System\Tune1\juni 30 2020.qgt

Chromatogram Ulyarti Sampel Minyak C:\GCMSsolution\Data\Project1\Rtx 5 MS 2019\Ulyarti Sampel

2
3,389,79 Minyak.qgd
9

TIC*1.00
5
3

7
6
1

10.0 20.0 30.0 40.0 50.0

min

Peak Report TIC

Peak# R.Time I.Time F.Time Area Area% Height
1 24.105 24.042 24.192 90255 0.18 21696
2 24.768 24.192 24.892 39841680 80.55 3345706
3 24.960 24.892 25.158 484228 0.98 97266
4 26.321 26.108 26.575 7935917 16.04 1535706
5 27.155 27.058 27.258 609498 1.23 149817
6 28.887 28.792 29.025 168497 0.34 33019
7 30.548 30.375 30.742 332941 0.67 60044
49463016 100.00 5243254

1/1
Library
<< Target >>
Line#:1 R.Time:24.108(Scan#:2270) MassPeaks:157
RawMode:Averaged 24.100-24.117(2269-2271) BasePeak:41.00(1919)
BG Mode:Calc. from Peak Group 1 - Event 1
100 41
105
43
91 119

81 161

28 65 133
148 173 184202220 244 253 269 292 304 318 328 338357 372 387395

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:48032 Library:WILEY229.LIB
SI:83 Formula:C13 H20 CAS:0-00-0 MolWeight:176 RetIndex:0
CompName:2-CARENE, 4-.ALPHA.-ISOPROPENYL-, (+)- $$
100 41 133
93 105
43

119
27
77
65 161
176
147

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:71100 Library:WILEY229.LIB
SI:82 Formula:C15 H24 CAS:56390-01-3 MolWeight:204 RetIndex:0
CompName:CIS,CIS,TRANS-3,3,6,6,9,9-HEXAMETHYL-TETRACYCLO[6.1.0.0(2,4).0(5,7)]NONANE $$ Tetracyclo[6.1.0.02,4.05,7]nonane, 3,3,6,6,9,9-hexamethyl- $$
100 41

43 91
105

119 161
133
27 69 77
147 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:71082 Library:WILEY229.LIB
SI:82 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0
CompName:.alpha.-Copaene $$ Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer (CAS) Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st (CAS) Copaene $$ Cop
100 105 119
41 Me
161 Me
91

55 77
39 i-Pr
65 204
133
145 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:71174 Library:WILEY229.LIB
SI:81 Formula:C15 H24 CAS:39029-41-9 MolWeight:204 RetIndex:0
CompName:.GAMMA.-CADINENE $$
100 41
161 CH2
119
91 105

5577 134
27 204
69 Me
Pr-i

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:16786 Library:NIST62.LIB
SI:80 Formula:C13H20 CAS:0-00-0 MolWeight:176 RetIndex:0
CompName:Megastigma-7(E),9,13-triene
100 91 105
41

27 119
77 161 176
55 67133

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
<< Target >>
Line#:2 R.Time:24.767(Scan#:2349) MassPeaks:87
RawMode:Averaged 24.758-24.775(2348-2350) BasePeak:76.95(238056)
BG Mode:Calc. from Peak Group 1 - Event 1
100 77
39 164
5591 103

65 131
149
121

28

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:38291 Library:WILEY229.LIB
SI:85 Formula:C10 H12 O2 CAS:97-53-0 MolWeight:164 RetIndex:0
CompName:EUGENOL $$
100 164

MeO CH2CH CH2

77
91 103 149
55 131
39
121
HO
27 65

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:24316 Library:NIST62.LIB
SI:83 Formula:C12H14O3 CAS:93-28-7 MolWeight:206 RetIndex:0
CompName:Phenol, 2-methoxy-4-(2-propenyl)-, acetate $$ Phenol, 4-allyl-2-methoxy-, acetate $$ Aceteugenol $$ Acetyleugenol $$ Eugenol acetate $$ Eugenyl acetate $$ 1,3,4-Eugenol acetate $$ Aceto eugenol
100 164 O
43
O
91
O
77
103 149
65 131
39 121

206

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:38192 Library:WILEY229.LIB
SI:80 Formula:C10 H12 O2 CAS:97-53-0 MolWeight:164 RetIndex:0
CompName:Phenol, 2-methoxy-4-(2-propenyl)- (CAS) Eugenol $$ 1-(2-PROPENYL)-4-HYDROXY-3-METHOXYBENZENE $$ Engenol $$ p-Eugenol $$ Eugenic acid $$ 4-Allylguaiacol $$ p-Allylguaiacol $
100 5577

39
103 MeO CH2CH CH2
91 149
131
65
121 HO

38

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:13391 Library:NIST62.LIB
SI:79 Formula:C10H12O2 CAS:97-54-1 MolWeight:164 RetIndex:0
CompName:Phenol, 2-methoxy-4-(1-propenyl)- $$ Phenol, 2-methoxy-4-propenyl- $$ Isoeugenol $$ 2-Methoxy-4-(1-propenyl)phenol $$ 2-Methoxy-4-propenylphenol $$ 4-Hydroxy-3-methoxypropenylbenzene
100 164
O
HO
77
91 103 149
55 121 131
39 65

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:5577 Library:NIST12.LIB
SI:79 Formula:C10H12O2 CAS:19784-98-6 MolWeight:164 RetIndex:0
CompName:Phenol, 2-methoxy-5-(1-propenyl)-, (E)-
100 164
O
HO
55
77 149

91 103 121 133

39 65
27 180

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
<< Target >>
Line#:3 R.Time:24.958(Scan#:2372) MassPeaks:75
RawMode:Averaged 24.950-24.967(2371-2373) BasePeak:41.00(7805)
BG Mode:Calc. from Peak Group 1 - Event 1
100 41
105
119
43
91
77 161
29
69 133 145
189 204

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:71082 Library:WILEY229.LIB
SI:88 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0
CompName:.alpha.-Copaene $$ Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer (CAS) Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st (CAS) Copaene $$ Cop
100 105 119

41 Me
161 Me
91

5577
39 i-Pr
65 204
133
145189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:71189 Library:WILEY229.LIB
SI:86 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0
CompName:.ALPHA.-COPAENE $$
100 105 119

161 Me
Me
91
41
77 i-Pr
43
39 67 133 204
145

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:71172 Library:WILEY229.LIB
SI:86 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0
CompName:.ALPHA.-COPAENE $$
100 105
119
41 161 Me
91 Me

77
3943
i-Pr
65 133 204

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:71083 Library:WILEY229.LIB
SI:85 Formula:C15 H24 CAS:3856-25-5 MolWeight:204 RetIndex:0
CompName:.alpha.-Copaene $$ Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer (CAS) Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st (CAS) Copaene $$ Cop
100 105 119 161

93
Me
41 Me

55 81 i-Pr
39
69 204
133
147 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:7690 Library:NIST12.LIB
SI:85 Formula:C15H24 CAS:3856-25-5 MolWeight:204 RetIndex:0
CompName:Copaene
100 105 119 161

93
41

55 81
39
69 204
133
147 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
<< Target >>
Line#:4 R.Time:26.325(Scan#:2536) MassPeaks:66
RawMode:Averaged 26.317-26.333(2535-2537) BasePeak:41.00(213013)
BG Mode:Calc. from Peak Group 1 - Event 1
100 41

69 79 91
55 105133
28 120 147 161 175 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:70832 Library:WILEY229.LIB
SI:93 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0
CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b
100 41
CH
Me 2

79 91 Me
53 67
27 105
119
133 Me
147 161 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:70837 Library:WILEY229.LIB
SI:93 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0
CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b
100 41
CH
Me 2

91 Me
39 69 79
53 105 133
120 Me
147 161 189
175

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:70840 Library:WILEY229.LIB
SI:89 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0
CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b
100 41
CH
69
93
Me 2
79
39 Me
55
105133
120 Me
147 161 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:70732 Library:WILEY229.LIB
SI:88 Formula:C15 H24 CAS:18794-84-8 MolWeight:204 RetIndex:0
CompName:.beta.-Farnesene $$ 1,6,10-Dodecatriene, 7,11-dimethyl-3-methylene-, (E)- (CAS) 7,11-DIMETHYL-3-METHYLEN-1,6,10-DODECATRIENE $$ .BETA.-FARNESEN $$ trans-.beta.-Farnesene $$
100 41 69

CH2
Me2C CHCH2CH2CMe CHCH2CH2CCH CH2
93

27 55 79
107 120 133
161
147 204

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:70838 Library:WILEY229.LIB
SI:87 Formula:C15 H24 CAS:87-44-5 MolWeight:204 RetIndex:0
CompName:trans-Caryophyllene $$ Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4E,9S*)]- (CAS) l-Caryophyllene $$ (-)-Caryophyllene $$ Caryophyllene $$ .beta.-Caryophyllen $$ .b
100 41
69 CH
93 Me 2

55
79 Me
133
27 105 120
147 161 Me
189 204

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
<< Target >>
Line#:5 R.Time:27.158(Scan#:2636) MassPeaks:58
RawMode:Averaged 27.150-27.167(2635-2637) BasePeak:93.00(18206)
BG Mode:Calc. from Peak Group 1 - Event 1
100 93
41

67 80
53
121
28 107 147
133161 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:70795 Library:WILEY229.LIB
SI:91 Formula:C15 H24 CAS:6753-98-6 MolWeight:204 RetIndex:0
CompName:.alpha.-Humulene $$ 1,4,8-Cycloundecatriene, 2,6,6,9-tetramethyl-, (E,E,E)- (CAS) 4,7,10-CYCLOUNDECATRIENE, 1,1,4,8-TETRAMETHYL-, ALL-CIS $$ Humulene $$ .alpha.-Caryophyllene
100 41
Me
93
53 67
27 79
Me
105 121 Me
133 147
Me
161 189 204

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:19307 Library:WILEY229.LIB
SI:90 Formula:C10 H16 CAS:502-99-8 MolWeight:136 RetIndex:0
CompName:Trans-Ocimene $$ 1,3,7-Octatriene, 3,7-dimethyl- (CAS) 2,6-Dimethyl-1,5,7-octatriene $$ Ocimene $$ .alpha.-Ocimene $$ 3,7-Dimethyl-1,3,7-octatriene $$
100 93

41
27 H2C CMe CH2CH2CH CMe CH CH2
79
43

67 121
105
136

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:6689 Library:NIST62.LIB
SI:90 Formula:C10H16 CAS:502-99-8 MolWeight:136 RetIndex:0
CompName:1,3,7-Octatriene, 3,7-dimethyl- $$ Ocimene $$ 2,6-Dimethyl-1,5,7-octatriene
100 93

41
27
79
43

67 121
105
136

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:70797 Library:WILEY229.LIB
SI:89 Formula:C15 H24 CAS:6753-98-6 MolWeight:204 RetIndex:0
CompName:.alpha.-Humulene $$ 1,4,8-Cycloundecatriene, 2,6,6,9-tetramethyl-, (E,E,E)- (CAS) 4,7,10-CYCLOUNDECATRIENE, 1,1,4,8-TETRAMETHYL-, ALL-CIS $$ Humulene $$ .alpha.-Caryophyllene
100 93
Me

41

80 Me
53 Me
67 121
107 147 Me
29 136 161 204

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:19306 Library:WILEY229.LIB
SI:88 Formula:C10 H16 CAS:502-99-8 MolWeight:136 RetIndex:0
CompName:Trans-Ocimene $$ 1,3,7-Octatriene, 3,7-dimethyl- (CAS) 2,6-Dimethyl-1,5,7-octatriene $$ Ocimene $$ .alpha.-Ocimene $$ 3,7-Dimethyl-1,3,7-octatriene $$
100 93

H2C CMe CH2CH2CH CMe CH CH2

41 79
27
53 67 121
105
136

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
<< Target >>
Line#:6 R.Time:28.883(Scan#:2843) MassPeaks:105
RawMode:Averaged 28.875-28.892(2842-2844) BasePeak:41.00(3734)
BG Mode:Calc. from Peak Group 1 - Event 1
100 41

43
91 105 119
159
134
81
28 65 204
143 169 189 229 279286 302 317 331 354 379396

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:71100 Library:WILEY229.LIB
SI:81 Formula:C15 H24 CAS:56390-01-3 MolWeight:204 RetIndex:0
CompName:CIS,CIS,TRANS-3,3,6,6,9,9-HEXAMETHYL-TETRACYCLO[6.1.0.0(2,4).0(5,7)]NONANE $$ Tetracyclo[6.1.0.02,4.05,7]nonane, 3,3,6,6,9,9-hexamethyl- $$
100 41

43 91
105

119 161
133
27 69 77
147 189

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:70958 Library:WILEY229.LIB
SI:78 Formula:C15 H24 CAS:16728-99-7 MolWeight:204 RetIndex:0
CompName:Naphthalene, 1,2,3,4,4a,7-hexahydro-1,6-dimethyl-4-(1-methylethyl)- (CAS) 4,10-DIMETHYL-7-ISOPROPYL-BICYCLO(4.4.0)-1,4-DECADIENE $$ 1,2,3,4,4A,7-HEXAHYDRO-4-ISOPROPY
100 105 119
Me
41

161
91
55
27 Me
69 77 204
133 Pr-i
147

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:71174 Library:WILEY229.LIB
SI:77 Formula:C15 H24 CAS:39029-41-9 MolWeight:204 RetIndex:0
CompName:.GAMMA.-CADINENE $$
100 41
161 CH2
119
91 105

5577 134
27 204
69 Me
Pr-i

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:7708 Library:NIST12.LIB
SI:77 Formula:C15H24 CAS:483-76-1 MolWeight:204 RetIndex:0
CompName:Naphthalene, 1,2,3,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)-
100 161

105 119
134
41 91 204
81
55
39 189
69 147

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:71317 Library:WILEY229.LIB
SI:77 Formula:C15 H24 CAS:0-00-0 MolWeight:204 RetIndex:0
CompName:.DELTA.-CADINENE $$
100 161

105 119
134
41 91 204
81
55
39 189
69 147

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
<< Target >>
Line#:7 R.Time:30.550(Scan#:3043) MassPeaks:69
RawMode:Averaged 30.542-30.558(3042-3044) BasePeak:41.00(8765)
BG Mode:Calc. from Peak Group 1 - Event 1
100 41

43

79
69 91
28 105 121 131
147 161 176

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:1 Entry:84614 Library:WILEY229.LIB
SI:86 Formula:C15 H24 O CAS:0-00-0 MolWeight:220 RetIndex:0
CompName:LONGIPINENEPOXIDE $$
100 41

55
27
67
81 95 107
124 135 149 161 177

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:2 Entry:36340 Library:NIST62.LIB
SI:84 Formula:C18H30O CAS:26537-71-3 MolWeight:262 RetIndex:0
CompName:9,12,15-Octadecatrienal
100 41

67 79
O
55
27
95
108
121 135 206 262

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:3 Entry:118683 Library:WILEY229.LIB
SI:84 Formula:C18 H30 O CAS:26537-71-3 MolWeight:262 RetIndex:0
CompName:9,12,15-Octadecatrienal (CAS)
100 41

67 79

55 OCH(CH2)7CH CHCH2CH CHCH2CH CHEt

27
95
108
121 135 206 262

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:4 Entry:38764 Library:WILEY229.LIB
SI:83 Formula:C12 H20 CAS:0-00-0 MolWeight:164 RetIndex:0
CompName:1,3-PENTADIENE, 5-(2,2-DIMETHYLCYCLOPROPYL)-2,4-DIMETHYL-, CIS OR TRANS $$
100 41

93
121
69
79
107
27 55
149
164

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Hit#:5 Entry:31231 Library:WILEY229.LIB
SI:83 Formula:C10 H18 O CAS:78-70-6 MolWeight:154 RetIndex:0
CompName:Linalool $$ 1,6-Octadien-3-ol, 3,7-dimethyl- (CAS) Linalol $$ .beta.-Linalool $$ Linalyl alcohol $$ 3,7-Dimethyl-1,6-octadien-3-ol $$
100 41 93

71
43 69
27 H2 C CH CMe(OH) CH 2CH 2 CH
CMe 2

121
107 136

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380