3ra Pc - Termodinámica y Cinética I

TABLA 1 - DATOS

x Al 1-xAl a Al gamma Al log gamma Al

0.9 0.1 0.89 0.989 -0.005
0.75 0.25 0.69 0.920 -0.036
0.63 0.37 0.5 0.794 -0.100
0.53 0.47 0.31 0.585 -0.233
0.45 0.55 0.2 0.444 -0.352
0.38 0.62 0.1 0.263 -0.580
0.3 0.7 0.03 0.100 -1.000
0.2 0.8 0.005 0.025 -1.602
0.1 0.9 0.008 0.080 -1.097

CONTINUACIÓN TABLA 1

x Al ^2 (1-xAl)^2 log gamma Al *(xAl)^2/(1-xAl)^2 gamma Cu

0.81 0.01 -0.393052726347378 0.404526776374
0.5625 0.0625 -0.325909553890003 0.472161363287
0.3969 0.1369 -0.290993932484739 0.511688984282
0.2809 0.2209 -0.296177419523832 0.505618062919
0.2025 0.3025 -0.235758545181986 0.581087395043
0.1444 0.3844 -0.217795919228583 0.605625399353
0.09 0.49 -0.183673469387755 0.65512855686
0.04 0.64 -0.100128749457998 0.794092785792
0.01 0.81 -0.013542098926025 0.9692993044

TABLA 2 - RESULTADOS

calor molar parcial Al(cal/mol) x Al

-30.4808749905296 0.9
-227.465857224578 0.75
-630.475069892344 0.63
-1463.04457222298 0.53
-2212.22568295357 0.45
-3641.89616755858 0.38
-6281.475 0.3
-10063.2997840268 0.2
-6890.21282395978 0.1
rmodinámica y Cinética I
ΔH vs xAl
- DATOS 0
0 0.1f(x) = 0.2 0.3 0.4 x² −0.5
7487.44694702815 54
-500
calor molar parcial Al(cal/mol)
-30.481 -1000
-227.466

ΔH
-630.475 -1500

-1463.045 -2000
-2212.226
-3641.896 -2500
-6281.475
-3000
-10063.300
xAl
-6890.213

CONTINUACIÓN TABLA 1

log gamma Cu calor molar parcial Cu(cal/mol) a cu ΔH

-0.393052726347378
-0.325909553890003
-0.290993932484739
-0.296177419523832
-0.235758545181986
-0.217795919228583
-0.183673469387755
-0.100128749457998
-0.013542098926025
-2468.9508742329 0.360028830972458 -274.327875
-2047.19271502121 0.325791340667724 -682.397572
-1827.87111205457 0.255844492140959 -1073.51161
-1860.43105630346 0.156741599504979 -1649.81622
-1480.91140759702 0.116217479008563 -1810.00283
-1368.07962173637 0.060562539935315 -2232.12991
-1153.74030612245 0.019653856705787 -2692.06071
-628.956236501676 0.003970463928961 -2515.82495
-85.0643558513553 0.007754394435202 -765.579203

TABLA 2 - RESULTADOS

X Cu calor molar parcial Cu(cal/mol) ΔH

0.1 -2468.9508742329 -274.327874914766
0.25 -2047.19271502121 -682.397571673735
0.37 -1827.87111205457 -1073.51160549237
0.47 -1860.43105630346 -1649.81621974081
0.55 -1480.91140759702 -1810.00283150747
0.62 -1368.07962173637 -2232.12990914881
0.7 -1153.74030612245 -2692.06071428571
0.8 -628.956236501676 -2515.8249460067
0.9 -85.0643558513553 -765.579202662198
 ΔH vs xAl
0.1f(x) = 0.2 0.3 0.4 x² −0.5
7487.44694702815 0.6 0.7 x − 1079.86642343795
5418.3970420969 0.8 0.9 1

xAl
Xal DHM cal/mol DHM cal/mol" DHM ideal cal/mol

1 989.1 989.1 989.1

0.9 -274.327874914766 108.334 782.2
0.75 -682.397571673735 -932.0375 471.85
0.63 -1073.51160549237 -1521.74294 223.57
0.53 -1649.81621974081 -1848.44134 16.6700000000001
0.45 -1810.00283150747 -2001.9815 -148.85
0.38 -2232.12990914881 -2057.71144 -293.68
0.3 -2692.06071428571 -2031.554 -459.2
0.2 -2515.8249460067 -1864.084 -666.1
0.1 -765.579202662198 -1546.866 -873
0 -1079.9 -1079.9 -1079.9

Calores extrapolados
X Al DHM cal/mol Calor molar integral de la mezcla ajustada a la
1 989.1 ecuación de la curva.
0 -1079.9

Ecuación de la Curva
y = 7487.4x2 - 5418.4x - 1079.9

Pendiente de la Curva
m = 1919.252x -2877.62474 y=

X Al H Al
1 0
0.9 -30.48087499053
0.75 -227.46585722458
0.63 -630.47506989234
0.53 -1463.044572223
0.45 -2212.2256829536
0.38 -3641.8961675586
0.3 -6281.475
0.2 -10063.299784027
0.1 -6890.2128239598
XAl Actividad Al Actividad Cu a Al Raoul a Cu Raoul
1 1.0 0.000 1 0
0.9 0.890 0.36003 0.9 0.1
0.75 0.690 0.32579 0.75 0.25
0.63 0.500 0.25584 0.63 0.37
0.53 0.310 0.15674 0.53 0.47
0.45 0.200 0.11622 0.45 0.55
0.38 0.100 0.06056 0.38 0.62
0.3 0.030 0.01965 0.3 0.7
0.2 0.005 0.00397 0.2 0.8
0.1 0.008 0.00775 0.1 0.9
0 0.0 1.000 0 1

Al - Cu
1.2

1.0

0.8
Acctividades (ai)

0.6

0.4

0.2

0.0
0 0.2 0.4 0.6 0.8 1 1.2

X Al
 Recta que pasa por el punto
buscado

-958.37274 ΔH v
-1150.29794
1500
-1438.18574
-1668.49598 1000
-1860.42118 f(x) = 7487.24858844032 x² − 5418.22421447413 x − 1079.89560896538
-2013.96134 500
-2148.30898
0
-2301.84914 0 0.2 0.4
-2493.77434 -500
-2685.69954 ΔH
-2877.62474 -1000
f(x) = 1919.252 x − 2877.62474

-1500

-2000
la mezcla ajustada a la
e la curva.
-2500

-3000

-3500

Column C Polynomial (Colum

-2877.62474 1919.252 x

∆G vs XAl
0
0 0.2 0.4 0.6 0.8
-10000

-20000

-30000
∆G

-40000

-50000
 -10000

-20000

∆G -30000

∆G
0
-40000
-2363.35890439647
-6377.31247968549 -50000
-10742.330099914
-60000
-17028.0587811662
-21780.140374039 -70000
-29833.5486015365 X Al
-43407.1948803593
-62586.3895844648
-55436.1403724003
0

Column B
Polynomial (Column B)
Column C
Polynomial (Column C)
Column D
Linear (Column D)
Column E
Linear (Column E)

0.8 1 1.2
 ΔH vs xAl

1447413 x − 1079.89560896538

0.4 0.6 0.8 1 1.2

xAl
Column C Polynomial (Column C) Column F Linear (Column F)

∆G vs XAl
.4 0.6 0.8 1 1.2
X Al
1.2