QUIZ (CHEMISTRY)

STOICHIOMETRY
NAME: ………………................ M.MARKS: M.Time: minutes SUB: CHEMISTRY

1. A sample of hard water cotnains 1 mg CaCl2 and 1 mg MgCl2 per litre. Calculate the hardness of
water in terms of CaCO3 present in per 106 parts of water
(A) 2.5 ppm (B) 1.95 ppm (C) 2.15 ppm (D) 195 ppm

2. When 100 mL of an aquoeus solution of H2O2 is titrated with an excess of KI solution in dilute
H2SO4, the liberated I2 required 50 mL of 0.1 M Na2S2O3 solution for complete reaction. Calculate
the percentage strength (w/v) and volume strength of H2O2 solution
(A) 0.85 %, 0.28 volume (B) 0.085%, 0.28 volume (C) 0.25 %, 0.14 volume (D) 0.025%, 0.14 volume

3. 10 g of CaOCl2 is dissolved in water to make 200 mL solution. 20 mL of it is acidified with acetic

acid and treated with KI solution. The I2 liberated required 40 mL of M/20 Na2S2O3 solution. Find
the percentage of available chlorine
(A) 71 % (B) 7.1 % (C) 35.5 % (D) 3.55 %

4. A sample of pyrolusite (MnO2) weighs 0.5 g. To its solution, 0.6674 g of As2O3 and dilute acid are
added. After the reaction has ceased, arsenic (As3+) in As2O3 is titrated with 45 mL of M/50 KMnO4
solution. Calculate the percentage of MnO2 in pyrolusite. (Atomic weight of As = 74.9 and Mn = 55)
(A) 78.2 % (B) 82.5 % (C) 35% (D) 55%

5. 1 g sample of CaCO3 react with 10 ml of 2M HCl solution. The unused HCl require 100 ml of 0.1 M
NaOH for complete neutralization percentage of pure CaCO3 in the sample is
(A) 20 (B) 25 (C) 50 (D) 75

6. When one mole of KMnO4 reacts with HCl, the volume of chlorine liberated at NTP will be
(A) 11.2 litres (B) 22.4 litres (C) 44.8 litres (D) 56.0 litre

7. For a given mixture of NaHCO3 and Na2CO3 volume of a given HCl required is X ml with
phenolphthalein indicator and further Y ml required with methyl orange indicator. Hence volume of
HCl for complete reaction of NaHCO3 is: -
(A) 2x (B) x/2 (C) y (D) (y-x)

8. Mass of KHC2O4 required to reduce 100 ml of 0.02 M KMnO4 in acidic medium is x gram. and to
neutralise 100 ml of 0.05 M Ca(OH)2 is y gram then
(A) x = y (B) 2x = y (C) x = 2y (D) none of these

9. 10 ml of 1 N HCl is mixed with 20 ml of 1 M H2SO4 and 30 ml of 1 M NaOH. The resultant solution

has
(A) 20 meq of H+ ions (B) 20 meq of OH (C) 0 meq of H+ or OH (D) 30 milli moles of H+

10. An aqueous solution of 6.3g oxalic acid dihydrate is made upto 250 mL. The volume of 0.1 NaOH
required to completely neutralise 10 mL of this solution is
(A) 40 mL (B) 20 mL (C) 10 mL (D) 4 mL

11. Which of the following samples contains the smallest number of atoms?
(A) 1 gm of CO2(g) (B) 1 g of C8H18(l) (C) 1 gm of LiF(s) (D) 1 g of B4H10(g)

12. What is the normality of 0.3 M H3PO3 when it undergoes the following reaction?
H3PO3 + 2OH  HPO32 + 2H2O
(A) 0.1 (B) 0.15 N (C) 0.6 N (D) 0.3 N

13. A gas mixture of 3 litres of propane and butane C4H10 on complete combustion at 25°C produced
10 litres CO2. The propane and butane are respectively
(A) 1, 2 litres (B) 2, 1 litres (C) 1.5 each (D) None

14. When KMnO4 acts as an oxidizing agent and ultimately forms MnO4-2, MnO2 Mn2O3 and Mn+2, then
the number of electrons transferred in each case per mole respectively is
(A) 4,3,1,5 (B) 1,5,3,7 (C) 1,3,4,5 (D) 3,5,7,1
 QUIZ (CHEMISTRY)
15. 1.82 gm of a metal required 32.5 mL of N – HCl to dissolve it what is the equivalent weight of
metal?
(A) 54 (B) 56 (C) 28 (D) 86

16. 0.52g of a dibasic acid required 100ml of 0.1N NaOH for complete neutralization. The equivalent
weight of acid is :
(A) 26 (B) 52 (C) 104 (D) 156
17. 8 g of sulphur is burnt to form SO2 which is oxidised by Cl2 water. The solution is treated with
BaCl2 solution. The amount of BaSO4 precipitated is
(A) 1 mole (B) 0.5 mole (C) 0.24 mole (D) 0.25 mole
18. The eq. wt. Of MnSO4 is half of its molecular wt. When it is converted to
(A) Mn2O3 (B) MnO2 (C) MnO4 (D) MnO 24

19. 75 ml of FeC2O4 required 100 ml of KMnO4 for complete oxidation. If the KMnO4 used is
0.5 M, calculate the molarity of FeC2O4 solution?
(A) 1.11 M (B) 11.1 M (C) 12.3 M (D) 1.23 M

20. Chlorophyll contains 2.68% of magnesium by mass. Calculate the number of magnesium atoms in
3.00 gms of chlorophyll.
(A) 1.98  1021 atoms (B) 6.0231023atoms (C) 1.7  1020 atoms (D) 2.8  1022 atoms

21. The molarity of 89% H2SO4 (d=1.8g/ml) by wt is

(A) 16.3M (B) 18M (C) 10M (D) 4M

22. Which of the following equations is a balanced one?

(A) 5BrO3 +22H++Mn2+ 5Br3++7H2O+ MnO4 (B) 5BrO3 +14H++2Mn2+5Br3++7H2O+ 2MnO4
(C) 2BrO3 +4H++Mn2+2Br3+ + 2H2O + MnO4 (D) 6BrO3 +12H++3Mn2+6Br3++6H2O+ 3MnO4

23. Which of the following is a redox reaction?

(A) N2O5+H2O  2HNO3 (B) AgNO3 + KI  AgI + KNO3
(C) BaO2 + H2SO4  BaSO4 + H2O2 (D) SnCl2 + HgCl2  SnCl4 + Hg

24. 2.76 g of silver carbonate on being strongly heated yields residue weighting
(A) 2.16 g (B) 2.48 g (C) 2.32 g (D) 2.64 g

25. 5 ml of N HCl, 20 ml of N/2 H2SO4 and 30 ml. of N/3 HNO3 are mixed together and volume made
one litre. The normality of the resulting solution is:
(A) N/5 (B) N/10 (C) N/20 (D) N/40

26. 45 g of acid of mol. wt. 90 neutralised by 200 ml of 5 N caustic potash. The basicity of the acid is:
(A) 1 (B) 2 (C) 3 (D) 4

27. 1.5 g of a divalent metal displaced 4 g of copper (atomic weight = 63.8) from a solution of copper
sulphate. The atomic weight of the metal is:
(A) 12 (B) 24 (C) 48 (D) 6

28. NH3  O 2  N2  H2 O

If molecular weights of NH3 and N2 are M1 and M2 respectively, and their equivalent weights are E1
and E2 respectively, then (E1 – E2) is equal to
 2M  M2 
(A)  1  (B) M1  M2  (C)  3M1  M2  (D)  M1  3M2 
 6 
29. 0.5 g of fuming sulphuric acid (H2SO4 + SO3) called oleum, is diluted with water. This solution
completly neutralized 26.7 mL of 0.4 NaOH. Find the percentage of free SO3 in the sample solution
(A) 80.6% (B) 60.6% (C) 40.6% (D) 20.6%
30. 1 gm H2O2 solution containing n% H2O2 by weight required n ml of KMnO4 for complete oxidation
in acid medium. Normality of KMnO4 solution is
(A) 0.588 (B) 0.48 (C) 0.38 (D) 0.68

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QUIZ (CHEMISTRY)
ANSWERS
STOICHIOMETRY
1. B 2. B 3. B 4. A

5. C 6. D 7. D 8. B

9. A 10. A 11. A 12. C

13. B 14. C 15. B 16. B

17. D 18. B 19. A 20. A

21. A 22. B 23. D 24. A

25. D 26. B 27. B 28. A

29. D 30. A