Manual AC32e Envea 2 - Manual - AC32e - 19.09

CHARACTERISTICS
GENERAL
TECHNICAL MANUAL
OPERATION
PRINCIPLE
AC32e
INSTRUCTIONS
OPERATING
CHEMILUMINESCENT NITROGEN
OXIDE ANALYZER
MAINTENANCE
PREVENTIVE
- SEPTEMBER 2019 -
MAINTENANCE
CORRECTIVE
111, Bd Robespierre / CS 80004 - 78304 Poissy Cedex 4 – France

Tél : +33(0)1 39 22 38 00 – Fax : +33(0)1 39 65 38 08 – www.envea.global
ENVEA AC32e Duplication prohibited
WARNING
The information contained in this document is subject to change without notice.
ENVEA all rights reserved.
This document does not represent a commitment under part of ENVEA.
0-2 SEPTEMBER 2019

Duplication prohibited AC32e ENVEA
Warranty
Defects that fall under warranty

The seller undertakes to remedy any operational defect resulting from a defect in materials or in manu-
facture within the limits of the provision below.
The seller shall not be liable in the case of a defect caused either by materials supplied by the buyer or
by a design imposed by the buyer.
Any warranty is also invalid in the case of incidents from accidental events or cases of force majeure as
well as in the case of replacements or repairs resulting from normal wear and tear to the equipment,
deterioration or accident resulting from negligence, lack of care or maintenance and defective use of the
said equipment.
Duration and starting point of the warranty

Unless otherwise stipulated, the warranty period shall have a duration of twelve months from the date
of delivery within the meaning of article 6 paragraph 2 above, even if the shipment or assembly are
postponed for any reason outside the seller's control.
The repair, modification or replacement of parts during the warranty period cannot result in extending
the said equipment warranty period.
Buyer's obligation
In order to claim under warranty, the buyer must notify the seller in writing immediately of any defect it
imputes to the equipment and supply any evidence in proof thereof. It must provide the seller with every
opportunity to observe the said defects and to remedy the same. In addition, the buyer must not carry
out any repairs or have repairs carried out by a third party without the written agreement of the seller.
The buyer shall be bound to check the equipment as soon as possible as it is accepted or handed over
and at the latest within eight days following it being made available, failing which it may not make any
later claims in respect of the declared defects.
Modalities or exercising the warranty

Once notified, the seller shall be responsible for remedying the defect at its own expense. The seller,
however, reserves the right, as necessary, to modify the mechanisms of the equipment in such a way
to comply with its obligations. The work resulting from the warranty obligation shall be carried out in
principle in the seller's workshop after the buyer has returned the equipment or the defective parts to
the seller for the purposes of repair or replacement, as the seller deems fit.
Nonetheless, if in view of the nature of the equipment, the repair has to be carried out on the site where
it was installed, the seller shall be responsible for the labour costs in respect of the said repair, excluding
the time spent on preliminary works or on dismantling and reassembly operations rendered necessary
by the conditions of use or the location of the said equipment and relating to items not included in the
supply in question.
The cost of carriage of the equipment or the defective parts, and in respect of the return of the repaired
or replaced equipment or part, shall be borne by the buyer and in case of repair on site, the buyer shall
be responsible for the travelling and accommodation expenses of the seller's representative.
Parts replaced free of charge shall be placed at the seller's disposal and shall become its property once
again.
Repairs
In the absence of express agreement to the contrary, repair operations shall not give rise to any warranty
other than that of satisfactory performance of the said operations.
SEPTEMBER 2019 0-3

CONTENTS
CHAPTER 1. GENERAL - CHARACTERISTICS

1.1 GENERAL 1–3
1.2 CHARACTERISTICS 1–10
CHAPTER 2 OPERATION PRINCIPLE

2.1 MEASUREMENT PRINCIPLE 2–3
2.2 GENERAL PRINCIPLE DIAGRAMS 2–7
2.3 MAIN MODULE DESCRIPTION 2–9
2.4 RESPONSE TIME PROGRAMMATION 2–12
2.5 E SERIES ELECTRONIC ARCHITECTURE 2–13
2.6 NETWORK LINK AND USB PORTS 2–14
CHAPTER 3 OPERATING INSTRUCTIONS

3.1. INITIAL STARTUP 3–3
3.2. PROGRAMMING THE AC32E 3–11
3.3. BROWSING ERGONOMY 3–15
3.4. DESCRIPTION OF ANALYZER FUNCTIONS AND SCREENS 3–20
3.5. CALIBRATION 3–48
CHAPTER 4 PREVENTIVE MAINTENANCE

4.1 SAFETY INSTRUCTIONS 4–3
4.2 MAINTENANCE CALENDAR 4–4
4.3 MAINTENANCE OPERATION SHEETS 4–4
4.4 AC32E MAINTENANCE KIT 4–24
4.5 AC32E RECOMMENDED SPARE PARTS 4–24
CHAPTER 5 CORRECTIVE MAINTENANCE
0-4 SEPTEMBER 2019

LIST OF FIGURES
Figure 1–1 – ENVEA AC32e (with touch screen). 1–2

Figure 1–2 – ENVEA AC32e (without touch screen). 1–2
Figure 1–3 – Color touch screen 1–3
Figure 1–4 – AC32e rear panel and external pump 1–5
Figure 1–5 – AC32e internal view 1–8
Figure 1–6 – Links between units 1–11
Figure 1–7 – AC32e dimensions (in mm) 1–12
Figure 2-1 – Black cycle (zero-reference) diagram 2–4

Figure 2-2 – NO cycle diagram 2–5
Figure 2-3 – NOx cycle diagram 2–6
Figure 2-4 – General principle diagram 2–7
Figure 2-5 – General principle diagram with NO2 permeation bench option 2–8
Figure 2-6 – PERMA-PURE dryer 2–10
Figure 2-7 – Electronic architecture 2–14
Figure 3–1 – Fluid and electrical connections 3–4

Figure 3–2 – Sample gas inlet installation 3–5
Figure 3–3 – Example of a pressurized gas connection 3–49
Figure 3–4 – Calibrator connection diagram 3–52
Figure 3–5 – Typical GTP diagram 3–62
Figure 4–1 – Sample inlet dust filter replacement 4–5

Figure 4–2 – Test for leaks 4–9
Figure 4–3 – Internal zero filter replacement 4–10
Figure 4–4 – Dryer filter replacement 4–11
Figure 4–5 – Ozone cleanser replacement 4–12
Figure 4–6 – KNF pump of AC32e 4–13
Figure 4–7 – KNF pump details 4–15
Figure 4–8 – Dust filter replacement 4–16
Figure 4–9 – Ozone restrictor cleaning 4–17
Figure 4–10 – Sample restrictor cleaning 4–18
Figure 4–11 – NOx molybdenum converter replacement 4–21
Figure 4–12 – Ozone scrubber maintenance 4–23
Figure 5–1 – Interconnection board diagram 5–19

Figure 5–2 – Controller board diagram 5–20
Figure 5–3 – Power supply board diagram 5–21
Figure 5–4 – Measurement board diagram 5–22
Figure 5–5 – Ozone generator board diagram 5–24
Figure 5–6 – PM preamplifier board diagram 5–25
Figure 5–7 – RTP board diagram 5–26
Figure 5–8 – SCP board diagram 5–27
Figure 5–9 – ICB board diagram 5–28
Figure 5–10 – ARM20 board diagram 5–30
SEPTEMBER 2019 0-5

LIST OF TABLES
Table 5–1 – List of faults and corrective actions 5–6

Table 5–2 – Interconnection board connections and LED description 5–18
Table 5–3 – Controller board connections and LED description 5–20
Table 5–4 – Power supply board connection and LED description 5–21
Table 5–5 – Measurement board connections, test points and LED description 5–22
Table 5–6 – Ozone generator board connection, adjustment, test points and LED description 5–23
Table 5–7 – Photomultiplier (PM) preamplifier board connection, test points, adjustments and LED
description 5–25
Table 5–8 – RTP board connections and LED description 5–26
Table 5–9 – SCP board connections and LED description 5–27
Table 5–10 – ICB board connections 5–28
Table 5–11 – ARM20 board connections and LED description 5–29
0-6 SEPTEMBER 2019

INDEX OF PAGES
Page Date Page Date Page Date

0-1 09.2019 3-17 09.2019 4-8 09.2019
0-2 09.2019 3-18 09.2019 4-9 09.2019
0-3 09.2019 3-19 09.2019 4-10 09.2019
0-4 09.2019 3-20 09.2019 4-11 09.2019
0-5 09.2019 3-21 09.2019 4-12 09.2019
0-6 09.2019 3-22 09.2019 4-13 09.2019
0-7 09.2019 3-23 09.2019 4-14 09.2019
0-8 09.2019 3-24 09.2019 4-15 09.2019
3-25 09.2019 4-16 09.2019
3-26 09.2019 4-17 09.2019
1-1 09.2019 3-27 09.2019 4-18 09.2019
1-2 09.2019 3-28 09.2019 4-19 09.2019
1-3 09.2019 3-2 09.2019 4-20 09.2019
1-4 09.2019 3-30 09.2019 4-21 09.2019
1-5 09.2019 3-31 09.2019 4-22 09.2019
1-6 09.2019 3-32 09.2019 4-23 09.2019
1-7 09.2019 3-33 09.2019 4-24 09.2019
1-8 09.2019 3-34 09.2019
1-9 09.2019 3-35 09.2019
1-10 09.2019 3-36 09.2019 5-1 09.2019
1-11 09.2019 3-37 09.2019 5-2 09.2019
1-12 09.2019 3-38 09.2019 5-3 09.2019
3-39 09.2019 5-4 09.2019
3-40 09.2019 5-5 09.2019
2-1 09.2019 3-41 09.2019 5-6 09.2019
2-2 09.2019 3-42 09.2019 5-7 09.2019
2-3 09.2019 3-43 09.2019 5-8 09.2019
2-4 09.2019 3-44 09.2019 5-9 09.2019
2-5 09.2019 3-45 09.2019 5-10 09.2019
2-6 09.2019 3-46 09.2019 5-11 09.2019
2-7 02.2018 3-47 09.2019 5-12 09.2019
2-8 02.2018 3-48 09.2019 5-13 09.2019
2-9 09.2019 3-49 09.2019 5-14 09.2019
2-10 09.2019 3-50 09.2019 5-15 09.2019
2-11 09.2019 3-51 09.2019 5-16 09.2019
2-12 09.2019 3-52 09.2019 5-17 09.2019
2-13 09.2019 3-53 09.2019 5-18 09.2019
2-14 09.2019 3-54 09.2019 5-19 09.2019
3-55 09.2019 5-20 09.2019
3-56 09.2019 5-21 09.2019
3-1 09.2019 3-57 09.2019 5-22 09.2019
3-2 09.2019 3-58 09.2019 5-23 09.2019
3-3 09.2019 3-59 09.2019 5-24 09.2019
3-4 09.2019 3-60 09.2019 5-25 09.2019
3-5 09.2019 3-61 09.2019 5-26 09.2019
3-6 09.2019 3-62 09.2019 5-27 09.2019
3-7 09.2019 5-28 09.2019
3-8 09.2019 5-29 09.2019
3-9 09.2019 5-30 09.2019
3-10 09.2019 4-1 09.2019
3-11 09.2019 4-2 09.2019
3-12 09.2019 4-3 09.2019
3-13 09.2019 4-4 09.2019
3-14 09.2019 4-5 09.2019
3-15 09.2019 4-6 09.2019
3-16 09.2019 4-7 09.2019
SEPTEMBER 2019 0-7

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0–8 SEPTEMBER 2019

CHAPTER 1
GENERAL - CHARACTERISTICS
1.1 GENERAL 1–3
1.1.1 PRESENTATION 1–3
1.1.2 DESCRIPTION 1–3
1.1.2.1 Front panel 1–3
1.1.2.2 Rear panel 1–4
1.1.2.3 Internal view 1–6
1.1.3 VARIOUS OPERATING MODES 1–9
1.1.3.1 Standard 1–9
1.1.3.2 Option 1–9
1.1.4 ASSOCIATED EQUIPMENT (OPTIONAL) 1–9
1.2 CHARACTERISTICS 1–10
1.2.1 TECHNICAL CHARACTERISTICS 1–10
1.2.2 STORAGE CHARACTERISTICS 1–11
1.2.3 INSTALLATION CHARACTERISTICS 1–11
1.2.3.1 Links between unit 1–11
1.2.3.2 Dimensions and weight 1–11
1.2.3.3 Handling and storage 1–11
1.2.4 STORAGE 1–11
Figure 1–1 – ENVEA AC32e (with touch screen). 1–2

Figure 1–2 – ENVEA AC32e (without touch screen). 1–2
Figure 1–3 – Color touch screen 1–3
Figure 1–4 – AC32e rear panel and external pump 1–5
Figure 1–5 – AC32e internal view 1–8
Figure 1–6 – Links between units 1–11
Figure 1–7 – AC32e dimensions (in mm) 1–12
SEPTEMBER 2019 1–1

1 GENERAL - CHARACTERISTICS
Figure 1–1 – ENVEA AC32e (with touch screen).
Figure 1–2 – ENVEA AC32e (without touch screen).

1.1 GENERAL
1.1.1 PRESENTATION
The AC32e is a nitrogen monoxide and nitrogen dioxide analyzer (with a detection limit of 0.2 ppb).
Its measurement principle is based on nitrogen oxide (NO) chemiluminescence in the presence of highly
oxidizing ozone molecules.
With the incorporation of recent optical and electronic technologies, the analyzer offers many
advantages while requiring only limited maintenance.
The sample is taken using a Teflon tube (6 mm external diameter) connected to the analyzer rear panel.
The sample is aspirated by an external pump.
The measurement is displayed on a color display equipped with a touch screen located on the front
panel.
This analyzer is also available in AC32e (without touch screen) version.
1.1.2 DESCRIPTION
1.1.2.1 Front panel
The front panel includes the following:
− StatusLightTM power button (color changing)
− Backlit color TFT LCD (Thin Film Transistor Liquid Crystal Display):
• Resolution of 800 x 480 (pixels), 7” screen,
• The display provides the measurement values and other system parameters, as desired.
− Interactive touch screen.
− USB port.
Figure 1–3 – Color touch screen

1.1.2.2 Rear panel

All of the AC32e electrical connectors and gas inlets/outlets are located on the rear panel. Refer to
Figure 1–4.
Gas inlets/outlets (right-hand side):

− The inlet for the sample to be analyzed (1) is a 4 mm (I.D.) and 6 mm (O.D.) tube fitting, attached
to the dust filter holder. The dust filter holder is equipped with a Teflon filtering diaphragm.
− The ambient air inlet (2) for supplying the ozone generator is a 4 mm (I.D.) and 6 mm (O.D.) Teflon
fitting.
− The pump outlet (15), to connect the external pump, is a 4 mm (I.D.) and 6 mm (O.D.) tube.
− The general fan (9), and the Peltier cooler fan (14).
− The span gas inlet (3) is a 4 mm (I.D.) and 6 mm (O.D.) Teflon fitting to connect an external span
gas at atmospheric pressure.
The following options are also located on the rear panel:
− Inlet for external zero air generator (4),
− Zero air inlet for permeation bench (12).
Electrical equipment and connections (left-hand side):

− One main power supply block consisting of a three-contact socket (5) to connect a standard power
cable and the general fuse (6): 3.15 A/250V.
− One Ethernet output (7) and two USB ports (8).
− One 4-point BL connection to connect the optional solenoid valve for external calibration (10),
− One connection for the 24 V power supply for ESTEL board option (11).
− One supply plug for external pump (13).
NOTE : The analyzer is equipped with power supply compatible with 100-240V voltage and 50-60 Hz
frequency main supply. However, the available main supply must be compatible with voltage
and frequency indicated on pump housing.

(1) sample inlet, (2) ozone generator air inlet, (3) span inlet, (4) optional inlet for external zero air
generator, (5) three-contact socket for main power supply, (6) general fuse, (7) Ethernet output, (8) two
USB ports, (9) general fan, (10) connector for external zero and span solenoid valves control, (11) 24 V
power supply for ESTEL board option, (12) zero air inlet for optional permeation bench, (13) external
pump supply, (14) Peltier fan, (15) fluid connection for external pump, (16) pump vent.
Figure 1–4 – AC32e rear panel and external pump

1.1.2.3 Internal view

The internal components of the analyzer are accessed by simply unscrewing the single knurled screw
at the rear panel and sliding the upper cover.
The internal elements include (refer to Figure 1–5):
− Sample inlet dust filter mounted on the rear panel (1),
− Optional dryer (2) used to remove sample gas humidity,
− Solenoid valve block (3) for sample/zero/span inlet,
− NOx cycle solenoid valve block (4) which selects the (NO-NOx) measurement cycle,
− Zero filter (5) which generates NO-free gas for zero-reference cycle,
− Sample pressure sensor (6)
− Interconnections board (7), which allows Supply, Arm20, Controller and Measurement board
interfacing,
− NOx cycle solenoid valve (9),
− Chemiluminescence reaction chamber pressure sensor (10),
− Converter case (11) which includes NOx converter oven (8), and ozone scrubber (17),
− 24 VDC power supply unit (12), with automatic universal input voltage 100~250 Vac 50/60Hz,
− Ozone circuit consisting of air inlet filter (13), dryer (14), ozone generator board (29) mounted on
ozone generator (15), ozone purifier (16), and ozone scrubber (17),
− ARM20 board (18),
− Measurement module (19) which includes chemiluminescence reaction chamber, refrigerated
photomultiplier tube enclosure (PM) and RTP board (Peltier temperature control) (28),
− Scavenging dryer filter (20),
− Measurement board (21),
− Controller board (22),
− Power supply board (23),
− Peltier fan (24), and electronic board cooler fan (25),
− Vacuum manifold (26),
− Pre-amplifier board housing (27),
− Pump relay board (30).

After passing through the dust inlet filter (1), the gas to be measured passes through the solenoid valve
block (3) which selects the input port (sample, span, zero). The optional dryer (2), inserted between the
dust filter and the solenoid valve block, eliminates any water interference.
The sample is aspirated into the reaction chamber, directly for the NO cycle, and through the NO2 →
NO converter oven (8) for the NOx cycle.
The ozone generator is used to generate ozone needed for ambient air measurement. First, dust
particles are removed from the aspirated air, and then air is dried through the dryer (14). Then, at the
ozone generator outlet (15), ozone generated is cleaned by passing through the scrubber (16) before
entering the reaction chamber inside the measurement module (19). The ozone generator board (29)
electrically supplies the ozone generator high-voltage transformer.
The dryer (14) also provides the scavenging air to the photomultiplier tube enclosure after passing
through the scavenging dryer filter (20).
The vacuum manifold (26), connected to the external pump, connects all the internal elements to be
placed under vacuum.

(1) sample inlet dust filter, (2) optional dryer, (3) inlet solenoid valve block, (4) NOx solenoid valve block,
(5) zero filter, (6) sample pressure sensor, (7) Interconnection board, (8) converter oven, (9) NOx cycle
solenoid valve, (10) reaction chamber pressure sensor, (11) converter enclosure, (12) 24 V power
supply, (13) air inlet filter of ozone generator, (14) ozone generator dryer, (15) ozone generator, (16)
ozone purifier, (17) ozone scrubber, (18) ARM20 board, (19) measurement module, (20) scavenging
dryer filter, (21) measurement board, (22) Controller board, (23) Supply board, (24) Peltier fan, (25)
cooler fan, (26) vacuum manifold, (27) Pre-amplifier board housing, (28) Peltier board, (29) ozone
generator board, (30) pump relay board.
Figure 1–5 – AC32e internal view

1.1.3 VARIOUS OPERATING MODES
1.1.3.1 Standard
− Programmable measurement range up to 10 ppm, with a detection limit of 0.2 ppb with a 25 second
response time.
− Automated monitoring of parameters influencing metrology (gas flow, temperature, pressure,
voltage and current) and correct operation tests.
− Measurement values in ppb or µg/m3 (integrated conversion coefficient).
− Memory storage of average measurements with programmable periods.
1.1.3.2 Option
The following analyzer options are available:
− One ESTEL board case, to be connected directly to USB ports on rear panel,
− One RS case, to be connected directly to USB ports on rear panel.
− A permeation bench.
1.1.4 ASSOCIATED EQUIPMENT (OPTIONAL)

− Analog recorders and data loggers.
− Digital data acquisition system.

1.2 CHARACTERISTICS
1.2.1 TECHNICAL CHARACTERISTICS
Measurement range : Programmable by user (maximum 10 ppm)

Units : ppb or µg/m3 (programmable)
Noise (σ) : 0.1 ppb (automatic response time)
Minimum detectable limit (2σ) : 0.2 ppb (automatic response time)
Minimum response time (0-90 %) : 40" (programmable)
Zero drift : < 1 ppb / 24 hours
Span drift : < 1% / 7 days
Linearity : 1%
Repeatability : 1%
Sample flow rate : 0.66 I/min.
Sample flow rate with available sample : 1 l/min.
dryer option
Ozone flow rate : 0.06 l/min.
Chamber pressure : 200 hPa absolute
NOx converter : Molybdenum, regulated at 340°C
Ozone scrubber Heated catalytic
P.M temperature : Controlled to 0°C
Reaction chamber temperature : 60°C
Display : : TFT LCD color screen, resolution : 800 (RGB) x 480,
size : 7 inches
Control : Touch screen
Output signals (option) : 4 analog outputs (0-1 V, 0-10 V, 0-20 mA, 4-20 mA)
Power supply : 100~250Vac, 50/60Hz + ground
Consumption : 250 VA when starting-up the unit
160 VA in normal operation
Working temperature : 0 °C to + 40 °C
Memory storage of measurement values : Capacity: 1 year, 15-minute base
EPROM flash storage
Alarm check : Detection and indication of operating anomalies:
temperatures, pressures, currents, voltages, out of NO,
NOx, NO2 programmable measurement thresholds,
calibration fault.
Maintenance test and diagnostics : Direct selection with the touch screen and/or remote
selection with the embedded Web server.
Back-up saving time for the real-time : 1 year maximum.
clock and RAM-stored data
Ethernet output : RJ45 socket, UDP protocol, Modbus TCP
USB port : Type A USB socket: 2.0 (3.0 compliant)
External Zero/span external SV control : Contact connector with screw terminals

1.2.2 STORAGE CHARACTERISTICS

− Temperature: − 10 °C to 60 °C.
1.2.3 INSTALLATION CHARACTERISTICS

1.2.3.1 Links between unit
The AC32e analyzer uses the external links and power supplies illustrated in Figure 1–6 :
Span gas
External pump
Sample
Pump
230V-50 Hz
outlet
or 115 V-60Hz
Power supply
100~250Vac / 3.15A
Electrical
AC32e connector
socket
USB USB Ethernet

External SV
user option (x2)
span option
Figure 1–6 – Links between units
1.2.3.2 Dimensions and weight

The analyzer comes in a standard 19-inch, three-unit high rack.
Length : 606 mm (approximately 24 inches)
Width : 483 mm (approximately 19 inches)
Height : 133 mm (approximately 5.25 inches)
Weight : 10.3 kg + 4.6 kg (external pump)
1.2.3.3 Handling and storage

The AC32e analyzer must be handled with care to avoid damage to the various connectors and fittings
on the rear panel.
Make sure that the analyzer fluid inlets and outlets are protected with caps during handling.
1.2.4 STORAGE
The unit should be stored in the foam-packed case provided for this purpose.
Make sure that the analyzer fluid inlets and outlets are protected with caps during storage.

Figure 1–7 – AC32e dimensions (in mm)

CHAPTER 2
OPERATION PRINCIPLE
2.1 MEASUREMENT PRINCIPLE 2–3
2.2 GENERAL PRINCIPLE DIAGRAMS 2–7
2.3 MAIN MODULE DESCRIPTION 2–9
2.3.1 NOX CONVERTER – OZONE SCRUBBER – OZONE PURIFIER ASSEMBLY 2–9
2.3.2 PM BLOCK (PHOTOMULTIPLIER) 2–9

2.3.2.1 Reaction chamber 2–9
2.3.2.2 PM enclosure (photo multiplier) 2–9
2.3.3 GAS INLET SOLENOID VALVE ASSEMBLY 2–10
2.3.4 OZONE GENERATOR DRYER 2–10
2.3.5 SAMPLE DRYER (OPTION) 2–10
2.3.6 OZONE GENERATOR 2–11
2.3.7 CYCLE SOLENOID VALVE 2–11
2.3.8 VACUUM PUMP 2–11
2.4 RESPONSE TIME PROGRAMMATION 2–12
2.4.1 PRINCIPLE 2–12
2.4.2 PROGRAMMING THE RESPONSE TIME 2–12
2.5 E SERIES ELECTRONIC ARCHITECTURE 2–13
2.6 NETWORK LINK AND USB PORTS 2–14
Figure 2-1 – Black cycle (zero-reference) diagram 2–4

Figure 2-2 – NO cycle diagram 2–5
Figure 2-3 – NOx cycle diagram 2–6
Figure 2-4 – General principle diagram 2–7
Figure 2-5 – General principle diagram with NO2 permeation bench option 2–8
Figure 2-6 – PERMA-PURE dryer 2–10
Figure 2-7 – Electronic architecture 2–14


2. OPERATION PRINCIPLE
2.1 MEASUREMENT PRINCIPLE
Chemilunescence corresponds to the NO molecules oxidation by ozone molecules.
Ozone in excess is injected with the sample gas into the reaction chamber to chemically react with all
the NO molecules present in the chamber.
NO + O3 → NO2* + O2
Ozone required for chemiluminescence reaction is generated from ambient air by a discharge ozone
generator, according to the reaction:
3 O2 → 2 O 3
Ozone excess is eliminated at reaction chamber outlet by a catalytic scrubber, according to the reverse
reaction:
2 O3 → 3 O 2
The excited NO2* molecules return to their fundamental state:

– Either by luminous radiation on a 600-to-1200 nanometers spectrum:
NO2* → NO2 + hv
– Or by collision with some molecules present in the sample (Quenching) :
NO2* + M → NO2 + M
Collision probability is reduced by lowering the reaction chamber pressure, which allows a better light
output. A decrease in chamber pressure is achieved using a vacuum pump at the circuit end which
allows molecules to enable sample flowing.
An optical filter separates the reaction chamber from the detector. It filters only wavelength radiations
greater than 610 nm wavelength, and thus eliminates hydrocarbon chemiluminescence interferences.
A photomultiplier tube carries out radiation the measurement. The output signal is amplified and digitized
for microprocessor processing.
For NO2 to be measured by chemiluminescence, it must first be reduced to NO. A molybdenum
converter is used for this redox reaction:
Mo + 3NO2 → MoO3 + 3NO
Measurement is split-up into three cycles: Zero-reference cycle, NO cycle, NOx cycle.
(*) Indicates that molecule is in an excited state.

Zero-reference cycle:
The sample is replaced by processed air in Purafil®-filled cartridge which oxidizes NO to NO2. This gas
is injected into the reaction chamber, and it does not generate any chemiluminescence reaction with
ozone because it is NO-free. The photomultiplier tube signal corresponds to the sum of photomultiplier
dark current and electronics shift voltages. This signal is recorded as a black signal.
(1) NO measurement, (2) NO2 measurement, (3) zero filter life-cycle, (4) sample pressure, (5) NOx
converter oven temperature, (6) NOx converter oven life-cycle, (7) reaction chamber temperature, (8)
internal pressure of the reaction chamber , (9) photomultiplier tube voltage, (10) photomultiplier tube
temperature, (11) ozone generator intensity, (12) ozone purifier life-cycle, (13) ozone scrubber life-
cycle, (14) internal analyzer temperature, (15) photomultiplier tube signal for NO cycle,
(16) photomultiplier tube signal for NOx cycle, (17) photomultiplier tube signal for zero-reference cycle
(black signal).
Figure 2-1 – Black cycle (zero-reference) diagram

NO cycle:
The sample moves directly into the measurement chamber where NO oxidation by ozone takes place.
The photomultiplier tube signal, minus black signal, is proportional to NO molecules number present in
sample.
converter oven temperature, (6) NOx converter oven life-cycle, (7) reaction chamber temperature,
(8) internal pressure of the reaction chamber, (9) photomultiplier tube voltage, (10) photomultiplier tube
(black signal).
Figure 2-2 – NO cycle diagram

NOx cycle:
The sample passes through the converter oven which reduces NO2 to NO, then it is mixed with ozone
in the reaction chamber. The photomultiplier tube signal, minus the black signal, is proportional to the
sum of NO and NO2 molecule (reduced to NO in the converter) contained in the sample.
converter oven temperature, (6) NOx converter oven life-cycle, (7) reaction chamber temperature,
(8) internal pressure of reaction chamber, (9) photomultiplier tube voltage, (10) photomultiplier tube
(black signal).
Figure 2-3 – NOx cycle diagram

2.2
Duplication prohibited
SEPTEMBER 2019
Sample Chamber
P pressure P pressure
sensor sensor
Zero filter
NOx
SV zero cycle
Span inlet SV Reaction Photomulitiplier tube
Sample
Refer to Figure 2-4 and Figure 2-5.
restrictor chamber enclosure

Span SV NOx converter oven
Ozone
restrictor
GENERAL PRINCIPLE DIAGRAMS
Scavenging Scavenging
Sample Sample filter restrictor valv e
inlet Sample dryer Air inlet filter
Ozone
(option) Ozone Ozone Ozone
scrubber Vent
drier generator purifier
AC32e
Vacuum manifold External

vacuum pump
Scavenging
dryer filter
Figure 2-4 – General principle diagram
2–7
ENVEA
2–8
ENVEA
External zero filter

Dust filter Option Dust filter Internal
inlet pump Permeation
bench
Restrictor
Purafil + charcoal
Sample Chamber
filter
P pressure P pressure
sensor sensor
Zero filter
NOx
Silicagel filter SV zero cycle
Span inlet SV Reaction Photomulit iplier tube
Sample
restrictor chamber enclosure
Air inlet Span SV NOx converter oven
Ozone
rectrictor Scavenging Scavenging
Sample Sample filter
AC32e
restrictor valv e
inlet Sample dryer Air inlet filter
Ozone Ozone
(option) Ozone Ozone
scrubber Vent
drier generator purifier
Vacuum manifold External

vacuum pump
Scavenging
dryer filter
Figure 2-5 – General principle diagram with NO2 permeation bench option
SEPTEMBER 2019
Duplication prohibited
2.3 MAIN MODULE DESCRIPTION
2.3.1 NOX CONVERTER – OZONE SCRUBBER – OZONE PURIFIER ASSEMBLY

The NOx converter consists of a welded block containing molybdenum grids. This assembly is kept at
340°C. by a heating clamp equipped with a Pt100 probe and glass-wool insulation. Control board
ensures temperature control.
The Ozone scrubber consists of a removable cartridge including a copper and manganese oxide
catalyst. This cartridge is kept at high temperature since it is near the NOx converter.
The Ozone purifier is inserted between ozone generator and reaction chamber. It consists of a
removable glass cartridge including a reagent to hold ozone impurities.
2.3.2 PM BLOCK (PHOTOMULTIPLIER)

The PM Block consists of two sub-assemblies: a reaction chamber and a PM enclosure (photomultiplier)
2.3.2.1 Reaction chamber
The reaction chamber is composed of a golden aluminum block. It includes:

– Sample inlet block which receives three couplers:
• Sample inlet coupler,
• Sample pressure sensor coupler,
• Coupler equipped with sample restrictor limiting flow towards the cycle valve.
– Ozone inlet block which includes ozone restrictor.
– Chamber inlet/outlet fittings and chamber pressure fitting which receive also the couplers.
– Reaction chamber is a cavity closed by a glass window.
– Temperature control to 60°C with heating resistor and Pt1000 probe is ensured by the Controller
board.
2.3.2.2 PM enclosure (photo multiplier)
A reaction chamber glass window separates the PM enclosure from the reaction chamber. A photo
multiplier tube is placed inside a thermo-conductor tube equipped with a red optical filter. The thermo-
conductor tube is kept to 0°C by a Peltier double-stage cooler where heat is radiated from the enclosure
cover. Temperature is controlled by a Pt1000 probe screwed into the cold plate attached to the thermo-
conductor.
The PM enclosure is under vacuum to allow thermal insulation of the thermo-conductor tube. A valve
allows to connect PM enclosure to the vacuum manifold linked to external vacuum pump.
If vacuum pump stops, the valve isolates PM enclosure against a sudden pressure increase while an
auxiliary circuit provides a slight dry air scavenging which prevents back-diffusion of gases contained in
vacuum manifold.
Photo multiplier tube is connected to a power base ensuring its high voltage supply. This power base
conveys output signal via coaxial cable.
The power base is linked with preamplifier board located outside PM enclosure. Preamplifier board
supplies the power base and amplifies PM signal.
The various cables (PM, Peltier, Pt1000) pass through the enclosure by vacuum-tight flanges.

2.3.3 GAS INLET SOLENOID VALVE ASSEMBLY

An assembly of two 3-way solenoid valves is used to select one of the three analyzer inlets: « sample »,
« zero air » or « span gas ». A PTFE filter connected to the « sample » inlet protects against dust.
2.3.4 OZONE GENERATOR DRYER

Air for the ozone generator is dried by a permeation dryer.
This dryer is made of two concentric tubes. The gas to be dried passes through an internal tube made
of Nafion, a special water-permeable polymer. Space between this internal tube and external tube
contains the dryer gas which copunterflows. Dryer gas is obtained by sampling a dried gas part and
expanding it to further reduce its partial humidity pressure.
Figure 2-6 – PERMA-PURE dryer
2.3.5 SAMPLE DRYER (OPTION)

The optional sample dryer is inserted between sample filter and sample port of the gas inlet solenoid
valve assembly. Its operating principle is identical to ozone generator dryer.

2.3.6 OZONE GENERATOR

The ozone generator is composed of two assemblies:
– an electronic board generating an impulse signal from a 24V supply,
– a high-voltage block enclosing a high-voltage transformer and an ozone generator tube.
The ozone generator tube is a double dielectric model: each of the two cylindrical electrodes is
associated with its own dielectric isolating it from gas. Thus, there is no physical contact between gas
and electrodes.
The ozone generator tube, the transformer and the high voltage wiring are enclosed in a casing. They
cannot be dismantled and they require no maintenance.
2.3.7 CYCLE SOLENOID VALVE

The cycle solenoid valve is mounted on a power base ensuring its connection with:
– the inlet and outlet of the NOx converter,
– the sample restrictor and sample inlet of the reaction chamber.
2.3.8 VACUUM PUMP

The vacuum pump is external.

2.4 RESPONSE TIME PROGRAMMATION

In order to optimize its metrology, the AC32e is equipped with a software function called Automatic
Response Time, which enables measurement filtration.
The Response Time Index, or RT, is an index from which to choose the operating mode; consequently
it has no unit. When the index is set to 13 (default), it corresponds to the analyzer’s optimum response
time, giving both a quick response and a low minimum detection limit.
2.4.1 PRINCIPLE
The RT allows the user to change the analyzer response time. The RT value can be programmed from
01 to 20, which falls into two groups:
− Manual RT from 01 to 10
− Automatic RT from 11 to 20
01 to 10: For each 5-second based acquisition, a number of elements equal to RT replaces the same
number of oldest RT values in a group of 60 elements. Therefore, the response time varies from 60 x 5
to 6 x 5 seconds. To calculate the theoretical value of the response time (in seconds), it is necessary to
60
compute: 5 x .
RT
With Manual RT, the user is advised that the greater the RT, the noisier the measurement.
The greater the RT, the quicker the response.
11 to 20: The response time is automatically adjusted depending on the measurements. First of all, a
group of 60 elements is filled every 5 seconds by the [RT] element to form the averaged value calculated
as follow:
1 60
[MEAS ]AVERAGE =  [MEAS ]INSTANTANE OUS
60 1
IMPORTANT! Response Time Index [RT] = 13 determines entire buffer refresh every 5 seconds.
Then a weighted average between the filtered values ( [MEAS ]FILTERED ) and the average value
( [MEAS ]AVERAGE ) is recursively calculated according to the following formula:
[MEAS]FILTERED(t ) = X × [MEAS]FILTERED(t−1) + Y × [MEAS]AVERAGE

with (X + Y) = 100%
When the difference ( [MEAS]FILTERED(t−1) − [MEAS]AVERAGE ) exceeds a determined threshold, the

value of Y is increased up to a 99 % to rapidly reach the concentration read.
When ( [MEAS]FILTERED (t-1) − [MEAS]AVERAGE) is below the threshold, the value Y is progressively
decreased to optimize filtration and noise
The more stable the measurement, the more X tends toward 99 %.
2.4.2 PROGRAMMING THE RESPONSE TIME

The Automatic Response Time function can be activated or inhibited in the «Analyzer Advanced
configuration» screen. The minimum response time can also be modified in this menu.

2.5 E SERIES ELECTRONIC ARCHITECTURE
Communication between the ARM20 board and the other electronic boards (Measurement board,
Interconnection board, Power supply board, Controller board, Pressure sensor board….) follows the
schematic shown in Figure 2-7.
The ARM20 board is a rapid calculation and interfacing (communication) board for the “e” series
measurement modules. It is installed in all analyzers and offers one Ethernet output (RJ45 socket), and
three USB ports (one on the front panel, and two on the rear panel through the Interconnection board).
For these analyzers, the ARM20 board is the central element for electronic and metrological operation,
and outward communication.
The measurement board performs measurement acquisition and operation parameter acquisitions. All
metrological parameters are sent to the ARM20 board through a USB communication protocol.
The power supply board provides internal analyzer voltages from the 24 V cut-out power supply, as
follows:
− +24 V filtered and secured,
− +12 V, for ARM20 board supplying,
− +5 V,
− +3.3 V.
The Controller board performs the main following functions:

− Provides (+ 24V) various power control for the internal solenoid valve switchings.
− Allows temperature acquisition and control management of the various internal heating elements.
− Allows pressure signal acquisition from the various pressure sensor boards.
− Integrates one USB hub to ensure communications between the various boards.
The Interconnection board allows interfacing of the Power-supply board, Arm20 board, Controller board
and Measurement board, and allows connection of all the connectors and sensors together.
Additionally to the e series standard electronics, AC32e is equipped with the following specific boards:
– The PM preamplifier board amplifies the photo multiplier tube signal and ensures the supply of its
high voltage power base.
– The RTP (Peltier temperature regulation) board:
• Converts the PWM (Pulse Width Modulation) signal from the controller board in direct current to
supply the Peltier module of the photomultiplier tube cooling.
• Recovers the temperature signal PM from the Pt1000 probe,
• Applies a positive temperature offset to manage negative temperatures.
• Sends the offset temperature signal to the Controller board.

CONTROLLER BOARD
Measurement module
MEASUREMENT BOARD
COLOR SCREEN
HUB USB, USB Communication,

DALLE TACTILE Various controls, USB communication,
24 V, 12 V, 5 V and 3.3 V supplies Various controls,
TOUCHSCREEN 12 V, 5 V, 3.3 V supplies
POWER SUPPLY BOARD Ext. Zero/span

SV external SV control
24V
i2C Bus
24 V, 12 V, 5 V and 3.3 V supplies
INTERCONNECTION BOARD USB USB port
LVDS Communication
USB USB port
Ethernet output
Ethernet
IP (protocole UDP )
Ethernet 24 V
USB Communication,
USB Port , 12 V supply
24 V supply
ARM 20 BOARD USB
USB
12 V
Cut-out 230 V or
USB Port USB 24 V
Ethernet Ethernet - IP link
power supply 115 V
Figure 2-7 – Electronic architecture
2.6 NETWORK LINK AND USB PORTS

− Network link (Ethernet) :
One RJ45 connector is interfaced on the analyzer rear panel via the Interconnection board. Network
communication (Ethernet) uses UDP protocol.
− USB ports:
Three USB ports are available in the “e” series electronic architecture.

CHAPTER 3
OPERATING INSTRUCTIONS
3.1. INITIAL START-UP 3–3
3.1.1. PRELIMINARY OPERATIONS 3–3
3.1.2. UNIT START-UP 3–6
3.2. PROGRAMMING THE AC32E 3–11

3.2.1. SCREEN AND KEYBOARD DESCRIPTION AND USE INSTRUCTIONS 3–11
3.2.1.1. Control screens 3–11
3.2.1.2. Keyboard input 3–12
3.2.2. PROGRAMMING OPERATING PARAMETERS 3–14

3.2.2.1. Fields requiring character input 3–14
3.2.2.2. Fields requiring parameter selection in a list 3–14
3.2.2.3. OFF/ON status buttons 3–14
3.3. BROWSING ERGONOMY 3–15
3.4. DESCRIPTION OF ANALYZER FUNCTIONS AND SCREENS 3–20
3.4.1. STANDARD FUNCTIONS 3–20

3.4.1.1. Analyzer controls 3–20
3.4.1.2. Measurement display 3–22
3.4.1.3. Real time graph display 3–25
3.4.1.4. Analyzer synoptic diagram 3–28
3.4.1.5. Information panel 3–29
3.4.1.6. Contextual help operation 3–30
3.4.2. ADVANCED FUNCTIONS 3–31

3.4.2.1. Password management 3–31
3.4.2.2. General configuration 3–32
3.4.2.3. Automatic cycle configuration 3–34
3.4.2.4. Language selection 3–35
3.4.2.5. Find and display recorded averages 3–35
3.4.2.6. Delete all recorded averages 3–37
3.4.2.7. List of connected clients 3–37
3.4.2.8. Open diagnostic pages (alarm, input / output, mux…) 3–38
3.4.2.9. Setting the analyzer in stand-by mode 3–42
3.4.2.10. Setting the analyzer in maintenance mode 3–42

3.4.2.11. Advanced analyzer configuration 3–43

3.4.2.12. Optional Estel board configuration 3–45
3.5. CALIBRATION 3–48
3.5.1. OVERVIEW OF CALIBRATION AND CONCEPTS 3–48

3.5.1.1. Zero air generation 3–50
3.5.1.2. Span gas (NOx) generation 3–51
3.5.1.3. Internal solenoid valves 3–52
3.5.2. ZERO AND SCALE POINT CHECK 3–53

3.5.2.1. Equipment required 3–53
3.5.2.2. Procedure 3–53
3.5.2.3. Use of automatic cycles 3–54
3.5.3. TWO-POINT CALIBRATION 3–56

3.5.3.1. Equipment required 3–56
3.5.3.2. Procedure 3–56
3.5.4. MULTI-POINT CALIBRATION 3–60

3.5.4.1. Presentation 3–60
3.5.4.2. Procedure 3–60
3.5.5. CHECK THE CONVERSION EFFICIENCY OF MOLYBDENUM OVEN BY GPT 3–61

3.5.5.1. Device 3–61
3.5.5.2. Procedure 3–61
Figure 3–1 – Fluid and electrical connections 3–4

Figure 3–2 – Sample gas inlet installation 3–5
Figure 3–3 – Example of a pressurized gas connection 3–49
Figure 3–4 – Calibrator connection diagram 3–52
Figure 3–5 – Typical GTP diagram 3–62

3. OPERATING INSTRUCTIONS
3.1. INITIAL START-UP
The analyzer is checked and calibrated before delivery. Calibration is verified at the factory.
3.1.1. PRELIMINARY OPERATIONS

Refer to Figure 3–1.
It is necessary to leave a free space of at least 10 cm (4 in.) between the rear panel and the wall behind
the analyzer to ensure correct analyzer ventilation.
Start-up involves the following preliminary operations:
– Visually examine the inside of the instrument to make sure no damage occurred during transport.
– Remove the caps from the gas inlet and outlet (1) (3) on the unit (set aside for future storage).
– Make sure a Teflon filter diaphragm is inside the dust filter, and then connect the 4 mm (I.D.) and 6
mm (O.D.) air sampling tube to the sample inlet (1).
– Connect the Ethernet output (7).
– If necessary, connect accessories via USB ports (8),
– Connect the analyzer supply plug (5) with the mains cable to a mains socket fitted with ground.
– Check that the voltage and the frequency indicated on the external pump casing correspond to those
of the available mains. Then connect the power supply (13) of the external pump to the rear panel.
– Connect the external pump (15) with a 4 mm (I.D.) and 6 mm (O.D.) Teflon tube.
– Connect the pump outlet (16) to vent with a 6 mm (I.D.) and 8 mm (O.D.) Teflon tube.
NOTE : The analyzer power supply is compatible with mains: 100-240V voltage/50-60 Hz frequency.
BUT, the available mains must be compatible with the voltage and frequency indicated on
the pump casing.

(1) sample inlet, (2) air inlet for ozone generator, (3) span inlet, (4) optional inlet for external zero air
generator, (5) three-contact socket for main power supply, (6) general fuse, (7) Ethernet output, (8) two
USB ports, (9) general fan, (10) connector for external zero and span solenoid valves control, (11) 24
V power supply for ESTEL board option, (12) zero air inlet for optional permeation bench,, (13) external
pump supply, (14) Peltier fan, (15) external pump fluid connection, (16) pump vent.
Figure 3–1 – Fluid and electrical connections

Figure 3–2 – Sample gas inlet installation

NOTE : Recommended height for sampling tap: 2.50 m
Maximum recommended length of Teflon sampling pipe: 6 m.

3.1.2. UNIT START-UP

To start-up the unit, carry out the installation/commissioning procedure described below in the following
order.
1/ Press the ON/OFF push button located on the front panel. The analyzer starts running, it begins the
warm-up cycle (duration of which is 1800 seconds maximum). The home page is displayed: it indicates
the warm-up progression.
Warm-up is terminated when all the metrology parameters are within the operating limits. The warm-up
icon disappears and the analyzer carries out an automatic zero reference:
When the zero reference ends, the zero reference icon disappears and the following screen is displayed.

This screen is the analyzer home page. It contains additional pages displayed by activating the top
buttons, from to . These pages display the measurement channel values, the real-time graph of
the instantaneous measurement values, and the analyzer synoptic diagram giving the main parameter
values. These are the analyzer standard functions.
From the touch screen mounted on the analyzer front panel: no password is required to access the
home page.
From a remote PC: a password is required. The user inputs in field (1) one of the passwords indicated
at page 3–9, and validates with to access the home page.

Button and icon definitions specific to these screens
: displays fluid inlet selection controls:

selects sample inlet, selects zero inlet, selects span inlet.
: status icon indicates that the analyzer is warming-up.
: status icon indicates that the analyzer operates normally.
: information area indicates model and current analyzer time.
: icon views warm-up progression.
: button stops the warm-up cycle in progress.
: button displays cycle start controls:

starts calibration cycle, starts zero reference cycle.
: button displays contextual help.
: button displays analyzer information panel.
: button accesses the advanced analyzer functions.

2/ Access to the advanced analyzer functions

From the touch screen mounted on the analyzer front panel:
Touch to display the password input window (1), then touch the field (2) to display the keyboard
(3) in the lower half-part of the screen. Touch to switch from alphanumeric to numeric keyboard
if necessary. Enter the password and validate with : the password window and keyboard close,
and the advanced function screen opens.
Activating closes the password window without input validation.
From a remote PC: do the same with the PC keyboard and mouse.
NOTE : Access to the advanced functions depends on the hierarchical level of the user’s password.
There are three hierarchical levels: User, Advanced, and Expert.
The factory passwords available in the analyzer on delivery are the followings, symbolized by
the icons:
Password level Login Icon
User 12345
Advanced 78300
Expert 00007
On the initial start-up, it is strongly advised to change the factory passwords: activate in
the advanced function access screen to display the password management window, input the
new passwords in the corresponding fields, and activate to validate the input and close
the password management window.

The advanced function access screen is shown below.

The allowed functions are white on blue background (refer to area 2). As explain above, they depend
on password level. They are contact-activated.
When a function is activated, it changes color from blue (e.g.) to green (e.g.), while its name
is displayed in area (1) at screen top and is activated to .
By clicking again on (e.g.), or activating , the user accesses the corresponding function
screen.

3.2. PROGRAMMING THE AC32E

3.2.1. SCREEN AND KEYBOARD DESCRIPTION AND USE INSTRUCTIONS
The touch screen mounted on the front panel is also used to visualize the control screens and the virtual
input screen allowing input and modification of the analyzer parameters. The control buttons are
activated by touching.
When the analyzer is connected to a remote computer, parameters are modified with the computer
keyboard, and control buttons are activated by clicking on with the mouse.
3.2.1.1. Control screens
The control screen areas are defined as follows:
(1) : Browsing bar of several-page screens. The user accesses the desired page by activating
its corresponding button from to .
(2) : Measurement or configuration area. This area displays the measurement parameters (gas,
value, units...) or the configurable parameters associated with the selected menu.
(3) : Manual controls, information and browsing bar. This bar allows inlet fluid selection and
manual launching of calibration and zero reference cycles, information panel and status
display, and advanced or standard functions access.
Manual controls, information and browsing bar (3) is available in all screens. Details are given in section
3.3 related to ergonomy browsing.

3.2.1.2. Keyboard input

From the analyzer touch screen, a virtual touch-sensitive keyboard is displayed instantly in the bottom
half screen part (2) when the user touches a field to be filled in or modified.
Two keyboard types are available: numeric keyboard if numeric entry is required or QWERTY keyboard
if alphanumeric entry is required.
Examples below show the keyboard display in the « General configuration » screen.
When the user touches any keyboard key, the button (1) becomes . It is used to validate
entries and close the virtual keyboard. Button (3) is used to close keyboard without validation.
NOTE : Field inputs are indexed.
These keyboard keys work like Android system keys found on tablets and smart-phones.
Numeric keyboard is shown below (2):
Alphanumeric keyboard is shown below (2):
(1) entry validation button, (2) numeric keyboard with touchscreens, (3) button to close keyboard without
validation.

Button definitions specific to the virtual keyboard
: switches from alphanumeric to numeric keyboard.
: switches from numeric to alphanumeric keyboard.
: switches from numeric to symbol keyboard.
: enters inputs.
: clears inputs.
From a remote computer, the user uses the computer keyboard with mouse.

3.2.2. PROGRAMMING OPERATING PARAMETERS

Two possible fields are available to input or modify parameters.
3.2.2.1. Fields requiring character input

In front of the analyzer touchscreen, touch the input field to be modified. The virtual input screen is
displayed with the QWERTY keyboard if alphanumeric entry is required, or the numeric keyboard if
numeric entry is required. If letters and numbers are required in the same field, touch the key
to switch from numeric to alphanumeric keyboard, and the key to switch from alphanumeric to
numeric keyboard. Input with the virtual touch keys, enter by touching the button, and
validate with . The virtual keyboard closes and the modified field is displayed properly filled in.
When modification is done from a remote computer, the computer keyboard and mouse is used.
3.2.2.2. Fields requiring parameter selection in a list

Touch the field to be modified. The list of parameters or values to be selected is displayed with the
current parameter or value in blue background. Touch the desired parameter or value to select it. The
new parameter or value is displayed in blue background. Validate with . The list closes, and this
new parameter or value replaces the previous.
3.2.2.3. OFF/ON status buttons

To switch OFF to ON, touch (or click on) the OFF button. The ON field becomes white in blue
background. And vice versa.
NOTE : After any modification performed in the same screen, the user must ALWAYS validate with
to take into account modification.

3.3. BROWSING ERGONOMY

The AC32e home page is the following:
The home page displays up to three measurement channels.
From the touch screen mounted on analyzer front panel, the home page gives access to the standard
functions without using a password.
From a remote computer, the following page is displayed first:
The user enters the password in field (1) and validates with to open the home page.

The home page is composed of two browsing bars:

− Top screen browsing bar
By activating to , the user drags the display sideways to view the other pages: measurement
channels, real time graph and analyzer synoptic diagram. This browsing bar is specific to the home
page.
− Bottom screen browsing bar

As indicated in 3.2.1.1 section, this bar allows manual selection of fluid inlet, manual launching of
calibration and zero reference cycles, information panel and status display, and advanced or
standard functions access. This browsing bar is available in all screens.
Button, control and icon functions of this browsing bar are as follows:
: button displays fluid inlet selection controls:

selects sample inlet, selects zero inlet, selects span inlet.
Status icon location. The various status icons are as follows:
: icon indicates that the analyzer operates normally.
: icon indicates that the analyzer is warming-up.
: icon indicates that the analyzer is in control mode.
: icon indicates that the analyzer is in alarm mode.
: icon indicates that the analyzer is disconnected from network.
: icon indicates that the analyzer is in maintenance mode.
: status icon indicating that the analyzer is in stand-by mode.
: icon views warm-up progress.
: button stops the warm-up cycle in progress.
: button indicates analyzer password level and displays the window to change this
password (shown below).

: button displays cycle start controls:

starts calibration cycle, starts zero reference cycle.
: button displays contextual help.
: button displays analyzer information panel.
: button accesses the advanced analyzer functions.
: button accesses the home page.
The user displays the advanced function access screen by touching / clicking on the button. The
user-accessible function buttons are white-framed in blue background. They depend on the password
level assigned to the user. Each button allows access to the associated screen.
The advanced function access screen is the following:

When a button is activated, it changes color from blue (e.g.) to green (e.g.), while its function
displayed at screen top and is activated to .
By touching / clicking on or touching / clicking on again (e.g.), the user accesses the
corresponding screen.
Refer to the example given below « General configuration (Address, Protocol, Measurement
channels…) »:
NOTE : For memory, as explained in page 3–9, access to the advanced functions depends on the
hierarchical level of the user’s password. There are three hierarchical levels: User, Advanced,
and Expert.
The factory passwords available in the analyzer on delivery are the followings, symbolized by
the icons:
Password level Login Icon
User 12345
Advanced 78300
Expert 00007
On the initial start-up, it is strongly advised to change the factory passwords: activate in
the advanced function screen to display the password management window, input the new
passwords in the corresponding fields, and activate to validate the input and close the
password management window.

Button functions are as follows:
: Restores factory settings.

It is recommended to backup before executing this operation.
: Passwords management.
: General configuration.
(Address, Protocol, Measurement channels...)
: Automatic cycle configuration.
: Language selection.
: Finds and displays the recorded averages.
: Deletes all recorded averages.

(Warning! this operation can’t be cancelled)
: List of connected clients.
: Open diagnostic pages.

(Alarm, input / output, mux...)
: Sets the analyzer in stand-by mode.
: Advanced analyzer configuration.
: Configuration and software backup on USB key.
: Restores software and configuration from USB key.
: Records instantaneous measurement on USB key.
: Gives USB key characteristics (free and total memory) when connected to the analyzer.
: Sets the analyzer in maintenance mode.
By touching / clicking on , the user returns to the home page.

3.4. DESCRIPTION OF ANALYZER FUNCTIONS AND SCREENS

3.4.1. STANDARD FUNCTIONS
3.4.1.1. Analyzer controls

Reminder:
– Touch/click on to display , , and access the corresponding controls.
– Touch/click on to display , , and access the corresponding controls.
The analyzer controls are the followings:
Controls Function description
This function switches the analyzer to the sample gas inlet. The gas is
continuously sampled through the inlet dust filter.
Selects sample inlet This mode can be interrupted at any time by manually selecting another gas
inlet (zero or span).
The measurement unit is selected in the « Advanced analyzer
configuration » screen.
This function switches the analyzer to the zero gas inlet.

This operation allows for checking the stability and the zero drift to
Selects zero inlet determine the need to launch a zero reference cycle or program its
repetition period.
This function switches the analyzer to the span inlet. The measured span
gas value, possibly increased by a programmed offset, is displayed on the
Selects span gas screen.
inlet This operation allows for checking the stability and the span drift to
determine the need to launch an auto-span cycle or programming its
repetition period.
An external calibrated span must be connected to this inlet.
This function launches manually an automatic span cycle.

The user touches / clicks on and views the cycle progression in the
Launches a
calibration cycle
scroll bar . At any time, it is possible to abort the
current cycle by touching / clicking on , or stop and validate the current
cycle by touching / clicking on .
The current cycle stop results in the Span Coeff. value modification in the
« Advanced analyzer configuration » screen.

Controls Function description
During an automatic calibration cycle, the analyzer adjusts its Span Coeff.
automatically to equal its reading value (minus the programmed offset) with
span gas concentration.
Launches a
calibration cycle The span gas concentrations are programmable in the « Advanced analyzer
(following) configuration » screen. Adjustment of the cycle duration takes place in the
Duration field of the « Automatic cycle configuration » screen.
The cycle is finished when the scroll bar is completely grey, . It

closes automatically.
This function allows manual launching of an automatic zero correction cycle

to adjust the zero drift.
Launches a zero
The user touches / click on and views the cycle progression in the
reference cycle
scroll bar .
At any time, it is possible to abort the current cycle by touching / clicking on

, or stop and validate the current cycle by touching / clicking on .
The cycle is finished when the scroll bar is completely gray ,

and closes automatically.

3.4.1.2. Measurement display

By default, the home page displays the NO, NOx, NO2 measurement channels. Column (1) gives the
instantaneous measurement values and column (2), the average measurement values.
To display additional measurement channels, it is necessary to first select them in the Measurement
channel section of the « General configuration » screen, as shown below (refer to green frame with
arrow):
Button definitions specific to this section:

: deletes the selected measurement channel.
: moves upwards the selected measurement channel.
: moves downwards the selected measurement channel.
: opens the selection window to add measurement channels.

To select additional channels, touch/click on to open the measurement channel selection window.
There are five measurement channel groups: Compounds, Voltage, Sensor, Calculation, and Analog
inputs. By default, the compound group field is set to ON, the NO, NOx, NO2 measurement channels
are selected and displayed in the measurement channel section (refer to green frame with arrow in the
above screen).
To select the other measurement channels, switch to in any other measurement

channel group field to display the corresponding available channels, touch/click on the channels to be
selected : they are displayed in white on blue sky background. Touch / click on to validate this
selection and close the window. The key closes the window without validating.
It is possible to select all the available channels as shown below. Once they are selected, the channels
no more appear in the right frame avoiding selection of the same channel twice.
Details of the various measurement channel groups are shown below:
– Voltage measurement channel selection:

– Sensors measurement channel selection:
– Calculation measurement channel selection:
The selected measurement channels are placed in the numbered fields (refer to frame with arrow in the
screen below). Touch / click on in the right side of the screen to validate the whole selection.
is used to quit the screen without validating.

Touch / click on to view the measurement channel display in the home page : only three
measurement channels are displayed per page. To display all of the selected channels, the GUI (graphic
user interface) adds as many pages as necessary. These additional pages are symbolized by the
buttons and displayed at the screen top (refer to frame with arrow). The user touches / clicks-
on these buttons to display pages successively.
3.4.1.3. Real time graph display

The user views the measurement channel graphs by touching / clicking on the next-to-last button in the
top screen browsing bar (refer to frame with arrow). If no channel selected, the below message is
displayed:

Touch / click on the channel names to be selected: they turn green, as shown in the screen below:
Go back to the next-to-last page to view the corresponding curve display. By default, the Y-scale setting
is automatic, and thus is adjusted in real time to allow each selected channel curve to be displayed
inside the screen.
A maximum of six curves can be displayed simultaneously.
To configure the Y-axis, the user touches / clicks in the current graph: the modifiable parameters are
displayed at screen top. Then the user switches OFF the Autoscale field, sets the minimum and
maximum Y-axis scale values (10 and 26 in the example on next page), and validates the modifications
with .

To activate the zoom function, the user selects the area to zoom by touching / clicking on it, or using the
mouse pointer: it greys the selected area. The user validates the selection by touching / clicking on
to display the zoomed graph.
The user exits the zoomed graph by touching / clicking again in the screen.

3.4.1.4. Analyzer synoptic diagram

The user views the synoptic diagram by touching / clicking on the last button in the top screen browsing
bar. This screen displays the entire fluid circuit and the significant operating parameter values.
Screen legends are as follows:

(1): NO measurement,
(2): NO2 measurement
(3): Zero filter life-cycle,
(4): Sample pressure,
(5): NOx converter oven temperature,
(6): NOx converter oven life-cycle,
(7): Reaction chamber temperature,
(8): Pressure inside reaction chamber,
(9): Photomultiplier tube voltage,
(10): Photomultiplier tube temperature,
(11): Ozone generator intensity,
(12): Ozone purifier life-cycle,
(13): Ozone destructor (ozone scrubber) life-cycle,
(14): Internal analyzer temperature,
(15): Photomultiplier tube signal for NO cycle,
(16): Photomultiplier tube signal for NOx cycle,
(17): Photomultiplier tube signal for Zero-Ref. cycle.

3.4.1.5. Information panel
The information panel is displayed by touching / clicking on in the bottom browsing bar. It allows
the user to view the software version, analyzer serial number, TCP/IP analyzer address, current date
programmed in the analyzer, memorization period for data archiving, remaining days up to the next
maintenance, if YES or NO an USB function is active on the analyzer, number of clients connected.
Definitions of icons and buttons specific to the information panel
: indicates that a WIFI key for remote connection from tablet or smartphone equips the
analyzer. ESA_AC32e_7 and 192.168.43.1 are WIFI TCP/IP identifier and address
required for connection.
: is used to email analyzer status (mux signal values).
: is used to email recorded events (history)
: sounds signal to locate the corresponding analyzer when not fitted with screen.
: closes the information panel.

3.4.1.6. Contextual help operation
The user activates the contextual help by touching / clicking on which turns green . Then, the
user touches / clicks on button (e.g. 1) or screen part to know the operation or use: a window (2) opens
to give the desired information.
The contextual help window closes by touching / clicking on (3).
NOTE : The contextual help is disabled by touching / clicking on again.
See the example below:
(1) Button selected to know the operation or use, (2) message giving the desired information, (3) button
used to close the contextual help window.

3.4.2. ADVANCED FUNCTIONS
The user accesses the advanced function access screen by touching / clicking on .
The advanced functions can only be accessed by allowed users with a password. As indicated in page
3–9, three hierarchical password levels are available: User, Advanced, and Expert.
All the advanced functions available for Expert users are described below.
3.4.2.1. Password management
The user touches / double-clicks on to open this window.
The passwords indicated in the screenshot below are the factory passwords available in the analyzer
on delivery. Upon initial startup, it is recommended to modify these factory passwords (refer to page 3–9).
The user modifies the password fields by filling-in them and validating entry with .
closes the window without validating the modifications.

3.4.2.2. General configuration
The user accesses this screen by touching / double clicking on . This button icon remains displayed
at the top right side of the screen.
This screen allows configuration of addresses and protocols required for communication, and
measurement channels configuration.
: This button is displayed when the analyzer is connected to a PC or a tablet. By touching / clicking
on it, the user updates the analyzer date and hour with the current date and hour of the PC or the tablet.
DATE and TIME fields: they are used to set the internal date and hour of the analyzer.
ARCHIVE PERIOD field: it is used to set the period of the stored averages (archives) of the analyzer.
NETWORK section: allows the automatic network configuration.

– DHCP field ON: allows connecting the analyzer to a TCP/IP network address managed by a DHCP
server.
– DHCP field OFF: allows displaying the ADDRESS, MASK and GATEWAY fields. Thus, the user
defines the TCP / IP address, gateway and mask required for connection.
UDP SERVER section: allows configuration of the two available UDP ports, Port A and Port B.
– PORT number field: can be fixed within the range 1000 to 9999.
– ADDRESS field: is only used for Mode4 (four alphanumeric characters) and JBUS (number 0000 to
0255).
– PROTOCOL field: Mode 4, PRN, JBUS and BAYERN are available.
TCP/IP MODBUS SERVER section: allows configuration of this communication protocol.

OPERATION section:
– MEASUREMENT MODE field: indicates the analyzer operating cycle. Depending on its options, the
analyzer can carry out 3 types of measurement cycles:
• NO cycle: sample enters the reaction chamber directly.
• NOx cycle: sample passes through the NOx converter oven, then enters the reaction chamber.
• Ny cycle: sample passes through the CNH3 oven, then the NOx converter oven and enters the
reaction chamber.
A combination of these cycles results in the following measurement modes: NO, NO/NO2, NH3,
NO/NO2/NH3. The default mode is NO/NO2.
The table below schematizes this:
Cycle NO NOx Ny
Measurement mode
NO
1 0 0
NO/NO2
1 1 0
NH3
0 1 1
NO/NO2/NH3
1 1 1
− CUSTOM IDENT. field: allows entering the identification user code.

− NEG. VALUES field: negative values are allowed when this field is ON, and not allowed when it is
OFF.
− ALARM field: alarm management is activated when this field is ON, and deactivated when it is OFF.
– REMOTE CONTROL field: allows configuring the remote control logic inputs.
– AUTOMATIC LOCK (SEC) field: it enables the user to set the duration in seconds between two
password entries.
MEASUREMENT CHANNEL section: allows configuration of the measurement channel display.

3.4.2.3. Automatic cycle configuration
The user accesses this screen by touching / double-clicking on . This button icon remains displayed
This screen allows the analyzer configuration of four periodic cycles: Zero, Span, Zero-Ref., and
Calibration. These cycles can be triggered in automatic or manual mode.
INLET field: allows selecting the channel used for the cycle (Zero, Span, Ref-Zero, Calibration).
PROGRAMMED INLET field: when ON, the programmed analyzer inlet is used when the cycle is
launched manually. When OFF, the active analyzer inlet is used.
REMOTE CONTROL field: allows triggering cycle on a remote-control inlet (when optional ESTEL
board(s) is/are available...).
CYCLIC field: activates or de-activates triggering of cycle in automatic mode.
DURATION field: allows fixing cycle time.
PURGE DURATION field: allows fixing purge time. Purge is applied before the cycle.
PERIOD field: allows fixing automatic triggering periods.
START HOUR field: allows fixing start hour to trigger cycles automatically. If several cycles are in
automatic mode, they will be triggered in the following order: Zero-Ref, Calibration, Zero, and Span.
AT STARTUP field: is used to force a Zero-Ref cycle upon analyzer starts up (at end of its warm-up
cycle). This function is optional.

3.4.2.4. Language selection
The user displays this window by touching / double-clicking on .
This window allows changing the analyzer language: the available languages are English and French.
The red frame around the flag indicates the language in use. The user touches/clicks-on the other flag
to select the desired language and close the window. Then, the « Language selection » message is
displayed at the top of the screen when English is selected, and « Choix de la langue » when French is
selected.
3.4.2.5. Find and display recorded averages
This screen allows setting the recorded average period the user wants to watch, and displays the data
for the measurement channels previously selected.
The user touches/clicks on the Start and/or Stop fields to select or modify the recorded averages start
and end periods, then he touches / clicks on to validate, close the window and display the data
screen.
closes the window without selection validation.

The user touches/ clicks on to display the next measurement channel data, and on to display
the previous measurement channel data.
allows user to quit the screen and return to the advanced function access screen.
Button definitions specific to this screen:
: opens the window to select another period.
: allows exporting the displayed data to a TXT file.

Icon functions:
: indicates an average stored with an alarm status. Alarm details are displayed by touching
/ clicking on this icon.
: indicates an average stored with a control status. Control details are displayed by
touching / clicking on this icon.
: indicates an average stored with a calibration status. Calibration details (zero, span) are
displayed by touching / clicking on this icon.
3.4.2.6. Delete all recorded averages
The user deletes all the recorded averages by touching / double-clicking on .
WARNING: this action is irreversible.
3.4.2.7. List of connected clients
The user displays this window by touching / double-clicking on . It displays the IP addresses and
inactivity duration of the connected clients.
allows user to close this window.

3.4.2.8. Open diagnostic pages (alarm, input / output, mux…)
The user accesses this screen by touching / double-clicking on .
This screen consists of two pages: the first page lists the current alarms and significant events, and the
second page displays the electric signal values and remote control inputs/outputs.
allows user to quit the screen and return to the advanced function access screen.
Button definitions specific to this first page:
: displays or hides all the archived events.
: displays or hides the simple events. Acts as a filter.
: exports the displayed data as TXT file.
All the second-page screenshots are presented below.
Screenshot 1 legends and units:

Marks Legends Units
1 24V power supply control (ON) Not applicable
2 24V power supply voltage Volt
3 24VDC power supply current Ampere
7 3.3V power supply voltage Volt
8 5V sensor power supply voltage Volt
9 Pump detection (ON) Not applicable

Marks Legends Units
10 Pump control (ON) Not applicable
11 Sample flow rate Normal liter/minute (SLPH)
12 Sample pressure (abs.) hectoPascal (abs.)
13 Reaction chamber pressure hectoPascal (abs.)
14 Add a decimal point Not applicable
SLPH: Standard Liter Per Hour

Marks Legends Units
1 Ozone generator detection (ON) Not applicable
2 Ozone generator control (ON) Not applicable
3 Ozone generator current Milliampere
4 NOx converter detection (ON) Not applicable
5 NOx converter temperature control (ON) Not applicable
6 NOx converter temperature Celsius degree
7 Peltier cooler detection (ON) Not applicable
8 Peltier cooler temperature control (ON) Not applicable
9 Peltier cooler current Ampere
10 Peltier fan detection (OFF) Not applicable
11 Peltier fan control (ON) Not applicable
12 Photomultiplier tube (PM) temperature Celsius degrees
13 Power supply command of photomultiplier tube (ON) Not applicable
14 Photomultiplier tube (PM) Voltage Volt

Marks Legends Units
15 Temperature control of reaction chamber (ON) Not applicable
16 Reaction chamber temperature Celsius degrees
Screenshot 2 in stand-by mode (1) is shown below: controls are lit-up (2) and can be modified.

Marks Legends Units
1 NOx solenoid valve detection (ON) Not applicable
2 NOx solenoid valve command (ON) Not applicable.
3 NH3 solenoid valve detection (OFF) Not applicable
4 NH3 solenoid valve command (OFF) Not applicable
5 Dark signal Millivolt
6 Response time filter %

Marks Legends Units
7 NO signal Millivolt
8 NO concentration ppb
9 NOx signal Millivolt
10 NOx concentration ppb
11 Ny signal Millivolt
12 Ny concentration ppb

Marks Legends Units
1 Rack fan detection (ON) Not applicable
2 Rack fan control (ON) Not applicable
3 Rack internal temperature Celsius degrees
4 Zero solenoid valve detection (ON) Not applicable
5 Zero solenoid valve control (OFF) Not applicable
6 Span solenoid valve detection (ON) Not applicable
7 Span solenoid valve control (OFF) Not applicable
8 Permeation bench detection (OFF) Not applicable
9 Permeation bench temperature control (OFF) Not applicable
10 Permeation bench temperature (invalid) Celsius degrees

3.4.2.9. Setting the analyzer in stand-by mode
The user activates stand-by mode by touching / double-clicking on which becomes .
Stand-by mode is used to stop the pump while all the other controls remain in operation. The user
reactivates the measurement mode by touching / double-clicking on .
When stand-by mode is activated, the status icon (in bottom left side of screen) is modified to .
However, alarm or control status icons are priority. Consequently, if stand-by mode is activated while
an alarm or a control is active, the alarm icon or control icon will remain displayed and the
stand-by icon will not be displayed. To verify if the measurement or stand-by status is active, the
user checks if the button is outlined in red or not in the advanced function access page.
3.4.2.10. Setting the analyzer in maintenance mode
The user activates the maintenance mode by touching / double-clicking on which becomes .
When the maintenance mode is activated, the recorded data is tagged with a status mark: Maintenance
is indicated close to the concerned data.
The user reactivates the measurement mode by touching / double-clicking on .
When the maintenance mode is activated, the status icon (in bottom left side of screen) is modified to
. However, alarm or control status icons are a priority. Consequently, if maintenance mode is
activated while an alarm or a control is active, the alarm icon or control icon will remain
displayed and the maintenance icon will not be displayed. To verify if the measurement or
maintenance status is active, the user checks if the button is outlined in red or not in the advanced
function access page.

3.4.2.11. Advanced analyzer configuration
This screen allows configuration of the metrological parameters.
NO, NOx and NO2 COMPOUND sections:

– UNIT field: selects the compound measurement unit.
– THRESHOLD 1 and THRESHOLD 2 fields: fixes a limit value to the measurement. If measurement
value is out of this limit, an alarm triggers.
– CONV. COEFF field: displays the coefficient used for unit conversion (for ex.: ppb  µg/Nm3). This
function is active if unit is µg/m3, mg/m3, g/m3.
– OFFSET and SPAN COEF. fields: these two values are used to calibrate the measurement with the
linearization curve Y = Ax + B. A is the span coefficient, B is the offset. The span coefficient can be
modified by the user or by a calibration cycle.
– ZERO ADJUST field: allows setting manually the compound baseline (zero).
– DELTA (%) field: when the span coefficient is modified by a calibration cycle, this value indicates
the difference between the new coefficient and the previous coefficient. If this value is greater than
50%, a span alarm is triggered. It is necessary to manually re-validate the span coefficient to disable
this alarm. When the analyzer is in alarm, it does not take into account the new calculated calibration
coefficient, but keeps the previous calibration coefficient.
SPAN GAS VALUE field: this setting specifies span gas cylinder concentration used to perform
calibration check. This concentration is the reference value to be reached.
CALIB. ON/OFF field: this field is used when the analyzer can measure many gases. It allows performing
a gas-by-gas calibration without any effect on the other gases. It invalidates or not the auto-calibration
for the considered gas:
– If ON, the compound is taken into account in the automatic analyzer calibration. The SPAN GAS
VALUE field is used to enter this compound concentration in the calibration mixture. This
concentration can be expressed in ppb or μg/m3.
– If OFF, the compound is not taken into account in the automatic analyzer calibration.

RESPONSE TIME field: shows response time value. Refer to Chapter 2 of this manual for more details.
DILUTION OFF/ON field: used to activate the dilution function and to set the dilution coefficient.
NOx AUTONOMY (d) field: indicates the NOx converter life-cycle. When NOx converter is new, life-
cycle is 730 days.
INIT. COUNTER OFF/ON field: reset filter life-cycle (in number of days) to the initial value after a filter
change.
Ny AUTOMONY (d) field: indicates the Ny filter life-cycle (Ny filter is installed on the CNH3 rack). When
Ny filter is new, life-cycle is 730 days.
FILTER AUTONOMY (d) field: indicates the new zero air filter life-cycle (day number). When zero air
filter is new, life-cycle is 365 days.
ON/OFF field: when ON, countdown is activated. When OFF, countdown is deactivated.
CLEANSER (d) field: indicates the ozone purifier filter (cleanser) life-cycle. When cleanser is new, life-
cycle is 365 days.
SCRUBBER (d) field: indicates the ozone destructor (scrubber) life-cycle. When scrubber is new, life-
cycle is 730 days.
SAMPLE REFERENCE PRESSURE CORRECTED OFF/ON field: indicates the sample

pressure in force on the last valid calibration cycle. This value will be used for the sample pressure
correction calculation. When ON, sample pressure correction is active. When OFF, the calculated
concentration is not corrected by sample pressure.
CHAMBER REFERENCE PRESSURE CORRECTED OFF/ON field: indicates the chamber

pressure in force on the last valid calibration cycle. This value will be used for the chamber pressure
correction calculation. When ON, chamber pressure correction is active. When OFF, the calculated
concentration is not corrected by chamber pressure.

3.4.2.12. Optional Estel board configuration
The user accesses this screen by touching / double clicking on .
This screen allows testing and configuration of the analyzer’s available i2C boards (ESTEL board).
NOTE : This screen is optional. is activated in the advanced function home page when an i2C
board interface is connected to the analyzer.
Analog and digital inputs and outputs monitoring screen:

DIG. OUTPUT column (1): monitors the digital outputs (relays). It is used to activate  de-activate them
by touching the associated buttons:
(yellow): relay is activated (normally closed)
(green): relay is de-activated (normally open).
ANALOG OUTPUT column (2): monitors the analog outputs. Output voltage modification is performed
by touching and moving the cursor: it allows calibrating outputs, voltages or the current mode.
DIG. INPUT column (3): monitors digital inputs.
(yellow): remote control is activated
(green): remote control is de-activated.
ANALOG INPUT column (4): monitors analog inputs. It shows the analog input voltage values. Scale is
0–2500 mV.
The user accesses also this analog and digital input and output monitoring screen by touching / double
clicking on

Analog and digital outputs configuration screen
DIGITAL OUTPUT column (1): for each digital output, a field allows channel selection to be assigned to
the associated output; a switch allows selection of output type: N.O. (normally open) or N.C. (normally
closed).
ANALOG OUTPUT column (2): allows setting the Ax+B linearization curve for the four analog outputs.
For each output:
– a field allows selection of the measurement source (for example NO2, as shown in field 3) and fields
A and B allow fixing the coefficient for conversion from the measured value to the point number.
– there are four possible ranges: they allow setting the dynamics of the output signal associated with
the measurement.

Analog and digital input configuration screen
ANALOG INPUTS column (1): allows linearization curve for the four analog inputs.
For each analog input:
– one field allows naming the analog input,
– one field allows unit input associated with the analog input,
– two fields allow setting coefficients A and B for the conversion (y = Ax + B).
DIGITAL INPUTS column (2): Displays the assignment of the four digital remote control inputs.
For each digital input, the available assignment choices are: « Disable», « Sample », « Zero »,
« Span », « Zero cycle », « Span cycle», « Ref. Zero », « Auto Calibration », and « Standby ».

3.5. CALIBRATION
IMPORTANT NOTICE:
Analyzer use, as an equivalent method for EPA reporting, requires periodic multipoint calibration and
subsequent zero/span checks as described below. All gases for calibration must be traceable to a
National Institute of Standards and Technology (NIST) reference.
3.5.1. OVERVIEW OF CALIBRATION AND CONCEPTS

To ensure the accuracy of performed measurements using the AC32e analyzer, the unit must be
regularly checked, calibrated and adjusted, following the user’s quality assurance plan.
– Zero and span check:

This operation compares the analyzer response, for the zero air and span points, to the used
standard gases.
This check is used to measure the analyzer drift in time without modifying the span coefficients.
This check can be performed by using the internal zero air and span gas.
Periodicity: generally 24 hours, in automatic cycle mode.
Note: by default, the analyzer carries out an automatic zero-reference cycle once a day (typically at
0:00).
– 2-point calibration:
This procedure is used for checking and correcting the analyzer response to zero and span points
located at approximately 0 % and 80 % respective of the full scale of the measurement range used.
Periodicity: monthly, or more frequently if the installation requires it.
– Multi-point span:
This procedure involves a complete checkup of the analyzer’s linearity performance.
Periodicity: quarterly, or following out-of-tolerance calibration check results requiring analyzer
intervention.
Note about gas cylinder connections:

The analyzer is equipped with an internal zero filter. The span inlet or sample inlet has to be
used to connect the internal zero filter to an external zero air supply.
When the analyzer is equipped with an internal permeation bench, calibration gas supplies will
be connected to the sample inlet.

Note about gas generation devices:

For pressurized gas devices, it is necessary to provide an excess system to deliver gas at atmospheric
pressure to the analyzer inlet. The device materials should be neutral for the gas used. When the device
is used in automatic cycle with a cylinder, it is necessary to provide a shutoff solenoid-valve remote-
controlled by the analyzer (refer to Figure 3–3).
Needle gate Solenoid valve

Double pressure
regulator
Vent Manifold
Gas cylinder External

solenoid valve
control
SPAN INLET
ANALYZER
Figure 3–3 – Example of a pressurized gas connection

3.5.1.1. Zero air generation

Zero air can be used for zero check or as a diluent in a gas dilutor. Several sources can be considered:
– Internal zero filter.
The internal zero filter (Purafil) is designed to oxidize NO to NO2, which is sufficient to perform the
zero-reference on NO cycle. But this filter does not completely remove NO2, consequently it cannot
be used to check the zero of the NOx channel.
– External zero filter.
NOx can be eliminated by associating:
• Purafil, at inlet, to oxidize NO to NO2.
• Activated carbon, at outlet, to absorb NO2.
A 1/4 liter volume of each adsorbent is sufficient for the analyzer inlet flow rate.
Moisture can be removed by inserting a silica gel cartridge before this filter.
– Synthetic air cylinder. It is a mixture of 80% nitrogen and 20% oxygen.
– Nitrogen cylinder, minimum 5.0 quality.
WARNING: Nitrogen is not suitable for TPG diluent (TPG: gaseous phase titration).
– Zero air generator.
A zero air generator includes an air compressor and several filtration systems to remove moisture
and gases measured by the analyzer. The zero air is under pressure and can supply a diluter.
In all cases, zero air must contain less than 0.5 ppb NOx.
The zero air sources must be appropriate to their possible use, as detailed in the below table.
Zero air sources Internal External Synthetic air Nitrogen Zero air
zero filter zero filter cylinder cylinder generator
Possible use
Zero reference YES YES YES YES YES
NO zero check YES YES YES YES YES
NOx zero check NO YES YES YES YES
Permeation bench NO YES NOT REQUIRED NOT REQUIRED YES
Diluent for dilutor NO NO YES YES YES
Diluent for TPG NO NO YES NO YES
NOTE : A permeation bench requires a permanent zero gas flow for tube scavenging, which may
quickly empty a synthetic air or nitrogen cylinder.

3.5.1.2. Span gas (NOx) generation

The following possible gas supplies can be used:
– NO cylinder diluted in nitrogen 80 % concentration of full scale i.e. 800 ppb with NOx titration (refer
to Figure 3–3).
– (Internal or external) permeation bench equipped with NO2 tube and supplied with dried air.
– Gas dilutor connected to NO cylinder pre-diluted in nitrogen (typically 50 ppm) with NOx titration,
and to a zero air generator. The diluter can be equipped with an ozone generator for TPG (gaseous
phase titration).
The following precautions should be taken:

– Gas cylinders must be equipped with a double-stage expansion valve to ensure stable pressure at
outlet.
– When installing the expansion valve on a NO-in-nitrogen mixture cylinder, the user must follow a
purging procedure to avoid the air initially contained in the expansion valve returning to the cylinder
where it will oxidize NO, and consequently modify its concentration.
– It is advised to connect the NO pre-mix cylinder and the diluter with a metallic tube (stainless steel).
As plastic tubes (mostly PTFE) are oxygen permeable, this can distort NO concentration at diluter
inlet.
– Analyzer can be connected to diluter with PTFE or PFA tube.
– All fittings, valves, pneumatic lines and other elements in contact with the span gases must be
manufactured with highly NOX-inert materials (i.e., PTFE, PFA, glass or stainless steel).
– Span gas sources must be appropriate to their possible use, as detailed in the table below.
Span gas sources NOx diluted (Internal or Simple Dilutor with

cylinder external) dilutor ozone generator
Possible use permeation bench
Scale point check YES YES YES YES
2-point calibration YES YES YES YES
Multipoint calibration NO NO YES YES
NOx converter TPG NO NO NO YES
NOTE : The span gas cylinders used should be certified following the user's quality assurance plan.

MGC101
RDM2
Double stage
expansion valve
NO in N2
cylinder Ozone
RDM1 Reaction chamber
generator
Air zero
generator
Manifold
Analyzer
Figure 3–4 – Calibrator connection diagram
3.5.1.3. Internal solenoid valves

An inlet selector equipped with 2 solenoid valves allows selecting the gas inlet to be analyzed between
3 inlet ports:
– Zero inlet, with internal zero cartridge (Purafil).
– Span inlet, available on the analyzer rear panel.
– Sample inlet, available on the filter holder of the analyzer rear panel.
Sample and span inlets can be used for zero and span checks. The user verifies that the analyzer gives
identical responses for these two inlets. Otherwise, the internal solenoid valves must be cleaned or
replaced.

3.5.2. ZERO AND SCALE POINT CHECK

3.5.2.1. Equipment required
– Zero check:
Use the internal zero filter, otherwise connect the zero air supply to the sample or span inlet.
– Span point:
Connect the span supply to the span port.
3.5.2.2. Procedure
– Zero check:
On the analyzer synoptic diagram, check that the internal zero filter life cycle (1) is greater than 30
days, touch/click on the button (2) to display the inlet selection buttons , , and
touch/click on to select the zero inlet.
The gas inlet arrow on the analyzer synoptic diagram moves in front of the zero filter (3), the fluid color
changes from blue to white (4) and the zero inlet icon appears at the bottom left side of the screen (6).
Wait for the measurement to stabilize. The NO measurement (5) must be within ± 2 ppb (taking
offset into account if programmed). Otherwise, it is necessary to carry out a zero reference.

– Span check:
Check that the span inlet is connected to the span gas source, touch/click on the button (2) to display
the inlet selection buttons , , , and touch/click on to select the span inlet.
The span inlet icon is displayed at the bottom left side of the screen (7).
Wait for the measurement to stabilize. Result (8) will be compared with the concentration generated
by the device used, taking into account its accuracy, as well as a possible programmed offset.
3.5.2.3. Use of automatic cycles
To program the cycles, touch/click on to access the « Automatic cycle configuration » screen.

– Zero-reference cycle:
The zero air filter is permanently connected to the analyzer zero inlet. The recommended duration
for zero check is 60 seconds and 30 seconds for purge, as indicated in the Duration field of the
Cycles / Zero column in the screen below.
The Programmed inlet ON (8) forces the analyzer to use the programmed inlet (9) which is the zero
port in the screen below.
WARNING: if the programmed inlet is OFF, the analyzer uses the port in operation before the cycle
(10), i.e. the sample port in the example below.
The Cyclic tab ON (13) forces the analyzer to perform zero-reference every day at 00:00.
The At startup tab ON (14) forces the analyzer to perform zero reference at each restart.
– Calibration cycle:
The span gas generation device is permanently connected to the analyzer span gas inlet port. The
recommended duration for the calibration cycle is 120 sec and 60 seconds for purge, as indicated
in the Duration field of the Cycles / Span column in the screen shown below.
WARNING: these durations only take in to account the analyzer response time. If the span gas
source is remote and requires time to stabilize, this duration must be added to the purge duration.
The Programmed inlet ON (11) forces the analyzer to use the Programmed inlet (12) which is the
Span port in the screen below.
WARNING: if the Programmed inlet is OFF, the analyzer uses the port in operation before the cycle
(10), i.e. the Sample port in the example below.

3.5.3. TWO-POINT CALIBRATION

3.5.3.1. Equipment required
Refer to section 3.5.2.1.
3.5.3.2. Procedure
– Zero-reference:
Touch/click on the button (15) to display the automatic cycle controls and .
Use to start a zero-reference cycle according to the control panel in section 3.4.1.1.
The gas inlet arrow on the analyzer synoptic diagram moves in front of the zero filter (17), the fluid color
changes from blue to white (18) and the zero-inlet icon is displayed at the bottom left side of the screen
(16).
A scroll bar (19) is displayed on the screen.
The NO signal (20) decreases and stabilizes, and the black signal stores this value (21).

The NO measurement (5) must be within ± 0.5 ppb (taking account the offset, if programmed).
At the end of the cycle, the analyzer automatically returns to the initial measurement configuration.
− Scale point calibration.

Check that the span inlet is connected to the span gas source. Touch/click on the button (15) to
display the automatic cycle controls and .
Use to start a calibration cycle.

The span inlet icon is displayed at the bottom left side of the screen (22) according to the span
configuration. A scroll bar (23) is displayed on the screen.
At the end of the cycle, the analyzer automatically returns to the initial measurement configuration
(sample inlet measurement in our example).
Calibration can be verified by selecting the span inlet port again (24).
Check that the NO measurement (25) corresponds to the injected concentration +/- 2 ppb.

This concentration is also the same concentration shown (26) in the « Advanced analyzer
configuration » screen.
The new span coefficients for NO (27) and NOx (28) are displayed in this page, after the automatic
calibration.

3.5.4. MULTI-POINT CALIBRATION

3.5.4.1. Presentation
An appropriate device consists of a diluter (MGC101 type), a certified span cylinder (NO) 1 % accuracy
with NOx titration, and a zero air generator. Certified span cylinder calibration should follow the National
Institute of Standards and Technology (NIST) for calibration in the US to meet US EPA requirements.
Refer to Figure 3–4.
Gases will be applied at atmospheric pressure to the analyzer sample gas inlet. The outlet flow rate of
the dilutor must be at least twice the flow rate sampled by the analyzer.
Analyzer calibration requires gas generation of 7 points including zero (example: 0, 15, 30, 45, 60, 75
and 90% of the full scale of the measurement range used). The dilution gas must be the same as for
zero measurement.
3.5.4.2. Procedure
First, proceed to a two-point calibration (refer to section § 3.5.3) adjusting the diluter concentration
output, [NO]gen, to 90% of the full scale of the range used.
NOTE : Verify that the NOx (NO + NO2 impurities) generated concentrations, plus an eventual
programmed offset, does not exceed the NOx programmed full scale. If this is the case,
decrease the NO concentration until a NOx concentration equal to 95% of the NOx
programmed full scale is obtained.
Generate several additional concentrations (at least five evenly spaced points through the remaining
scale are required to verify linearity), wait for stabilization (10 min) between 2 points.
For each generated concentration, record the (NO, NOx) values measured by the dilutor, and the (NO,
NOx) corresponding measurements given by the analyzer.
Compare the analyzer’s responses to the generated concentrations. Verify that these responses are
within the generated concentrations ± 0.4 ppb or the generated concentrations ±1% (taking account the
gas generator accuracy).
[NO]resp = [NO]gen ± 0.4 ppb (for [NO]gen < 40 ppb)

[NO]resp = [NO]gen ± 1% (for [NO]gen > 40 ppb)
[NOx]resp = [NOx]gen ± 0.4 ppb (for [NOx]gen < 40 ppb)
[NOx]resp = [NOx]gen ± 1% (for [NOx]gen > 40 ppb)
Where [NO]resp and [NOx]resp are the analyzer’s responses in ppb

[NO]gen and [NOx]gen are the generated concentrations in ppb.
If analyzer’s responses are out of limits, a complete maintenance must be performed.
NOTE : For more information about calibration procedure refer to EPA CFR40 Part 50 appendix F.

3.5.5. CHECK THE CONVERSION EFFICIENCY OF MOLYBDENUM OVEN BY GPT

The Gas Phase Titration (GPT) method with NO in excess allows the user to check the NO/NO2
conversion efficiency from a NO concentration used as reference.
GPT uses the following reaction: NO+O3→NO2+O2, allowing the NO2 gas quantitative analysis as a
function of NO variation concentration.
3.5.5.1. Device
− Zero air generator.
− NO in N2 cylinder. Concentration is chosen in order to obtain, after dilution, a NO concentration of
about 90% of the measurement full scale used.
− Diluter fitted with an O3 generator using photolysis (MGC101), refer to Figure 3-4.
− Analyzer in operation for at least 2h.
3.5.5.2. Procedure
First, carry-out a 2-point calibration (refer to section 3.5.3) by adjusting the [NO] concentration generated
by the dilutor to 90% of the full scale of the ranges used.
Generate a [NO] concentration point at 80% of the NO2 full scale (400 ppb for NO2 full scale at 500 ppb).
After stabilization, write down the concentrations read on the analyzer [NO]initial and [NOx]initial.
While keeping the same adjustments on the diluter (NO concentration and outlet flow rate), activate the
dilutor ozone generator to generate an ozone concentration of about 80% of the previous [NO]
concentration (320 ppb O3 for 400 ppb NO). After stabilization, write down the concentrations read on
the analyzer, [NO]final and [NOx]final.
Check that [NO]final > 40 ppb (NO excess). If not, decrease the ozone concentration and repeat the
operation.
Calculate the R converter efficiency as follows:
R (%) = 100 x (1 – ([NOx]initial - [NOx]final) / ([NO]initial -[NO]final))
Efficiency must be greater than 98%.
Remarks:
– Ozone generator activation does not change outlet flow rate nor operating point of mass flow
controller (MFC).
– NOx concentration (= NO + NO2) remains constant during GPT. Only the NO / NO2 ratio is modified
by the ozone addition.

Figure 3–5 – Typical GTP diagram
The above diagram shows the various concentrations evolution during GPT.
An ideal converter (R = 100%) converts 100% of NO2 to NO, resulting in [NOx]initial = [NOx]final and thus a
stable NOx measurement during TPG.
Inversely, a significant drop in the NOx measurement during the ozone generator activation of the dilutor
indicates a converter efficiency fault.

CHAPTER 4
PREVENTIVE MAINTENANCE
4.1 SAFETY INSTRUCTIONS 4–3
4.2 MAINTENANCE CALENDAR 4–4
4.3 MAINTENANCE OPERATION SHEETS 4–4
4.4 AC32E MAINTENANCE KIT 4–24
4.5 AC32E RECOMMENDED SPARE PARTS 4–24
Figure 4–1 – Sample inlet dust filter replacement 4–5

Figure 4–2 – Test for leaks 4–9
Figure 4–3 – Internal zero filter replacement 4–10
Figure 4–4 – Dryer filter replacement 4–11
Figure 4–5 – Ozone cleanser replacement 4–12
Figure 4–6 – KNF pump of AC32e 4–13
Figure 4–7 – KNF pump details 4–15
Figure 4–8 – Dust filter replacement 4–16
Figure 4–9 – Ozone restrictor cleaning 4–17
Figure 4–10 – Sample restrictor cleaning 4–18
Figure 4–11 – NOx molybdenum converter replacement 4–21
Figure 4–12 – Ozone scrubber maintenance 4–23
SEPTEMBER 2019
4–1

4 PREVENTIVE MAINTENANCE
4.1 SAFETY INSTRUCTIONS

The user must follow these safety instructions at all times:
− Always turn off the power supply when performing analyzer maintenance.
− Personnel should be trained in the proper operation of this equipment before attempting to operate it.
− The manufacturer shall not be responsible for any adverse outcomes resulting from the following:
• Use of the monitor by unqualified service personnel.
• Use of the monitor under conditions other than those specified in this document.
• Use of components or accessories not manufactured by ENVEA, failure to use recommended

parts may reduce the safety features.
• Use of this equipment in a manner not approved by ENVEA, as it can cause harm to the
equipment or operating personnel.
• Inappropriate maintenance of the analyzer.
− A periodic inspection is required.
SEPTEMBER 2019
4–3
4.2 MAINTENANCE CALENDAR

By design, the AC32e requires very limited maintenance. However, the unit must be regularly serviced
to ensure proper performance over time. The routine maintenance schedule shown below is an example,
and this schedule can vary according to operating conditions.
Nature of operations Frequency Sheet N°
2 to 4 weeks according
Sample inlet dust filter replacement 4.3.1
to dust amount
Flow rate check 1 month 4.3.2
Parameter check 1 month 4.3.3
Test for leaks When necessary 4.3.4
Internal zero filter replacement 1 year 4.3.5
Dryer filter replacement 1 year 4.3.6
Ozone filter replacement 1 year 4.3.7
KNF pump maintenance 1 year 4.3.8
Dust filter replacement 1 year 4.3.9
According to parameter
Ozone restrictor cleaning 4.3.10
checking
According to parameter
Sample restrictor cleaning 4.3.11
checking
NOx molybdenum converter replacement 2 years 4.3.12
Ozone scrubber maintenance 2 years 4.3.13
Annual check
The monitor must undergo a thorough cleaning (measurement chamber, restrictors, flow circuit, etc.) in
the laboratory at least once a year. All metrological parameters and fitting tightness should be checked
at this time.
4.3 MAINTENANCE OPERATION SHEETS

MAINTENANCE SHEET
MONITOR Serial No.: OPERATION SHEET: 4.3.1

Scope: Sample inlet dust filter replacement PAGE: 1/1 Frequency: 2 to 4 weeks
according to dust amount
Proceed in the following order: Date
− Turn off the analyzer power switch and disconnect the sample inlet.
− Unlock the filter holder cover (1) by pulling the spring (2) upwards.
− Remove the worn filter (3).
− Remove the separating blue sheet of the new filter, and place the new filter (4) on the filter holder.
− Make sure that the filter correctly covers the filter-holder surface and that it is correctly placed flat
on top of it.
− Reposition the filter holder cover, and lock it by lowering the spring (2).
− Connect the sample inlet and power on the analyzer.
(1) Filter holder cover, (2) spring, (3) worn filter, (4) new filter.
Figure 4–1 – Sample inlet dust filter replacement
Tools and parts required:

• Tweezers
• Sample inlet filter (Teflon filter - porosity 5 µm - ∅ 47 mm) - Ref.: F05-11-842
SEPTEMBER 2019
4–5
MAINTENANCE SHEET

Scope: Flow rate check PAGE: 1/1 Frequency : 1 month
Sample flow rate check : Date
Connect a 0-120 SLPH flow meter (1) on the AC32e sample inlet (2), and make sure that the flow
rate value indicated on the flow meter is 43 SLPH ± 3.
Sample flow rate check :

Connect a 0-40 SLPH flow meter (3) on the AC32e ozone generator air inlet (4), and make sure that
the flow rate value indicated on the flow meter is 8 SLPH +2/- 1.
SLPH : Standard Liter Per Hour

Tools required
• Flow meters, 0-120 SLPH, 0-40 SLPH.

MAINTENANCE SHEET
MONITOR Serial No.: OPERATION SHEET : 4.3.3

Scope : Parameter check PAGE : 1/1 Frequency : 1 month
Date
Parameters are checked when the analyzer is in normal operation without alarm (status icon ):
− Compare the values given on the «Open diagnostic pages (alarm, input / output, mux…) » second
page screen with the limits listed in the table below.
Typical
Parameter Min. values Max values
values
24V power supply voltage 23 V 24 V 25 V
24VDC power supply current 1.5 A 2.5 A 3A
Sample flow rate ( in « Diagnostic »
39 SLPH 43 SLPH 46 SLPH
screen page
Sample pressure 850 hPa 1000 hPa 1150 hPa
Reaction chamber pressure 140 hPa 200 hPa 230 hPa
Ozone generator current 40 mA 65 mA 100 mA
Peltier cooler current 0.5 A 1.4 A 2A
Photomultiplier tube (PM) voltage 450 V 650 V 750 V
Rack internal temperature 10°C 30°C 50°C
Chamber temperature 59°C 60°C 61°C
PM temperature - 0,5°C 0,0°C + 0,5°C
Converter temperature 338°C 340°C 342°C
Black signal 20 mV 70 mV 150 mV
SLPH : Standard Liter Per Hour
− Compare the values given on the « Advanced analyzer configuration » screen with the limits listed
in the table below.
Typical
Parameter Min. values Max values
values
NO Span coefficient 0.3 1 3
NOx Span coefficient 0.3 1 3
Tools required
• None
SEPTEMBER 2019
4–7
MAINTENANCE SHEET

Scope: Test for leaks PAGE: 1/2 Frequency : when necessary
Date
Proceed in the following order:
− Touch to set the analyzer into stand-by mode: this button becomes , the status icon
is displayed and the pump stops.
− Insert a quarter-turn valve (1) between the analyzer pump outlet and the pump inlet. Close the
quarter-turn valve. Plug the sample inlet (2) and the ozone generator air inlet (3) on the analyzer
rear panel.
− Display the « Open diagnostic pages (alarm, input / output, mux…) » second page screen, notice
that the pump stop/start button (4) is OFF, and the sample pressure (5) is equal to reaction
chamber pressure (6), i.e. 1008 hPa in screen 1 of Figure 4–2.
− Switch ON the pump stop/start button (4), then open the quarter-turn valve (1). When the sample
pressure (5) and the reaction chamber pressure (6) decreased up to 200 hPa +/- 20 hPa, close
the quarter-turn valve (1). E.G.: 202 hPa in screen 2 of Figure 4–2.
− Use a chronometer, write down the pressure value at t = 0 and at t = 1 minute. There is NO LEAK
when pressure increase is lower than 10 hPa for 1 minute duration.
Tools and parts required

• Quarter-turn valve,
• Chronometer,
• Plugs

MAINTENANCE SHEET

Scope: Test for leaks PAGE: 2/2 Frequency : when necessary
Screen 1 Screen 2
(1) quarter-turn valve, (2) sample inlet, (3) ozone generator air inlet, (4) stop/start pump button, (5) sample
pressure, (6) reaction chamber pressure
Figure 4–2 – Test for leaks

• Quarter-turn valve,
• Chronometer,
• Plugs
SEPTEMBER 2019
4–9
MAINTENANCE SHEET

Scope: Internal zero filter replacement PAGE: 1/1 Frequency: 1 year
Dates
− Turn off the analyzer and unplug the power cable.
− Remove the cover screw located on the analyzer rear panel. Remove the protective cover.
− Pull to unclip the internal zero filter (1).
− Remove the plugs (2) and empty the zero filter load.
− Check seals (3), clean or change them if necessary. Then, replace a plug and fill-in the cartridge
with a new zero filter load. Replace the second plug.
− Reassemble the cartridge and replace the internal zero filter in the clips.
− Replace the analyzer cover, plug in the power cable and power on the analyzer.
− In the « Advanced Analyzer configuration » screen, switch ON the FILTER AUTONOMY INIT.
COUNTER field to reset the filter life-cycle.
(1) zero filter load, (2) metal plugs, (3) seals

Figure 4–3 – Internal zero filter replacement

• AC32e zero filter filling kit, Ref.: SAV-K-000267-A
• Flat blade screwdriver, 5.5 mm length

MAINTENANCE SHEET

Scope: Dryer filter replacement PAGE: 1/1 Frequency: 1 year
Dates
− Pull to unclip the dryer filter (1).
− Remove the plugs (2) and empty the dryer filter load.
− Check seals (3), clean or change them if necessary. Then, replace a plug and fill-in the cartridge
with a new dryer filter load. Replace the second plug.
− Reassemble the cartridge and replace the dryer filter in the clips.
(1) dryer filter load, (2) metal plugs, (3) seals

Figure 4–4 – Dryer filter replacement

• AC32e dryer filter filling kit, Ref.: SAV-K-000266-A
SEPTEMBER 2019
4–11
MAINTENANCE SHEET

Scope: Ozone cleanser replacement PAGE: 1/1 Frequency: 1 year
Dates
− Pull to unclip the ozone cleanser (1).
− Remove the plugs (2) and empty the ozone cleanser load.
− Change seals (3), replace a plug and fill-in the cartridge with a new ozone cleanser load. Replace
the second plug.
− Reassemble the cartridge and replace the ozone cleanser in the clips.
− In the « Advanced Analyzer configuration » screen, switch ON the CLEANSER INIT. COUNTER
field to reset the cleanser life-cycle.
(1) Ozone cleanser load, (2) metal plugs, (3) seals

Figure 4–5 – Ozone cleanser replacement

• AC32e ozone cleanser filling kit, Ref.: SAV-K-000268-A

MAINTENANCE SHEET

Scope: KNF pump maintenance PAGE: 1/3 Frequency: 1 year
Date
WARNING: Before any intervention, unplug the power cable and make sure the pump is turned off.
The diaphragm and valves are the only pump parts that need replacement. Maintenance operation
consists of cleaning and/or replacing them. It is also advised to dust off pump fan impellers.
Preliminary operation:
− Disconnect the pump from its electrical connection (1) on rack rear panel. Disconnect the fluid
inlet (2), and the pump vent (3).
(1) Pump power supply, (2) pump fluid inlet, (3) pump vent.
Figure 4–6 – KNF pump of AC32e

• Flat wrench, 11 mm
• Allen wrenches, 3 and 4 mm
• Open ended wrench, 5 mm
• Marking felt
• Set of 2 stainless steel valves, Ref.: V02-N022-5-0340
• Teflon diaphragm, Ref.: 02-N026-11-2-A
• Pump head seal (PJ9425-026), Ref.: V02-N022-5-0343
SEPTEMBER 2019
4–13
MAINTENANCE SHEET

Replacing the diaphragm, follow steps in the order below: Date
− Before de-assembling, with a pencil mark the position between the casing (15) and the cylinder
head (16).
− Unscrew the four hex socket screws (12) and remove the cylinder head cover (17).
− Loosen the screw (5), remove the clamping disk (3) and the diaphragms (4).
− Remove the screws (13) and remove the casing (15).
− Place the connecting rod (6) in half-stroke position turning the wheel half-way (14), set up the
new assembly of diaphragms (4) with flat side underneath.
− Put the disk (3) in place on the diaphragms (4) and securely tighten the assembly using the screw
(5).
− Position the cylinder head cover (17) as marked before de-assembling, then secure with the hex
socket screws (12) operating regularly in criss-cross order.
− Be sure armature moves smoothly by hand, put the casing on (15) and re-attach with the 4 screws
(13).
Replacing the valves

− Head de-assembling: see above instructions.
− Before de-assembling, with a pencil mark the position between the casing (15) and the cylinder
head (16).
− Unscrew the four hex socket screws (12) and remove the cylinder head cover (17).
− Unscrew the screws (10), remove the cover (9) and the flat seal (18).
− Unscrew the nut (11) by using a socket wrench, take the screw out (1), and replace the valves
(7) and (8).
− Install the new valves using the screw (1), the washer (2) and the nut (11). Replace the flat seal
(18), replace the cover (9), and secure the assembly by using the screws (10). Tighten securely.
− Position the cylinder head cover (17) as marked before de-assembling, then secure with the hex
socket screws (12) operating regularly in a criss-cross order.
− Be sure armature moves smoothly by hand, put the casing on (15) and re-attach with the 4 screws
(13).

• Marking felt

MAINTENANCE SHEET

(1) screw, (2) washer, (3) clamping disk, (4) diaphragms, (5) screw, (6) connecting rod, (7) and (8) valves, (9)
cover, (10) screw, (11) nut, (12) hex socket screw, (13) screw, (14) wheel, (15) casing, (16) cylinder head, (17)
cylinder head cover, (18) flat seal
Figure 4–7 – KNF pump details

• Marking felt
SEPTEMBER 2019
4–15
MAINTENANCE SHEET

Scope: Dust filter replacement PAGE: 1/1 Frequency: 1 year
Dates

− First hold the union-fitting (1) with a 16 mm wrench before manually unscrewing the nut (2) to
remove the worn dust filter (3). Remove the filter inlet tube (4)
− Replace the worn dust filter with a new one and replace the filter inlet tube (4) on the new dust
filter. Be careful to respect flow direction as indicated on the filter: see FLOW arrow (5).
− Take care to hold the union-fitting (1) with a 16 mm wrench before manually screwing the nut (2).
When unscrewing and screwing the nut (2), it is essential to keep the union-fitting in
place (1) by holding it with a 16 mm wrench.
(1) union-fitting, (2) nut, (3) dust filter, (4) filter inlet tube, (5) arrow indicating flow direction
Figure 4–8 – Dust filter replacement

• In-line dust filter, ref.: F05-IDN-10G

MAINTENANCE SHEET

Scope: Ozone restrictor cleaning PAGE: 1/1 Frequency: according to
parameter checking
Dates
− Remove the cover screw located on the analyzer rear panel. Remove the protective cover, then
the foam cover of measurement module: ozone restrictor is located under mark (1) and sample
restrictor is located behind mark (2).
− Unscrew the screws (3) to remove the plate and free up the ozone restrictor (4).
− Unscrew (4) and disassemble the restrictor (5). Dip it in alcohol solution, and dry it with dry oil-
free compressed air. Replace the seals (6).
− Re-assemble the restrictor and the plate. Then, replace the screws (3).
− DO NOT tighten the restrictor too tightly when re-assembling, to avoid crushing the seals.
Following this maintenance operation, the ozone flow rate and leak test must be
checked
(1) ozone restrictor location, (2) sample restrictor location, (3) screws, (4) and (5) ozone restrictor, (6) seals
Figure 4–9 – Ozone restrictor cleaning

• Flat screwdrivers, 5.5 and 4 mm length
• Pliers
• Allen wrench, 2.5 mm
• Alcohol solution, cleaning rag, oil-free and dry compressed air
SEPTEMBER 2019
4–17
MAINTENANCE SHEET

Scope: Sample restrictor cleaning PAGE: 1/1 Frequency: according to
parameter checking
Dates
− Remove the cover screw located on the analyzer rear panel. Remove the protective cover, then
the foam cover of measurement module: ozone restrictor is located under mark (1) and sample
restrictor is located behind mark (2).
− Use a pliers (3) to pull and remove the restrictor (5) out of its housing (4).
− Unscrew (6) and disassemble the restrictor (5). Dip it alcohol solution, and dry it with dry oil-free
compressed air. Change the seals (7).
− Re-assemble the restrictor with the screwdriver (6), and insert it in its housing (4).
− DO NOT tighten the restrictor strongly when assembling again, to avoid crushing the seals.
Following this maintenance operation, the sample flow rate and leak test must be
checked.
(1) ozone restrictor location, (2) sample restrictor location, (3) pliers, (4) restrictor housing, (5) sample
restrictor, (6) screwdriver, (7) seals
Figure 4–10 – Sample restrictor cleaning

• Flat screwdrivers, 5.5 and 4 mm length
• Pliers
• Allen wrench, 2.5 mm
• Alcohol solution, cleaning rag, oil-free and dry compressed air

MAINTENANCE SHEET

Scope: NOx molybdenum converter replacement PAGE: 1/3 Frequency: 2 years
Dates
− The NOx molybdenum converter (1), ozone scrubber (2) and NOx solenoid valve (3) are located
in a box, on the left side behind the front panel. Converter temperature is 340°C: wait for it to cool
down, then unscrew the screws (17) keeping in place the box cover (16), and remove the box
cover.
− Unscrew (4) and remove (5) the solenoid valve.
− Disconnect the scrubber fluid connections (6) and (7).
− Loosen the left-hand screw (8), unscrew and remove the right-hand screw (9). Pull and lift up to
remove the case out of the analyzer.
− Disconnect the electrical connector (10), and unscrew (11) to free the wires.
− Pull up the converter surrounded with its insulating material (12), and put it on a table.
− Put-off the insulation material, and remove the two heating clamp screws (13).
− Slide the converter cartridge (14) out of the heating clamp. Replace it with a new cartridge.
− Re-assemble the heating clamp on the converter cartridge and screw it in place. Wrap the
converter assembly in the insulating material, and replace it in the case. Put on the insulating
plate (15) and the box cover (16). Then, screw (17) the box cover.
− Screw the screws (8) and (9) to affix the case on the bottom plate.
− Replace the NOx solenoid valve (3), connect the fluid connections (6) and (7), and the electric
connections (10) and (11).
Following this maintenance operation, the leak test and the molybdenum oven
efficiency must be checked.
Reminder: check of conversion efficiency of G.P.T molybdenum oven is detailed in chapter 3,

paragraph 3.5.5.

• Molybdenum converter, Ref.: F05-0388-C
• Flat blade screwdrivers, 5.5 mm and 2.5 mm
• Pliers
• Allen wrenches, 2.5 mm and 3 mm
• Combination wrench, 5mm
SEPTEMBER 2019
4–19
MAINTENANCE SHEET

(1) NOx molybdenum converter, (2) ozone scrubber, (3) NOx solenoid valve, (4) and (5) NOx solenoid valve
dismantling, (6) and (7) scrubber fluid connections, (8) and (9) screws, (16) box cover, (17) cover box screws.

• Pliers

MAINTENANCE SHEET

(10) Electrical connector, (11) screws, (12) converter wrapped with insulating material, (13) heating clamp screws,
(14) converter cartridge, (15) insulating plate, (16) box cover, (17) cover box screws.
Figure 4–11 – NOx molybdenum converter replacement

• Pliers
SEPTEMBER 2019
4–21
MAINTENANCE SHEET

Scope: Ozone scrubber maintenance PAGE: 1/2 Frequency: 2 years
Dates
− Ozone scrubber is located in a box (1) with the NOx molybdenum converter, at the left side behind
the front panel of the analyzer. Wait for the converter to cool down (its temperature is about
340°C), then unscrew the screws on both box sides (2), and remove the box cover to see the
ozone scrubber cover (3).
− Disconnect the two fluid connections (4) and (5) of the ozone scrubber, then remove it up and out
of the analyzer to carry out maintenance on a table or flat surface.
− Remove the ozone scrubber cover (3), empty the load (6). Then, remove the opposite side cover,
change the seals (7) and filters (8) of both covers.
− Re-assemble the scrubber, refill with a new load and replace the cover.
− Install it in the box, re-connect the two fluid connections (4) and (5).
− Put on the insulating plate (9) and the box cover (1). Then, screw on (2) the box cover.
Following this maintenance operation, the sample flow rate and leak test must be
checked.

• AC32e ozone scrubber filling kit, Ref.: SAV-K-000269-A
• Flat blade screwdriver, 5.5 mm
• Pliers
• Combination wrench, 5 mm

MAINTENANCE SHEET

Scope: Ozone scrubber maintenance PAGE: 2/2 Frequency: 2 years
(1) Box, (2) screws, (3) ozone scrubber cover, (4) and (5) fluid connections, (6) scrubber load, (7) seal, (8) filter,
(9) insulating plate.
Figure 4–12 – Ozone scrubber maintenance

• AC32e ozone scrubber filling kit, Ref.: SAV-K-000269-A
• Flat blade screwdriver, 5.5 mm
• Pliers
• Combination wrench, 5 mm
SEPTEMBER 2019
4–23
4.4 AC32E MAINTENANCE KIT
Maintenance kit for 1 year, Ref.: AC32e-K
Line nb. Reference Designation Quantity

1 F05-11-842 Teflon filter - porosity 5 µm - ∅ 47 mm 25
2 V02-N022-5-0340 Set of 2 stainless steel valves 1
3 V02-N026-11-2-A Set of 3 Teflon diaphragms 1
4 V02-N022-5-0343 Pump head seal (PJ 9425-026) 1
5 SAV-K-000266-A AC32e dryer filter filling kit 1
6 SAV-K-000267-A AC32e zero filter filling kit 1
7 SAV-K-000268-A AC32e ozone cleanser filling kit 1
8 F05-IDN-10G In-line dust filter 1
4.5 AC32E RECOMMENDED SPARE PARTS

Recommended spare parts set for 2 years, Ref. : AC32e-RSP
Line nb. Reference Designation Quantity

1 F01-0300-C E-series wired solenoid valve 1
2 SAV-K-000269-A AC32e ozone scrubber filling kit 1
3 F05-0388-C Molybdenum converter 1
4 T01-CC-24-60 Heating clamp, 25 x 60 mm, 24V 60W 1
5 V03-0025-B 24VDC wired fan 1
6 F02-0010-A Assembled ejector, ∅ 0.1 mm 1
7 F02-0035-A Flow restrictor, ∅ 0.31 mm 1

CHAPTER 5
CORRECTIVE MAINTENANCE
Figure 5–1 – Interconnection board diagram 5–19

Figure 5–2 – Controller board diagram 5–20
Figure 5–3 – Power supply board diagram 5–21
Figure 5–4 – Measurement board diagram 5–22
Figure 5–5 – Ozone generator board diagram 5–24
Figure 5–6 – PM preamplifier board diagram 5–25
Figure 5–7 – RTP board diagram 5–26
Figure 5–8 – SCP board diagram 5–27
Figure 5–9 – ICB board diagram 5–28
Figure 5–10 – ARM20 board diagram 5–30
Table 5–1 – List of faults and corrective actions 5–6

Table 5–2 – Interconnection board connections and LED description 5–18
Table 5–3 – Controller board connections and LED description 5–20
Table 5–4 – Power supply board connection and LED description 5–21
Table 5–5 – Measurement board connections, test points and LED description 5–22
Table 5–6 – Ozone generator board connection, adjustment, test points and LED description 5–23
Table 5–7 – Photomultiplier (PM) preamplifier board connection, test points, adjustments and LED description 5–25
Table 5–8 – RTP board connections and LED description 5–26
Table 5–9 – SCP board connections and LED description 5–27
Table 5–10 – ICB board connections 5–28
Table 5–11 – ARM20 board connections and LED description 5–29
SEPTEMBER 2019
5–1

5. CORRECTIVE MAINTENANCE
Analyzer corrective maintenance must be carried out only by qualified people using the information
provided in this document.
The AC32e monitor automatically and continuously performs self-tests of its main components. When
any malfunction is detected, it is indicated by a three level warning system: CONTROL, ALARM,
SECURITY.
− Level 1: CONTROL.
When a minor malfunction is detected, the CONTROL icon is displayed in the lower
browsing bar common to all screens, while the analysis cycle is going on.
This CONTROL icon alerts the user that one or many parameters are about to cause an
alarm which will interrupt the measurement.
− Level 2: ALARM.
When a malfunction which distorts metrology is detected, the ALARM icon is displayed in the
lower browsing bar common to all screens, while the analysis cycle is interrupted and the analyzer
switches to STAND-BY mode in most cases.
− Level 3: SECURITY.
When a major malfunction which could damage the analyzer is detected, the SECURITY icon
is displayed in the lower browsing bar common to all screens while the 24V power supply is
interrupted to prevent any overheating.
In any case, the user touches /clicks on the icon to access the « Open diagnostic pages (alarm, input /
output, mux…) screen and view the malfunction origin.
SEPTEMBER 2019
5–3
The first page of the « Diagnostic functions (alarm, input / output, mux…) » screen indicates the
ongoing messages and malfunctions occurring on the analyzer.
The user displays / removes display of the analyzer event and malfunction history by touching /
clicking on . The history documents the event:
− Date and time of event / malfunction beginning (1),

− Level (2) (control, alarm, security),
− Date and time of event / malfunction end (3).

The user touches / clicks on icon (2) on the screen shot shown on the previous page to open a window
which notifies about:
− Malfunction level (4),
− Malfunction description (5),
− Alarm threshold(s) (6),
− Unit (7),
− Alarm temporization (8),
− Parameter value at alarm temporization end (9).
NOTE: The alarm is triggered only if the parameter value exceeds the alarm threshold during a
period equal or higher than the alarm temporization.
SEPTEMBER 2019
5–5
Table 5–1 summarizes the main faults indicated by the unit with their corresponding possible
corrective actions.
Table 5–1 – List of faults and corrective actions
Alarm message Possible cause(s) Possible corrective action(s)

(Min./Max. values)
Sample pressure is lower than 800 – Check sample pressure in the

Sample Pr. → Too hPa. synoptic screen. Refer to chapter 3,
low page 3-28, (4).
Min = 800 hPa
Sample dust filter is dirty. – Replace sample dust filter as
described in chapter 4.
Sample line is clogged. – Disconnect sample line at sample

inlet filter block and check that
pressure is close to atmospheric
pressure. If so, search for the cause
of sample line depressurization.
Sample pressure sensor is faulty. – Disconnect sample line at sample

pressure. If not, replace sample
pressure sensor.
Sample pressure is higher than 1200 – Check sample pressure in the

Sample Pr. → Too hPa. synoptic screen. Refer to chapter 3,
high page 3-28, (4).
Max = 1200 hPa
Sample line is under pressure. – Disconnect sample line at sample
pressure.
Sample pressure sensor is faulty. – Disconnect sample line at sample

pressure. If not, replace sample
pressure sensor.
Pressure inside reaction chamber is – Check pressure inside reaction

Chamber Pr. → Too lower than 140 hPa. chamber in the synoptic screen.
low Refer to chapter 3, page 3-28, (8).


(Min./Max. values)
Min = 140 hPa

Sample restrictor is clogged. – Check sample flow as described in
chapter 4.
– Clean sample restrictor as described
in chapter 4.
Sample inlet is clogged. – Refer to the above alarm message:

Sample Pr. → Too low.
Pressure inside reaction chamber is – Check pressure inside reaction

Chamber Pr. → Too higher than 240 hPa. chamber in the synoptic screen.
high Refer to chapter 3, page 3-28, (8).
Max = 240 hPa
Fluid circuit leaks. – Test for leaks as described in chapter
4.
Pump is faulty. – Check pump limit vacuum with a

vacuum gauge.
– If pump limit vacuum is higher than
100 hPa, carry out pump
maintenance as described in chapter
4.
Electric current of ozone generator – Check electric current of ozone

I ozone generator → current is lower than 20 mA. generator in the synoptic screen.
Too low Refer to chapter 3, page 3-28, (11).
Min = 20mA
Electric current of ozone generator is – Check electric connection between
zero. ozone generator and interconnection
board.
– Replace fuse on ozone generator
board.
– Replace ozone generator board.
– Replace ozone generator.
Electric current of ozone generator is – Check electric current of ozone

I ozone generator → higher than 150mA. generator in the synoptic screen.
Too high Refer to chapter 3, page 3-28, (11).
Max = 150mA – Replacer ozone generator board.
– Replace ozone generator.
SEPTEMBER 2019
5–7

(Min./Max. values)
Photomultiplier tube temperature is no – Check photomultiplier tube

PM T → Out of longer maintained at 0°C +/- 0.5°C. temperature in the synoptic screen.
regulation Refer to chapter 3, page 3-28, (10).
Min = -0.5°C – Check Peltier cooler current in the
Max = +0.5°C « Open diagnostic pages (alarm,
input / output, mux…) screen. Refer
to chapter 3, page 3-39, (9).
PM T > 0.5°C. – Check that Peltier fan operates

correctly. Refer to chapter 1, (14) of
I Peltier > 3A.
figure 1-4.
– Check that foam cover of
measurement module is correctly
seated.
– Check that heat sink is not hot (T >
50°C). Otherwise, switch off the
analyzer and wait for complete
cooling to ambient temperature
before restarting.
PM T > 0.5°C. – Check connection between RTP

board and Peltier.
I Peltier < 0.5A.
– Check connection between RTP
board and Interconnection board.
– Replace RTP board.
– Replace Peltier.
Reaction chamber temperature is no – Check reaction chamber temperature

Chamber T → Out of longer maintained at 60°C +/- 1°C. in synoptic screen. Refer to chapter
regulation 3, page 3-28, (7).
Min = 59°C
Max = 61°C
Chamber T ≈ Internal T. – Check heating cable connection to J8

Chamber T → Out of of measurement board.
regulation No heating.
– Check heating led operation in front
Min = 59°C of J8 of measurement board:
Max = 61°C • If off: replace Controller board.


(Min./Max. values)
(following) • If on: check heating resistor on

cable connector is near to 22 Ω.
If R > 30 Ω, replace heating
resistor.
Chamber T > 61°C. – Check heating led operation in front

of J8 of measurement board. If led is
on without blinking, replace controller
board.
Molybdenum converter oven – Check Molybdenum converter oven

Oven T → Out of temperature is no longer controlled at temperature in synoptic screen. Refer
regulation 340°C +/-2°C. to chapter 3, page 3-28, (5).
Min = 338°C
Max = 342°C Oven T° < 338°C. – Check converter cable connection to
J32 of interconnection board.
Not enough heating, or no heating.
– Check heating led operation in front
of J32 of interconnection board.
• If off: do a stop/start. If still off,
replace controller board.
• If on without blinking: check if
heating resistor on cable
connector is near to 10Ω. If R >
15 Ω, replace heater band of
converter.
Oven T > 340°C. – Check heating led operation in front

of J32 of interconnection board. If on
without blinking, replace controller
board.
Optional permeation bench – Check optional permeation bench

Bench T → Out of temperature is no longer controlled to temperature in the « Open diagnostic
regulation 50°C +/- 0.5°C. pages (alarm, input / output, mux…)
Min = 49.5°C screen. Refer to chapter 3, pages 3-
41 and 3-42, screenshot 4, (10).
Max = 50.5°C
Bench T < 49.5°C. – Check permeation bench connection

to J33 of interconnection board.
Bench T → Out of Not enough heating or no heating.
regulation – Check heating led operation in front
of J33 of interconnection board:
Min = 49.5°C
• If off: do a stop/start. If still off,
Max = 50.5°C replace the controller board.
SEPTEMBER 2019
5–9

(Min./Max. values)
(following) • If on without blinking, check

heating resistor on cable
connector is near to 38 Ω. If R >
50 Ω, replace permeation bench.
Bench T > 50.5°C. – Check heating led operation in front

of J33 of interconnection board: if on
without blinking, replace controller
board.
Analyzer temperature is higher than – Check internal temperature in

Internal T. → Too 50°C. synoptic screen. Refer to chapter 3,
high page 3-28, (14).
Max = 50°C – Check that room temperature where
analyzer operates is lower than 45°C.
Internal temperature is lower than 5°C. – Check internal temperature in

Internal T. → Too synoptic screen. Refer to chapter 3,
low page 3-28, (14).
Min = 5°C – Check that room temperature where
analyzer operates is higher than 0°C.
Invalid pressure measurement is – Check sample pressure in synoptic

Sample Pr. → No displayed. screen. Refer to chapter 3, page 3-
sensor 28, (4).
Min = 65hPa – Check that sample pressure sensor is
correctly connected to J9 of
interconnection board.
– Replace sample pressure sensor.
Invalid measurement of reaction – Check reaction chamber pressure in

Chamber Pr. → No chamber pressure is displayed. synoptic screen. Refer to chapter 3,
sensor page 3-28, (8).
Min = 65hPa – Check that reaction chamber
pressure sensor is correctly
connected to J5 of interconnection
board.


(Min./Max. values)
– Replace reaction chamber pressure

sensor.
Invalid internal temperature – Check internal temperature in

Internal T. → No measurement is displayed. synoptic screen. Refer to chapter 3,
sensor page 3-28, (14).
Max = 80°C – Check Pt1000 internal temperature
probe connection in J29 of
interconnection board.
– Replace Pt1000 internal temperature
probe.
Invalid measurement of reaction – Check reaction chamber temperature

Chamber T. → No chamber temperature is displayed. in synoptic screen. Refer to chapter
sensor 3, page 3-28, (7).
Max = 80°C – Check connection of reaction
chamber temperature probe to J7 of
measurement board.
– Replace Pt1000 reaction chamber
temperature probe.
Invalid measurement of photomultiplier – Check photomultiplier tube

PM T. → No sensor tube temperature is displayed. temperature in synoptic screen. Refer
Max = 70°C to chapter 3, page 3-28, (10).
– Check connection of Pt1000
photomultiplier tube probe to the RPT
board connector.
– Replace Pt1000 temperature probe of
photomultiplier tube.
Invalid measurement of molybdenum – Check molybdenum converter oven

Oven T. → No converter oven is displayed. temperature in synoptic screen. Refer
sensor to chapter 3, page 3-28, (5).
Max = 420°C – Check connection of Pt100
temperature probe of molybdenum
converter oven to ICB board
connector assembled on scrubber-
converter casing.
SEPTEMBER 2019
5–11

(Min./Max. values)
– Check molybdenum converter cable

connection to J32 of interconnection
board.
molybdenum converter oven.
Invalid measurement of optional – Check optional permeation bench

Bench T. → No permeation bench temperature is temperature in synoptic screen.
sensor displayed.
– Check connection of Pt100
Max = 60°C temperature probe of optional
permeation bench to ICB board
connector mounted on its casing.
– Check connection of permeation
bench cable to J33 of interconnection
board.
optional permeation bench.
24V supply voltage is lower than – Check 24V supply voltage in the
+24V → Too low 22.8V. « Open diagnostic pages (alarm,
Min = 22.8V input / output, mux…) screen. Refer
to chapter 3, pages 3-38 and 3-39,
screenshot 1, (2).
– Check 24V supply current in the
« Open diagnostic pages (alarm,
input / output, mux…) screen. Refer
screenshot 1, (3). If I 24V > 4A,
search for overconsumption cause.
– With a multi-meter, check 24V
voltage at 24V supply output. If
measurement confirms voltage fault,
replace power supply.
24V supply voltage is higher than – Check 24V supply voltage in the
+24V → Too high 25.2V. « Open diagnostic pages (alarm,
Max = 25.2V input / output, mux…) screen. Refer
screenshot 1, (2).
– With a multimeter, check 24V voltage
at 24V supply output. If measurement
confirms voltage fault, replace power
supply.


(Min./Max. values)
5V (pressure and temperature) sensor – Check 5V sensor power supply

+5V sensor → Too supply voltage is lower than 4.75V. voltage in the « Open diagnostic
low pages (alarm, input / output, mux…)
Min = 4.75 screen. Refer to chapter 3, pages 3-
One of the two pressure sensors is – Check 5V sensor power supply

faulty and decreases the 5V sensor voltage in the « Open diagnostic
supply. pages (alarm, input / output, mux…)
screen. Refer to chapter 3, pages 3-
Disconnect successively pressure
sensors at J5 and J9:
• If voltage becomes normal again,
replace the faulty pressure
sensor.
• If voltage remains out of
specifications, replace supply
board.
5V (pressure and temperature) sensor – Check 5V sensor power supply

+5V sensor → Too supply voltage is higher than 5.25V. voltage in the « Open diagnostic
high pages (alarm, input / output, mux…)
Max = 5.25V screen. Refer to chapter 3, pages 3-
One of intermediate voltages – Check corresponding voltage in the

+xxV → Too high generated by power supply board does « Open diagnostic pages (alarm,
not comply with the table below. input / output, mux…) screen. Refer
+xxV → Too low to chapter 3, pages 3-38 and 3-39.
Low +xxV high
– Replace supply board.
3.135 +3.3V 3.465
3.8 +4V 4.2
4.75 +5V 5.25
11.4 +12V 12.6
Flow calculated from sample pressure – Check flow rate in the « Open
Flow → Too low is lower than 10 Nl/min. diagnostic pages (alarm, input /
Min = 10 Nl/min output, mux…) screen. Refer to
chapter 3, pages 3-38 and 3-39,
screenshot 1, (11).
– Check sample pressure and reaction
chamber pressure in the synoptic
screen. Refer to chapter 3, page 3-28
(4) and (8).
SEPTEMBER 2019
5–13

(Min./Max. values)
– Check flow rate at sample inlet with a

reference flowmeter.
Calculated flow rate is zero because – Refer to the above alarm message:
reaction chamber pressure is too high. Chamber Pr. → Too high
Calculated flow rate is low because – Refer to the above alarm message:
sample pressure is too low. Sample Pr. → Too low
Flow rate calculated from sample – Check flow rate in the « Open
Flow → Too high pressure is higher than 90 Nl/min. diagnostic pages (alarm, input /
Max = 90 Nl/min output, mux…) screen. Refer to
chapter 3, pages 3-38 and 3-39,
screenshot 1, (11).
– Check sample pressure and pressure
inside reaction chamber in the
synoptic screen. Refer to chapter 3,
page 3-28, (4) and (8).
– Check flow rate at sample inlet with a
reference flowmeter.
Calculated flow rate is too high – Refer to the above alarm message:
because of too high sample pressure. Sample Pr. → Too high.
Theoretical molybdenum cartridge – Perform a GPT (gaseous phase

NOx filter → Low lifetime of NOx converter is exceeded. titration) efficiency test. Refer to
level chapter 3, page 3-58, section 3.5.5.
• Positive GPT test: Update NOx
life-cycle counter in the
« Advanced analyzer
configuration » screen according
to the next programmed GPT
test. Refer to chapter 3, page 3-
44.
• Negative GPT test: perform NOx
converter maintenance, then re-
initialize NOx life-cycle counter.
NO or NOx span coefficient, – Search for big sensitivity change

NO → Calibration determined by automatic calibration, is cause and remedy it.
fault more than 50% different from the
previous coefficient. The analyzer
NOx → Calibration keeps the previous coefficient and
fault calibration alarm is triggered.
Span gas was not used to perform – Check that hard span gas inlet
calibration cycle. corresponds to inlet set for automatic


(Min./Max. values)
calibration cycle in the « Automatic

cycle configuration » screen. Refer to
chapter 3, page 3-34.
– Check that span gas cylinder is open
and that an excess flow rate is
present.
– If diluter is used as span source,
make sure that generated
concentration corresponds to
required concentration.
Declared concentrations are incorrect. – Check that span concentrations

declared in the « Advanced analyzer
configuration » screen correspond to
span mixture composition. Refer to
Previous span coefficient is not valid. – Manually enter a new coefficient

close to the calculated coefficient in
the « Advanced analyzer
configuration » screen, and restart an
automatic calibration. Refer to
Note: manual coefficient modification
cancels calibration alarm.
Calculated (NO, NOx or NO2) – Search for exceedance cause.

NO → Overflow compound concentration exceeds
Threshold1 – Adjust Threshold 1 in the « Advanced
declared value at threshold 1 for this
analyzer configuration » screen.
compound in the « Advanced analyzer
Refer to chapter 3, page 3-43.
NOx → Overflow configuration » screen.
Threshold1
NO2 → Overflow
Threshold1
Calculated (NO, NOx or NO2) – Search for exceedance cause.

NO → Overflow compound concentration exceeds
Threshold2 – Adjust Threshold 2 in the « Advanced
declared value at threshold 2 for this
analyzer configuration » screen.
compound in the « Advanced analyzer
Refer to chapter 3, page 3-43.
NOx → Overflow configuration » screen.
Threshold2
NO2 → Overflow
Threshold2
SEPTEMBER 2019
5–15

(Min./Max. values)

SEPTEMBER 2019
5–17
Table 5–2 – Interconnection board connections and LED description
Jumpers Connections
J1 Controller board (with ribbon cable)
J2 Power supply board
J3 ARM20 board (with ribbon cable) J2
J4 24VDC input
J5 Chamber pressure sensor
J6 Zero solenoid valve
J7 SCP board
J8 Span solenoid valve
J9 Sample pressure sensor
J10 Rack fan
J11 NH3 solenoid valve (optional)
J12 Peltier fan
J13 NOx solenoid valve
J15 24 V external supply of ESTEL
J17 J1 Ozone generator
J19 External Zero/Span solenoid valves
J23 External Ethernet port
J24 Ethernet port LAN1 of ARM20 board
J26 J1 RTP board (with ribbon cable)
J27 J1 Measurement board (with ribbon cable)
J28 External USB1
J29 Internal temperature sensor
J30 External USB2
J31 Internal USB3
J32 NOx converter oven
J33 Permeation bench (optional)
F1 8A T Fuse
LED N° Identification Turned ON Turned OFF Blinking Jumper

LED1 Span solenoid valve Active Disabled N.A. J8
LED2 SCP board for vacuum pump Active Disabled N.A. J7
LED3 Rack fan (electronics side) Active Disabled N.A. J10
LED4 Zero solenoid valve Active Disabled N.A. J6
LED5 NH3 solenoid valve (option) Active Disabled N.A. J11
LED6 Peltier fan (CLD module side) Active Disabled N.A. J12
LED7 NOx solenoid valve Active Disabled N.A. J13
LED9 NOx converter oven Heating Disabled Regulating J32
LED10 Permeation bench (option) Heating Disabled Regulating J33
LED12 Ozone generator Active Disabled N.A. J17
LED13 Input 24VDC Active Disabled N.A. J4

Figure 5–1 – Interconnection board diagram
SEPTEMBER 2019
5–19
Table 5–3 – Controller board connections and LED description
Jumpers Connections
J1 Interconnection board
J3 Programming
LED N° Identification Color Turned on Turned off Blinking

LED1 Activity indicator Amber Active Disabled – Fast: loading mode
– Slow (1Hz): normal
mode
LED3 USB on channel 1 Green Detected Not N.A.
detected
detected
detected
detected
Figure 5–2 – Controller board diagram

Table 5–4 – Power supply board connection and LED description
Jumper Connection
J1 J2 interconnection board
Jumper Function Normal status

ST1 ON/OFF front panel switch Not present (open)
LED N° Identification Color Turned on Turned off

LED1 + 24 V indicator Orange Present Not present
LED4 + 3.3 V indicator Blue Present Not present
Figure 5–3 – Power supply board diagram
SEPTEMBER 2019
5–21
Table 5–5 – Measurement board connections, test points and LED description
Jumpers Connections
J1 Ribbon cable towards Interconnection board J27
J7 Reaction chamber temperature sensor
J8 Reaction chamber heating resistor
J41 Photomultiplier (PM) preamplifier board (with ribbon cable) J1
Test points Signal

PT1 GND
PT2 Analog GND
PT41 Photomultiplier (PM) signal (high gain amplification)
PT43 Photomultiplier (PM) high voltage (HV) setting
PT114 Photomultiplier (PM) signal (low gain channel)

LED1 USB indicator Green Detected Not detected N.A.
LED2 Board activity indicator Orange Active No activity Fast: loading
Slow: normal
LED3 Reaction Chamber heater Red Heater ON Heater OFF Regulation
LED4 5 V supply Red Active Disabled N.A.
Figure 5–4 – Measurement board diagram

Table 5–6 – Ozone generator board connection,

adjustment, test points and LED description
Jumper Connection
J1 Interconnection board J17
Jumper Function
S1 DIP switch adjustment of Ozone generator intensity ( 66mA typically )
Min. Max.
Left OFF ON OFF ON OFF ON OFF ON
Middle OFF OFF ON ON OFF OFF ON ON
Right OFF OFF OFF OFF ON ON ON ON
Test points Signals

PT1 GND
PT2 +21V
PT3 Clock signal
PT4 Transformer input

LED5 +21V Orange Active Disabled N.A.
LED6 +5V (local) Blue Active Disabled N.A.
SEPTEMBER 2019
5–23
Figure 5–5 – Ozone generator board diagram

Table 5–7 – Photomultiplier (PM) preamplifier board connection,

test points, adjustments and LED description
Jumper Connection
J1 Measurement board (ribbon cable)
Potentiometers* Nature of adjustments

P1 Photomultiplier (PM) signal amplification (high CH1 gain)
P2 Photomultiplier (PM) signal offset (high CH1 gain)
P4 Photomultiplier (PM) signal amplification (low CH2 gain)
P5 Photomultiplier (PM) signal offset (low CH2 gain)
Test points Signal

PT1 GND
PT2 Photomultiplier (PM) signal (high CH1 gain)
PT6 Photomultiplier (PM) signal (low CH2 gain)
LED N° Identification Color Turned Turned off Blinking

on
LED1 5 V supply Red Active No supply N.A.
* Turn clock wise (CW) to increase the gain/offset. Turn counter-clock wise (CCW) to decrease the
gain/offset.
Figure 5–6 – PM preamplifier board diagram
SEPTEMBER 2019
5–25
Table 5–8 – RTP board connections and LED description
Jumpers Connections
J1 Cable to Peltier and photomultiplier (PM) of temperature probe
J2 Interconnection board (ribbon cable) J14
LED N° Identification Color Turned Turned off Blinking

on
LED1 Peltier activity Orange Cooling Inactive N.A.
LED2 Converter control Orange Good Bad N.A.
Figure 5–7 – RTP board diagram

Table 5–9 – SCP board connections and LED description
Jumpers Connections
J1 Mains supply, external pump socket, 24VDC power supply AC input
J2 Cable to interconnection board J7

LD1 Vacuum pump control Red ON OFF N.A.
Figure 5–8 – SCP board diagram
SEPTEMBER 2019
5–27
Table 5–10 – ICB board connections
Jumpers Connections
J1 Interconnection board J32 (NOx converter) J33 (Permeation oven)
J2 Cable to Pt100 temperature probe (1&2) cable to heater (3&4). No polarity.
Figure 5–9 – ICB board diagram

Table 5–11 – ARM20 board connections and LED description
Jumpers Connections
J1 LVDS color display
J2 Interconnection board (ribbon cable) J3
J6 Touch screen (capacitive)
J9 ON/OFF front switch with red/blue indicator
LAN1 Ethernet port. Interconnection board J24
USB-HOS1 USB 2.0 on front panel
SD/MMC1 SD memory board
SC1 Supercar
BT1 Clock battery
Switches Functions
SW1 Recovery
SW2 Reset
SW3 Power ON/OFF
S1 DIP switch
OFF/OFF/OFF: normal mode
OFF/ON/OFF: restore mode

LED1 USB1 Green Active Inactive N.A.
LED7 Supercar charge Orange Charge ON Charge OFF N.A.
LED14 3.3V supply Green OK OFF N.A.
LED15 5V supply Green OK OFF N.A.
LED16 12V supply Green OK OFF N.A.
LED17 5V ext Red OK OFF N.A.
SEPTEMBER 2019
5–29
ARM20 board (back view)
ARM20 board (front view)
Figure 5–10 – ARM20 board diagram

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Defects that fall under warranty

Duration and starting point of the warranty

Modalities or exercising the warranty

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CHAPTER 1. GENERAL - CHARACTERISTICS

CHAPTER 2 OPERATION PRINCIPLE

CHAPTER 3 OPERATING INSTRUCTIONS

CHAPTER 4 PREVENTIVE MAINTENANCE

CHAPTER 5 CORRECTIVE MAINTENANCE

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Figure 1–1 – ENVEA AC32e (with touch screen). 1–2

Figure 2-1 – Black cycle (zero-reference) diagram 2–4

Figure 3–1 – Fluid and electrical connections 3–4

Figure 4–1 – Sample inlet dust filter replacement 4–5

Figure 5–1 – Interconnection board diagram 5–19

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Table 5–1 – List of faults and corrective actions 5–6

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Page Date Page Date Page Date

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Figure 1–1 – ENVEA AC32e (with touch screen). 1–2

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Figure 1–1 – ENVEA AC32e (with touch screen).

Figure 1–2 – ENVEA AC32e (without touch screen).

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This analyzer is also available in AC32e (without touch screen) version.

Figure 1–3 – Color touch screen

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1.1.2.2 Rear panel

Gas inlets/outlets (right-hand side):

Electrical equipment and connections (left-hand side):

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Figure 1–4 – AC32e rear panel and external pump

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1.1.2.3 Internal view

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Figure 1–5 – AC32e internal view

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1.1.3 VARIOUS OPERATING MODES

1.1.4 ASSOCIATED EQUIPMENT (OPTIONAL)

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1.2.1 TECHNICAL CHARACTERISTICS

Measurement range : Programmable by user (maximum 10 ppm)

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1.2.2 STORAGE CHARACTERISTICS

1.2.3 INSTALLATION CHARACTERISTICS

USB USB Ethernet

Figure 1–6 – Links between units

1.2.3.2 Dimensions and weight

1.2.3.3 Handling and storage

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Figure 1–7 – AC32e dimensions (in mm)

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2.1 MEASUREMENT PRINCIPLE 2–3

2.2 GENERAL PRINCIPLE DIAGRAMS 2–7