Awetek Engineering Starch Crosslinking Agent CMS-431 (Rev.01032016)

CHUEN HUAH CHEMICAL
1

QUALITY BEYOND YOUR THINKING

SAFETY DATA SHEET

Starch Crosslinking Agent CMS-431

1. INFORMATION OF PRODUCT AND MANUFACTURER

Material Name Starch Crosslinking Agent

Product Code CMS-431

Chemical Name Amino Copolymer Resin

Chemical Description Amino Copolymer

CAS NO. Copolymer Mixture

Product Use Corrugated Starch Glue Additive

CHUEN HUAH CHEMICAL CO., LTD.

No. 365, Da Jen N., Rd., Gang Shan,

Kaohsiung, Taiwan, 82054
Manufacturer
Tel: +886-7-6217177

Fax: +886-7-6220593

24-Hr Assistance: +886-911347985

2. HAZARDS IDENTIFICATION

GHS Pictograms

Physical Hazards Not Classified

Skin Sensitization- Category 1
Health Hazards
Eye Irritation- Category 2A

Signal Word WARNING

Causes skin irritation. May be harmful in contact with skin. Causes
Hazard Statement
serious eye irritation. Harmful if inhaled.

Wear protective gloves/clothing. Use only outdoors or in a

well-ventilated area. Avoid breathing fume/gas/mist/vapours. If in
Precautionary Statement
eyes: rinse cautiously with water for several minutes. Continue rinsing.

If eye irritation persists, get medical advice/attention.

SDS-SC006-EN-1.0 Website: www.chctw.com Email: sales@chctw.com
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SAFETY DATA SHEET


If exposed or concerned: Get medical advice/attention. If inhaled:

Remove victim to fresh air and keep at rest in a position confortable for

breathing. If experiencing respiratory symptoms: Call a poison

center/doctor. If in eyes: Rinse continuously with water for several
Response
minutes. Remove contact lenses, if present and easy to do. Continue

rinsing. If on skin: wash with plenty of soap and water. If skin irritation

or rash occurs: Get medical attention. Eliminate all ignition sources if

safe to do so.

Store in a well-ventilated place. Store locked up. Protect from sunlight.

Storage Do not expose to temperatures exceeding 40°C/104°F. Keep container

tightly closed.

Dispose of contents/container in accordance with applicable
Disposal
local/regional/national/international regulations.

3. COMPOSITION / INFORMATION OF INGREDIENTS

Components CAS Number Content Percentage

Amino copolymer Copolymer mixture 55.0~60.0%

Additives Copolymer mixture <2.0%

Water 7732-18-5 <40.0%

4. FIRST AID MEASURES

If contact with the eye(s) occurs, wash with plenty of warm water. Take

care not to rinse contaminated water into the non-affected eye. If
Eye Contact
irritation persists, seek medical attention. Contact lenses should not be

worn when working with this product.

Wash the damaged skin with plenty of soap and water and remove the
Skin Contact
contaminated clothes. If effects persist, seek medical advice.

CHUEN HUAH CHEMICAL
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SAFETY DATA SHEET


Wash out the mouth with plenty of water. Ingestion can cause nausea

Ingestion and gastrointestinal tract irritation. Seek medical advice and show all

the details of the product.

This product is only for industrial use and is not for human

consumption. Ensure that medical personnel are aware of the

material(s) involved, and take precautions to protect themselves. If
General Advice
exposed or concerned: Get medical advice/attention. In case of

shortness of breath, give oxygen. Keep victim warm. Keep victim under

observation.

5. FIRE FIGHTING MEASURES

Flammable Properties Not flammable by OSHA criteria. Not combustible by OSHA criteria.

Extinguishing Media Water, fog, or dry chemical powder.

Protection of Firefighters Wear suitable protective equipment.

Use self-contained breathing apparatus and full protective clothing

Fire Fighting Procedures when fighting a chemical fire. Use water spray or fog to keep

fire-exposed vessels and containers cool.

Formaldehyde, CO, CO2, and NOx. Formaldehyde is a suspected
Hazardous combustion products
carciongen.

6. ACCIDENTIAL RELEASE MEASURES

Avoid direct contact. Do not touch damaged containers or spilled

Individual Precautions material unless wearing appropriate protective clothing. Keep upwind.

Keep out of low areas.

Eliminate all ignition sources (no smoking, sparks or flames in

immediate area). Collect the spilled products back into a labeled
Environment Precautions
container as much as possible, if this is without risk. Prevent this

material entering the waterways or contaminating soil.

CHUEN HUAH CHEMICAL
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SAFETY DATA SHEET


Wash the contaminated area with warm water and soap and collect the

waste water for disposal in an authorized treatment plant following the

local regulations.

Small Spills: Wipe up with absorbent materials and clean surface
Environment Precautions
thoroughly.

Large Spills: Stop the flow of material, if this is without risk. Dike the

spilled material, where it is possible. Absorb in dry sand or earth and

place into containers. Flush area with water.

7. HANDLING AND STORAGE

Wear sufficient protection and protective clothing to minimize skin and

eye exposure to the product. Do not handle, store or open near an open

Handling flame, sources of heat or sources of ignition. Protect material from

direct sunlight. Do not use in areas without adequate ventilation. Wash

thoroughly after handling.

Avoid storage temperature >104°F (40°C) or <32°F (0°C). Do not store in

direct sunlight. Keep container tightly closed. Keep away from heat,

sparks, and open flame. Keep out of the reach of children.
Storage
Open slowly in order to control possible pressure release. Store in a

cool, well-ventilated area. Treat empty containers containing residue

with same precautions as filled containers.

8 months in original and sealed packaging at the proper storage

temperature >104°F (40°C) or <32°F (0°C). Do not store outside or in
Shelf Life
direct sunlight. Storage for longer periods or beyond recommended

temperature range may reduce product performance.

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SAFETY DATA SHEET


8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Occupational Exposure Limit

U.S. ACGIH Threshold Limit Values

Components Type Value

Formaldehyde (50-00-0) Ceiling 0.3ppm

U.S. –OSHA

Material Type Value Form

PEL-STEL 2.0ppm Free gaseous formaldehyde
Aldehyde Resin
PEL-TWA 0.75ppm Free gaseous formaldehyde

U.S. –OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Components Type Value

STEL 2.0ppm
Formaldehyde
TWA 0.75ppm

Exposure Guidelines

U.S. OSHA Specifically Regulated Substances: Action Level and Reference

Formaldehyde (CAS 50-00-0) 0.5ppm

Engineering Controls Ensure adequate ventilation.

Individual Exposure Control

No necessary if the product is kept at proper temperature range and in

a well aired place. If proper ventilation cannot be maintained, then a
Respiratory Protection
full-face respirator should be used with formaldehyde cartridges.

(10ppm formaldehyde cartridge limit)

Eye Protection Safety glasses with side shields, goggles or full-face shield.

Gloves of impervious materials (e.g. polychloroprene or nitril rubber).
Skin Protection
Impermeable clothes.

Keep away from food and drink. Handle in accordance with good
General Hygiene Considerations
industrial hygiene and safety practice.

CHUEN HUAH CHEMICAL
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SAFETY DATA SHEET


9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Dark red viscous liquid.

Form Liquid.

Odor Slightly aroma.

Melting Point Not available.

Boiling Point >212°F (>100°C)

Solubility in Water Infinite

Solubility in Organic Solvents Immiscible in non-polar solvents

pH Value (77°F/25°C) 7.0~10.5 (by pH meter)

Vapor Pressure Not available.

Vapor Density Not available.

Flash Point Not applicable.

Flammability Limits-Lower Not applicable.

Flammability Limits-Upper Not applicable.

Auto-ignition Temperature Not applicable.
Viscosity (77°F/25°C) >50 cps
Specific Gravity (77°F/25°C) 1.25±0.05
10. CHEMICAL STABILITY & REACTIVITY INFORMATION

Chemical Stability Stable under normal conditions.

Nearby heat sources. Prolonged temperature >104°F (40°C) or <32°F
Conditions to Avoid
(0°C).

Incompatible Materials Strong alkalis, oxidants and strong acids.

Hazardous Decomposition The products of thermal decompositions include CO, CO2, H2O, and

Products NOx. Formaldehyde is a suspected carciongen.

Hazardous Polymerization Not occur.

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SAFETY DATA SHEET


11. TOXICOLOGICAL INFORMATION

Acute Oral Toxicity Expected to have low acute oral toxicity.

Acute Inhalation Toxicity Expected to have low acute inhalation toxicity.

Acute Dermal Toxicity Expected to have low acute dermal toxicity.

Skin Irritation Causes skin irritation.

Eye Irritation Causes serious eye irritation.

Sensitization May be harmful in contact with skin.

Genotoxicity No data available.

Mutagenicity No data available.

Specific Organ Toxicity- Single
No data available.
Exposure

Specific Organ Toxicity-
No data available.
Repeated Exposure

Aspiration Hazard No data available.

Additional Information No data available.
12. ECOLOGICAL INFORMATION

Ecological Information No data available for this product.

Contain a substance which causes risk of hazardous effects to the
Ecotoxicity
environment.

An environment hazard cannot be excluded in the event of
Environmental Effects
unprofessional handling or disposal.

Persistence and degradability Not available.

Bioaccumulation Negligible.

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SAFETY DATA SHEET


13. DISPOSAL CONSIDERATIONS

This product, in its present state, when discarded or disposed of, is

not a hazardous waste according to Federal regulations [40 CFR

261.4 (b)(4)]. Dispose of the product and waste in accordance with

Disposal Instructions all applicable regulations.

Do not allow this material to drain into sewers/water supplies. Do

not contaminate ponds, waterways or ditches with chemical or used

container.

Empty containers should be taken to an approved waste handling
Contaminated Packaging
site for recycling or disposal.

14. TRANSPORT INFORMATION

U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size or

mode of transport. You will need to apply the appropriate regulations to properly classify your shipment

for transportation.

A. Tank Truck Shipping

Proper Shipping Name: Non-regulated

UN/NA Number N/A

Hazard Class N/A

Packing Group N/A

B. Totes and Drums

Proper Shipping Name Non-regulated

UN/NA Number N/A

Hazard Class N/A

Packing Group N/A

CHUEN HUAH CHEMICAL
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SAFETY DATA SHEET


15. REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the

requirements of the Occupational Safety and Healthy Administration 29 CFR Part 1910.1200 “Hazard

Communication” Standard.

FDA

This product is approved under 21 CFR 175.105(c)(5) for use in adhesives to be used as components of

articles intended or used in packaging, transporting or holding food.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Immediate Hazard- No

Delayed Hazard- Yes

Hazard Categories Fire Hazard- No

Pressure Hazard- No

Reactivity Hazard- No

Section 311 Hazardous Chemical No

TSCA Inventory

All reportable chemical substances are listed on TSCA Inventory.

16. OTHER INFORMATION

User’s Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Material

Information System (WHMIS) require that the information contained on these sheets be made available

to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your

workers to handle this product properly. Consult with appropriate experts to guard against hazards

associated with use of this product and its ingredients.

CHUEN HUAH CHEMICAL
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SAFETY DATA SHEET


Continue

Disclaimer

The data and information presented in this material safety data sheet was prepared based on our best
knowledge and experience currently available. We reserve the right to alter specifications, according to
technical progress and new developments. The information contained herein is furnished without
warranty of any kind. It is the responsibility of the user to investigate and understand other pertinent
sources of information, to comply with all laws and procedures applicable to the safe handling and use of
the product and to determine the suitability of the product for its intended use.
Nothing contained herein constitutes an offer for the sales of any product.
Issue Date
March 1st/2016


Awetek Engineering Starch Crosslinking Agent CMS-431 (Rev.01032016)

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CHUEN HUAH CHEMICAL

SAFETY DATA SHEET

1. INFORMATION OF PRODUCT AND MANUFACTURER

SAFETY DATA SHEET

3. COMPOSITION / INFORMATION OF INGREDIENTS

4. FIRST AID MEASURES

SAFETY DATA SHEET

5. FIRE FIGHTING MEASURES

6. ACCIDENTIAL RELEASE MEASURES

SAFETY DATA SHEET

7. HANDLING AND STORAGE

SAFETY DATA SHEET

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

SAFETY DATA SHEET

9. PHYSICAL AND CHEMICAL PROPERTIES

10. CHEMICAL STABILITY & REACTIVITY INFORMATION

SAFETY DATA SHEET

11. TOXICOLOGICAL INFORMATION

12. ECOLOGICAL INFORMATION

SAFETY DATA SHEET

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

SAFETY DATA SHEET

15. REGULATORY INFORMATION

16. OTHER INFORMATION

SAFETY DATA SHEET

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