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Control No.

IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

A. PRODUCT NAME : FELDSPAR


B. RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE
Recommended use : Glass making, foundry, metallurgical, abrasives, fillers, ceramic,
filtration, petroleum industry, recreational
Restrictions on use : Used for recommended use.
C. MANUFACTURER/SUPPLIER/DISTRIBUTOR INFORMATION
MANUFACTURER : IL Shin Materials Co.,LTD

TEL: +82-43-872-3710, +82-31-777-3710, FAX:+82-31- 777-3713

2. HAZARDS IDENTIFICATION

A. HAZARD CLASSIFICATION
HEALTH HAZARDS
: Carcinogenicity: Category 1A
: Specific target organ toxicity – single exposure: Category 1
: Specific target organ toxicity – repeated exposure: Category 1

B. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS


PICTOGRAMS :

SIGNAL WORD : DANGER


HAZARD STATEMENTS
H350 : May cause cancer.
Causes damage to organs(respiratory system).
H370 :
Causes damage to organs(kidney) through prolonged or repeated
H372 :
exposure.
PRECAUTIONARY STATEMENTS
[Prevention] :
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and
understood.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270 Do no eat, drink or smoke when using this product.
P281 Use personal protective equipment as required.
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.
P308+P313 IF exposed or concerned: Get medical advice/attention.
[Response] :
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.

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Control No. IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

[Storage]
: P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with
:
local/regional/national regulations.
C. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION (e.g. Dust explosion
hazards) Health Hazard: 1 Slight.
: Flammability Hazard: 0 Minimal.
Physical Hazard: 0 Minimal.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical name / Synonym CAS No. or ID Content (%)


FELDSPAR / LITHOSPAR 68476-25-5 / 270-666-7* 100
* EU NO.

4. FIRST AID MEASURES

Do not rub eyes. Flush affected area with water. If symptoms


A. EYE CONTACT :
develop, seek medical advice.

Wash skin gently with soap and water. Remove contaminated


B. SKIN CONTACT :
clothing. If symptoms develop, seek medical advice.
Remove to fresh air and keep at rest in a position comfortable for
C. INHALATION : breathing. If not breathing, give artificial respiration. Seek medical
advice immediately.
Do not induce vomiting without medical advice. If large amounts of
D. INGESTION :
this substance are swallowed, get medical attention immediately.

E. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND NOTES FOR PHYSICIAN


Based on the individual reactions of the patient, the physician's
:
judgment should be used to control symptoms and clinical condition.

5. FIRE FIGHTING MEASURES

A. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA


: Use extinguishing media appropriate for surrounding fire.
B. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Low fire hazard. Not flammable or combustible. Not expected to be
sensitive to mechanical impact. This material is an inorganic dust and
:
will not create nor support conditions that would result in a dust
explosion or fire. Avoid breathing dust.
C. SPECIAL PROTECTIVE EQUIPMENT AND ACTIONS FOR FIRE FIGHTERS
In case of fire, wear a full face positive-pressure self contained
:
breathing apparatus and protective suit.

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Control No. IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

6. ACCIDENTAL RELEASE MEASURES

A. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY MEASURES


Do not create a dust cloud by using a brush or compressed air.
Avoid breathing dust. Do not touch spilled material. Restrict access to
: area as appropriate until clean-up operations are complete. Stop or
reduce any leaks if it is safe to do so. Wear appropriate personal
protective equipment. Ventilate spill area if possible.
B. ENVIRONMENTAL PRECAUTIONS

: Prevent runoff from entering drains, sewers, or streams.

C. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP


FOR SMALL SPILLS - Clean up promptly by vacuum.
FOR LARGE SPILLS - Persons not wearing protective equipment
should be excluded from the area of the spill until cleanup has been
completed. Stop spill at source. Prevent spilled material from
:
contaminating soil or entering drains, sewers, streams or other
bodies of water. Remove mechanically. Wash affected area. Pick up
and transfer to properly labelled containers. Dispose of material in
compliance with national regulations.

7. HANDLING AND STORAGE

A. PRECAUTIONS FOR SAFE HANDLING


Do not take internally. Protect against physical damage. Avoid dust
formation. Use with adequate ventilation. Avoid inhalation and
:
contact with eyes, skin, and clothing. Wash hands thoroughly after
handling and before eating or drinking.
B. CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES)
Store in a tightly closed container. Store in original containers away
: from incompatibles. Store container in a cool, well-ventilated area.
Store in accordance with local regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

A. OCCUPATIONAL EXPOSURE LIMIT(S), BIOLOGICAL EXPOSURE STANDARD


ACGIH Threshold Limit Values The 8-Hour Exposure Limit (TLV-TWA) is: 0.025 mg/m3

Korea. OELs (ISHL Article 42; MOL Public Notice No. 1986-45, as amended through MOL
Public Notice No. 2008-26, June 17, 2008)
The 8-hour TWA is: 0.05 mg/m3

B. APPROPRIATE ENGINEERING CONTROLS


General ventilation is recommended. Local exhaust ventilation may
:
be necessary when dusts or mists are generated.
C. INDIVIDUAL PROTECTION MEASURES

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Control No. IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

If significant dusts or, vapors or aerosols are generated an approved


respirator is recommended. A dust cartridge may be used. If
Respiratory protection : respiratory protection is required, institute a complete respiratory
protection program including selection, fit testing, training,
maintenance and inspection.
Eye protection : Not applicable

Hand protection : Not applicable

Body protection : Not applicable

9. PHYSICAL AND CHEMICAL PROPERTIES

A. APPEARANCE (PHYSICAL STATE, COLOUR etc.): Powder (IUCLID)


B. Odour : Odorless
C. ODOR THRESHOLD : Not applicable
D. pH : 6(6~7)10 vol % and 100 deg c) (IUCLID)
E. MELTING POINT/FREEZING POINT : 1,165~1,600°C [IUCLID]
F. INITIAL BOILING POINT AND BOILING RANGE : 1,600°C [IUCLID]
G. FLASH POINT : Not applicable
H. EVAPORATION RATE: Not applicable
I. FLAMMABILITY (SOLID, GAS) : Not applicable
J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS
: - / -((6~7)10vol % and 100 deg c) (IUCLID)
K. VAPOR PRESSURE : Not applicable
L. SOLUBILITY : (<0.1 vol% at22 deg c) (IUCLID)
M. VAPOR DENSITY : Not applicable
N. RELATIVE DENSITY : 2.56(2.56~2.59)g/cm3 at 22°C)[IUCLID]
O. PARTITION COEFFICIENT OF n-OCTANOL/WATER
: Not applicable
P. AUTO-IGNITION TEMPERATURE : Not applicable
Q. DECOMPOSITION TEMPERATURE : Not applicable
R. VISCOSITY : Not applicable

S. MOLECULAR WEIGHT : Not applicable

10. STABILITY AND REACTIVITY

Material is stable under recommended storage temperatures and


A. CHEMICAL STABILITY :
pressures. Hazardous polymerization will not occur.
B. POSSIBILITY OF HAZARDOUS REACTIONS : Not available.
C. CONDITIONS TO AVOID (STATIC DISCHARGE, SHOCK, VIBRATION etc.):
: Dust generation.
D. SUBSTANCES TO AVOID
: Avoid contact with excessive heat and incompatible materials.

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Control No. IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

E. HAZARDOUS DECOMPOSITION PRODUCTS


: Corrosiveness/Toxicity Gas/Fume

11. TOXICOLOGICAL INFORMATION

A. Information on the likely routes of exposure


Inhalation : Yes
Ingestion : No
Eye/Skin
Eye : Yes
Skin : Yes
B. Delayed and immediate effects and also chronic effects from short and long term exposure
Acute toxicity (possible route of exposure) :
Oral (LD50) : Not available
Skin (LD50) : Not available
Inhalation (LC50) : Not available
Skin corrosion/irritation : Not available
Serious eye damage/irritation Not available
Respiratory sensitization : Not available
Skin sensitization : : Not available
Carcinogenicity :
IARC : Group1
National Toxicology Program (NTP): K
EU : Not available

: Not available
Germ cell mutagenicity

: Not available
Reproductive toxicity
STOST-single exposure

Its short-term exposure also affects the respiratory system in humans


: in case of high inhalation concentration although there is much little
data compared with repeated exposure.

STOST-repeated exposure
: The respiratory system and the kidney are affected in humans
Aspiration hazard : Not available

12. ECOLOGICAL INFORMATION

A. Aquatic/terrestrial ecology toxicity


Fish (LC50) : Not available
Daphnia (EC50) : Not available
Algae (EC50) : Not available
B. Persistence and degradability

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Control No. IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

Persistence : Not available


Degradability : Not available
C. Bioaccumulative potential : Not available
D. Mobility in soil : Not available
E. Other hazardous effects :
: Not available

13. DISPOSAL CONSIDERATIONS

A. DISPOSAL METHODS

Do not allow material to contaminate ground water system. Recycle


or reuse waste. Dispose of surplus and non-recyclable products via a
:
licensed waste disposal contractor. Remove waste in accordance with
local and national regulations, disposal by landfill incineration.

B. PRECAUTIONS (INCLUDING DISPOSAL OF CONTAMINATED CONTAINER OR PACKAGE)


Contaoners should be cleaned by appropriate method and the reused
: or disposed by landfill or incinerate as appropriate, in accordance
with local and national regulations. Do not remove label until
container is throughly cleaned.

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping
paper (BL). Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation.
A. UN NUMBER : Not regulated
B. UN PROPER SHIPPING NAME
: Not regulated
C. TRANSPORT HAZARD CLASS(ES)
: Not regulated
D. PACKING GROUP (IF APPLICABLE)
: Not regulated
E. MARINE POLLUTANT SUBSTANCES (APPLICABLE/NOT APPLICABLE)
: Not applicable
F. SPECIAL PRECAUTIONS FOR USER
: Not available

15. REGULATORY INFORMATION

A. REGULATIONS BY THE INDUSTRY SAFETY HEALTH LAW (ISHL) - Korea


Listed in occupational exposure limits
: Regulated
B. REGULATIONS BY THE TOXIC CHEMICAL CONTROL LAW (TCCL) - Korea
Korean Existing Chemicals : KE-16962

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Control No. IS-10-5

Material Safety Data sheet (MSDS) Date First 29-Dec-08

Date Final 1-Jun-17

HPV Program : Regulated


C. REGULATIONS BY THE DANGEROUS SUBSTANCES SAFETY MANAGEMENT ACT
: Not regulated.
D. REGULATIONS BY THE WASTE CONTROL ACT
: Public Controlled Waste(dust)
E. OTHER DOMESTIC AND OVERSEAS REGULATIONS
EUROPEAN UNION
Not regulated
UNITED STATES REGULATORY INFORMATION
OSHA Hazard
Communication Not regulated
Standard
CERCLA Not regulated
NOTE: The regulatory information given above only indicates the principal regulations specifically
applicable to the product described in the Safety Data Sheet. The user's attention is drawn to the
possible existence of additional provisions which complete these regulations. Refer to all applicable
national, international and local regulations or provisions.

16. OTHER INFORMATION

A. SOURCE OF DATA :
Guideline for Globally Harmonized System of Classification and Labelling of Chemicals
(GHS).
International Uniform Chemical Information Database
B. THE DATE OF PREPARATION OF THE MSDS : December 29, 2008
C. THE NUMBER OF TIMES REVISED AND THE DATE OF PREPARATION OF THE LATEST REVISION
3th
revision number :
date of the latest revision
: June 1, 2017
D. OTHER INFORMATION :
The above information is believed to be correct but does not propose to be all inclusive and
shall be used only as a guide. IL SHIN Materials Co.,LTD shall not be held liable for any
damage resulting from handling or from contact with the above product. Each individual
should make a determination as to the suitability of the information for their particular
purpose(s). Various government agencies may have specific regulations regarding the
transportation, handling, storage, use, or disposal of this product which may not be covered
by this MSDS. The user is responsible for full compliance.

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