Safety data sheet

According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: ASUDEL BLACK BM-SD
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Textile dyes. For professional use only.
1.3 Details of the supplier of the safety data sheet: APLICACIÓN Y SUMINISTROS TEXTILES, S.A.
AV. CAMÍ REIAL 13-15
08184 PALAU-SOLITÀ I PLEGAMANS - BARCELONA - España
Phone.: +34938647111 - Fax: +34938645104
chemicals@asutex.es
www.asutex.com
1.4 Emergency telephone number: +34938647111 (8:00 - 17:00)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
Directive 67/548/EC and Directive 1999/45/EC:
This product was classified in accordance with Directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to
Regulation (EC) nº1907/2006 (REACH regulation).
Xi: R43 - May cause sensitisation by skin contact
CLP Regulation (EC) nº 1272/2008:
The product is not classified as dangerous according to CLP Regulation (EC) nº 1272/2008.
2.2 Label elements:
Directive 67/548/EC and Directive 1999/45/EC:
In accordance with the legislation, the elements on the label are as follows:
Xi

Irritant

R Phrases:
R43: May cause sensitisation by skin contact
S Phrases:
S24: Avoid contact with skin
S37: Wear suitable gloves
Supplementary information:
Non-applicable
CLP Regulation (EC) nº 1272/2008:
See sections 11 and 12.
2.3 Other hazards:
Non-applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical description: Soluble dye/s
Components:
None of the substances contained in the mixture are above the values fixed in Annex II of Regulation (EC) nº1907/2006

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
Consult a doctor in case of discomfort with this Security Data Sheet.
By inhalation:

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTION 4: FIRST AID MEASURES (continue)

By inhalation:
In case of symptoms, move the person affected into fresh air.
By skin contact:
In case of contact it is recommended to clean the affected area thoroughly with water and neutral soap. In case of modifications
on the skin (stinging, redness, rashes, blisters,…), seek medical advice with this Security Data Sheet
By eye contact:
Rinse with water until the product has been eliminated. In case of problems, consult a doctor with the MSDS of this product.
By consumption:
In case of consumption in large quantities, it is recommended to seek medical assistance.
4.2 Most important symptoms and effects, both acute and delayed:
No symptoms or delayed effects.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
Product is non-flammable, low risk of fire by the inflammability characteristics of the product in normal conditions of storage,
manipulation and use. In the case of the existence of sustained combustion as a result of improper manipulation, storage or use
any type of extinguishing agent can be used (ABC Powder, water,...)
5.2 Special hazards arising from the substance or mixture:
Due to its non-flammable nature, the product does not present a fire risk under normal conditions of storage, manipulation and
use.
5.3 Advice for firefighters:
Have available a minimum of emergency facilities or equipment (fire blankets, portable first aid kit,...) in accordance with
Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
Sweep up and shovel product or other means and place in container for reuse (preferred) or disposal See sections 8 and 13.
6.2 Environmental precautions:
In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Sweep up and shovel product or other means and place in container for reuse (preferred) or disposal
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
A.- Precautions for safe manipulation
Comply with the current legislation concerning the prevention of industrial risks with regards manually handling weights.
Maintain order, cleanliness and destroy using safe methods (section 6).
B.- Technical recommendations for the prevention of fires and explosions
It is recommended to transfer at a slow speed to avoid the creation of electrostatic charges that could affect flammable
products. Consult section 10 for conditions and materials that should be avoided.

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTIONIt7:is HANDLING
recommendedAND
to transfer
STORAGEat a slow speed to avoid the creation of electrostatic charges that could affect flammable
(continue)
products. Consult section 10 for conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container.
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximun Temp.: 30 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the work environment
There are no environmental limits for the substances contained in the product
DNEL (Workers):
Non-applicable
DNEL (Population):
Non-applicable
PNEC:
Non-applicable
8.2 Exposure controls:
A.- General security and hygiene measures in the work place
As a preventative measure it is recommended to use basic individual protection equipment, with the corresponding "CE
marking" in accordance with Directive 89/686/EC. For more information on individual protection equipment (storage, use,
cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more
infomation see epigraph 7.1.
B.- Respiratory protection
LRP Pictogram PPE Labelling CEN Standard Remarks

Replace when an increase in resistence to

Filter mask for particles EN 149:2001+A1:2009
breathing is observed.
Compulsory use of
face mask
C.- Specific protection for the hands
LRP Pictogram PPE Labelling CEN Standard Remarks

EN 374-1:2003
Chemical protective gloves EN 374-3:2003/AC:2006 Replace the gloves at any sign of deterioration.
EN 420:2003+A1:2009
Mandatory hand
protection
D.- Ocular and facial protection

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

LRP Pictogram PPE Labelling CEN Standard Remarks

EN 166:2001
Panoramic glasses against EN 172:1994/A1:2000 Clean daily and disinfect periodically according to
liquid splash EN 172:1994/A2:2001 the manufacturer´s instructions.
Mandatory face EN 165:2005
protection
E.- Bodily protection
LRP Pictogram PPE Labelling CEN Standard Remarks

Work clothing EN 340:2003 For professional use only.

EN ISO 20347:2004/A1:2007
Anti-slip work shoes None
EN ISO 20344:2011

F.- Additional emergency measures

It is not necessary to take additional emergency measures.

Environmental exposure controls:

This product does not contain substances dangerous to the environment, although it is recommended not to spill it. For additional
information see epigraph 7.1.D
Volatil organic compounds:
With regard to Directive 1999/13/EC, this product has the following characteristics:
V.O.C. (Supply): 0 % weight
V.O.C. density at 20 ºC: 0 kg/m³ (0 g/L)
Average carbon number: Non-applicable
Average molecular weight: Non-applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:
For complete information see the product datasheet.
Apperance:
Physical state at 20 ºC: Solid
Apperance: Powdery
Color: Black
Odor: Odourless
Volatility:
Boiling point at atmospheric pressure: Non-applicable *
Vapour pressure at 20 ºC: Non-applicable *
Vapour pressure at 50 ºC: Non-applicable *
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: Non-applicable *
Relative density at 20 ºC: Non-applicable *
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

Concentration: Non-applicable *
pH: 7 - 8,5
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: 30 kg/m³
Solubility property: Non-applicable *
Decomposition temperature: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Autoignition temperature: 324 ºC
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
9.2 Other information:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the conditions no hazardous reactions are expected to produce a pressure or excessive temperatures.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

10.5 Incompatible materials:

Acids Water Combustive materials Combustible materials Others
Not applicable Not applicable Not applicable Not applicable Not applicable

10.6 Hazardous decomposition products:

See epigraph 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic
compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:
LD50 oral > 2000 mg/kg (rat)
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure
limits, it may result in adverse effects on health depending on the means of exposure:
A.- Ingestion:
Based on available data, the classification criteria are not met
B- Inhalation:
Based on available data, the classification criteria are not met

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTION 11: TOXICOLOGICAL INFORMATION (continue)

C- Contact with the skin and the eyes:
Based on available data, the classification criteria are not met
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
Based on available data, the classification criteria are not met
E- Sensitizing effects:
Based on available data, the classification criteria are not met
F- Specific target organ toxicity (STOT)-time exposure:
Based on available data, the classification criteria are not met
G- Specific target organ toxicity (STOT)-repeated exposure:
Based on available data, the classification criteria are not met
H- Aspiration hazard:
Based on available data, the classification criteria are not met
Other information:
Non-applicable
Specific toxicology information on the substances:
Not available

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the ecotoxicological properties of the mixture itself is not available
12.1 Toxicity:
Not available
12.2 Persistence and degradability:
Not available
12.3 Bioaccumulative potential:
Not available
12.4 Mobility in soil:
Not available
12.5 Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Code Description Waste class (Directive 2008/98/EC)
04 02 16* Dyestuffs and pigments containing dangerous substances Dangerous
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex
2 (Directive 2008/98/EC). As under 15 01 (2000/532/EC) of the code and in case the container has been in direct contact with
the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue.
We do not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) nº1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2000/532/EC: Commission Decision of 3 May 2000

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

ASUDEL BLACK BM-SD

SECTION 14: TRANSPORT INFORMATION

This product is not regulated for transport (ADR/RID,IMDG,IATA)

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable
Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable
Active substances for which a decision of non-inclusion onto Annex I or IA of Directive 98/8/EC Non-applicable
Regulation (EC) 689/2008, in relation to the import and export of hazardous chemical products: Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Non-applicable
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local
circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this
product.
Other legislation:
Non-applicable
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of
Regulation (EC) Nº 1907/2006
Modifications related to the previous security card which concerns the ways of managing risks. :
Directive 67/548/EC and Directive 1999/45/EC:
· Pictograms
· R Phrases
· S Phrases
Text of R-phrases considered in section 3:
Directive 67/548/EC and Directive 1999/45/EC:
Non-applicable
CLP Regulation (EC) nº 1272/2008:
Non-applicable
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension
and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu
http://echa.europa.eu
http://eur-lex.europa.eu

The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy.
This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users
of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the
manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those
specified.

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