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Topic 5 and 15 Mixed Answers
Topic 5 and 15 Mixed Answers
Topic 5 and 15 Mixed Answers
A
[1]
0.41 (kJ)
(iii) ∆HcO = 0.0163(mol) / –25153 (J mol–1);
IB Questionbank Chemistry 1
3. D
[1]
4. A
[1]
(ii) the enthalpy change when (one mole of) the gaseous bond is
broken (or formed) / X–Y(g) → X(g) + Y(g) / X(g) + Y(g) → X–Y(g);
averaged for the same bond in a number of similar compounds / OWTTE;
2
(iii) energy in: C=C + H–H and energy out: C–C + 2C–H;
Accept energy in C–C + 6C–H + C=C + H–H and energy
out 2C–C + 8C–H.
∆H = (612 + 436) – (347 + 826) = 1048 – 1173 / –125 (kJ mol–1); 2
Award [2] for correct final answer.
Award [1] for +125.
If old Data Booklet values then allow: ∆H = 1048 – 1172
= –124 (kJ mol–1)
(iv) due to the relative strength of the C–C and 2C–H bonds
compared to the C=C and H–H bonds / bonds in products
stronger than bonds in reactants; 1
[7]
7. D
[1]
IB Questionbank Chemistry 2
8. C
[1]
9. B
[1]
10. D
[1]
11. the reaction gives out (Gibbs Free) energy that can do work;
∆G for the reaction has a negative value;
a reaction that occurs without adding energy (beyond that required to
overcome energy barrier); 1 max
[1]
˜Þ12. (i) by definition ∆HhO of elements (in their standard states) is zero / no
reaction involved / OWTTE; 1
(128 298)
(iv) ∆G = ∆H – T∆S = –124.4 – 1000 ;
= –86.3 kJ mol–1; 2
Units needed for the mark.
Award [2] for correct final answer.
Allow ECF if only one error in first marking point.
IB Questionbank Chemistry 3
(v) ∆G = ∆H – T∆S = 0 / ∆H = T∆S;
124.4
T = 128 / 1000 = 972 K / 699 °C; 2
Only penalize incorrect units for T and inconsistent ΔS value
once in (iv) and (v).
[9]
13. B
[1]
14. A
[1]
15. A
[1]
16. (i) I:
atomization/sublimation (of Mg) / ∆HOatomization(Mg) / ∆HOsublimation(Mg);
V:
enthalpy change of formation of (MgCl2) / ∆HOformation(MgCl2); 2
IB Questionbank Chemistry 4
17. (i) c: atomization (enthalpy);
d: electron affinity; 2
(ii) d and e; 1
(iv) Ca2+ is smaller than K+ and Ca2+ has more charge than K+ / Ca2+ has a
greater charge density;
so the attractive forces between the ions are stronger;
Do not accept “stronger ionic bonds”
Award [1 max] if reference is made to atoms or molecules instead of ions.
2
[7]
18. C
[1]
e; 1
(iv) Ca2+ is smaller than K+ and Ca2+ has more charge than K+ / Ca2+ has a
greater charge density;
so the attractive forces between the ions are stronger;
Do not accept “stronger ionic bonds”
Award [1 max] if reference is made to atoms or molecules instead of ions.
2
[7]
19. D
[1]
IB Questionbank Chemistry 5
20. (i) lattice enthalpy for a particular ionic compound is defined as ΔH for the
process, MX(s) → M+(g) + X–(g);
Accept definition for exothermic process
electron affinity is the energy change that occurs when an electron is
added
to a gaseous atom or ion; 2
(ii)
H f = – 4 1 1 k J m o l –1
N a (s) + 1 2 C l2 (g ) N a C l(s )
+ 1 0 8 k J m o l –1 + 1 2 1 k J m o l –1
N a (g ) C l(g )
–1
+494 kJ m ol – 3 6 4 k J m o l –1
–
N a+ (g ) + C l (g )
lattice enthalpy = –[(–411) – (+108) – (+494) – (+121) – (–364)]
= 770 (kJ mol–1)
Award [2] for all correct formulas in correct positions
on cycle diagram.
1 incorrect or missing label award [1].
Award [1] for all correct values in correct positions
on cycle diagram.
calculation of lattice enthalpy of NaCl(s) = 770 (kJ mol –1); 4
Allow ECF.
Accept alternative method e.g. energy level diagram.
IB Questionbank Chemistry 6