766 ) Objective Chemistry for NEET/AIIMS

288. In which of the following lewis dot structure is (c) CIO <ClO, < Cl0, < ClO, (CI-O bond
written with incorrect formal charge ?
(d) SO <SO <SO (S-O bond)
(a) N-N (b) o 297. Which of the following order is not correct?
(c):0-N-0: d)-N-N (a) C=o>C=C>C= C Bond ener
289. Which of the following bond strength order is not
correct?
(b)=CH<C-H<-C-H Bond length
(a) Diamond < Graphite [C-C bond]
(6) HCO HCO, [C-0 bond] (c) Cl2> Br2 >F2 2l2 Bond length
() Axial P -Cl bond is PCls <P-Cl bond in Pcl; (d) PO< SO <CIO Bond order
d) Equatorial I- F bond> AxialI - F bond [InIF, 1 298. The correct order of increasing C-O bond strength
290. Incorrect statement for HPO ion is: of CO,CO,co, is
(a) All HPO bond angles are identical due to (a) CO < CO2 < CO (b) CO, <co <Co
resonance.
(c) CO<CO <CO2 (d) Co<CO, <Co
b) All bond lengths are identical due to resonance.
299. Resonance structures can be written for ;
(c) The bond order of all P - O bond is 1.33
(a) Og (b) NH3 (c) CH (d) H,0
d) None of the above
291. The formal charges on different atoms in the lewis
300. The correct order of Cl --0 bond order is
structure of N3 are not

(a) -1+1, -1 (b) -1, +1,0

(a) Clo <
ClO, <
Cl0, <
Clo
(c)-2, +1,0 (d) 0, +1,-2 (b) Clo CIO, CIO < CIO2
< <

292. Bond order and formal

charge of perchlorate ion are: (c) Clo < ClO2 < ClO <ClO
(a) 1.75 and -0.25 (b) 1.75 and -0.33
(c) 1.66 and -0.33 (d) 1.50 and -0.50
(d) Clo <
ClO, <Cl02 <
ClO
293. Arrange the molecules 301. The strongest P-O bond is found in
H2,02,F2,N2
in the order of the molecule:
increasing bond length: (a) FPO (b) Ci,PO
(a) H2>F2 <02 <N2 (b) H2 <N2 <O2 <F2 (c)BrPO (d) (CH),PO
(c) N2 <02 <F2 <H2 (a) O2 <N2 <H2 <F2 302. The bond length of the S-O bond is maximum in
294. Which of the following statement is which of the following
not correct? compounds?
(a) All C-0 bond length are (a) SOCl2 b) SOBr2
equal in HcOO but
not in HCOOH (c) SOF2 (d) All have same lengt
b) C-O bond length in HCO0 and C0 bond
length in CO are equal Bond Angle
(c) No. of shared and unshared electrons are equal in 303. In which of the
following change, adjacent bonc
N angle increases?
(d) PCl, and PCl have different (P-CI) bond
(a) BeF2 +2F BeF2
energy (b) SiF4 +2F SiF
295. Which of the following molecule contains shortest
N-Obond? (c)BF3+F BF4
(a) NOF (d) NH +H*. > NH
(b) NO (c) NO3 (d) NHOH
304. Molecule which does
296. The correct order of increasing bond order: not contain any F-X=
bond angle which is less than
(a) Co < CO2 < CO (C-0 bond) 90°?
(X = central atom)

(a) IF (b) BrF3 (c) PF5 (d) SF

305. Which of the
b) CN < NCN <R-C-NH, (C-bond) following molecule has two lonepa
and bond angle < 109°28'?
 hemical Bonding
767 )
(a) SF2 (b) KrF4
(c) ICl4 (d) All of these (A) BF3,BCl (B) PO,SO
hese is not effect of
306. lonepair on bond angle in (C) BF3,PF3 (D) NO,,N,0
(a) XeF2,ICI b) BF,,OFa (e) N3,NOD2
() IFs,NH (d) I3. Correct option are:
307. Minin bond angle is associated with (a) A, B, D (b) B, D

(a) H2S (b) SF6 (c) PH (c)B,C, D (d) A, D, E

(d) NO2
208. The highest H-C-Hbond angle present in 317. XH3 +H* > XH (X = N, P, As, Sb)

(a) CH2F2 (b) CH In the process, max bond angle increase will be in

(c) CH,C (d) CH F case of:

309. The molecule/ion in which bond angle is less than (a) NH3 (b) PH (c)AsH (d) SbH 3
angle order is not
109 28': 318. Which of the following bond
correct ?
(a) NH4 (b) OCl2 (c)Clo4 (d) OF2 (a) BCl> PCl3> AsCl3
310. The bond angle around central atom in highest in: (b) HS<SF2 < NH3 < BF3
(a) BBr (b) CS2 (c) SO2 (d) SF (c) OF2<H20 <CH3-O-CH
311. In which of the following isostructural pair both (d) PO< SO < Clo4
molecules has identical bond angle? 319. Which of the following order is not correct?
(a) SO2,H,N (a) NO > NOg bond order
(b) H,0,:CH, (singlet carbene) (b) NO < NO, bond angle
(c) BeF2,XeF2 (c) NO2 < NOg formal charge on terminal oxygen
(d) NF3,PF3
312. In which of the following pair of species, all bond
(d) NO> NOg bond length

angles are equal ? 320. Which of the following property ofNO is lower than

(a) CO,COcl, (b) PO} ,POCl3 NO,?

(a) Bond angle
() Clo,PO (d) CHF, CH4
(b) Bond dissociation energy
13. Which of the following order is not correct about the
(c) s-character in hybrid orbitals
bond angle ? (d) Spin magnetic moment
(a) OF2 <H,0<Cl,0 < CIO2 321. Which of the following order of bond angle is not
(xCx bond
(6)COF2 < COCl2 COBr2 < COl2
<
correct?
angle) (a) NH3 > NF3 > PF3
c) PH>PF3 (b) N(SiH) s > N(CH,)
(d) KrF < SF2 < N2H2 (c) O(CH3)2 > OCl2 > OBr2 > NO
sam hybridisation and
having
e t planar species (d) All are correct
somebond angle: 322. Which of the following is incorrect order ot
(a) CH3,BF,,NH3 (b) CH4,BF,, NH X-P-X bond angle?
(d) CF3,CFg,SO, (a) PBr > PCl, >PF
CH,CH,,
315.
BF covalent bond is (b) OPBr>OPCI > OPF,(X P - x)
In which of the following option,
maximum s% character
? (c) PBr >PCI >PF
dVing
(a) s-H bond in H2S (d) PCI> PCl
(6) P-H bond in PH 3 323. Which of the following statenment is correct, as the
)N-H bond in NH s-character of a
hybrid orbital decreases?
u have equal s% character (a) The bond angle decreases
6, Which part (s) as same bond angles
(b) The bond strength increases
768 0bjective Chemistry for NEET/AIIMS
(c) The bond length decreases 336. The "o-N-O" bond angle is maximum in
d) Size of orbital decreases (a) N0 (b) NO (c) NO (d) NO
324. Incorect order of bond angle is 337. Which of the following is the correct order for
(a) NH> PH,> AsH (b) H,0>HS> H,Se increasingbond angle?
(c) BCl> AlCl, > GaCl, (d) NO, > NO2> NO2 (a) NH< PH3 < AsH3 <SbH3
325. Lone pair of phosphine occupies: b) H0<OF2 <Cl20
(a) Spherical s-orbital b) sp hybrid orbital (c) H,Te <H,Se" <H,S" <H,o
(d) BF <BCl, <BBr3 < Bl3
()Purep-orbital (d) pd-hybrid orbital
326. Which of the following B.A. order is not correct ? 338. Which of the following has largest bond angle?
() clo,>BrO, >10 (b) co =NO =SO3 (a) H,0 b) F,O (c) Cl,0 (d) H,S
C) NFg <NH, <NCl d) PF3 <PH3 <PCl3
327. Which of the following B.A. order is not correct? Molecular OrbitalTheory (MOT)
(a) BrF < CIF, < XeF, 339. Which of thefollowing molecule contain only twop
(b) NH>NH3> NH2 bonds between carbon atoms?
(c)SOF,> SOCl,> SOBr X- S-X B.A. (a) CH2 b) CH,Cda
d) HS<SF2 <OF2 (c) CaC2 (d) C2
328. Which 340. In which of the following pairs of
one of the following compounds has the
both the species are not likely to exist ?
molecules/ions,
smallest bond angle ?
(a) OH2 (b) SH2 (c) NH3 (d) SO2 (a) H,He (b) H,He2
329. Maximum bond angle is present in : ()H,He (d) H2,He
(a) BBr3 (b) BCl3 341. If Hund's rule does not hold
good, then which of the
(c) BF3 (d) none of these following pairs is diamagnetic?
330. The correct order
of H M-H bonds angle is (a) B,.0 (b) C2.02
(a) NH< PH3< SbH3
<BiH3
(b) AsH< SbH3 < PH < NH3
() O,N2 (d) N2,NO
342. In Which of the
(c) NH < PH3< BiH < SbH3 following ionization processes, the
bond order has increased and the
(d) BiH SbH3 < AsH3 < PH3 magnetic behaviour
has changed?
331. The correct
increasing order of adjacent bond angle
among BF3, PF3 and CIF3 (a) NgN (b) C2c2
(a) BF <PF < CIF3 (b) PF < BF3 (c) NO NO
(c) CIF<PF3 <BF3
<
ClFg (d) O 0
(d) BF3 =PF3 ClF3
= 343. In which of the
332. Among the following species, the least angle around following processes, the value o
the central atom is in magnetic moment does not
changes ?
(a) N2 >N2
(a) O b)l5 (b) B B
(c)NO (d) PH3 (c) O 02
333. The bond angles of
NH3,NH and (d) O 0 2
NH2 are in the 344. Which of the
order following order is not correct?
(a) NH2 (a) C2 > CN>0, (% of n
>
NH3 > NH (b) NH> NH3 > NH2 bond character)
(c) NH, NH2 >NH4 (d) NH3>NH > (b) C =N2 =NO (%
334. The molecule
NH2 of o bond character)
having the largest bond angle (c) O2> N" > C2
(a) H,0 (b) H,s
is:
(d)
(Paramagnetic nature)
335. The compound MX4 is
(c) HSe (d) H,Te
tetrahedral. The number
C>02>
345. Which of the
N2 (% of ABNO es)
XMX angles in the compound is
of following molecular orbital in ungeterade
with one nodal
(a) three
plane?
(b) four (a) 2p (b) T
(c) five (d) six
2px (c) T2py (d) o2
hemicalBonding
( 769
dhich
:6. Wh following statement is not correct ?
of the moments
(a) C2,02 and Li, are diamagnetic (b) All species have s o m e dipole
(c) All species are isoelectronic
In N2 molecul. the energy of a bond order and are
(b) 2p: is more than (d) All species have identical
2px diamagnetic in nature
() The O-0 bond length H202 in is very 354. Which of the following is not correct ?
smaller than in O ion. slightly, will be less
(a) Carbon-carbon bond length is CaC2
d) 0, and O2 species are
paramagnetic but not
than that in CH2CCH2
than in
be
have same no. of unpaired electrons. (6) O - O bond length in KO2 will more

47. Ahich of thefollowing bond energy order is due to Na,02 be less than
higher number of electron in antibonding molecular (c) 0 - O bond length in O,[PtF,] will
orbitals? in that in KO 2.
molecule will
(d) N - O bond length in NO gaseous
(a) C2>C2 (b) C2>B2 be smaller than that bond length in NOCl gaseousS

d) O2>02 molecule.
(C) N2 <N2
355. Which of the following pairs of species would youu
48. Incorrect statement on the basis of molecular orbital
expect to have largest difference in magnetic
theory moment?
(a) Removal of 2e" from N2, magnetic behaviour
(a) O2.0 (b) O2.0
does not change
() O2,03 (d) O2,02
(b) lonisation energy of O2 is less than O atom.
356. Which isoelectronic pair show different magnetic
(c)S- p mixing is observed in N2 but not in O2.
nature?
(d) All statemant are incorrect
(a) CsHg. (inorganic benzene)
49. No change in p bonds order in reaction:
(b) N2,Co
(a) B2 B2 (b) O 02
() F2,02
(c) C2 C2 (d) N2 N2 (d) SO2,S2
50. During change of 0, to Oz ion, the electron adds on 357. Which is set of paramagnetic molecules or ions ?
which one of the following orbitals ? (a) NO,NO2,0,02 (b) O2,0,NO,NO
(a) o orbital (b) a orbital
(c) C2,B2,02,S2 (d) B2,N2.02,02
(d) n orbital
c)7orbital 358. Which of the following pair of species have same no.
statement
S51. Which of the following is not the correct
regarding C, molecule?
ofunpaired electron but bond order is different?
a) It has total 12 electrons, out of which 8e occupy (a) CO,CN (b) O,0
bonding orbital 4e are antibonding orbitals (c) O2,B2 (d) NO,N2
(D C2 molecules has been found to exist in vapour 359. Which of the following property is not common in
phase both VBT
as well as MOT?
bonds and both
C2 Molecule containing double (a) Linear combination of atomic orbitals
are T-bonds (b) Losing of nature of atomic orbitals
C2 d) Molecule is paramagnetic (c) Mixing of atomic orbitals
have
which of the following pairs of molecules (d) Wave nature of electron
Dond order three and are isoelectronic ? Which
360. of the following statement is not correct ?
(a) NO,Co (b) CN ,CO
(a) Both M.O.T. and VB.T. are based upon
c) CN ,02 (d) CO,O combination of atomic orbitals
53. Which of the following statement(s) is not true for (b) According to VBT, two atomic orbitals of two
the given
species ?
atoms
combine with each other and
form one
molecular orbital
and NO"
N2, CO,CN (c) According to MOT when
(a) All species
spe have linear shape. two atomic orbitals
combine two molecular orbitals are formed.
 Objective Chemistry for NEET/AltMG
770 (a) BF, and BCl (b) CH, and B,N.H,
(d) According to MOT, orbitals which have paired
other. (c)CO and XeF2 and (d) PCl,F2
electron can not combine with each
370. In which type of molecule, the dipole moment e
PClF
361. O and N are differ in:
non zero may be
order
(a) Number of electrons and bond Where A-Central atom, B-Bondend atom, Ll.
(b) Bond order of electrons and bond
order one.
aBMO
pair?
(c) Bondlength and energy level of TBMO and (a) AB2L2 (b) AB
ABMO electrons.
(d) Magnetic nature and number of (c)ABL2 (d) AB4
not correct?
362. Which of the following statement is 371. Which of the following are incorrect for dipje
fractional
(a) Bond order may be positive, negative, moment ?
o r zero (a) Lone pair of elements present on central atom
same atoms,have
(b) If 2 molecular species having can give rise to dipole moment
same bond order then the species
which has less
(b) Dipole moment is vector quantity
ABMO electrons, is more stable.
(c) Molecules have pyramidal shape, are general
have same bond
(c)Isoelectronicdiatomic species nonpolar.
order and same magnetic nature
(d) Difference in electronegativities of combining
Isoelectronic diatomicspecies have same bond
(d) atom can lead to dipole moment
length and same bond strength
donot exist ?
363. Which pair of species
(a) He2,Li2 b) H2,He 372. Dipole moment of| O|is 1.5 D. The dipole momer
(c) B2.S2 (d) Be2,Ne

Dipole Moment
364. For which of the following molecule significant u0?
X
Cl CN OH SH X 3
(a) 1.5 D (b) 1D () 2.35 D (d) 3D

O (BO oO 373. In correct

lonepair
statement for molecule AB, which has

Molecules will be planar and non polar, wte

CN OH SH (a) 38
n = 4
(a) Only (C) (b) (C) and (D) when n =3

(d) (A) and (B) (b) Molecule will be planar and polar
(c) Only (A) when n =
365. If compound AX3 is polar and planar then possible (c) Molecule will be planar and polar
to molecule polarity,wrc
hybridisation state of A is (d) Bond polarity is equal
n =2
(a) sp2 (b) sp is
(d) both sp* and sp'd 374. Incorrect order of dipole moment
() spd (a) CH4 < NF3 < NH3 <H20
molecule which have both polar
366. Polar and nonplanar (b) CO < SO2 <H20
and nonpolar bonds (c) SOCl2 < Al,Cl%
(a) H,02 (b) N,0 PCI,Pa (d)(CN), < m-dichloro
benzene
(d) p-dichloro benzene
molecules is polar ? moment is
.

367. Which set of 375. Correct s t a t e m e n t about dipole

(a) XeF IF, , SO, (b) PCl3,CH6,SP%
(R,PO), (b) (R,NO),
>
(R3PO)
(d) co,CS,,CH,
(a) (R,NO), <
these 38F
(c) SnCl2, SO2, NO, (C)(R ,N0), =

(R,P0), (d) None of

lone pair)
How many
electron pair (bond pair or
376. Correct statement:
bond

368. in PH3 ?
affects dipole moment
molecules but has
non
po
polar 8
bond

(a)PH, is a
(c) 3 (d) 1
(a) 4 (b) 0
(b) CO, is non-polar molecule
but has poi
both species are not bonu
which of the following pair, is a polar molecule
with polar
369. In and dipole m o m e n t ? (C) SO,
on the basis of shape
identical
 ehemical Bonding
(771
d) All of the above than oxygen
(b)Be has more electronegativity
Which of the following is not correct
match of (c) H20 molecule is linear and BeF2
is bent
hybridisation state ?
bent
(d) molecule is linear and H,0 is
BeF2
(a) AX2 nonpolar and linear sp or sp'd
385. Which pair of molecules are polar species?
b) AX polar and planar > sp'd (b) BF and PCl
(a) CO and H,0
()AX3 polar and nonplanar sp3 (c) SO and SCl2 (d) CS and SO3
atom has
(d) AX, nonpolar and nonplanar =s sp°d 386. In which molecule does the chlorine
positive partial charge ?
8Which of the following statement is not correct? (a) HCI (b) BrCI (C) OCl2 (d) SCl2
(a) Molecules having V-shape, T-shape or pyramidal have
shape are generally polar
387. Which of the following pair of molecules will
permanent dipole moment ?
(b) If central atom has only h one lp then molecule (b) NO and O
(a) NO2 and CO2
will be polar
(c)SiF and CO2 (d) SiF and NO2
(c) If central atom has no lp and all terminal atoms
388. Which of the following molecules has highest dipole
are same then molecule will be polar.
moment?
(d) Molecules having trigonal planar or square (c) NF (d) BH
(a) BF3 (b) NH3
planar shape are always nonpolar
389. In terms of polar character, which of the following
379. BF and NF3 both are covalent compounds but NF is order is correct ?
polar whereas BF, is non-polar. This is because (a) NH< H,0 <HF <H2S
(a) Nitrogen atom is smaller than boron atom
(b) HS< NH, <H,O <HF
b) N-F bond is more polar than B-F bond (c) H0 < NH3 <H2S <HF
(NF is pyramidal whereas BF3 is planar triangular (d) HF <H,O < NH, <H2S
d) BF is electron deficient whereas NF is not
390. The correct order of dipole moment is
380. Dipole moment ofNF, is smaller than: (a) CH, < NF3 <NH3 <H,0
(a) NH3 (b) CO2 (c) BF3 d) CCl4 (b) NF, < CH, < NH, <H,0
41. Which of the following molecules will have polar
(c) NH < NF3 < CH4 <H,O
bonds but zero dipole moment ?
(d) H0 < NH3 < NF3 < CH4
(a) O2 (b) CHCI
(c) CF4 (d) none of these Back Bonding
9. Which has maximum dipole moment ?
391. Back bonding is absent in:
CI CI
Cl (a) (SiH)N (b) HSi-N =C==0
Cl Cl (c) O(SiH3)2 (d) P(SiH ,)s
(a) (b) IOJ 392. Which of the
(a) State of
following is not due to back bonding ?
hybridisation may change
(b) Bond order increase
(c) Bond angle always increases
Cl (d) Lewis acidity decreases
c)
O 393. B-F bond distance in minimum
in:
(a) BF (b) BF OH
CI
CI (c) BFNH2 d) BF NMe
394. Back bonding
Which , of the following compound is planar
and in BF, does not affect
(a) planarity, Lewis acidic
non-polar? (d) CF (b) bond length, strength and bond angle
a)
44. HOXeO
has (b) SF4 (c) XeFa
(c) bond angle,
hybridisation
and bond
strength
while Bel'2 has zero
planarity, geometry
net dipole moment

upole moment because (d) Lewis acidity, bond

than oxygen
length, bond order (B- F)
as more electronegativity
 772) Objective Chemistry for
NEET/AIIM
395. Which of the following molecule has wealker (pt - dr) (b) B(NR,), <BH(NR ), <H,B-NR,
back bonding? (c) BH(NR,)2 >B(NR2)3 BH2 -NR, >

(a) OCl b) N(SiH,) (d) BH2 NR2> B(NR ,), >

BH(NR ,),
(c) SiF (d) O(SiH,) 405. Incorrect order of Lewis basic
strength is :
396. Hybridization of central atom does not change due to (a) NH,>PH3 (b) NCl,>NF
(2pm-3dn)back bonding: (c)OCH,)2>OSiH,)2 (d) CH,NCS<H,S
.

406. Back bonding is present in dimer of

(a) O(SiH2 (b) N(SiH 3)
(a) BF (b) NO (C) AlF (d) BeC
c)PF3 (d) H ,SiNCS
407. Which of the following statements is true on
397. In which of the following compound, observed bond the ba
of back bonding ?
angle is found to be greater than expected, but not
due to backbonding? (a) CHCl3 is more acidic than CHF
(a) NSiH,) (b) BCl (b) Dimethyl ether acts as a better Lewis base but
(c) OCH ) (d) O(SiH3)2 disilyl ether (SiH-0- SiH,)
398. Which of the following molecule has maximum (c) (CH3)3C-0- H is less acidic tz
extent
of back bonding? (CH)Si-0- H
(a) O(SiH,)2 (d) All of the above
(b) OCl2
(c) NF3 408. Which of the following statement is /are false ?
(d) PF
399. Which of the following always change
is due to back
(a) NMe3 and N(SiH ,)3 are not iso-structural
bonding? (b) Methyl isocyanat (CH-N =C=0) ber
(a) Bond angle but siliyl isocyanate (SiH -N =C=0E
(b) Hybridisation of central atomn linear
(c) Planarity ) In trisilyl amine [(SiH,),N] all N-Si b
(d) Bond length lengths are identical but shorter than
400. Which among the expected N-Si bond length
following is stronger Lewis base (d) None of these
than N(SiH,)3?
(a) HN-CH, 409. Which statement is correct?
b) NH3
(c) HN- SiH, (d) All of these (a) Relative strength of r bonding in BX, follos
401. In which of the sequence BF3 = BCl3
following species, N-atom is not
sp-hybridised? 0 The correct order of bond length (S-0) tol
the sequence SO
(a) Nitronium ion (b) Nitrate ion
<
SO
(c)Trisilylamine (d) Borazine c)n-bond order follows the sequence
402. CF2 is more stable than Clo, >CIo, Clo
: CH2 (both have all paired
electron) (d) All of the above
(a) Due to more EN difference 410. If lone pair of central in

(b) Due to pT
atom partieipa
pr back bonding
-

bonding then
() Due da
- back bonding
to pr (a) Lewis basic strength decreases
(d) Due to one lp (b) Hybridisation state of central atom * chal

403. Which of the following molecule has 2pm-3pr back due to back
bonding
bonding? (c) Bond strength and bond angle increase
(a) OCl (b) BE, (d) All are correct
-F
(c) CCl (d) CCl 411. In which of the
following compoun
404. Choose tne cOrrect order for the energy barrier to length is shortest?
rotation around the B - N bond (a) BF (b)BF-NH
(a) H,B- NH2 BH(NR ,)2 <B(NR,), (c) BF, (d) B, N(CH
 hemica Bonding S(773
MS both
nerisation (Banana Bond)
m e r i s 420. Which of the following compound
contains

bonds ?
bonds as well as 3c 4e
-

Which ofthe following is/are isostructural pairs 2c-2e

?
12. (a) B Hs (b) AlCl6
(a) BH,C2H (b) AlCl.C,Cls
(d) Al2(CH,)6
(c) BH,,Al,Cl (d) Al,Cl.1,Cl6 (c)BeH4
of the
421. Find the incorrect match
In Which following molecule all following
CS 13. characteristics are found ? (a) AlCl, :3c- 4e bond is present
atoms a r e sp
*
hybridised
(6) Al2(CH,) : All carbon
cn3hybridisation, empty orbital participate in
2
hybridisation and All bond length are identical. (c) 1,Cl: Non planar
basis (d) AlBrs : Non polar
(a) BH (b) AlCl6 matched for
(d) BF4 422. Which of the following is not correctly
(c) (BeCl,)2 ?
solid state of following compound
it not of the following molecule 2c-2e bond
14. In Which is
(a) Alcl3 non planar, all bonds
-
a r e not identical1

than
absent ?
(b) S O P r - dr bonding present, sp
(a) BeCl2 in Vapour state (b) I,Cl
hybridisation
(c) BeH 20 (d) BH
(c) PBrs-sp" and sp°a* hybridisation
415. 3 centered 2 electron bond is present in
(d) BeCl2 complete octet, non planar
(a) BeH4 b) Al2(CH ,)
bent (d) All of these
423. Which of the following pair represent nidoborane and
(c) BH6 archanoborane respectively ?
0) is
differ in
416. Solid BeH and solid BeCl2 are
(a) BHB,H1o (b) BH1o ,B,H6
(a) Hybridisation state of Be
bond (c)BHg,B,H6 (d) BH10o ,B 5H9
n the (b) Planarity of molecule plaranity 424. Incorrect statement about B 2H6 is:
(c) Octet completion (a) Incomplete octet, nonplanar molecule
d) Polymarisation (b) B-Hb bond length is greater than B -HT
orbitals
In which of the following molecule,
vacant bond length
wsthe
cannot participate in bonding? (c) H - B-H, bond angle is less than
(a) BH (b) Al,Cl H - B H , bond angle
llows
(c) [HN BF3] (d) SiH (d) Act as Lewis acid and nonpolar molecule
contain
of the following set of molecule 425. Similarity between Al,Cl, and I,Cl, is:
Which
nree-centre two electron bonds ?
(a) Both nonplanar and nonpolar molecule
a) (BeCl,) . (BeH 2), ,B,Hs (b) Both follow octet rule and have same
back
b) (BeCl2), . (BeH 2)n ,H3 hybridisation state
()Both have allidentical bond lengths
c) (BeH2), ,H3,B,H6
(d) Both have 3c- 4e bonds, and nonpolar
anged
(d) (BeCl,), ,H; ,B,H6 molecules
19. The hybridisation of
central atom in dimer

t e of
orm ofboth BH and BeH2 iS
(a) sp,sp (c) sp*,sp
(d) sp ,sp3
bond
(6) sp*, sp